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1 oride, sodium monofluorophosphate, or sodium fluoride).
2 mercially available polymer, poly(vinylidene fluoride).
3 combination of oxalyl chloride and potassium fluoride.
4 p to four NH hydrogen-bond donors (HBDs) for fluoride.
5 lium atoms from an atomic lattice of lithium fluoride.
6 ediate that undergoes subsequent trapping by fluoride.
7 by desulfurative fluorination with silver(I) fluoride.
8 clinically relevant concentrations of (18)F-fluoride.
9 tries, attributable to the widespread use of fluoride.
10 valent hNE inhibitor: benzene-1,2-disulfonyl fluoride.
11 Ti(3+), d(1) site, and one type of bridging fluoride.
12 le organic iodides, bromides, chlorides, and fluorides.
13 used functional aryl substituents, including fluorides.
14 associated with the low reactivity of metal fluorides.
15 lization of the corresponding amino sulfonyl fluorides.
16 catalysts for fluorination with alkali metal fluorides.
17 to access both the E and Z isomers of vinyl fluorides.
18 emission tomography (PET) using (18)F-sodium fluoride ((18)F-fluoride) to detect microcalcification m
19 tion 1 h after the injection of (18)F-sodium fluoride ((18)F-NaF) at 248 +/- 10 MBq (mean +/- SD) and
21 ystal structures, we elaborated arylsulfonyl fluoride 2 to 12, which to our knowledge is the first co
22 showed large beneficial effects compared to fluoride (3.93; 0.34-7.53) with moderate certainty; for
24 fluorobenzyl palladium(II) complexes undergo fluoride abstraction followed by 1,1-migratory insertion
26 study on the general suitability of silicon-fluoride-acceptor (SiFA)-conjugated radiopharmaceuticals
27 oach is presented to access arynes and their fluoride-activated precursors based on Ru-catalyzed C-H
29 an-rescan reproducibility of increased (18)F-fluoride activity in coronary atherosclerotic plaque.
32 opening reaction in the presence of aluminum fluoride (AlF(3) ) to create SPEs inside LiNi(0.6) Co(0.
33 d evidence of superiority against placebo or fluorides (amine fluoride, sodium monofluorophosphate, o
34 its four NH groups in hydrogen bonding with fluoride, an arrangement that allows effective phase-tra
36 in magnesium flanking a core rich in sodium, fluoride and carbonate ions; this sandwich core is surro
37 luorspar (CaF(2)), the precursor to hydrogen fluoride and fluorine, has embarked on an industrial ini
39 route to [(18)F]CF(3)SO(2)NH(4) from [(18)F]fluoride and its application to direct [(18)F]CF(3) inco
40 ance, which unequivocally identifies lithium fluoride and lithium alkylcarbonates as the main chemica
41 tonated form shows considerable affinity for fluoride and perchlorate, which in turn affects the isom
45 he continuous growth of poorly conducting Li fluorides and carbonates to ensure efficient Li(+) trans
46 ifluoromethyl)sulfur oxyimines from sulfonyl fluorides and iminosulfur oxydifluorides, respectively.
48 (WFs) are a complex mix of metallic oxides, fluorides and silicates that can cause or exacerbate hea
50 efined Z- and E-alkenyl chlorides, bromides, fluorides, and boronates or Z-trifluoromethyl-substitute
54 or non- and microinvasive caries treatment (fluoride- and nonfluoride-based interventions) is to man
55 n-group cations are highly selective for the fluoride anion, which is transported more than 20 times
56 with Mo(6+) coordinated by two cis bridging fluoride anions that are trans to terminal oxide anions.
58 s that the three hydrogen-bond contacts with fluoride are not equal in terms of their contribution to
63 ng primary, secondary, and tertiary benzylic fluorides as well as unactivated tertiary fluorides, tha
64 ith relaxor-like behavior in poly(vinylidene fluoride), as required for high energy storage density,
65 talytic S(N) Ar reaction of unactivated aryl fluorides at ambient temperature without strong base is
67 olving alkyl-group migration, intermolecular fluoride attack is product- and enantio-determining.
69 is proposed to produce beta-poly(vinylidene fluoride) (beta-phase content: ~98%) with relaxor-like b
71 ea catalysts undergo urea isomerization upon fluoride binding and form dynamically rigid trifurcated
72 n/proton exchanger ClC-ec1 and observed that fluoride binds incoming protons within the selectivity f
73 eered P. putida is demonstrated with mineral fluoride both as only fluorine source (i.e. substrate of
74 on measurements, the partial substitution of fluoride by cyanide ligands leads to a marked increase i
75 nt functionality about the benzylic tertiary fluoride by virtue of the diversity of both reaction par
76 -PSMA-11 using direct labeling with aluminum fluoride can be produced in NH(4)OAc, pH 6.9; shows a hi
77 responded strongly to low concentrations of fluoride, carbonate, and acetate ions, weakly to phospha
80 in solution, but with smaller halide anions (fluoride, chloride, and bromide), the catalysts fold aro
81 s on both the arene and the olefin including fluoride, chloride, trifluoromethyl, ester, nitro, aceta
82 oromethylsulfonyl)imide, and poly(vinylidene fluoride-co-hexafluoropropylene) as the ion exchange gel
84 tructure and properties of the carbonic acid-fluoride complex, F(-)(H(2)CO(3)), and its deuterated is
86 nsight into how the countercation influences fluoride complexation is provided based on NMR data char
87 ity of high-oxidation-state transition-metal fluoride complexes combined with the use of directing gr
88 ynamically rigid trifurcated hydrogen-bonded fluoride complexes that are structurally similar to thei
89 ey revealed the clear relation between water fluoride concentration, and therefore fluoride exposure,
92 f using tetralactam macrocycles to stabilize fluoride-containing liquid electrolytes within redox dev
93 ified for dental fluorosis were ingestion of fluoride-containing toothpaste, water fluoridation, fluo
94 (test) or (2) toothpaste containing 1450 ppm fluoride (control), and were instructed to brush with th
95 tertiary alkyl bromide, chloride, ester, and fluoride could therefore be easily prepared in only thre
101 covalent bond formation by an aryl sulfonyl fluoride electrophile at a tyrosine residue (Tyr-82) inh
102 molecules, each bearing a sulfuramidimidoyl fluoride electrophile, with human cell lysate, and the p
103 de range of gem-difluoroalkenes through beta-fluoride elimination of the generated alpha-CF(3) carban
104 al approach to O-sulfation by the sulfur(VI) fluoride exchange (SuFEx) reaction between aryl fluorosu
108 Policies were introduced to reduce excessive fluoride exposure during the period of tooth development
110 dental fluorosis, we analyzed the effects of fluoride exposure in enamel cells to assess its impact o
111 water fluoride concentration, and therefore fluoride exposure, and prevalence and severity of dental
112 irreversible and potentially severe forms of fluoride (F(-)) toxicity such as skeletal fluorosis bein
113 transport various ions of interest, such as fluoride (F(-)), potassium (K(+)), calcium (Ca(++)), and
115 lyl pyrrole latent nucleophiles with allylic fluorides followed by hydrogenation and diastereoselecti
119 ary drinks between meals, 4) receive topical fluoride from a health professional, 5) visit the dentis
120 served steps including elution of the [(18)F]fluoride from an anion exchange cartridge with a basic s
121 n site and an industry lab purchasing [(18)F]fluoride from an outside vendor), and provides [(18)F]FD
122 h strength of the C-F bond, the departure of fluoride from metabolic intermediates can be facile.
123 date, the direct preparation of [(18)F]-aryl fluorides from aryl halides remains limited to S(N)Ar re
124 l, and practical procedures to prepare vinyl fluorides from readily available precursors remains a sy
125 click derivatization of the pendant sulfonyl fluoride group in 96 well-plates-demonstrating the versa
126 nucleophilic fluorination with metal alkali fluoride has been accomplished with BINAM-derived bisure
129 e fed low dose fluoride (LF(-)) or high dose fluoride (HF(-)) and given intrauterine injections of li
130 biofluorination are wired to the presence of fluoride (i.e. circumventing the need of feeding expensi
131 total fluorine (TF) analysis, and inorganic fluoride (IF) analysis was applied to disclose the chemi
132 of cyclic enediynes using tetrabutylammonium fluoride in an acetone/water mixture and the investigati
133 ing aluminum nitrate, potassium and ammonium fluoride in an acid medium, with reduction of the reagen
134 e resulted in decreased cell viability under fluoride in both the planktonic state and single-/dual-s
135 nformation on hydrogen-bonding networks with fluoride in solution, as well as how these arrangements
137 col that allows a single substitution of one fluoride in trifluoromethyl groups with neutral phosphin
138 rovides access to a broad range of aliphatic fluorides, including primary, secondary, and tertiary be
142 rting ligands, diamagnetic Ni(IV) sigma-aryl fluoride intermediates can be detected spectroscopically
143 ) at super-concentration, leading to lithium fluoride interphase formation, while precipitation of th
145 as proposed for the on-site determination of fluoride ion (F(-)) with high sensitivity and accuracy.
148 ynthesis of [(18)F]fluoromethane from [(18)F]fluoride ion and then cobalt(III) fluoride mediated gas
150 ors: Michael addition, enamine addition, and fluoride ion elimination followed by conjugate addition.
151 e efficacy of the dyes as probes, a turn-off fluoride ion probe was prepared from 3C, which consisted
152 s consistent with results showing incomplete fluoride ion release (up to 53% of the F content in AFFF
155 onged consumption of water contaminated with fluoride ions (F(-)) at concentrations exceeding 1.5 ppm
163 The ammonium salt tetra-n-butylammonium fluoride is simply admixed with the conjugated polymer p
165 n ascribed principally to stabilization of a fluoride leaving group (LG) in covalent reactions of sul
168 ium anode is suppressed by forming a lithium fluoride (LiF)-enriched solid electrolyte interphase (SE
174 tasurface of microstructured poly(vinylidene fluoride) membrane, referred to as a "meta-skin" insulat
175 cused chemical screen revealed that the aryl fluoride motif on YJH08 is essential for high-affinity G
176 the interobserver agreement in (18)F-sodium fluoride (NaF) PET/CT for the detection of bone metastas
177 ts, and changes in quantitative (18)F-sodium fluoride (NaF) positron emission tomography/computed tom
178 )F-fluorodeoxyglucose (FDG) and (18)F-sodium fluoride (NaF) uptake in culprit versus nonculprit carot
180 cetuximab was performed, and (18)F-aluminium fluoride-NOTA-Z(EGFR:03115) (12 mug, 1.5-2 MBq/mouse) wa
181 ater had been the only significant source of fluoride, now there are many, and this led to an increas
182 insoluble CsF and KF into solution, control fluoride nucleophilicity, and provide a chiral microenvi
183 can be achieved from the free alcohols using fluoride or silanolate, allylic acetate precursors to 5-
184 um salts with in situ formed carboxylic acid fluorides or 2-pyridyl esters under reducing conditions
185 an amine (propargylamine and ethanolamine), fluoride, or a nucleoside monophosphate (uridine monopho
188 enerate bioprosthetic valves displayed (18)F-fluoride PET uptake that colocalized with tissue degener
189 sel coronary atherosclerosis underwent (18)F-fluoride PET-computed tomography angiography and compute
190 was to determine if additional (18)F-sodium fluoride PET/CT (NaF PET/CT) improves the prognostic acc
191 This study tested the hypothesis that (18)F-fluoride PET/CT can identify early microcalcifications.
193 t broadly cover metal oxides, chalcogenides, fluorides, phosphides, nitrides, and silicates with spec
194 The authors sought to assess whether (18)F-fluoride positron emission tomography (PET)-computed tom
195 with increased morbidity and mortality.(18)F-fluoride positron emission tomography (PET)/computed tom
198 or 16 different substituents, by determining fluoride production rates, quantum yields, and half-live
199 id fluoride substitution to generate allylic fluoride products with excellent levels of branched-to-l
200 igh Lewis basicity and small ionic radius of fluoride promote the formation of strong ionic hydrogen
201 rinciple of sensing strategy is based on the fluoride-promoted Si-O bond cleavage of 2-(tert-butyldip
202 [(11) C]carbonyl difluoride over silver(II) fluoride provides easy access to this new synthon in rob
203 phate) (PB2MP) functionalised polyvinylidene fluoride (PVDF) track-etched membranes, PB2MP-g-PVDF, wa
204 focus on materials involving polyvinylidene fluoride (PVDF), and also discussed both their current a
205 R mutant was used for RNA-sequencing and the fluoride related permease gene (frtP) was found as 1 of
206 was constructed and the transcription factor fluoride related transcriptional regulator (FrtR) was id
209 ubations, while total fluorine (organic plus fluoride) remained constant throughout the incubations.
210 yster shells can be an effective sorbent for fluoride removal, with the added benefit of re-use of a
212 rategies for unmodified peptides with [(18)F]fluoride require (18)F-labeled prosthetics for bioconjug
214 olabeled IL2 variants, namely aluminum (18)F-fluoride-(restrained complexing agent)-IL2 ((18)F-AlF-RE
216 In the presence of a highly concentrated, fluoride-rich electrolyte, the inner SEI layer has an el
218 scourage the dissolution of Cr in the molten fluoride salts which is widely recognized as the mechani
219 We showcase 2-Substituted-Alkynyl-1-Sulfonyl Fluorides (SASFs) as a new class of connective hub in co
221 iocontainment strategy leveraging engineered fluoride sensitivity and DNA vectors enabling use of flu
224 lls and an enamel cell line (LS8) exposed to fluoride showed decreased internal Ca(2+) stores and sto
226 evidence (SMD; 95% CI): potassium + stannous fluoride (SnF(2)) (3.05; 1.69-4.41), calcium sodium phos
227 eriority against placebo or fluorides (amine fluoride, sodium monofluorophosphate, or sodium fluoride
228 electrospray ionization of an aqueous sodium fluoride solution in the presence of gas-phase carbon di
229 e of an iridium(I) catalyst and nucleophilic fluoride source (Et(3)N.3HF), allylic trichloroacetimida
230 -bromostyrenes, utilizing HF-pyridine as the fluoride source and m-CPBA as the stoichiometric oxidant
234 t ages 9, 13, 17, and 23 as part of the Iowa Fluoride Study, which has followed a cohort from birth.
236 allylic trichloroacetimidates undergo rapid fluoride substitution to generate allylic fluoride produ
237 to make a prediction on whether a given aryl fluoride substrate favors a concerted or stepwise mechan
239 of this study was to explore the effects of fluoride supplementation using a mouse model of preterm
241 r combo consisting of tannic acid and sodium fluoride (TA-NaF), which exhibits clear synergistic inhi
242 e-containing toothpaste, water fluoridation, fluoride tablets (which were sometimes ingested in areas
245 triclosan + 2.0% PVM/MA copolymer + 1450 ppm fluoride (test) or (2) toothpaste containing 1450 ppm fl
246 catalytic decarbonylative borylation of acid fluorides that proved applicable to a variety of (hetero
247 ed covalent docking to identify arylsulfonyl fluorides that target a noncatalytic lysine (Lys162) in
248 ic fluorides as well as unactivated tertiary fluorides, that are typically inaccessible by nucleophil
249 ence of external stimuli (tetrabutylammonium fluoride), the organogel of 1 disassembles into sol.
251 erstanding Streptococcus mutans' response to fluoride, the mechanism regulating intrinsic fluoride to
252 agnetic ordering of U(IV) atoms in a complex fluoride through the incorporation of 3 d transition met
253 d electrolyte interphase composed of lithium fluoride, tin, and the tin-lithium alloy is formed, whic
254 35 (33.7%) patients who had increased (18)F-fluoride (tissue-to-background ratio, 2.32 [95% CI, 1.81
255 catalyst system requires tetramethylammonium fluoride (TMAF) and [Fp(THF)][BF(4)] (Fp = Fe(eta(5)-C(5
256 t equilibrium binding of a sulfuramidimidoyl fluoride to a protein can allow nucleophilic attack by a
257 rained linker, which orients an arylsulfonyl fluoride to react rapidly and enantioselectively with Ly
258 t has been demonstrated that the addition of fluoride to the resulted complex induces the release of
259 phy (PET) using (18)F-sodium fluoride ((18)F-fluoride) to detect microcalcification may provide insig
263 triclosan was more effective than a regular fluoride toothpaste in improving the periodontal clinica
264 hing mechanism involving direct and indirect fluoride transfer from a CF(3) anionoid to TMSCF(3) (1)
265 ormed in situ, allows effective nucleophilic fluoride transfer to a range of primary and secondary al
267 achieve high EC strength in poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene)-based n
268 for determining total (TF) and total soluble fluorides (TSF) in 5 child formula dentifrices (CFD) usi
270 ssion of sub-15 nm alkaline-earth rare-earth fluoride UCNPs (M(1-x) Ln(x) F(2+x,) MLnF) with a CaF(2)
271 tor AEBSF (4-[2-aminoethyl] benzene sulfonyl fluoride) up-regulated full-length Dicer, both in MM6 ce
272 remained unchanged in segments without (18)F-fluoride uptake (from 46 [16-113] to 49 [20-115] AU; P=0
273 ly increased in coronary segments with (18)F-fluoride uptake (from 95 [30-209] to 148 [61-289] AU; P<
274 , and to categorize increased coronary (18)F-fluoride uptake and determine its reproducibility has ye
275 o investigate the relationship between (18)F-fluoride uptake and progression of coronary calcificatio
284 electrochemical approach to prepare sulfonyl fluorides using thiols or disulfides, as widely availabl
286 are regimen (periodic prophylaxis and serial fluoride varnish applications) appropriate for the manag
289 the non-invasive imaging radiotracer, (18)F-fluoride, was highly selective for hydroxyapatite deposi
290 , and multifunctional cyclic alkenylsulfonyl fluorides were efficiently prepared from the correspondi
294 showed large beneficial effects compared to fluoride with moderate certainty of evidence (SMD; 95% C
297 decarbonylative coupling of carboxylic acid fluorides with diboron reagents to selectively afford ar
298 or-like behavior observed in poly(vinylidene fluoride) with high molecular weight > 534 kg mol(-1), w
299 .F(-)] reveals that the encapsulation of one fluoride, within 3, occurs through NH...F(-) H-bonding w