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1 ) reaction coordinate is best designated as "forbidden".
2 vector by the ferroelectric polarization was forbidden.
3 tter interactions that are typically weak or forbidden.
4 radical ion pair A*-D*+ is thermodynamically forbidden.
5 ngth as previously calculated, are optically forbidden.
6 ons in the natal cloud core is energetically forbidden.
7 enticity of hay milk where silage feeding is forbidden.
8 diffusion of C(2) H(2) is electrostatically forbidden.
9 for which relaxation to the ground state is forbidden.
10 he transfer of other available H is symmetry-forbidden.
11 hich are traditionally considered as quantum-forbidden.
12 nsitions arising from hole doping are dipole forbidden.
13 of distillation boundaries that are normally forbidden.
14 into [Tp(tBu,Me)Cr(V)(O)2] (S = 1/2) is spin-forbidden.
15 the perception that targeting of MYC-MAX is forbidding.
16 )/mnm tetragonal, and a crystallographically forbidden 12-fold symmetry liquid quasicrystal) and prov
17 hat heteroatom substitution has on thermally forbidden [2 + 2] addition reactions using high-level de
19 ition to the quartet ground state being spin-forbidden, a contrast to most first-row literature examp
24 the active conformation of the kinase is not forbidden and can be visited transiently, it is not the
29 ed to norbornene, the energy gap between the forbidden and the allowed transition state is only 4.1 k
30 cyano-bearing carbon atom from (-)-trans-1, "forbidden" and the result of zero internal rotations fro
31 It suggests to avoid attributing graft with forbidden antigens to sensitized candidates with Luminex
32 s that can change people's behaviour without forbidding any options or significantly changing their e
34 particle (QP) orbits of two bands, which are forbidden as half of the trajectory would oppose the Lor
36 -1 by reconstitution with B cells containing forbidden, autoreactive clones provides direct evidence
37 pertoire reacts to self-antigens, and these "forbidden" B cells are culled by immunological tolerance
38 uartet state, persists for 67 ns due to spin-forbidden back-electron transfer, constituting a more th
41 ) reductions occurred at energies within the forbidden bandgap, while the three [Ru(bpy)(3)](2+) redu
42 oncerted pericyclic reactions are allowed or forbidden based on the number of electrons involved and
45 ects more likely to judge harmful actions as forbidden, but only in cases where harms were emotionall
46 the superradiant phase transition (SRPT), is forbidden by a no-go theorem due to the existence of the
48 dynamical phases(2-8) that may otherwise be forbidden by equilibrium thermodynamics, a paradigmatic
51 ve atomic transition that would otherwise be forbidden by established spectroscopic selection rules.
55 te melting stages of long-chain crystals are forbidden by steric overcrowding at the crystal-liquid i
56 tion from the ground state (S(0)) to S(1) is forbidden by symmetry, making a determination of the S(1
59 ith H2 to yield ground-state HCl products is forbidden by the Born-Oppenheimer (BO) approximation.
60 mmetry) to the QBS (A(g) symmetry) is triply forbidden by the electric and magnetic dipoles and the e
61 erfect copying of unknown quantum systems is forbidden by the laws of quantum mechanics, approximate
64 ic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a ma
65 al benzene derivatives are associated with a forbidden character and show marked vibrational progress
67 generalized to the microlasers based on the forbidden clock transitions, holding the prospect for mi
68 rance, clonal selection of lymphocytes, and "forbidden clones" of activated immune cells were forming
71 ut 100 degrees ) but explores the previously forbidden conformational space around the syn conformati
72 ucture is the transition state) and symmetry-forbidden conrotatory ring closing (whose transition sta
73 ll-optical storage and retrieval of the spin-forbidden dark exciton in a quantum dot from the ground
74 ond ultraviolet pulses can energize a parity-forbidden dark exciton state in black phosphorus while m
75 non interaction selectively couples the spin-forbidden dark exciton to the intravalley spin-allowed b
77 We obtained a direct visual of the momentum-forbidden dark excitons and studied their properties, in
79 , such a capability could probe the momentum-forbidden dark excitons, which critically affect propose
83 tant precedent for extremely rapid, formally forbidden (DeltaS = 2) nonradiative relaxation as well a
86 and is responsible for slowness of the spin-forbidden deprotonation of (1)HNO by OH(-); the spin pro
87 reaction with (3)O(2), the kinetics of spin-forbidden deprotonation reaction (1)HNO + OH(-) --> (3)N
88 t recurrent unwanted thoughts; attraction to forbidden desires; expression of objectionable social pr
90 ry electrocyclic ring-opening, (2) thermally forbidden disrotatory electrocyclic ring-opening, or (3)
92 nical advantage in accelerating the symmetry forbidden disrotatory ring opening of benzocyclobutene (
99 etric molecules should display alternatively forbidden electronic transitions; however, for organic f
100 ce can play an important role in allowing or forbidding electrons from passing through a system.
102 particle-hole continuum, extending into the forbidden energy gap that is free from particle-hole exc
103 Interband tunnelling of carriers through a forbidden energy gap, known as Zener tunnelling, is a ph
107 We report the observation of a symmetry-forbidden excited quadrupole-bound state (QBS) in the te
108 s is furnished through a low-lying optically forbidden excited state, populated through internal conv
112 eriodic pattern whose rotational symmetry is forbidden for periodic crystals (such as five-fold symme
113 ation, and we have also concluded that it is forbidden for the water molecule to form a hydrogen bond
116 however, the result of a formally "symmetry-forbidden" fragmentation is observed yielding cis,cis-cy
119 ndesirable energy sink because they are spin-forbidden from emitting light and their high binding ene
121 homo-nuclear spin pairs are both diluted and forbidden from forming strongly coupled, nearest-neighbo
123 nd a trend is found toward a reduced allowed/forbidden gap as the planarity of the cyclobutene is enf
126 tood, and unexplained phenomena such as the "forbidden gap" in the nano capillary rise (unreachable h
127 ple sharp photoluminescence emissions in the forbidden gap, which are related to defects localized ar
131 law of extraordinary photons is modulated by forbidden gaps near the boundaries of photonic Brillouin
132 ub-Tg annealing can be combined to access a "forbidden glass" regime that is inaccessible through the
133 ption mechanisms across the petawatt regime, forbidding high absorption values at low laser power and
134 s give high optical gap materials owing to a forbidden HOMO to LUMO transition, yet have narrow elect
137 ected flexibility allowing activation of the forbidden IFN-gamma gene after reactivation and growth.
139 resselhaus-like spin polarizations which are forbidden in any sample with two-fold rotational symmetr
140 Quasicrystals permit symmetry operations forbidden in classical crystallography, for example five
141 tations of the Bogoliugov quasiparticles are forbidden in conventional Bardeen-Cooper-Schrieffer supe
144 -active phonons is conventionally considered forbidden in inversion symmetric quantum materials, the
145 accurate identification of five meat species forbidden in Islamic foods in a single assay platform.
146 less particles, backscattering is completely forbidden in Klein tunnelling, leading to perfect transm
151 e in pure PbTiO(3); whereas the Raman lines (forbidden in the cubic phase) remain until ca. 17 GPa, w
153 oldenone and androstadienedione to cattle is forbidden in the European Union, while prednisolone is p
155 magnetoelectric couplings that are symmetry-forbidden in the parent compounds, LiNiPO(4) and LiFePO(
156 ement by purely local control is however not forbidden in the presence of non-Markovian dynamics, and
157 (chiral) rotation of a mechanical ratchet is forbidden in thermal equilibrium, but becomes possible i
162 pological domain boundary, allowing normally forbidden interactions between at least three forebrain-
164 in Global Health Assistance (PLGHA) policy, forbidding international organizations receiving all U.S
166 a conventional CCD-based Raman spectrometer forbids its applications under extreme conditions, inclu
167 olerance of diverse beliefs and behaviors by forbidding judgment on foreign societal codes of conduct
172 This theory reveals that conventionally forbidden light-matter interactions--such as extremely h
175 and ecological trait mismatches constraints (forbidden links hypothesis), and how these processes str
176 portance of morphological traits, beyond the forbidden links hypothesis, in structuring interactions
177 s of unfeasible species interactions, termed forbidden links, due to physiological or morphological e
180 ible-absorbing rhodopsins, with an optically forbidden low-lying S(1) excited state that has Ag(-) sy
184 orption lineshapes are modified, or infrared-forbidden modes are detectable as a modulation of the el
186 ight-matter states emerge that enable dipole-forbidden multi-quantum transitions at integer and fract
187 f nitrogen to the metal cation causes the IR-forbidden N-N stretch of N2 to become active in these co
188 slow magnetic relaxation driven by the spin-forbidden nature of quantum tunneling of the f-electron-
189 hole pairs) are 'dark states' because of the forbidden nature of the direct optical transition betwee
192 of active galactic nuclei), as well as semi-forbidden nebular lines tracing gas densities higher tha
194 paipai* excited state instead of the dipole-forbidden npai* state, the quantum yield of isomerizatio
195 intermolecular interactions that perturb the forbidden O(2)(a(1)Delta(g)) -> O(2)(X(3)Sigma(g)(-)) tr
198 in single-layer WSe(2), which involves spin-forbidden optical transitions with an out-of-plane dipol
201 rventions promoting healthy behavior without forbidding options or substantial incentives; the Apple
202 potential energy surfaces so that otherwise forbidden or slow processes proceed under mild condition
203 f the increments of pH reduction revealed no forbidden ordinal patterns, implying that the phagosomal
204 In this work, with parathion, a typical forbidden organophosphate pesticide as target drug, an e
205 ompletely dark, the other one is only dipole forbidden out-of-plane, hence referred to as grey excito
206 y on the use of materials or structures that forbid outgoing waves-that is, mirrors, which are often
209 g also becomes strongly affected, making the forbidden oxirane-type photoproduct to decay more effici
210 complex formation, which revealed a formally forbidden pathway in [2+2] cycloaddition reactions of ma
213 ong both their symmetry-allowed and symmetry-forbidden pathways, which enables us to quantify just ho
214 c shift is an example of an orbital-symmetry forbidden pericyclic reaction that is outcompeted by the
216 Fourth Lateran Council, a papal edict which forbade physicians (most of whom where clergy) from perf
217 sitizers studied herein, is no longer a spin-forbidden process and becomes highly sensitive to solven
218 do not show N-N coupling (since it is a spin-forbidden process), the hs-Fe(II)/{Fe(NO)(2)}(9/10) DNIC
225 stent with a pathway that overcomes the spin forbidden reaction of (3)O(2) with the bound singlet sub
226 tate will be much more efficient than the BO-forbidden reaction of the excited spin-orbit state.
229 thermore, our results indicate that the spin-forbidden reactions of (3)O2 with closed-shell clusters
230 by lowering the barrier to the formally spin-forbidden reactions of triplet dioxygen with the closed
231 ligand addition) is proposed for these spin forbidden reactions that gives good agreement with the n
232 rimental benchmarks for mechanically induced forbidden reactions, and in some cases suggest revisions
234 -molecule pathway analysis of 'allowed' and 'forbidden' reactions reveals that sulfur-sulfur substitu
238 s provide insight into the thermodynamically forbidden region of the antiferroelectric transition in
241 ve electrochemical reactivity in classically forbidden regions, e.g., insulating solvents and gases.
243 bulge of the epsilon signal and generates a "forbidden" residue at the -3 position of the signal pept
247 the ~0.1 s timescale of the experiments, the forbidden ring-opening reactions of benzocyclobutene, ge
248 exploring substituent effects in allowed and forbidden ring-opening reactions of cyclobutene (CBE) an
249 evirapine complex revealed how NNRTI binding forbids RT from forming a polymerase competent complex.
253 derive the dissociation energy for the spin-forbidden SO(3)(X(1)A(1)') -> SO(2)(X(1)A(1)) + O((3)P)
254 tion from a thermally allowed to a thermally forbidden spin-orbit entangled quadrupolar ordered state
257 imethylcyclohexenes through orbital symmetry-forbidden suprafacial,retention and antarafacial,inversi
260 ranges in which the propagation of light is forbidden-that make them well-suited to the scientific a
261 g site close to the symmetry axes sterically forbids the binding of more than one Fab molecule per sp
262 ntum fluids, the quantization of circulation forbids the diffusion of a vortex swirling flow seen in
266 ting, ordering, and counting compulsions; 2) forbidden thoughts: aggression, sexual, religious, and s
267 nglet finer states (m(z) = 0) were no longer forbidden, thus some o-Ps converts to p-Ps spontaneously
269 e measurements and because such fermions are forbidden to exist in conventional materials harbouring
270 rmations of GlyB20 and GlyB23 are ordinarily forbidden to L-amino acids, turn architecture may contri
271 asiperiodic atomic structures and symmetries forbidden to ordinary periodic crystals-e.g., 5-fold sym
272 ine-2,4-dioxygenase (HOD) catalyzes the spin-forbidden transfer of dioxygen to its N-heteroaromatic s
273 al process which provides an example of spin-forbidden transformation with a characteristic spin sele
275 rocess is employed to overcome a first order forbidden transition and the first, second and third Foc
277 sponding to a two-photon allowed, one-photon forbidden transition) for rhodol bearing 1-aza-15-crown-
278 ted by the observation of the DeltaMs = +/-2 forbidden transition, electron spin resonance (ESR) simu
281 effect, can accelerate quantum-mechanically forbidden transitions at non-adiabatic crossings(4,5).
283 interatomic radiative transitions and dipole-forbidden transitions can become comparable to the norma
287 void the higher barriers imposed by the spin-forbidden transitions required for unassisted O(2) disso
289 ple points, ten allowed transitions and two 'forbidden' transitions, as well as complex hysteresis lo
290 ers where interactions between multiple spin-forbidden triplet excitons can be significant and are me
291 m, with Fe3+ acting as a buffer for the spin-forbidden two-electron redox process between PCA and O(2
292 ular recognition process that is kinetically forbidden under ambient conditions-can be accelerated su
293 (95%CI, 0.94-1.25), P= 0.28; unrestricted vs forbidden visitations: RR, 1.08 (0.93-1.24), P= 0.33).
294 ase the reduction of EC is thermodynamically forbidden, whereas in bulk solvent it is likely to under
295 cal forms of beta-1a and beta-1b is symmetry forbidden, while the photochemical transformation is sym
297 Concerted [1,2]-rearrangements are formally forbidden, with these processes believed to proceed thro
298 f anabolic substances in animal husbandry is forbidden within the EU and well controlled by detecting