ライフサイエンスコーパス: equilibration

1 s in the phenomenology of thermalisation and equilibration.

2 of life is its peculiar capability to avoid equilibration.

3 ns; a DNA catalyst is designed to accelerate equilibration.

4 e tetrahydropyrans, allowing a thermodynamic equilibration.

5 till poorly defined, level of metal-silicate equilibration.

6 of overshooting from initiation until final equilibration.

7 ds to extremely rapid intermolecular enolate equilibration.

8 omass and biofilm thickness following column equilibration.

9 ion, vapor-wall deposition, and gas-particle equilibration.

10 0(-4) M(-1) s(-1)) from the half-life of the equilibration.

11 acidic media is employed to achieve isotope equilibration.

12 urement, returning to equilibrium after 16 h equilibration.

13 on of metallacyclobutene-eta(3)-vinylcarbene equilibration.

14 samples need to be analyzed after H isotope equilibration.

15 minent fast component (62% versus 48%) of re-equilibration.

16 initial solid phase present during the first equilibration.

17 t the air-water interface was measured after equilibration.

18 ating in an upper layer that grows during re-equilibration.

19 qubit state initialization relies on thermal equilibration.

20 ith stereocontrol arising from thermodynamic equilibration.

21 hose rates are modulated by rapid mechanical equilibration.

22 sess the role of morphology on the diffusive equilibration.

23 rinciple of measuring a pH change upon CO(2) equilibration across a membrane.

24 ons with subsequent annealing to simulate re-equilibration after decompression.

25 The flow-through equilibration allows for continuous (~1 Hz) detection an

26 anhydrase (CA) enzymes catalyze the chemical equilibration among CO2, HCO3(-) and H(+).

27 s C60 and C70 to the cage brought about a re-equilibration among the different cage diastereomers in

28 d oxime groups of the bis-oximes resulted in equilibration among up to 16 distinct ionization forms,

29 s less than 5 min, including both the column equilibration and autosampler movement.

30 les, baseline disturbances, and slow (2)D re-equilibration and demonstrate improvements in (2)D separ

31 ical incubation system component dimensions, equilibration and equilibrium condition confirmation, qu

32 sks and generator columns, require hours for equilibration and milliliter quantities of sample soluti

33 ope fractionation associated with NAPL-vapor equilibration and normal diffusion isotope fractionation

34 Hydrogels display nonswelling equilibration and offer temporal control over material d

35 e effect of kinetic barriers which intercept equilibration and preserve highly ordered, high energy n

36 ovalent or non-covalent bonds, thermodynamic equilibration and structure templating, are also accessi

37 The well-degradable compounds showed slow equilibration and the least mineralization in OECD 308,

38 undamental competition between thermodynamic equilibration and the persistence of metastable configur

39 ed with PE and POM to correct for incomplete equilibration, and the resulting POP concentrations, det

40 The analysis of errors shows that the slow-equilibration approximation guarantees that the errors i

41 The approach is based on the slow-equilibration approximation, which is applicable to KSEC

42 Equilibration at different pH introduces intentional Mn

43 After equilibration at different water activities (a(w)) for t

44 Equilibration at high temperatures in the aftermath of g

45 a hyperpolarized LLS is populated by thermal equilibration at liquid helium temperature.

46 le at 40 degrees C for 2 h followed by water equilibration at room temperature under controlled condi

47 calculations and test against recent buffer-equilibration atomic emission spectroscopy measurements.

48 mean uptake was found to be 112x and 33x the equilibration bath concentration in healthy and arthriti

49 otometric method to achieve flow-through CO2 equilibration between an acidified sample and an indicat

50 (Teflon AF 2400) to achieve flow-through CO2 equilibration between an acidified sample and an indicat

51 pped here is metastable and can enable rapid equilibration between bent and extended-open integrin co

52 on a simple kinetic technique to track H2O2 equilibration between cellular compartments, suggesting

53 Equilibration between Chol and Phos via thiolate-disulfi

54 of the photoproduct and is attributed to an equilibration between different K-intermediates.

55 Thus, equilibration between inactive oligomers and active mono

56 However, they assume fast equilibration between internal states and hence are inad

57 Equilibration between NaSMe and water also affords NaOH

58 cubations, however, indicate oxygen isotopic equilibration between nitrite (NO(2)(-)) and water, and

59 folded proteins and BiP oligomers and slower equilibration between oligomers and inactive, covalently

60 on-body sweat chloride measurement, however, equilibration between reference and test solutions has l

61 Equilibration between the blood and unbound (18)F-FMISO

62 esterol loading or depletion, there is rapid equilibration between the ER and plasma membrane cholest

63 show how the salt bridge geometry determines equilibration between the reference and test solutions.

64 charged constituents, allowing a controlled equilibration between the two counter-propagating charge

65 ein particles HDL and LDL/VLDL, resulting in equilibration between these lipoprotein fractions.

66 Equilibration between these modes can be controlled with

67 However, charge equilibration between these two modes always led to an o

68 n surface-hole density, which is assigned to equilibration between three surface holes and M(OH)-O-M(

69 O/(16)O ratio of water, mediated by isotopic equilibration between water and NO(2)(-), as well as (2)

70 of electron transfer and to facilitate redox equilibration between working electrodes and minerals in

71 porated unnatural tyrosine analogs; however, equilibration between Y122* and Y356* has not been detec

72 ve worked out practical means of controlling equilibration by mechanically deforming their samples.

73 abolism in the citric acid cycle, incomplete equilibration by triose phosphate isomerase, or the tran

74 nstrates that it is possible to minimize the equilibration (conditioning) time of SC ISEs with aqueou

75 lthy patients and early prediction of PetCO2 equilibration could therefore also be used for the titra

76 and (13)CH4) with CRDS via a closed loop gas equilibration device during a survey along an estuary an

77 n compared to a (210)Po based bipolar charge equilibration device.

78 The equilibration distribution of the macrocycles on the dum

79 This equilibration does not occur when Cx43 is not present.

80 m-temperature measurement of singlet-triplet equilibration dynamics in this family of emitters.

81 After equilibration each tissue underwent a series of protocol

82 verge so rapidly that, upon further cooling, equilibration eventually becomes impossible and glass fo

83 etic delay in which characteristic times for equilibration exceed the dust-air contact time, and equi

84 experiments and during polydisperse droplet equilibration experiments at 75% relative humidity, and

85 Abiotic fuel-blends/aqueous-phase equilibration experiments revealed that the FAMEs of bio

86 Batch equilibration experiments were used to examine the sorpt

87 al a complex pattern of tissue-retention and equilibration for CD4(+) memory T cells in skin, which i

88 surprisingly slow and similar time course of equilibration for the two compounds, although memantine

89 f the bath when 50% strain was applied after equilibration in 0.5, 1, and 2x PBS, with a trend for an

90 of high temperature-pressure core and mantle equilibration in a deep magma-ocean.

91 ilicate Moon can instead reflect core-mantle equilibration in a largely to fully molten Moon.

92 Following equilibration in air, mackinawite was oxidized to mainly

93 ficant negative potential drift during their equilibration in an aqueous solution.

94 ag phase for HCO(2)H formation and a lack of equilibration in pulse-chase assays) were also seen with

95 fied binding assay using micro-CT after plug equilibration in serial dilutions of each agent.

96 as used to obtain the timescale of diffusive equilibration in spines and followed by global sparse ph

97 eitol (DTT), and shows typical half-times of equilibration in the 10 h range.

98 min (~120 min including extended hold and re-equilibration in the first dimension).

99 The role of the dynamics of solvent equilibration in the nature of mechanistic intermediates

100 ive gradients in thin films (DGT), diffusive equilibration in thin films (DET) and the "DGT-induced f

101 gradients in thin films (DGT) and diffusive equilibration in thin films (DET) techniques.

102 sensitive elements (e.g., Fe, Mn), Diffusive Equilibration in Thin-films (DET) devices were inserted

103 This equilibration involves the relaxation of intramolecular

104 erential mobility analyzer, nES DMA), charge equilibration is based on bionanoparticle interaction wi

105 ical rates, because SlyD-catalyzed cis/trans equilibration is faster than conformational folding.

106 Furthermore, isomer equilibration is much faster than migratory insertion so

107 th excess isocyanate and heat, thermodynamic equilibration is possible affording ureas.

108 r, the molecular basis for this metabolic re-equilibration is unclear.

109 tereomers was isolated, and by following the equilibration kinetics, activation barriers for all reac

110 Here, we describe a field-deployable gas equilibration mass spectrometer (GEMS) that provides con

111 A surface equilibration mechanism predicts the highly smectic-like

112 te, which suggests that a polarizable charge equilibration method (PQEq) method might be needed to ta

113 The new equilibration method displays a small solvent effect and

114 ng reactive molecular dynamics with a charge equilibration method extended to describe electrochemica

115 ow how a version of the semiempirical charge equilibration method suitable for periodic materials can

116 an lead to different product compositions or equilibration mixtures than in solution.

117 ult is inconsistent with the low-energy disk equilibration model, but supports the high-energy, high-

118 d our system to investigate various pressure equilibration models and dynamic, nonuniform membrane te

119 Certain compounds show evidence for equilibration, mostly consistent with surface partitioni

120 However, whilst mineral re-equilibration occurred very rapidly on cooling, changes

121 ium carriers followed by the electron-phonon equilibration, occurring in a few picoseconds, and then

122 Equilibration of 1 with its 2,3-dihydro isomer 2, which

123 and dehydration, with CuCN catalyzing a key equilibration of a formyl imine to an N-formyl enamine.

124 such timescales are critical to observe the equilibration of a pLGIC from its crystalized conformati

125 tes that approximately 7 mus is required for equilibration of a preformed 6-peptide pore; the pore re

126 Acid-catalyzed equilibration of a series of anancomeric 2-tert-butyl-5-

127 of hemi-equilibrium, the state of partial re-equilibration of agonist, antagonist, and receptor in so

128 an any other known example the thermodynamic equilibration of alkene isomers, as the trans-2-alkenes

129 Pre-equilibration of an interconverting set of isomeric ally

130 discovered, highly selective TMSOTf-mediated equilibration of C38-epi-halichondrin A to halichondrin

131 rature appeared almost instantaneous whereas equilibration of casein was considerably slower, particu

132 ia or atrophy, organ turnover demands strict equilibration of cell production and loss.

133 The stabilization of this polaron impedes equilibration of charge density across the nanowire and

134 Given the temperature-dependent re-equilibration of clumped isotopes in aragonitic carbonat

135 ttle production of hydrogen, despite partial equilibration of CO2 with carbonic acid-a low pKa acid.

136 Equilibration of complexes 2-5 with H2 in the presence o

137 nts on the phenyl rings has been studied via equilibration of configurationally isomeric 2,2-diaryl-c

138 into the liposome results in trans-membrane equilibration of detergent and subsequent micellization

139 into the outer monolayer; 2), trans-membrane equilibration of detergent monomers between the two mono

140 azacyclic molecules in which dynamic kinetic equilibration of diastereomeric iminium ions precedes a

141 emission is comparable to the timescale for equilibration of electrons and phonons.

142 with the ER membrane protein Ldb16, prevents equilibration of ER and LD surface components by stabili

143 now afforded the opportunity to investigate equilibration of F3Y122* and Y356*.

144 ansfer of heme from the core to the HRMs and equilibration of heme between the core and HRMs.

145 Equilibration of initially 7 mM solutions was slow--on t

146 However, CGM-independent data suggest rapid equilibration of interstitial glucose.

147 quire strong scale separation or conditional equilibration of local statistics.

148 ession of high-pressure minerals, or lack of equilibration of mineral assemblages.

149 The equilibration of monomeric (Z)-1 and (E)-1 in THF as the

150 sides has been developed on the basis of the equilibration of O-sialyl hydroxylamines by reversible h

151 proposed nonvesicular pathways for the rapid equilibration of oxysterols between membranes, direct im

152 6, -8, +10, -12, +14 breaths/min and awaited equilibration of Petco2.

153 nd the rate determining processes during the equilibration of poly(3,4-ethylenedioxythiophene):polyst

154 lls with lower cell stiffness, expected from equilibration of pressure toward least resistance.

155 The cohort platelet counts achieved after equilibration of production and consumption both enumera

156 ross mitotic clone boundaries and enable the equilibration of protein between transcriptionally mosai

157 It thus remained unclear how equilibration of protein disulfides with the IMS glutath

158 After equilibration of soils with citric or oxalic acids, the

159 ing solid was sufficiently hydrated to allow equilibration of sorbed Hg species with the aqueous solu

160 and Fe(II) sorption to Feppt, combined with equilibration of sorbed iron and with Fe(II)aq using pub

161 We show equilibration of structural kinetic transitions in the m

162 of excited state decay that involves initial equilibration of the (3)MLCT and pyrene triplet states f

163 After electrolysis, full equilibration of the alkalized solution with air led to

164 of 7 min, including the clean-up and the re-equilibration of the column.

165 ysis of metal uptake kinetics indicated that equilibration of the cytoplasm with externally applied h

166 ration structure seems responsible for local equilibration of the defective surface in water and even

167 Equilibration of the heat flow from the substrate to the

168 surements overestimated pH due to incomplete equilibration of the hyperpolarized (13)C label between

169 Conditioning refers to the equilibration of the ion-selective electrode in an aqueo

170 irradiation above 2000 cm(-1) results in an equilibration of the isotopomeric ratio.

171 sodium methoxide) have been found to promote equilibration of the kinetically favored products from I

172 : (1) deprotonation of pro-R or pro-S-H, (2) equilibration of the lithiated stereogenic carbanion, (3

173 ow relaxation of the charge sector and rapid equilibration of the magnetic sector to a prethermal sta

174 sition of a SPB without the need for thermal equilibration of the measurement chamber and, thus, has

175 ed by a response model that assumes complete equilibration of the membrane at every applied potential

176 g the relaxation properties and the complete equilibration of the metal-nanoparticulate complex dispe

177 insertion of iridium is reversible, allowing equilibration of the metallacycle products via a diiridi

178 The thermal equilibration of the methyl esters of endiandric acids D

179 Investigation of the equilibration of the methyl ethylene isomers in the pres

180 Equilibration of the mother liquor (enriched in 2R) to a

181 ck-driven reconfiguration and time-dependent equilibration of the networks.

182 milar or shorter time scales compared to the equilibration of the optically populated excited state.

183 From the kinetic measurement of the bulk equilibration of the pH, we fully determine the adsorpti

184 s inversion at S and accounts for the facile equilibration of the SAuPPh3 units, with an energy barri

185 or impact on the system leading to a fast re-equilibration of the solid to a Ba1-xRaxSO4 solid soluti

186 omers of 8 was reducing faster to 9 than the equilibration of the stereocenter of 8.

187 alkyl sulfonates were determined at pH 7 by equilibration of the test analytes between fiber and wat

188 For three enol-ketone pairs, equilibration of the thermodynamically disfavored tautom

189 Equilibration of the three possible tetraphenylbenzenes

190 ergodicity of the fast subsystem impedes the equilibration of the whole system because of the presenc

191 Further, equilibration of the zwitterionic benzotriazolyl species

192 liums and the kinetics of the diastereomeric equilibration of these and one other example.

193 oth the tracer and sample isotopes when full equilibration of tracer isotopes with sample isotopes is

194 Equilibration of Y356*, Y731*, and Y730* was recently ob

195 Slow equilibration on the ribosome can delay premature foldin

196 Our results also indicated that a pre-equilibration period is essential for growth and stabili

197 Following an equilibration period, baseline brain levels of glucose (

198 h faster than Pu(V) sorption over the 30 day equilibration period.

199 nsition from HF to LF-occurs during the fast equilibration phase of the system, leading to sudden inc

200 periods as short as 15 min (3 min of thermal equilibration plus 12 min of carrier gas flow) were show

201 eophilic substrates was revealed which makes equilibration predictable.

202 ansient overshoots during equilibration; the equilibration process follows serpentine trajectories in

203 ty, V260A introduces a temperature-dependent equilibration process not previously reported by such me

204 cludes interpretations based on electron-ion equilibration process, or on thermodynamic heating proce

205 r congener (ceph F) through an acid-mediated equilibration process, was reported.

206 featuring a phase transition from the simple equilibration processes taking place in reversible dynam

207 ndamental equations describing the diffusive equilibration processes, including a complementary trans

208 advised, and, after that step, preanalytical equilibration rarely exceeds 3 h.

209 f vanishing particle-to-wall mass ratio, the equilibration rates remain strictly positive only when t

210 tion in C. hyperboreus is maintained through equilibration rather than feeding.

211 10.0 mus timescales were observed, with post-equilibration sampling providing detailed representation

212 cid-mediated delta-hydroxy enone cyclization/equilibration sequence, and a functional-group-tolerant

213 bitor, mNOX-E36, the intrahepatic macrophage equilibration shifted toward the "restorative" Ly-6C(-)

214 hown to be good indicators of sampler-tissue equilibration status.

215 s, followed by a Lewis acid-mediated product equilibration step.

216 toinduced electron transfer preceding energy equilibration still poses many experimental and conceptu

217 After a 3-h tracer equilibration, subjects received 1) dapagliflozin 10 mg

218 increase in the response time of solution P equilibration (Tc) was observed.

219 enthalpies (BDE) in t-butanol by EPR radical equilibration technique consistently indicated a ca. 1.5

220 dimethylsulfoxide) by using the EPR radical equilibration technique.

221 e lower at 1 h than at 4 h of the peritoneal equilibration test but the reductions in cytokine releas

222 ched controls using 3.86% glucose peritoneal equilibration tests.

223 pe fractionation is larger during NAPL-vapor equilibration than air-water partitioning.

224 cular case of (S)-TATA it is shown that upon equilibration the initially formed fibers undergo a conf

225 > Smectitic, while at the end of the second equilibration the organic system was the least effective

226 ersion into its previtamin D form by thermal equilibration, the corresponding 19-nor-compound 26 was

227 However, after one year of equilibration, the extent of Pu(V) adsorption was simila

228 curs, we observe transient overshoots during equilibration; the equilibration process follows serpent

229 Brine was mixed with CO(2) for equilibration, then the mixture was circulated through a

230 .5 mL min(-1)), mobile phase composition and equilibration time (1-5 min).

231 it provided a good compromise between column equilibration time (ca. 25 column volumes) and retention

232 l as between changes in respiratory rate and equilibration time (teq) for mechanically ventilated pat

233 Both the partition coefficient and equilibration time agree well with predictions from the

234 The required equilibration time benefits from the acceptor solution i

235 ions and (ii) a mismatch-induced increase of equilibration time in respect to that of a fully matched

236 apacity of 12.33 mg g(-1) with an ultrashort equilibration time of 3.5 days, suggesting that SSUP fib

237 The gas-particle equilibration time scale depends on the gas-particle acc

238 kinetics was studied experimentally, and the equilibration time scale for impervious surfaces was fou

239 scribes the observed evaporation, suggesting equilibration time scales of atmospheric SOA on the orde

240 ght to be "glassy." Here, we investigate the equilibration time scales of SOA formed from alpha-pinen

241 atmospheric conditions, this translates into equilibration time scales on the order of minutes to ten

242 ain as viscous Newtonian fluids) under fixed equilibration time scales, we demonstrate that gel phase

243 The DEHP-particle sorption equilibration time was demonstrated to be less than 1 mi

244 mple in the NMR tube, mixing, waiting for an equilibration time, and acquisition of a second spectrum

245 teristics (theoretical response slope, short equilibration time, excellent potential stability, etc.)

246 and after a minimum approximately 30 min of equilibration time.

247 rwood Virginia oil constituents with typical equilibration times < 1 h, (ii) demonstrating how to con

248 254)), and Hg(II)-DOM and Hg(II)-DOM-sulfide equilibration times (4-142 h).

249 built on GC and Au had significantly shorter equilibration times (between 5 and 13 min) than the SC e

250 lenge because at length scales of 10-100 mum equilibration times already become prohibitively long.

251 w detection limit of LFA and associated long equilibration times are due to kinetically limited surfa

252 Equilibration times are fast (less than a minute) becaus

253 Because of the low aqueous concentrations, equilibration times are very long and BCFs are sensitive

254 vol) aerosol, indicating that unusually long equilibration times can be required for HTDMA measuremen

255 The Hg(II)-DOM or Hg(II)-DOM-sulfide equilibration times did not significantly influence the

256 io between the characteristic separation and equilibration times does not exceed 0.1.

257 ce for the selection of appropriate sorption equilibration times for experiments that are designed to

258 68 cracked gas oil constituents with typical equilibration times of 5-10 min and for 21 cederwood Vir

259 Such significant differences in the equilibration times of SC ISEs built on different substr

260 liliter volumes of solvents and sample, long equilibration times, and manual procedures.

261 m decreased chromatographic resolution, long equilibration times, indefinite retention, and column bl

262 ng on the sampler used) because of prolonged equilibration times.

263 and used these transients to determine their equilibration times.

264 dynamic range, and require extended thermal equilibration times.

265 ould determine a robust relation between the equilibration timescale and a generalized shape factor c

266 tion of the aldol product A with LDA induces equilibration to form the minor diastereomer of Michael

267 ed mantle fluids precipitate diamond upon re-equilibration to lighter species in the upwelling mantle

268 ional variants of proteins and that the slow equilibration to multiple stable conformations in soluti

269 Re-equilibration to physiological pH restores the fixed neg

270 en into two pieces, and can heal by siloxane equilibration to restore the original strength of the si

271 ound to have a crucial impact on the rate of equilibration to the corresponding cyclopropanone.

272 block can be released and the kinetics of re-equilibration to the native conformational equilibrium c

273 The rapid isotopic re-equilibration to the new MeHg-food source reflects its h

274 on of chymosin, for mixes before or after re-equilibration to the original milk pH.

275 alance of a resting rotor, following thermal equilibration under high vacuum, closely corresponded to

276 ved-gas concentrations in water by gas/water equilibration using membrane contractors (gas-equilibriu

277 ditions are (1) the use of a miniature vapor-equilibration vessel (the "saturator") to minimize the t

278 perature control, obviates extended detector equilibration wait times.

279 It is shown that equilibration was faster in dense suspensions and at hig

280 Experimentally, we found that diffusive equilibration was often slower, but rarely faster than p

281 Rapid equilibration was recorded with pyridine-based aldehydes

282 The films obtained after drying and equilibration were characterised in terms of composition

283 d Cu for the systems at the end of the first equilibration were Fe-Ox > Organic > Smectitic, while at

284 The differences in the rate of equilibration were interpreted as a consequence of diffe

285 50-125 muL/g water:solid ratio, and 24-48 h equilibration were used.

286 of the cytoplasm that leads to slow pressure equilibration when compared to the timescale of bleb exp

287 of an in situ base-promoted alkyne to allene equilibration which takes place prior to the silylcuprat

288 The bubbling action allows for quick equilibration while the small size of the chamber limits

289 erpolarization to approximately -80 mV), via equilibration with 145 mm [K(+)]o (depolarization to app

290 enantioselectivity, where 3-sulfolene is in equilibration with 2-sulfolene by base-catalyzed isomeri

291 electrolyte of 100 mM NaCl and 1 mM CaCl2 in equilibration with 400 ppmv CO2(g) ([U(VI)] = 4 muM and

292 microscopic pathways underlying a molecule's equilibration with a surface in a prototypical system: C

293 serves to mix TT luminal content and assists equilibration with bulk extracellular fluid.

294 h three different concentrations of NaOH and equilibration with multiple pressures of CO2.

295 orted by faster voltage-dependent blocker re-equilibration with several experimental manipulations of

296 ringy billiards and their random models show equilibration with similar positive rates.

297 rom the dynamic NMR behavior, its endergonic equilibration with the [Zr]-O-CH2-B(C6F5)2 isomer was de

298 phases, but Hg speciation indicated lack of equilibration with the final solution.

299 llus subtilis, this labile pool is sensed by equilibration with the metalloregulator Zur, as an indic

300 omitant increase in the intraviral pH due to equilibration with the pH of an external buffer.