ライフサイエンスコーパス: equilibria

1 or which the system has a unique or multiple equilibria.

2 rmined by the corresponding local interphase equilibria.

3 omponent of many noncooperative Cournot-Nash equilibria.

4 ectronic effects modulated by conformational equilibria.

5 deconvolution of other intricate host-guest equilibria.

6 r selection and measuring of aptamer-protein equilibria.

7 he cytoplasmic domain shifts the protonation equilibria.

8 ing between cAMP binding and tetramerization equilibria.

9 tration, and DNA sequence to vary the system equilibria.

10 a-tubulin-microtubule and/or G-actin-F-actin equilibria.

11 from the coupling of inhibitory and binding equilibria.

12 rin leg domains contribute to conformational equilibria.

13 ion- and substrate-dependent conformational equilibria.

14 membrane proteins existing in monomer-dimer equilibria.

15 A/IRP1 equilibria and enhanced IRE-RNA/eIF4F equilibria.

16 tailed-balance systems, irrelevant for phase equilibria.

17 uncommon in nature, and thus so will pooled equilibria.

18 post-translational modifications and linked equilibria.

19 EC50 and IC50 from simpler (binary complex) equilibria.

20 otein conformational transitions and folding equilibria.

21 ar pucker and phosphate backbone BI <--> BII equilibria.

22 unds provides information on the dynamic E/Z equilibria.

23 conceptually different outlook on acid-base equilibria.

24 ion interface that are in dynamic stochastic equilibria.

25 ces through simple perturbation of the imine equilibria.

26 and product due to unfavorable thermodynamic equilibria.

27 ronment that alter kinetic and thermodynamic equilibria.

28 finement effects are known to alter reaction equilibria.

29 (AA.DD) where there are no competing folding equilibria.

30 olume of parameter space leading to feasible equilibria.

31 ibe domain separation to thermodynamic phase equilibria.

32 to drive otherwise unfavorable biosynthetic equilibria.

33 wo, and this interplay of mutually dependent equilibria abrogated DB270's inhibitory activity, which

34 he synergistic interplay between two binding equilibria, acting at different sites of a (Zn)phthalocy

35 The transition between PetCO2 equilibria after changes in respiratory rate might not b

36 The effect on keto-enol equilibria also was examined.

37 n by iron tetraphenylporphyrin where the pre-equilibria among ferric, ferrous, and ferric-superoxide

38 ments are being imposed upon the established equilibria among these LIB components, and it became cle

39 conformational changes and multisite binding equilibria, among other factors.

40 ted to account for several gas/aqueous-phase equilibria and aqueous-phase processes, including the fo

41 of proteins onto DNA, and enhancing binding equilibria and catalysis.

42 TRPCs) channels to control cytosolic calcium equilibria and consequent cell behavior.

43 previously shown to destabilize IRE-RNA/IRP1 equilibria and enhanced IRE-RNA/eIF4F equilibria.

44 e for new ecological interactions, community equilibria and evolutionary responses.

45 cycles show solvent-dependent conformational equilibria and excited-state properties.

46 ve cooperativity between host conformational equilibria and guest binding has been widely reported in

47 This study evaluates the equilibria and kinetics of co-precipitation reactions in

48 blished data and models for CH4/CO2 sorption equilibria and kinetics.

49 y optimal accounting for nonlinear algebraic equilibria and nonlinear measurement equations.

50 ts unexpected behavior including polymorphic equilibria and oscillatory dynamics.

51 bria, stable periodic orbits, convergence to equilibria and persistence, with the potential for incor

52 erimental investigation of methyl rotational equilibria and proton chemical shifts in a variety of 2-

53 /E. coli consortia lead to stable population equilibria and provide a mechanism for tuning compositio

54 ne binding greatly affects the imide-enamide equilibria and that alane complexation might even provid

55 on, based on the constants of the interphase equilibria and the concentrations established at a given

56 by modifying the His37-water proton exchange equilibria and the His37 backbone conformational distrib

57 he public good, then we find multiple stable equilibria and the possibility for coexistence between c

58 y developed model, this study predicts phase equilibria and thermodynamic properties of the system H(

59 m solution is guided by stable or metastable equilibria and thus can be rationalized by using phase d

60 rchers to model multiple coupled protonation equilibria and to identify the underlying pH-dependent c

61 asure different components of the host-guest equilibria and together provide a complete picture of th

62 e extra methyl, affecting the conformational equilibria and, hence, the electronic excited states, in

63 s by (15)N NMR, IR spectroscopy, association equilibria, and DFT studies indicates that the H-bonding

64 nce to evaluate FG Nup conformation, binding equilibria, and interaction kinetics associated with the

65 nsights into the electronic nature, chemical equilibria, and kinetics of the elementary reactions of

66 lculate in vivo mass action ratios, reaction equilibria, and metabolite turnover times.

67 etween PCET rate constants, hydrogen-bonding equilibria, and rate-driving force relationships jointly

68 ave similar dimerization and oligomerization equilibria, and that Swi6 binds slightly ( 3-fold) more

69 the composition of the different photocycle equilibria, and the spectra of the involved photointerme

70 ing complexation/interaction based secondary equilibria, and the use of charged and neutral labels ar

71 ical sensors work on the basis of extraction equilibria, and their response toward the analyte ion is

72 a chain stopper in supramolecular ring-chain equilibria, and we reveal here the influence of various

73 losteric systems in which metal coordination equilibria are coupled to other chemical events that tak

74 Nevertheless, only three to five rotameric equilibria are found for each amino acid residue, indica

75 Conformational equilibria are increasingly recognized as pivotal for bi

76 omplex solution behavior, where Schlenk-type equilibria are involved, very little is known about thei

77 Those equilibria are not globally stable, but allow the mainte

78 ange, protonation/deprotonation, and binding equilibria are routinely studied by 2D exchange NMR tech

79 iv of cucurbit[7]uril, CB[7], with which all equilibria are shifted toward the quinone form, which un

80 Defect equilibria are used in derivation of defect diagrams sho

81 rature, the conformational voltage-dependent equilibria are virtually insensitive to temperature.

82 Analysis of redox equilibria arising from the reaction of (L)Pd(OAc)(2) an

83 ificantly altered protonation and tautomeric equilibria at H37.

84 urements provided site-specific snapshots of equilibria between a majority state of well-ordered heli

85 oint mutations alter delicate conformational equilibria between active and inactive states.

86 usual characteristics of the complex coupled equilibria between agonist-receptor and receptor-G prote

87 ive computational algorithm to solve coupled equilibria between an arbitrary number of ligands and a

88 eptor, we identify ligand efficacy-dependent equilibria between an inactive and pre-active state and,

89 rofluidic techniques to characterize binding equilibria between biomolecules under native solution co

90 encoded by Nalpha-chiral side chains and the equilibria between cis- and trans-amide junctions in cyc

91 l amines, and metals); temperature-dependent equilibria between diastereomeric cages are also quantif

92 The equilibria between diastereomers were influenced through

93 ability of ligands to switch conformational equilibria between different G-quadruplex structures is

94 edict the DeltaG degrees values for exchange equilibria between enamines and ketones with similar acc

95 hat all changes are the result of reversible equilibria between free, metal-complexed and oxidized fo

96 We also find the presence of several equilibria between isomeric intermediates where water, o

97 s show positive cooperativity of NTD up/down equilibria between neighboring protomers, allowing us to

98 e, cellular S-nitrosylation reflects dynamic equilibria between S-nitrosothiols (SNOs) in proteins an

99 establish due to the involvement of multiple equilibria between several reactive intermediates.

100 combination with FTIR spectroscopy to reveal equilibria between spectroscopically resolved substates

101 Controlling the equilibria between the cis and trans conformations of th

102 Establishing redox equilibria between the minerals and working electrodes i

103 e conclude by highlighting the importance of equilibria between these accumulated species and reactiv

104 proteins Dcp1 and Edc1 influence the dynamic equilibria between these states and how this modulates c

105 cal phytochromes that display conformational equilibria between two sub-states exhibiting small struc

106 ate how allosteric models represent shifting equilibria between various functional receptor states (c

107 otherm to predict the competitive adsorption equilibria between VOC and water vapor, which is describ

108 substrate, and is dictated by resultant pre-equilibria between, and the relative stability of, magne

109 not significantly impact nucleotide binding equilibria, but does stimulate a 2-fold increase in the

110 ) designed for the analysis of reactions and equilibria by NMR.

111 The position of the equilibria can be altered reversibly by changing the sol

112 For pure pathogen transferring, system equilibria can be derived analytically to explicitly qua

113 d demonstrate that two different methylation equilibria can be maintained within single individuals.

114 eversibly by changing the solvent, while the equilibria can be reversibly and irreversibly driven tow

115 hange reaction and derived carbenes, carbene equilibria, carbocations from diazotates, and carbocatio

116 eactions are coupled to homogeneous chemical equilibria (complexations, protonations, ion association

117 uinones, which are interchangeable via redox equilibria, contribute to both thermal and photochemical

118 ) to show a direct impact on the protonation equilibria, copper binding affinities, reduction potenti

119 Interestingly, the stable biogeomorphic equilibria correspond to suboptimal rates of biomass pro

120 e possible coexistence of two locally-stable equilibria, corresponding to great-ape-like and human-li

121 the policymaker determines which of the Nash equilibria could be adopted, which allows us to compare

122 l-3-silatetrahydropyran 4 the conformational equilibria could be frozen and assigned.

123 r dynamics (MD) simulations, indicating that equilibria determined by MD for ring configurations with

124 alpha4beta1 basal conformational equilibria differ among three cell types, define affinit

125 ieved, but the rates of converging to system equilibria differ based on specific model parameterizati

126 cement of the chelating ethers, with binding equilibria dramatically altered through lithium and sodi

127 tating the fast attainment of solid-solution equilibria (e.g., in stagnant waters), Fe-rich freshwate

128 in their environment, inducing many chemical equilibria each differentiated by the mutual affinities

129 ard bifurcations; that is, multiple positive equilibria exist with one of which being stable even if

130 and a setting in which subthreshold endemic equilibria exist.

131 reas for primary and secondary alcohols, pre-equilibria favoring primary alkoxides are product-determ

132 e the gas- and solution-phase conformational equilibria for a series of symmetrically substituted (th

133 Ring conformational equilibria for methyl idohexopyranosides differ signific

134 Equilibria for the reactions of benzhydryl cations (Ar2C

135 products involved in the network of reaction equilibria for the three-component reaction provide mech

136 sociated with Nup54, shifting conformational equilibria from homo-oligomers to hetero-oligomers.

137 comprised of protonation and conformational equilibria has remained an elusive goal.

138 An alternative "pooled equilibria" has been proposed.

139 These competing equilibria have been quantified using NMR titration and

140 The observed tautomeric equilibria have been rationalized with computational cal

141 lyses of closure consider only static airway equilibria; here we construct, to our knowledge, a new m

142 lues in order to determine its (i) acid-base equilibria, (ii) coordination equilibria, (iii) substitu

143 (i) acid-base equilibria, (ii) coordination equilibria, (iii) substitution lability and operative me

144 tatic pressure shifts protein conformational equilibria in a direction to reduce the volume of the sy

145 he convergence of evolution dynamics to Nash equilibria in a potential game, our formulation provides

146 riations on the cis-trans amide bond rotamer equilibria in a selection of monomer model systems.

147 ults highlight the critical role of PCET pre-equilibria in catalyst self-assembly and turnover, and a

148 iences, namely the Nash equlibrium and other equilibria in economics and game theory, and certain pro

149 y low-dimensional magnetic chaos near saddle equilibria in enhancement of the switching rate.

150 rowd one another and regulate conformational equilibria in favor of headpiece opening.

151 This commentary discusses the role of Nash equilibria in game theory, focusing especially on coordi

152 acromolecular crowding affects most chemical equilibria in living cells, as the presence of high conc

153 Biodiversity equilibria in models occur due to the onset of ecologica

154 for the first time, parallel assay of oxygen equilibria in multiple samples.

155 he effect of the ring size that controls the equilibria in nonfluorinated compounds.

156 otentially help in understanding the complex equilibria in NP-containing solutions and suspensions, i

157 0A and C505A, that shift Drp1 polymerization equilibria in opposite directions, we demonstrate that d

158 dium trihalides leads to compounds that form equilibria in solution between their In-X oxidative addi

159 agged Drp1 exhibits impaired oligomerization equilibria in solution that corresponds to a greatly dim

160 ermodynamic properties, such as distribution equilibria in solvent extraction.

161 tic Monte Carlo search for stable mechanical equilibria in the effective energy landscape of the spin

162 s a unique application of responsive complex equilibria in the form of a cryptographic algorithm that

163 ace chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silano

164 n constants are strongly affected by folding equilibria in the monomeric states.

165 ions demonstrate the relevance of ion-linked equilibria in the operation and regulation of complex bi

166 nd how reactant structure controls rates and equilibria in the process.

167 ufficiently large to ensure the stability of equilibria in the unforced system.

168 eractions lead to a host of nonuniform shape equilibria, in which filaments progressively unwind from

169 emphasize the unique feature of photodynamic equilibria, in which population of the states is dictate

170 conclusion and give further insight into the equilibria involved in the competitive adsorption proces

171 n calorimetry (ITC) methods, for the binding equilibria involving anions of high negative charge, lik

172 ctivation in which the P14 mutations perturb equilibria involving distinct native, intermediate, and

173 s of different ligands on the conformational equilibria involving helices VI and VII provide insights

174 sion utilizing triplet-triplet excited-state equilibria is detailed.

175 analyte into the vesicle based on acid-base equilibria is developed to predict the concentration enr

176 e coupling of protonation and conformational equilibria is essential to a full in silico characteriza

177 e coupling of protonation and conformational equilibria is not exact in the simulation, the results a

178 stribution of species present in complicated equilibria is still in its infancy, and a direct correla

179 rmed on small biomolecules (such as shifting equilibria like in the NAD(+)/NADH or GSH/GSSG couples),

180 qually fit, continuous paths of intermediate equilibria link the two sex chromosome systems.

181 affinities for ligand of each state and the equilibria linking them.

182 dation, and how modulators of conformational equilibria may influence substrate turnover.

183 These results demonstrate that defect equilibria mediated by selective doping in complex TE an

184 In vivo biochemical reaction rates and equilibria might differ significantly from those measure

185 Reduction potentials determined from equilibria mirrored oxidation potentials reported by Chi

186 Here, using phase equilibria modelling of the Coucal basalts, we confirm t

187 mechanism where changes to the positions of equilibria negate changes in the rate of the turnover-li

188 he quantitatively defined side chain rotamer equilibria obtained from our study set new benchmarks fo

189 The initial stable equilibria occur because help is assumed subject to dimi

190 solate at will a single tautomer, as dynamic equilibria occur easily, even in the solid state, and ar

191 s demonstrated that no shift in ion exchange equilibria occurs due to a pressure increase.

192 The conformational equilibria of 1-hydroxy-1-phenylsilacyclohexane 2 and 3-

193 ozen at 103 K and the present conformational equilibria of 3 and 4 could be determined.

194 the effect of pressure on the conformational equilibria of a functional thermostabilized beta(1)-adre

195 These idealistic networks are Nash equilibria of a network construction game whose purpose

196 For this purpose, the adsorption equilibria of alpha,alpha,alpha-trifluorotoluene, toluen

197 ence was further narrowed to the protonation equilibria of Asp(309) with a parallel set of spectrosco

198 rcome the lack of experimental data on phase equilibria of biomass carbohydrates in ionic liquids, th

199 d to quantitatively analyze the kinetics and equilibria of chemical exchange at atomic resolution, in

200 In the current study, the structure and equilibria of complexes forming in such strongly alkalin

201 proach to study the interactions and binding equilibria of cooperatively-bound clusters of the single

202 minor Cu-dopants can substantially alter the equilibria of defect reactions, selectively mediate the

203 Phase equilibria of fluid mixtures are important in numerous i

204 urea can be used to modulate conformational equilibria of folded proteins toward more expanded state

205 s keto/enol tautomerization or deprotonation equilibria of four titratable groups.

206 ht on the correlation between conformational equilibria of free host and guest binding, selected stru

207 Conformational equilibria of G-protein-coupled receptors (GPCRs) are in

208 f post-combustion carbon capture, adsorption equilibria of gas mixtures including CO2, N2, and H2O, w

209 ine converted the protonation and tautomeric equilibria of H19 to be similar to the H37 behavior in A

210 The FTIR results show how the equilibria of inactive and active protein states of the

211 The complex interconversions and equilibria of LMC, LEMC and LEDC in dimethyl sulfoxide s

212 of conformational ensembles, and affects the equilibria of macromolecular interactions.

213 om for which any feasible solutions are Nash equilibria of microbial community metabolic models with/

214 oposed approach to describing conformational equilibria of multidomain proteins can be further combin

215 Complex behavior emerges as equilibria of multiple reactions are coupled.

216 at accurately simulates binding kinetics and equilibria of multivalent protein-protein interactions a

217 f an isotherm equation to predict adsorption equilibria of n-component volatile organic compounds (VO

218 n understanding pressure effect on rates and equilibria of organic reactions.

219 dy management, suggesting novel steady-state equilibria of P dynamics had been reached in these man-m

220 observed transition arises from the dynamic equilibria of photogenerated surface charge carriers.

221 Representative examples of the tautomeric equilibria of pi-conjugated heterocyclic compounds in pr

222 the purpose of modulating the copigmentation equilibria of red wines, an environmentally sustainable

223 Traditionally, game theory studies the equilibria of simple games.

224 he Monod-Wyman-Changeux model to include pre-equilibria of tertiary as well as quaternary conformatio

225 er, through destabilizations of (meta)stable equilibria of the constituents.

226 d studied with respect to the conformational equilibria of the heterosix-membered ring by low tempera

227 However, the effect on the conformational equilibria of the open-chain precursors is very importan

228 ing large-scale shifts in the conformational equilibria of the regulatory domains.

229 Conformational pyranose ring equilibria of the superarmed disaccharide donors with ax

230 d always take into account that the variable equilibria of the two open states depend on light intens

231 The comprehension of tautomeric equilibria of this new class of quinoid compounds is str

232 asses of ligands modulate the conformational equilibria of this receptor.

233 rate the utility of exploiting excited state equilibria of this type in the development of highly eff

234 ieved via the modulation of highly dynamical equilibria of various conformational receptor states.

235 ted by constraints imposed by liquidus phase-equilibria on evolution of mantle-derived magmas.

236 evant states of PimA that coexist in dynamic equilibria on millisecond-to-second timescales in soluti

237 l aspects describing the influence of Donnan equilibria on neuronal chloride ion (Cl(-)) distribution

238 librium concepts such as Pareto optimal Nash equilibria or evolutionarily stable strategies.

239 ure of reduced TiO2 systems at thermodynamic equilibria or photostationary states and should be consi

240 evolutionary rates reaches several new rate equilibria, possibly relating to the modified protein tu

241 Peak H is characteristic of the coal-water equilibria present in all basins, while peaks P and M(2)

242 These equilibria produce concentration dependent solution stat

243 m can then be described as a pair of coupled equilibria (protein folding/unfolding and ligand binding

244 ion of reactants and products thus affecting equilibria, rates and selectivity, pre-arranges the reac

245 -assemble in solution based on thermodynamic equilibria rather than nucleation kinetics.

246 configurations during association, biphasic equilibria resulting from interligand competition at hig

247 Analysis of the monomer/dimer equilibria reveals a dissociation constant of K(d) =0.14

248 (11)B NMR spectroscopy of the H3BO3-catechol equilibria reveals a large pressure-driven exchange rate

249 Analytical treatment of linked equilibria scales poorly with increasing numbers of reac

250 ylation modulates transporter conformational equilibria, shifting the transporter between high and lo

251 The conformational equilibria should therefore be an important consideratio

252 Analysis of multiple equilibria showed that multivalent interactions of Kapbe

253 ular interactions are sensitive to solvation equilibria, so molecular recognition probes provide fund

254 /or sufficient structural tests for multiple equilibria, stable periodic orbits, convergence to equil

255 which can concurrently sustain two different equilibria states, separated by transition regions, and

256 y of fungal oxyluciferin arises from diverse equilibria such as keto/enol tautomerization or deproton

257 hlight the dangers of using simple reference equilibria such as pKa values as measures of leaving gro

258 r the Raman spectra is proposed based on the equilibria taking place in the bath.

259 l difficulties, a calibration curve based on equilibria taking place in the melt has been developed a

260 species are measured using hydride transfer equilibria, taking advantage of expedient new synthetic

261 the supramolecular organization is tuned by equilibria that can be shifted by changes in environment

262 conomic incentives, allows us to predict new equilibria that can serve as a baseline for designing su

263 We show that the continuum of equilibria that characterizes the slow die-out dynamics

264 ths between networks leads to different Nash equilibria that determine their structural and dynamical

265 They are based on supply-demand equilibria that do not exist during recessionary shocks.

266 Such games can produce multiple equilibria that may or may not include fair outcomes.

267 ructure can be accounted for by appealing to equilibria that result from these two pressures.

268 al framework to describe the coupled dynamic equilibria that result in this effect.

269 port thermodynamic predictions of fluid-rock equilibria that tie together models of the thermal struc

270 d that the only attractors in the system are equilibria, that E and M states dominate across paramete

271 me characterized by an exponential number of equilibria, the vast majority of which are expected to b

272 of supramolecular events within networks of equilibria through the adjustment of the kinetics of the

273 ergy of the TT to TR and TR to RR allosteric equilibria to be 27 +/- 11 and 46 +/- 2 kJ/mol, respecti

274 es in AtAPSK alter the energetics of binding equilibria to control its activity.

275 We describe the use of thioester exchange equilibria to measure the propensities of amino acid res

276 o-player coordination game that had multiple equilibria: two equilibria with highly asymmetric payoff

277 We explored binding equilibria under ligand/receptor conditions used in mixt

278 mic processes associated with conformational equilibria, underscore not only the challenge of designi

279 egy for the characterization of vapor-liquid equilibria (VLE) is presented, which is based on phase (

280 l solutions and asymptotic analysis of shape equilibria, we show that filament conformations are crit

281 psoils (depths </= 18 cm) until steady-state equilibria were reached within 200 years of land use.

282 trong anticonformity and the presence of new equilibria when both conformity and anticonformity act a

283 rks (IRMOFs) exhibit true vapor-liquid phase equilibria where the effective critical point may be red

284 fer closer insight onto thiol-sulphenic acid equilibria which are involved in intracellular redox-med

285 etallates is the presence of complex anionic equilibria, which depend both on the type and on the con

286 framework for understanding ternary complex equilibria, which relates directly to familiar concepts

287 cohol right harpoon over left harpoon alkene equilibria, while Pd/C catalyzes the subsequent, exother

288 escent material is based on a complex set of equilibria, whose fluorescence output depends non-linear

289 Nevertheless, phase equilibria with biomass derived compounds is still lacki

290 t Yellowknife Bay (YKB), by coupling mineral equilibria with carbonate precipitation kinetics and rat

291 ation game that had multiple equilibria: two equilibria with highly asymmetric payoffs and another eq

292 y, these complexes exhibit increased binding equilibria with increasing pressure, with important impl

293 ups (EWGs) (0 < Esigma > 0.63) populated the equilibria with isospiropyrans (12-74% yield), while tho

294 compared with earlier pK(Li)s reported from equilibria with lithium amides in which aggregation was

295 Numerical solutions of coupled binding equilibria with our results show that networks of homolo

296 cally active species are involved in complex equilibria with unusual dormant (reversibly inactivated)

297 at matrix handling can affect analyte/matrix equilibria, with consequent release of high concentratio

298 tion was found to affect ring conformational equilibria, with the percentages of (4)C1 forms based on

299 Manipulation of the solution equilibria within a cross-coupling milieu enables the fo

300 probes minimally perturb a protein's folding equilibria within cells during and after cell lysis, bec