ライフサイエンスコーパス: exothermic

1 energies (i.e., the adsorption processes are exothermic).

2 borylenes to multiple C-C bonds are strongly exothermic.

3 ons proceed without barrier and are the most exothermic.

4 ) requires much lower barriers and is highly exothermic.

5 verall conversion of MeOH to CH(2)(OH)(2) is exothermic.

6 ion of one to three silver cations is highly exothermic.

7 activation of the C-CN bond was found to be exothermic.

8 n energy, and renders such cyclizations less exothermic.

9 of the interaction between IA(3) and YprA is exothermic.

10 Binding of both cytochrome c molecules is exothermic.

11 atalyzed reaction and the reaction is highly exothermic.

12 -like as the metathesis becomes increasingly exothermic.

13 analogous one-electron reductive coupling is exothermic.

14 oceeds via chairlike transition state and is exothermic.

15 because the pathway is pseudopericyclic and exothermic.

16 cies SiCl2 was theoretically predicted to be exothermic.

17 lations indicates that the process is highly exothermic.

18 that the steps leading ultimately to NO are exothermic.

19 1.3 eV) metal electrons caused by moderately exothermic (1-3 eV) chemical reactions over high work fu

20 s for a significant range of endothermic and exothermic [1,5]-shifts with different intrinsic activat

21 n of methanol to acetyl chloride is slightly exothermic (4.4 kcal/mol).

22 CPCM calculations show that the highly exothermic [4 + 2] pathway becomes kinetically more favo

23 In addition this new mechanism is very exothermic (45 kcal/mol) leading to a large net energy r

24 The reaction was calculated to be very exothermic (-69 kcal/mol), and this was confirmed via ca

25 Although loss of hydroxide ion is hugely exothermic, a concerted reaction is not enforced by the

26 ions are identified, and all are shown to be exothermic according to G3(MP2) calculations; strain ene

27 e device performance was characterized using exothermic acid-base neutralizations and a detailed nume

28 An exothermic addition/H-elimination reaction of acetylene

29 lly for systems showing complex and strongly exothermic adsorption behavior.

30 libria, while Pd/C catalyzes the subsequent, exothermic alkene hydrogenation.

31 nters act as nucleophiles) are actually both exothermic and accompanied by low activation barriers.

32 Con-G dimerization was shown to be exothermic and accompanied by positive heat capacity cha

33 n process with a high energy barrier into an exothermic and almost barrierless Huckel-Mobius transiti

34 ffect of binding the anionic carboxylates is exothermic and also, the source of positive cooperativit

35 perature is that the partitioning process is exothermic and becomes less favorable with increasing te

36 to the natural sequence ribozyme is strongly exothermic and can be analyzed in terms of sequential in

37 evealed that the interaction is spontaneous, exothermic and driven by entropy.

38 ansfer to protonated HAL and AHL triggers an exothermic and dynamically barrierless transfer of the c

39 Both exothermic and endothermic phases produce highly negativ

40 The binding data conformed to both exothermic and endothermic phases with magnitudes of Del

41 FeCrAl) is an exceptional support for highly exothermic and endothermic reactions that operate above

42 ite with distinct kinetic and thermodynamic (exothermic and endothermic) properties.

43 g reactions, which are characterized more by exothermic and enthalpic interactions.

44 Tetraloop-receptor docking is significantly exothermic and entropically unfavorable in 1 mM MgCl(2)

45 ving more strained alkynes not only are more exothermic and exhibit lower activation barriers but als

46 hin 3, the protonation of 2 by 1 is fast and exothermic and forms 6, an aggregate between betaine 4 (

47 uctural reorganization during dehydration is exothermic and irreversible.

48 Binding to the second site is highly exothermic and is accompanied by an unfavorable entropic

49 ing of betaine 4 in aggregate 6 are fast and exothermic and lead irreversibly to E-11, the aggregate

50 which in turn indicated that the process is exothermic and low-energy interactions are involved in t

51 C-H or C identical withC bonds are all more exothermic and more strongly activating than for the cor

52 bilization of products that makes hydrolysis exothermic and needs to be considered in achieving impro

53 ITC data indicate that binding is exothermic and occurs with a 1:1 stoichiometry.

54 Each step in the associative pathway is exothermic and occurs with small energy barriers.

55 tions were all chemical, and were favorable, exothermic and order-increasing processes.

56 alpy of intact apoE4 (-39 kcal/mol) was less exothermic and rather similar to that of each fragment,

57 the binding of maltotriose to the protein is exothermic and tight, whereas no thermal effect was obse

58 hthalene-type ion is calculated to be highly exothermic and without a barrier.

59 N by apo-FRP was found to be noncooperative, exothermic, and primarily enthalpy driven.

60 O(S) formation is exothermic, and the oxygen atoms tend to avoid O-O dimer

61 The changes in molar enthalpy become more exothermic as ring number increases and as annelation st

62 DNA bending, while the 6-bp mode is modestly exothermic at all salt concentrations examined.

63 related charged phenyl radicals in different exothermic atom and group abstraction reactions in the g

64 d state, we report experimental evidence for exothermic atom-exchange chemical reactions.

65 Reactions are increasingly exothermic based on metal complex, Mo(PiPr3)2(CO)3 < W(P

66 n without exception (i.e., E(isom) is always exothermic), Be(2+)@C(10)H(16) (T(d)(); -235.5 kcal/mol)

67 from N,N'-dipp-substituted boranes underwent exothermic beta-scissions with production of dipp-Imd-BH

68 A-I to SUVs of POPC plus 0-20% (mole) FC was exothermic between 15 and 37 degrees C studied, accompan

69 GuanidineHCl binds to mAb with an exothermic binding enthalpy, which partially compensates

70 titration calorimetry showed the sequential exothermic binding of two manganese ions in solution, wi

71 c helices were the major determinants of the exothermic binding reactions.

72 ry (ITC) studies supported these findings as exothermic binding was observed under conditions with fr

73 < PVCap < VIMA, have increasingly negative (exothermic) binding energies of -0.2 < -20.6 < -37.5 < -

74 ally driven in PF6- and TF2N-based RTILs and exothermic but entropically driven in BF4-based RTILs.

75 Formation of these 1:1 complexes was also exothermic, but additional endothermic events occurred a

76 A less exothermic, but more plausible pathway for photochemical

77 ydrogen by the FLP Rp(-)/[(Tol)Im(F4)](+) is exothermic, but the formation of the initial Lewis pair

78 alphaKG decarboxylation, is barrierless and exothermic, but the subsequent hydrogen abstraction step

79 n of ZIFs from these components at 298 K are exothermic, but the ZIFs are metastable energetically wi

80 rmation of endohedral He@F(8)@Ge(60)F(52) is exothermic by -10.4 kcal mol(-1), while Cs and Bi guests

81 ults, which show the two-step reaction to be exothermic by -215 kJ mol(-1), in agreement with results

82 ium-nitride linkage and was calculated to be exothermic by -3.25 kcal mol(-1).

83 SSP starts on crystal defect sites; it is exothermic by 14 kcal/mol and requires activation energy

84 erthiyl radical make the foregoing reactions exothermic by 15-34 kcal/mol.

85 tion of 1 to form 3 was found to be strongly exothermic by 176.0 kcal/mol.

86 Bergman reaction of triggered 1 is slightly exothermic by 2.8 kcal/mol.

87 Isomerization of ROONO to RONO(2) is exothermic by 22-28 kcal mol(-)(1).

88 tonation of 3 to form 5 was also found to be exothermic by 28.4 kcal/mol.

89 e with an Os(PH3)3 fragment in place of C is exothermic by 3 kcal/mol (the parent Bergman reaction is

90 The former reaction is computed to be exothermic by 37.2 kcal/mol, whereas the latter is calcu

91 The analogous decomposition is exothermic by 8 to 11 kcal mol-1 for the anions, indicat

92 The 5',8-cyclization is found to be exothermic by approximately 20 kcal/mol but kinetically

93 ngement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical,

94 g a continuous feedback loop between various exothermic catalytic reactions in the nutrient layer and

95 NA analogue of the loop, was associated with exothermic changes, consistent with predominantly outer-

96 +/- 2.5) s(-1)) reaction by two branches: an exothermic channel that produces NDMA, and an entropy-dr

97 cal calculations predict that by coupling an exothermic chemical reaction with a nanotube or nanowire

98 ion-induced mixing), or self-propagating (by exothermic chemical reaction).

99 Exothermic chemical reactions may be an important source

100 reactions: electronic excitation upon highly exothermic chemisorption has been observed, and indirect

101 uced when carried out concomitantly with the exothermic chlorination step.

102 The strongly exothermic cleavage of the dinitrogen bond takes place,

103 e high-entropy nitride phase was obtained by exothermic combustion of mechanically-activated nanostru

104 a low-temperature solution process utilizing exothermic "combustion" precursors.

105 ral bis-urea and bis-thiourea receptors form exothermic complexes with dicarboxylates in DMSO, with a

106 IV undergoes a very exothermic coupling of alkyl and hydroxy groups to give

107 a CN x H y material formed via the rapid and exothermic decomposition of a reactive triazine precurso

108 All of the products exhibit exothermic decomposition properties with heats of decomp

109 reasonably large activation energies for its exothermic decomposition to CsF+2 F2 , or to CsF3 (three

110 We present DSC data on ADT that show exothermic decomposition with an initiation temperature

111 n a significantly decreased affinity, a less exothermic Delta H, and a more negative Delta C(p) for s

112 us solution on granular activated carbon was exothermic (Delta H = -14.4 +/- 3.2 kJ mol(-1) for T = 2

113 , I(H(2)O), with O(2) is a 4-electron highly exothermic [DeltaE(gas) = 62.5 (DeltaE(gas) + DeltaG(sol

114 Adsorption using the P(i)-PBP resin was exothermic (DeltaH = -6.3 +/- 1.3 kJ/mol) and spontaneou

115 ta show that binding of pTppAp to RNase A is exothermic (DeltaH = -60.1 +/- 4.1 kJ/mol) with a dissoc

116 t was shown that the complexation process is exothermic (DeltaH degrees approximately -7.6 kcal mol(-

117 In potassium, association is highly exothermic (DeltaH(25 degrees C) = -41.6 +/- 1.2 kcal/mo

118 of formation of 1-[eta(2)-NCNMe(2)] is more exothermic (DeltaH(degrees) = -22.0 +/- 1.0 kcal mol(-1)

119 tal-bound product is calculated to be highly exothermic, DeltaH(reg) = -36.7 kcal/mol.

120 ith an extended lysine chain triggers highly exothermic dissociation by loss of ammonia from the Gly

121 dehydrogenation to form PtCH(2)(+) + H(2) is exothermic, efficient, and the only process observed at

122 te a mechanism in which the initial event is exothermic electron transfer from the hydrazone to (1)O(

123 rate at room temperature, as expected for an exothermic, electron tunneling reaction in RCs.

124 er of 22 +/- 3 kcal mol(-1) and is driven by exothermic elimination of DMSO.

125 Ni(II) and Cd(II) exhibited a characteristic exothermic-endothermic pattern that was used to infer th

126 ther high-affinity sites, which bind NC with exothermic energetics, binding to these sites occurs end

127 othermal titration calorimetry studies yield exothermic enthalpy changes (deltaH) for protonation of

128 statherin adsorption is characterized by an exothermic enthalpy of approximately 3 kcal/mol that dim

129 The exothermic enthalpy of complex formation varies with dif

130 The interaction is entirely driven by exothermic enthalpy, consistent with the abundance of po

131 The interaction is an exothermic event that is both enthalpically and entropic

132 l of the reactions were found to be strongly exothermic, expect the case of the sulfur dioxide-involv

133 The exothermic F + H(2)O --> HF + OH reaction has a decidedl

134 proportionation 2SiO(s) --> Si(s)+SiO2(s) is exothermic, falling right into the series of group 14 mo

135 nthalpies of the aminoglycosides become more exothermic (favorable) with increasing pH, an observatio

136 is higher than that reported previously for exothermic feedstock type.

137 dothermic for alkyl-substituted alkenes, but exothermic for conjugated alkenes (addition of an NHC-bo

138 rsistent RISC cofactor is significantly more exothermic for effective antiviral siRNAs than their ine

139 2O)(n+1) + H2O-->C6H5.(H2O)nH+ would also be exothermic for n > or = 4, but lack of H/D exchange with

140 + (H2O)nH+ is thermoneutral or exothermic for n > or = 4.

141 respectively, despite being 9 kcal/mol less exothermic for RSeOH.

142 s, in contrast to TIPS-tetracene, SF becomes exothermic for various PTD derivatives, which show S(1)-

143 l method indicate that reaction proceeds via exothermic formation of a primary nitrosamine intermedia

144 yl = methyl, isopropyl) proceeds via initial exothermic formation of an eta(2)-nitrile complex.

145 The exothermic formation of salt byproducts provides a drivi

146 h epsilon-Al(13) Keggin cluster compounds is exothermic from oxide-based components but energetically

147 protein); (2) binding to membranes was very exothermic (> -60 kcal/ mol of protein); and (3) binding

148 ker Fe=N pi-bonding) and thermodynamic (more exothermic HAT) effects.

149 pproximately 30 kcal/mol) in contrast to the exothermic heat (ca. -85 kcal/mol) generated upon bindin

150 g of apoA-I to SUV is accompanied by a large exothermic heat and deletions in the C-terminal regions

151 This exothermic heat arises from an approximately 25% increas

152 hilst the demethylation reaction provoked an exothermic heat change.

153 Titration calorimetry reveals an exothermic heat for the interaction glycosaminoglycans w

154 binding in a manner that compensates for the exothermic heat generated by alpha-helix formation.

155 can be seen as a partial cancellation of the exothermic heat of reaction of the hydrogenation with th

156 results from the compensation of a favorable exothermic heat with an unfavorable entropy contribution

157 roductivities are possible; because they are exothermic, heat is available for downstream protein pro

158 Our results reveal exothermic heats between -9.8 and -16.0 kcal/bp for temp

159 This is in excellent agreement with the exothermic heats of -16.8 kcal/mol and -25.7 kcal/mol fo

160 organic adsorbents, which show only moderate exothermic heats of binding, from -5 to -15 kJ/(mol I2).

161 Nanoparticles with exothermic heats of interaction were stabilized against

162 ing of K(+) to G-triplexes is accompanied by exothermic heats, and the binding of Ca(2+) with G-tripl

163 that yield highly stable cations by the most exothermic, hence least reversible 1,2-H shift.

164 heir respective hairpin cognate sequences is exothermic; however, changes in enthalpy, entropy, and h

165 .3 water molecules are still involved in the exothermic hydration of 2-oxopropanoic acid (PA) into it

166 ectron reduction in 1a(+) and 5a(+) triggers exothermic hydrogen atom migration from the terminal COO

167 h an endothermic hydrophobic interaction and exothermic hydrogen bond component.

168 Coupling exothermic hydrogenolysis with endothermic aromatization

169 owever, association of tetrahedral anions is exothermic in nature and both entropy- and enthalpy-driv

170 rsible monomer-dimer assembly that is highly exothermic in nature.

171 ylammonium metal formate series becomes less exothermic in the order Mn, Zn, Co, Ni.

172 Enthalpy of binding is less exothermic in the presence of metal-nucleotide.

173 er neat conditions and promoted by AlCl3, an exothermic in-line quench of high concentrations of prec

174 w that the binding mechanism changes from an exothermic independent two-site binding mechanism at pH

175 Haber cycle analysis of ITC data revealed an exothermic interaction between Rh(OH)3 nanoparticles and

176 bound by OlyA, is induced by stoichiometric, exothermic interactions with cholesterol, properties tha

177 te cleavage, and the second step is strongly exothermic, involving hydrolysis of an oxacarbenium ion

178 re-forming the COOH group and accomplishing exothermic isomerization of the initial (3H)-imidazole r

179 ecies vinylidene, and its subsequent, highly exothermic isomerization to acetylene, via electron remo

180 itration with [Co(NH(3))(6)](3+) resulted in exothermic isotherms with (dC-dG)(4) being more exotherm

181 (2) binding to membranes was relatively less exothermic (< -33 kcal/ mol of protein); and (3) binding

182 s an effective heat scavenger for the highly exothermic magnesium reduction process, promotes the for

183 be treated with caution, being of comparable exothermic magnitude to tosyl azide (TsN(3)).

184 this study reveal a structural basis for an exothermic maturation process probably present in many d

185 nergy upon cocrystallization agrees with the exothermic mixing of NIC and RMA liquids (a base and an

186 mic analysis reveals that the association is exothermic, more favorable in D(2) O than H(2) O, and in

187 HMX hydrolysis at pH 10 represents a highly exothermic multistep process involving initial deprotona

188 sistent with the absence of a barrier in the exothermic N-C bond forming reaction leading to the form

189 some experimental setups in which the highly exothermic nature of the fusion of two heavy-quark baryo

190 with increasing temperature, reflecting the exothermic nature of the process.

191 The discovery of this exothermic, net redox process was enabled by the simple

192 CAPTEAR process with Cu(NO3)2.2.5H2O uses an exothermic nitrate moiety to suppress empty-cage fullere

193 y binding shows a weaker affinity and a less exothermic or even endothermic enthalpy change.

194 The exothermic oxidative dehydrogenation of propane reaction

195 e-like" carbocation conformations provide an exothermic pathway to taxadiene and are validated by com

196 Each system exhibited exothermic pathways via formation of cyclic intermediate

197 The exothermic peak at 78.5 degrees C probably corresponds t

198 metry showed endothermic (123 degrees C) and exothermic peaks (192 degrees C).

199 dominated by favorable entropic changes, the exothermic phase has about 6.7 kcal/mol enthalpic advant

200 The initial exothermic phase of adsorption exhibited by native stath

201 l of bound Ni(2+) from PDF(Ec) abolished the exothermic phase without affecting the endothermic phase

202 through non-radiative energy dissipation and exothermic photochemical reactions.

203 plex for which the enthalpy of formation was exothermic, presumably because of DOPE amine group proto

204 herichia coli QueF binds preQ0 in a strongly exothermic process (DeltaH = -80.3 kJ/mol; -TDeltaS = 37

205 changes the folding enthalpy from a strongly exothermic process [e.g., DeltaH degrees = -26(2) kcal/m

206 ees = -26(2) kcal/mol at 180 mM] to a weakly exothermic process [e.g., DeltaH degrees = -4(1) kcal/mo

207 This is consistent with the existence of an exothermic process leading from the initial diyl to the

208 e, P22, showed that capsid maturation was an exothermic process that resulted in a release of 90 kJ m

209 air-free reaction proceeds via a significant exothermic process to form marcasite.

210 Mixing of water and DMF is an exothermic process where the micelle formation process o

211 he inclusion of rutin into HP-beta-CD was an exothermic process which occurred spontaneously.

212 results indicated that the adsorption was an exothermic process.

213 1), the dissociation of water becomes a very exothermic process.

214 riple bonded nitrogen completely in a highly exothermic process.

215 R by physisorption through a spontaneous and exothermic process.

216 d to proceed without barrier and is a highly exothermic process.

217 showed that apoE binding to emulsions was an exothermic process.

218 lization of the metal sulfide is a much less exothermic process.

219 fety concerns due to the reaction's inherent exothermic profile.

220 These states underwent facile exothermic proton migrations to form aminoketyl radical

221 in the model peptide dication, facilitating exothermic proton transfer from one of the two sites of

222 by ionization of saturated hydrocarbons via exothermic proton-transfer reactions involving highly ac

223 Exothermic pyrolysis of refuse, which is hypothesized to

224 gy via an activating molybdate kinase and an exothermic pyrophosphatase reaction to overcome a protei

225 he corrosive nature of triflic acid, and the exothermic quenching were addressed by designing a suita

226 preferred CO(2)-AlCl(3) complex forms in an exothermic reaction (-6.0 kcal/mol) as does CO(2)AlCl(2)

227 ediyne 1 is triggered by NADPH in a strongly exothermic reaction (-88 kcal/mol), which involves a num

228 in two exemplary applications: First, a fast exothermic reaction (Michael addition) was monitored wit

229 ed proteins catalyzed by HlyC was overall an exothermic reaction driven by a negative enthalpy.

230 trong binding enables a quark-rearrangement, exothermic reaction in which two heavy baryons (Lambdac)

231 l remains a significant challenge due to the exothermic reaction nature.

232 three solvents that lead to endothermic and exothermic reaction processes, and we show that within t

233 ~ um spatial resolution as applied to highly exothermic reaction propagation to directly observe reac

234 calculated activation barrier for the highly exothermic reaction to a classical Lewis structure never

235 id and thereby stabilized against the highly exothermic reaction with atmospheric oxygen.

236 acetyl-lysine-bearing peptides revealing an exothermic reaction with relatively little discriminatio

237 -I interaction with POPC/SM SUVs produces an exothermic reaction, characterized as nonclassical hydro

238 Binding and cleavage is an exothermic reaction, while binding to D99 has negligible

239 diastereoselectivity unusual for a strongly exothermic reaction.

240 which involves propagation of self-sustained exothermic reactions along an aqueous or sol-gel media.

241 Exothermic reactions and photons generate hot electrons

242 This growth can be attributed to the exothermic reactions going inside the remnant.

243 trolyte interfaces breakdown, uncontrollable exothermic reactions in electrodes and Joule heating can

244 olution of few muW as required to follow low exothermic reactions like oxidation.

245 Here, we report that exothermic reactions of fluorine (F) atoms in d3-acetoni

246 Our ab initio calculations identify new exothermic reactions of KHP forming a cyclic peroxide is

247 nique can be applied more generally to other exothermic reactions that are not readily accessible to

248 inst conventional notions that expect highly exothermic reactions to be irreversible.

249 ze to 1H-diazirenes of the type 24 in mildly exothermic reactions with activation energies in the ran

250 ipyridine, were calculated to undergo highly exothermic reactions with ArN3 to form the nitrene activ

251 hemical heaters are electricity-free and use exothermic reactions.

252 electron transfer, this time being a highly exothermic reduction of the rearranged species to genera

253 ity, low tendency for carbon deposition, and exothermic reduction reactions.

254 The exothermic S(N)2 reaction is inefficient compared with p

255 initiation steps is subsequently utilized in exothermic secondary reactions, leading finally to forma

256 ading axis, and may be driven by the heat of exothermic serpentinization reactions between sea water

257 ion and that this is true for both endo- and exothermic singlet fission materials.

258 Exothermic solution energies calculated for tetravalent

259 on the entire nervous system, especially in exothermic species.

260 The global reaction is exothermic, spontaneous, permitted by enthalpy, and proh

261 ored energy when needed through a reversible exothermic step.

262 The reaction sequence involved two exothermic steps where the standard procedure demands sl

263 ic proton-transfer reaction with a competing exothermic substitution (S(N)2) channel, F(-) with boran

264 ithium leading to polylithiated benzenes are exothermic, suggesting that it may be posible to prepare

265 thermic isotherms with (dC-dG)(4) being more exothermic than (dm(5)C-dG)(4) by 720 cal/mol basepair.

266 with both Al metal and Al clusters are more exothermic than are reactions of Cl2 with them.

267 roton transfer is usually significantly more exothermic than electron transfer.

268 etween -20 and -30 kJ mol(-1), slightly more exothermic than enthalpies of condensation (-16.1 kJ mol

269 action energy of SB-3CT is 8.0 kcal/mol more exothermic than that of its oxirane analogue.

270 nts to the substituted CHTE species are more exothermic than that of the parent PC.

271 with lower activation barriers and are more exothermic than the analogous process involving the pare

272 of the C-F bond at the metal is usually more exothermic than the corresponding reaction of the C-H bo

273 ase of -63 kcal/mol and is considerably more exothermic than the ECO2 path whose energy release is -2

274 HF)(3)-3(C) x (THF)(3) are 6-8 kcal/mol less exothermic than the experimentally determined values in

275 because the second ion-pairing step is more exothermic than the first, and the reduction of [KA] (A

276 the reduction of [KA] (A = COT, NB) is more exothermic than the reduction of A(-1).

277 C scission with the loss of CO(2) is usually exothermic, the C-S scission with the loss of SO(2) is g

278 action of neutral 1 is computed to be highly exothermic, the finding that 1*- apparently does not und

279 nd subjected to DSC analysis, they underwent exothermic thermodenaturation with transition temperatur

280 In particular, garnet minerals undergo exothermic transformations near this depth, acting to co

281 a small hump near 60 degrees C, and a broad exothermic transition at 78.5 degrees C, whereas the PPC

282 This exothermic transition disappears in the subsequent heati

283 eprocessing protocol, it is likely that this exothermic trapping process proved to be a tipping point

284 hydro-phenanthrene intermediate, followed by exothermic unimolecular isomerization to a 9,10-dihydrop

285 yield markedly distinct ITC profiles (i.e., exothermic versus endothermic) upon interaction with act

286 thermodynamic point of view, the reaction is exothermic whatever the substituent R (from approximatel

287 (oxy)anions (As, B, and PO4) is consistently exothermic, whereas surface complexation of cations (Ca

288 use, radical chlorination is barrierless and exothermic, whereas the analogous hydroxylation is found

289 t different sites on VO2.CeO2(111) is highly exothermic with adsorption energies of 1.8 to 1.9 eV (HS

290 Complexation is exothermic with large negative entropy, consistent with

291 uid crystalline temperature, partitioning is exothermic with negative changes in entropy.

292 from endothermic with the wild-type hSBDb to exothermic with the hSBDb* variant.

293 the syncon promoter to the RNA polymerase is exothermic, with a binding constant (K(b)) = 2.1 +/- 0.2

294 ated and the results suggest the reaction is exothermic, with a calculated overall energy change betw

295 The substrate binding step is exothermic, with a DeltaG of -5.2 kcal/mol at 37 degrees

296 rriers, and the reactions are computed to be exothermic, with all intermediates and transition states

297 The binding of PutA52 to operator 2 is exothermic, with an enthalpy of -1.8 kcal/mol and a diss

298 he release of 2.5 protons, which is slightly exothermic, with DeltaHrxn of -2.0 kcal mol-1, and large

299 Crystallization of the capsules is highly exothermic, with the most favorable DeltaH(cryst)(o) of

300 Binding to serum albumin is exothermic, yielding enthalpies (DeltaH(obs)) of -3 to -