ライフサイエンスコーパス: esterification

1 y and calcium pectate contents and degree of esterification).

2 electrophilic C-atom at its carbonyl group (esterification).

3 ation of cholesterol and reduced cholesterol esterification.

4 t regulates the SREBP2 pathway and undergoes esterification.

5 amework of myo-inositol and a regioselective esterification.

6 tin changed significantly (P<0.05) after OSA esterification.

7 olyzed from the amylopectin molecules during esterification.

8 pancreatic cancer by inhibiting cholesterol esterification.

9 d hyperlipidemia due to increased fatty acid esterification.

10 the candidate enzymes catalyzing astaxanthin esterification.

11 sterol, including membrane incorporation and esterification.

12 ntioxidant system and enhanced pectin methyl esterification.

13 sters via membrane electrolysis and biphasic esterification.

14 ss to more stable anthocyanins via enzymatic esterification.

15 nt-free system involving both hydrolysis and esterification.

16 s well as a decrease in the degree of pectin esterification.

17 ng to B-ring substitution, glucosylation and esterification.

18 tial interactions was minimal with degree of esterification.

19 nd merged with the first fragment via Shiina esterification.

20 ible bis-Mosher esters (16) was then made by esterification.

21 e altered by 5-PAHSA through selective FA re-esterification.

22 sferase (ACAT) mediates cellular cholesterol esterification.

23 quires the presence of 10% DMAP to drive the esterification.

24 42, 37, and 33)] having different degrees of esterification.

25 chromosomes 7D and 7H(ch) are important for esterification.

26 uman health and can be produced by enzymatic esterification.

27 esides, H. chilense has additional genes for esterification.

28 the bilayer to the phospholipase A2-like and esterification active sites of LCAT, respectively.

29 fluorescence method to accurately detect the esterification activity of lecithin:cholesterol acyltran

30 tain accurate and robust measurement of LCAT esterification activity.

31 on of enzymes involved in hepatic fatty acid esterification, ameliorates hepatic steatosis and lipid-

32 linkage of each glycan using the solid-phase esterification/amidation strategy.

33 The differences for lutein esterification among tritordeums suggest the existence o

34 re winterization), (iii) two-steps enzymatic esterification and (iv) triacylglycerols (TAG) purificat

35 uki coupling, a Stille coupling, a Yamaguchi esterification and a Yamaguchi macrolactonization.

36 lic acid derivatives has been carried out by esterification and amidation reactions.

37 in sources, while variation in the degree of esterification and amidation, respectively, had negligib

38 t of apple pectins having similar degrees of esterification and amidation, respectively.

39 by application of click chemistry or classic esterification and amidation.

40 protection is compatible with commonly used esterification and amide bond formation techniques, incl

41 ich can effectively catalyze pentyl valerate esterification and be easily separated by an external ma

42 ally achieved via enzymatic enantioselective esterification and ester hydrolysis.

43 d on day 4 of the experiment indicating that esterification and hydrolysis concomitantly occurred.

44 lusively to HG that has a very low degree of esterification and in the presence of divalent ions.

45 Olefin cross-metathesis, trans-esterification and Nozaki-Hiyama-Kishi (NHK) macrocycliz

46 ed to provide a third new synthesis based on esterification and Nozaki-Hiyama-Kishi reaction.

47 pite the postprandial decrease in FFA-driven esterification and oxidation, VLDL-TAG secretion is main

48 of genes involved in lipogenesis/fatty acid esterification and resultant hepatic steatosis (simple f

49 a newer and more practical approach based on esterification and ring-closing metathesis reaction.

50 cription of genes responsible for fatty acid esterification and steatosis.

51 PARgamma target genes involved in fatty acid esterification and storage in 3T3-L1-derived adipocytes.

52 Here we discuss catalytic esterification and transesterification solutions to the

53 e propose that the close proximity of sterol esterification and transport proteins to each other comb

54 port into memory CD8+ T cells for fatty acid esterification and triglyceride (TAG) synthesis and stor

55 f biocatalysis as demonstrated in high yield esterifications and in the sesquiterpene cyclase-catalyz

56 TMZ was employed to conduct esterifications and metal-catalyzed cyclopropanations, a

57 tabolism (lipogenesis, oxidation, lipolysis, esterification) and fatty acid uptake in >9000 primary o

58 principle, the effects of hydrophobic (e.g., esterification) and hydrophilic (e.g., glycosylation) bi

59 yne, a Mukaiyama aldol reaction, a Yamaguchi esterification, and a homemade mild di-esterification ca

60 d alpha2,6-linked sialic acids through ethyl esterification, and alpha2,3-linked sialic acids via ami

61 yte triglyceride accumulation and fatty acid esterification, and decreasing fatty acid oxidation and

62 include modified Crimmins aldols, Yamaguchi esterification, and Grubbs ring-closing metathesis react

63 tive ring-closing metathesis, De Brabander's esterification, and Jacobsen's hydrolytic kinetic resolu

64 Placental FA uptake, esterification, and oxidation pathways were studied by m

65 ic modification reactions, namely amidation, esterification, and thioesterification, were demonstrate

66 up in this repeating unit through methyl (de)esterification, another known dynamic trigger in planta.

67 of this useful catalytic asymmetric allylic esterification are defined.

68 de insight into how the mutations affect the esterification arrangement of cutin.

69 cellular homeostasis by inducing cholesterol esterification as a mechanism of detoxification while at

70 vides striking evidence for the mechanism of esterification as the pathway for possible oligomerizati

71 model to explain the process of cholesterol esterification, as well as details of the interaction be

72 palmitic vs. linoleic) and regioselectivity (esterification at positions 3 vs. 3').

73 esised by both chemical and lipase catalysed esterification between fatty acids and methionol.

74 can be used as reagents, exemplified by some esterifications between simple acids and alcohols.

75 owed substantial decreases in pectin amount, esterification, branching, hydration, and mobility in an

76 lodextrins causes an increase in cholesterol esterification by acyl CoA:cholesterol acyl transferase,

77 cholesterol efflux, facilitates cholesterol esterification by promoting fatty acid synthesis, and in

78 ) cholesterol efflux and reduced cholesterol esterification by sterol-O-acyltransferase 1 (SOAT1).

79 Host FA are assimilated via esterification by the bacterial acyl-acyl carrier protei

80 d oil, concentration of PUFAs, and enzymatic esterification by the Celite-immobilized lipase.

81 guchi esterification, and a homemade mild di-esterification can be cited.

82 In secondary cell walls, mannan esterification can prevent probe recognition of epitopes

83 this study was the evaluation of cholesterol esterification (CE) fraction (esterified cholesterol vs.

84 Fatty acid esterification, common in naturally occurring astaxanthi

85 ds from beta,gamma-butenolides by an in situ esterification, condensation, and reduction in a one-pot

86 Esterification condensations were observed in the assays

87 Thus, esterification could provide a general means to deliver

88 rase 2 act coordinately in the hydrolysis/re-esterification cycle of TAGs on lipid droplets.

89 for automated determination pectin degree of esterification (DE) using micro sequential injection lab

90 intrinsic viscosity [eta](w), and degree of esterification (DE) were compared to those parameters ob

91 and 9)], with different levels of degree of esterification (DE), to investigate the complex coacerva

92 Increased esterification decelerated degradation of all-trans-asta

93 onal groups and at determining the effect of esterification degree on resistance and pasting characte

94 aste used to produce retrograded starch, and esterification degree, on selected properties of the res

95 e formation, whereas preventing HG de-methyl-esterification delays pore initiation and inhibits pore

96 vitro experiments indicated that astaxanthin esterification drove the formation and accumulation of a

97 Abrogation of cholesterol esterification, either by an ACAT-1 inhibitor or by shRN

98 nctional impairment of cholesterol efflux or esterification, either of which would be expected to imp

99 ll sialic acids regardless of linkage, while esterification enables differentiation between alpha2,3-

100 gical inhibition of ACAT1, a key cholesterol esterification enzyme, led to potentiated effector funct

101 d the higher equivalent weight and degree of esterification for the microwave-extracted pectin than t

102 , e-Lcy from H. chilense and the high lutein esterification found in tritordeum may serve to explain

103 The cholesterol esterification fraction is a valid biomarker for liver s

104 The key steps in this approach included esterification, Friedel-Crafts acylation, and ring-closi

105 esterol loading or inhibition of cholesterol esterification further elevated CHOP expression in ARV1

106 ditions for attachment of the spin-label via esterification have been optimized on the direct synthes

107 When processed to low degrees of esterification, HG can form complexes with divalent calc

108 rom OFI cladodes (UAEPC) has a low degree of esterification, high uronic acid content, important func

109 involving methylation and one-pot Mitsunobu esterification-hydrolysis.

110 c or oleic acid as acyl donors, reaching 90% esterification in 3h with the recombinant enzyme.

111 oth necessary and sufficient for xanthophyll esterification in bread wheat grain.

112 ngly suggests its involvement in xanthophyll esterification in citrus fruit tissues and its influence

113 are now greatly improved by their enzymatic esterification in ionic liquids (ILs).

114 ementation of n-3 significantly decreased FA esterification in isolated trophoblasts without affectin

115 itable acyl transfer agents in amidation and esterification in organic synthesis.

116 Inhibiting cholesterol esterification in T cells by genetic ablation or pharmac

117 Moreover, the accessibility of esterification in the absence of light is especially not

118 nown if glucose regulates LCFA oxidation and esterification in the MBH and, if so, which hypothalamic

119 of PME activity and homogalacturonan methyl esterification in the seed.

120 tors show that ACAT plays a key role in PREG esterification in various cell types examined.

121 ysis in rat digestive fluid, and cellular re-esterification in vivo, were evaluated to examine the me

122 esterol acyltransferase-mediated cholesterol esterification, in combination with increased free chole

123 trate; with cholesterol, the V(max) for PREG esterification increases by 100-fold.

124 explained by the observation that palmitate esterification influenced the cis-trans equilibrium.

125 Rates of fatty acid esterification into hepatic triglyceride were found to b

126 )C] palmitate to measure rates of fatty acid esterification into hepatic triglyceride while varying p

127 glucose increases palmitate, but not oleate, esterification into neutral lipids in neurons and MBH sl

128 Transmembrane transport (CD36) and esterification into triglycerides (DGAT) may be rate-lim

129 The reaction proceeds via a domino esterification/intramolecular 1,4-addition-type Friedel-

130 Esterification is a common means of carotenoid sequestra

131 port from the plasma membrane to the site of esterification is associated with the physical interacti

132 tive and regioselective Ir-catalyzed allylic esterification is described, in which branched allylic e

133 vealed that in intact tomato fruit pectin de-esterification is endogenously regulated by physical res

134 yeicosatetraenoic acid (HETE) ether-LPC sn-1 esterification is markedly activated by thrombin treatme

135 Thus esterification is not acting as a metabolific sink befor

136 High selectivity for esterification is observed even in the presence of unpro

137 cyclic enamine formation, decarboxylation or esterification, isomerization, and lactamization, to fur

138 ellulose biosynthesis can be affected by the esterification levels of pectin, possibly through modify

139 ization led to an alternative intramolecular esterification/macrolactamization strategy employing the

140 fore hypothesized that increased cholesterol esterification may have detrimental effects on adipose t

141 could be attributed to decreased fatty acid esterification measured by the incorporation of [U-(13)

142 genes associated with fatty acid transport, esterification, mitochondrial import, and beta-oxidation

143 Methyl esterification neutralizes the negative charge of the pr

144 es rapid, high-capacity sterol transport and esterification, obviating any requirement for soluble in

145 that both free astaxanthin biosynthesis and esterification occurred in the endoplasmic reticulum, an

146 omers in a mixture, while the stereospecific esterification of 1,2- or 2,3-isopropylidene-sn-glycerol

147 ixture combinations for the oxidative methyl esterification of 1-octanol at 60 degrees C in methanol.

148 Selective esterification of 11-cis-ROL is one possibility.

149 disproportionation is arrested by silylative esterification of a mono-CO2 adduct.

150 mitations and efficiently catalyze the redox esterification of a whole series of alpha/beta-substitut

151 Tomato ASATs catalyze the sequential esterification of acyl-coenzyme A thioesters to the R4,

152 n the presence of oxygen, the cross and self-esterification of alcohols to esters proceeds in good to

153 have been developed for the direct oxidative esterification of alcohols using molecular oxygen as ben

154 t a one-pot process for the direct oxidative esterification of aliphatic alcohols that is significant

155 s and light energy to drive direct oxidative esterification of aliphatic alcohols under base-free, mi

156 Selective esterification of aliphatic and aromatic carboxylic acid

157 ((13)C-TrEnDi), which results in the methyl esterification of all acidic sites and the conversion of

158 tors in ethanol achieved near-complete ethyl esterification of alpha2,6-linked sialic acids and lacto

159 We now report the nickel-catalyzed esterification of amides derived from aliphatic carboxyl

160 The esterification of amphiphilic alcohols with fatty acids

161 Selective esterification of apoptolidins A and H with 5-azidopenta

162 , and NMR spectroscopy indicated complete de-esterification of arabinoxylan oligosaccharides from whe

163 r 4 (enzyme that generates substrate for the esterification of arachidonic/adrenic acid into phosphat

164 Ni-catalyzed amination, etherification, and esterification of aromatic bromides showed higher yields

165 trates in the amination, etherification, and esterification of aryl bromides, the latter of which has

166 chain), and TmAAE4 as suitable candidate for esterification of benzoic acid with CoA (Taxol side chai

167 Therefore, in planta, CUS1 can catalyze the esterification of both primary and secondary alcohol gro

168 Furthermore, in these mutants, the esterification of both sn-1,3 and sn-2 positions of glyc

169 Although esterification of cholesterol imparts measurable stereoe

170 It catalyzes the esterification of cholesterol to generate cholesteryl es

171 he absorption of dietary fat involves the re-esterification of digested triacylglycerol in the entero

172 rein, four different ILs were tested for the esterification of dihydrocaffeic acid with hexanol and t

173 dentify a specific role for hepatic DGAT1 in esterification of exogenous fatty acids and indicate tha

174 mains and a significant decrease (53-36%) in esterification of exogenous sterol.

175 step in triacylglycerol (TAG) synthesis, the esterification of fatty acyl-CoA to diacylglycerol.

176 Although esterification of free cholesterol to cholesteryl ester

177 is of diacylglycerols in rapeseed oil by the esterification of free fatty acids and monoacylglycerols

178 y acid, leading to a radical increase in the esterification of free fatty acids into triacylglycerol.

179 involved in lipid storage through efficient esterification of free fatty acids.

180 Esterification of GFP with 2-diazo-2-(p-methylphenyl)-N,

181 IalphaI is essential for the trans-esterification of HCs onto hyaluronan (HA).

182 lasma fraction was able to promote the trans-esterification of HCs to HA in the presence of TSG-6, wh

183 ork, biosurfactants were synthesized via the esterification of lactose with lauric acid in different

184 cholesterol and sphingolipids and defective esterification of LDL-derived cholesterol.

185 glucose flux into glycerol-3-phosphate, and esterification of long chain CoAs resulting in rapid con

186 The esterification of methylecgonine (2-carbomethoxy-3beta-t

187 Modified maize starches were obtained by the esterification of native starch with octenyl succinic an

188 derivatives were obtained by simple one-step esterification of oleanolic acid prior to pharmacologica

189 nt 2-arachidonoyl-lysophospholipids, and the esterification of oxidized 2-arachidonoyl-lysophospholip

190 high-pressure pretreated tomatoes), with de-esterification of pectin by PME, which resulted in a hig

191 omato tissue on the other hand, intensive de-esterification of pectin by the activity of PME occurred

192 The de-esterification of pectin resulted in more rigid and stif

193 hat lobe period can be reduced when demethyl-esterification of pectins increases under conditions of

194 ides, lignins, pectins) and by the degree of esterification of pectins.

195 n, total polyphenols index and the degree of esterification of pectins.

196 Esterification of phytosterols with DHA may render impro

197 This study shows CA esterification of plantain flour as a successful strateg

198 the major source of hepatic lipid synthesis, esterification of preformed fatty acids, is primarily de

199 ighly effective for aerobic oxidative methyl esterification of primary alcohols.

200 nol acyl transferase (LRAT), which catalyzes esterification of retinol to its storage species retinyl

201 They catalyze the esterification of specific amino acids to the 3'-end of

202 onent of eukaryotic lipid homeostasis is the esterification of sterols with fatty acids by sterol O-a

203 Esterification of the 11-OH of 17-AAG eliminated Hsp90 b

204 ease in cutin deposition, mid-chain hydroxyl esterification of the dihydroxyhexadecanoic acid was aff

205 ives reported in the literature are based on esterification of the Finland trityl, which is prone to

206 onformation-controlled highly regioselective esterification of the glucose diol in the disaccharide c

207 so synthesized double prodrugs by additional esterification of the hydroxamate moiety.

208 significantly to higher pHs as the degree of esterification of the pectin decreased, whereas the shif

209 nic phosphinates containing two P-C bonds or esterification of the phosphonate group.

210 An increase in the total degree of esterification of the produced ADA-R-preparation caused

211 In Arabidopsis seeds, esterification of the R-group of hydroxylated GSLs (OH-G

212 The mechanism of esterification of the secondary alcohol 1-(1-naphthyl)et

213 active lead compound was made accessible by esterification of the terpenols with commercially availa

214 f the peroxisomal membrane for subsequent re-esterification of the VLCFAs.

215 Esterification of this alcohol with a C1-C19 carboxylic

216 GC-MS system was used for the trans-esterification of triglycerides to fatty acid methyl est

217 Lastly, analysis of the methyl esterification of ubiquitin and single point mutation of

218 s tested for the production of capsinoids by esterification of vanillyl alcohol (VA) with free fatty

219 and evaluated as (pre)catalysts in the redox esterification of various alpha- or beta-substituted ena

220 of fatty alcohols on the reaction rate, the esterifications of C4-C18 straight-chain fatty alcohol w

221 Our results showed that simple esterifications of haemanthamine or its derivative dihyd

222 hylls were evaluated, since the influence of esterification on bioaccessibility and bioavailability i

223 Esterification or amidation in solution effectively prot

224 ated multidrug resistance was established by esterification or etherification of hydroxylated 5alpha/

225 te, and trapping of this arrangement through esterification or ring-closing metathesis produces the c

226 been synthesized at 28 degrees C via direct esterification or transesterification catalyzed by the v

227 adamantanes (guest moieties) via controlled esterification or with beta-cyclodextrins (host moieties

228 fied the fatty acids involved in carotenoids esterification: palmitic (C16:0), myristic (C14:0) and s

229 ethyl carbonate) were partly consumed via an esterification pathway.

230 selectivity between the decarboxylation and esterification pathways under thermal acidic conditions,

231 the esterified fraction, suggesting that the esterification process facilitates the accumulation of t

232 cs as a tool for rational optimization of an esterification process with down to equimolar ratios of

233 During the esterification process, both their aromatic and aliphati

234 donor molecules involved in the xanthophyll esterification process.

235 Esterification promotes the sequestration and accumulati

236 esulting lack of substrates for triglyceride esterification protects severely hypothyroid mice agains

237 previously reported group IV metal-catalyzed esterification protocols, the work presented herein circ

238 d as high-methoxyl pectin with the degree of esterification ranged from 82% to 90%.

239 the free fatty acids did not improve direct esterification rate, and the enzyme did not convert one

240 o-step reaction consisting of hydrolysis and esterification, rather than alcoholysis.

241 restored cellulose levels, and restored the esterification ratio of pectin to wild-type levels.

242 yzed "click" reaction and P(n-Bu)3-catalyzed esterification reaction as stoppering reactions.

243 Afterwards, the esterification reaction between HbA1c and T3BA produces

244 overy, which we demonstrate by developing an esterification reaction found within the mapped space.

245 otected amino acids via a one-pot activation/esterification reaction in the presence of various dialk

246 A serendipitously discovered oxidative esterification reaction of cyclohexane hexacarboxylic ac

247 trate that Cas1 catalyses an efficient trans-esterification reaction on branched DNA substrates, whic

248 These were then cleaved via a Ni-catalyzed esterification reaction with EtOH to give valuable N-Boc

249 induced proton concentration can catalyze an esterification reaction, and greatly alter the volume of

250 In a trans-esterification reaction, triglycerides esterified from a

251 poxides, followed by an intramolecular trans-esterification reaction.

252 The esterification reactions are allosterically activated by

253 y and selectivity in biodiesel synthesis and esterification reactions at room temperature.

254 Chemical and lipase-catalysed esterification reactions between fatty acids of C4-C18 a

255 Turnover rates for condensation and esterification reactions decrease with increasing Cu dis

256 ione, BN82685, block the second of two trans-esterification reactions in splicing, preventing the rel

257 alyzed Meinwald rearrangement, and Mitsunobu esterification reactions were used as key steps.

258 l events for base-catalyzed condensation and esterification reactions, indicate that both reactions i

259 talyzed transesterification, hydrolysis, and esterification reactions, is used to demonstrate the pot

260 , 0.2 mol/l in methanol) was used as a trans-esterification reagent.

261 and hydroxyl (OH) groups were enumerated by esterification, reducing, and acetylation reactions, res

262 roach, we show that genes controlling pectin esterification regulate the root clock and lateral root

263 mounts of 9-cis isomer whereas monopalmitate esterification resulted in increased 13-cis isomerizatio

264 r oxygenates via aldol-type condensation and esterification routes without detectable involvement of

265 diols and 2,4-diene-1,6-diols, and by a DODH/esterification sequence of sugar acids to unsaturated es

266 l Fischer titration method suffering from an esterification side reaction which generates water as a

267 may be utilized to also reveal phospholipid esterification site information in tandem mass spectrome

268 n of the acyl chains at the two phospholipid esterification sites has been performed based on the R(1

269 f intercellular adhesion, whereas the pectin esterification state is essential for a functional root

270 f PME6 rescues guard cell wall pectin methyl-esterification status, stomatal function, and plant grow

271 In addition, we added a peptide esterification step to increase phosphopeptide specifici

272 process by combining other reactions such as esterification, Suzuki-Miyaura coupling, hydrogenolysis,

273 er of hepatic processes including fatty acid esterification, the pentose phosphate pathway, and gluco

274 As a function of esterification, the SiPcs 1-7 exhibit moderate-to-good s

275 Esterification then provided vinyl boronate esters as us

276 d similar trend of increase in pectin methyl esterification through decreasing PME activity as observ

277 e the C1-C13 alkyl scaffold, and a Yamaguchi esterification to set the side chain.

278 late anion by acyl-CoA synthetase(s), and re-esterification to the sn-2 position by sn-2 acyltransfer

279 The effect of flavan-3-ols on pectin methyl esterification under salt stressed conditions was furthe

280 ally active alcohol can also be subjected to esterification under the optimized conditions.

281 of a small-molecule fluorophore is masked by esterification until entry into a cell, where endogenous

282 ants produced higher degree of pectin methyl esterification via decreasing pectin methyl esterase (PM

283 The impact of esterification was also studied using three triglyceride

284 Direct esterification was conducted in biphasic isooctane: wate

285 The reversible nature of boronate esterification was exploited to switch the receptor sequ

286 ine residues and myristic acid; this type of esterification was further confirmed by its resistance t

287 Esterification was partial and a mixture of esters was o

288 Esterification was shown to play the most significant ro

289 Fatty acid esterification was transient in the fasted state but con

290 Esterification was used to simultaneously increase solub

291 pyl-, octyl-, octadecyl-trimethoxysilane and esterification) were estimated to 1.10, 1.02, 0.86, and

292 synthesis, which is important for fatty acid esterification when dietary fat is in excess.

293 and the retinal significance of cholesterol esterification, which could be cell-specific and both be

294 Esterification with 3% OSA results in starch that has OS

295 derivative of alpha-lipoic acid (ALA) by its esterification with 4-methoxybenzyl alcohol (4-MBA, anis

296 ctivity with the exception of increased self-esterification with a methanol solvent, resulting in met

297 blend using Candida cylindracea followed by esterification with glycerol using Lipozyme RM1M.

298 indicating that PNPLA1 catalyses the omega-O-esterification with linoleic acid to form acylceramides.

299 erivatization, in which FAs are sent through esterification with the acidic catalyst boron trifluorid

300 zolin-5-one was realized by direct enzymatic esterification without need of further protective groups