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1 (electrooxidation of methanol, ethanol, and formic acid).
2 that enables hydrogen gas release from neat formic acid.
3 ethane, bromochloromethane, formaldehyde and formic acid.
4 in the third step, yielding an estrogen and formic acid.
5 d electrolyte system consisted of 100 mmol/L formic acid.
6 he Pd(0)-mediated formation of hydrogen from formic acid.
7 rotective groups were cleaved with refluxing formic acid.
8 ate and the direct overlay of organisms with formic acid.
9 t or by renewable reductants such as formate/formic acid.
10 mary secondary amine and acidified with 0.1% formic acid.
11 s such as 5-hydroxy-methylfurfural (HMF) and formic acid.
12 der mild conditions using CO(2), formate and formic acid.
13 t uses CO(2) and hydrogen to store energy in formic acid.
14 in CO stripping and the electro-oxidation of formic acid.
15 proximately equal production of methanol and formic acid.
16 of acetonitrile/water (80:20) (v/v), with 1% formic acid.
17 1-naphthylnitrenium cation is 860 ps in 88% formic acid.
18 ion was found for 50% H2O/33% 2-propanol/17% formic acid.
19 photolysis of the appropriate azides in 88% formic acid.
20 oning all plants except its host plants with formic acid.
21 may undergo rapid aromatization, as well as formic acid.
22 dent and reproducible with sodium lactate or formic acid.
23 and proton were recombined to form molecular formic acid.
26 single extraction using water acidified with formic acid (1%) was performed, while in nuts, the clean
27 xtraction conditions reveals that the use of formic acid (1%), in place of the more commonly used per
29 Low-temperature 1H and 13C NMR spectra of formic acid (1) showed separate signals for the E and Z
30 and Ea = 31 kJ/mol) and one-pot reactions of formic acid, 2-nitrophenol, and aldehydes into benzoxazo
31 pH 2.25; 500 mM acetic acid, pH 2.54; 200 mM formic acid, 200 mM acetic acid, pH 2.05; and 200 mM imi
34 phase of acetonitrile-water containing 0.1% formic acid (50:50, v/v) and an optimal mobile phase flo
36 g-cleavage products, including acetaldehyde, formic acid, 6-, 7-, or 8-carbon oxoenals and oxodials.
41 od was applied to measure the enrichments of formic acid, acetic acid, and propionic acid in the perf
42 t for the low isotopomer enrichment assay of formic acid, acetic acid, propionic aicd, butyric acid,
44 Moreover, although not explicitly sought, formic acid/ammonium formate is produced as an important
45 el target plate, overlaid with 1 mul of neat formic acid and 1 mul HCCA matrix (alpha hydroxyl 4 cinn
48 age systems based on liquids, in particular, formic acid and alcohols, are highly attractive hydrogen
49 low temperatures by 1H and 13C NMR for both formic acid and an adduct with hexafluoroacetone, HCO2C(
50 ates of decay of the singlet nitrenes in 88% formic acid and are as follows: p-biphenylyl (taugrowth
51 e ethylenediaminetetraacetic acid (EDTA) and formic acid and are efficient in extracting dyes, but pr
54 es was accomplished with mixtures of aqueous formic acid and dimethylsulfoxide with increasing concen
55 t Py catalyzes the homogeneous reductions of formic acid and formaldehyde en route to formation of CH
57 nd its two succeeding intermediates, namely, formic acid and formaldehyde, to ultimately form CH3OH.
58 redicted to undergo fragmentation to produce formic acid and formaldehyde, with regeneration of (*)OH
61 electric field is switched on and identifies formic acid and formamide as key intermediate products o
63 tandem process involving dehydrogenation of formic acid and hydrogenation of C-C multiple bonds usin
65 actions, namely, the hydrogenation of CO2 to formic acid and methanol and the reverse dehydrogenation
67 talytic activity and very high stability for formic acid and methanol oxidation and the oxygen reduct
68 lower onset potentials for the oxidation of formic acid and methanol than either pure Pt or Pt-Ru na
69 higher oxidation current densities for both formic acid and methanol than pure Pt, Pt-Ru, or atomica
70 solar energy to convert CO2 to fuels (e.g., formic acid and methanol) apparently could simultaneousl
73 yde dehydrogenase to convert formaldehyde to formic acid and monitors the creation of an NADH analog
74 foliation syndrome (XFS) were homogenized in formic acid and subjected to cyanogen bromide (CNBr) cle
75 furic anhydride (FSA), that is produced from formic acid and sulfur trioxide under supersonic jet con
77 rsion of aldehydes and oxygen to alkanes and formic acid and uses oxygen and a cellular reductant suc
78 (70%) provided lower conductivity than 0.25% formic acid and was evaluated as low ionic-strength and
79 to both internal and terminal alkynes using formic acid and Zn as the terminal reductants has been d
81 f a mobile phase comprising water (with 0.5% formic acid) and acetonitrile (90:10, v/v) on Phenomenex
82 h a gradient system of ultrapure water (0.1% formic acid) and acetonitrile, a temperature of 35 degre
83 homogenised sample with 20 ml methanol (+1% formic acid) and measurement by LC-MS/MS multiple reacti
84 ed to rapidly convert 100% of gaseous CO2 to formic acid, and >500 mM formate was observed to accumul
86 a mixture of a functionalized PDMS oligomer, formic acid, and an IL (or lithium-in-IL solution), a re
87 tion methods, including the direct, on-plate formic acid, and ethanol/formic acid tube extraction met
88 ented using incubation with Pronase E and/or formic acid, and in each case a complete set of fluoresc
89 cpcT mutant and wild type were cleaved with formic acid, and the products were analyzed by SDS-PAGE.
90 nanoparticle structure, slow dehydration of formic acid, and weak binding of CO on Au147@Pt surface.
91 cid as a putative sex pheromone and measured formic acid- and propionic acid-elicited robust electroa
94 purity-free V(3.5+) electrolyte by utilizing formic acid as a reducing agent and Pt/C as a catalyst.
96 dimethylacetamide (dmac) with acetic acid or formic acid as modulators: [Bi(2)(cpb)(acetato)(2)(dmf)(
97 the presence of [Rh2(OAc)4] as catalyst and formic acid as reducing agent, leading to the high yield
98 transfer hydrogenation conditions employing formic acid as terminal reductant, 2-butyne couples to a
99 e analytes were collected in 21 muL of 10 mM formic acid as the acceptor phase, and the extracts were
101 quantify the stoichiometric accumulation of formic acid as the product of the reaction and demonstra
103 potential for reduction of carbon dioxide to formic acid at -1.45 V vs. Ag/Ag(+), representing a low
108 ing, we infer a substantial emission flux of formic acid at the canopy level ( approximately 1 nmol m
111 protein detection from complex mixtures: (1) formic acid-based formulations, (2) perfluorooctanoic ac
112 d 94 (M + H)+ ions, 119 were observed from a formic acid-based matrix with no more than 10 common to
113 a user-supplemented database and an on-plate formic acid-based preparation method and compared result
115 ate in the presence of sodium metal to yield formic acid, [bis(N,N-diisopropylamino)phosphino]-beta-(
118 Photochemical reduction of CO(2) (to produce formic acid) can be seen both as a method to produce a t
119 osphates, however, mixtures of acidic (0.1 M formic acid-containing) acetonitrile/water (80:20) or ac
121 lysts, as demonstrated here for the cases of formic acid decomposition and formic acid electro-oxidat
122 tions of several WSOGs, including acetic and formic acids, decreased considerably (~30-50%) when the
124 three-step extractions (TBS, detergent, and formic acid) demonstrated that the lower level of total
127 smenyl (vinyl-ether) containing lipids using formic acid enabled these species to be readily differen
128 = H, OH, OMe, OCHO, OC(O)NMe(2)) reveal that formic acid equilibrium is approximately temperature-ind
129 f CO(2) , providing selective formation of a formic acid equivalent via the dialuminum carbonate comp
130 onic strength mobile phases at low pH (e.g., formic acid), even with highly inert silica RP-HPLC colu
132 grees C are in the order pre-LGA < pre-HMF < formic acid, explaining why LGA is the kinetically favor
134 a with treatment up to 5 weeks in WT mice or formic acid-extractable brain Abeta with 3 month treatme
135 -treated mice in cortical levels of soluble, formic acid extracted, or histologically detectable beta
136 beta plaque load and biochemical analysis of formic acid-extracted Abetax-40 and Abetax-42 levels and
137 ion of nucleobases and nucleobase analogs in formic acid extracts of 12 different meteorites by liqui
139 found that the widely used conditions, 0.1% formic acid (FA) and NH(4)Ac at different pH, are far fr
142 This report describes a short, on-plate formic acid (FA) extraction method for the identificatio
147 CA is applied to the case of electrochemical formic acid (FA) production via supercritical CO(2) (scC
148 , and hydrogen (H(2)); and chemicals such as formic acid (FA), ammonia (NH(3)), ethylene (C(2)H(4)),
151 The SECM tip, which generated a constant formic acid flux, was scanned above the array and the ox
152 ylurea and p-toluenesulfinic acid in aqueous formic acid followed by reaction of the obtained N-[(2-a
158 bably promoting the release of formaldehyde, formic acid, glycolaldehyde, glyoxal, acetic acid, glyco
161 CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and acetic acid (CH3 COOH), employin
166 tic cycles, involving the decarboxylation of formic acid, hydration of the alkyne, and hydrogenation
171 Briefly, the samples were extracted with 1% formic acid in acetonitrile and directly analysed with H
173 hat are very selective for the production of formic acid in dimethylformamide (DMF)/water mixtures (F
174 ence cluster Fe(3)O(MeCOO)(6)(H(2)O)(3) with formic acid in dimethylformamide exposed to air at 110 d
175 ion of the fermentation products ethanol and formic acid in LOS cases before the onset of disease.
178 T in chloroform/methanol (2:1, v/v), with 1% formic acid in the final mixture, 57 lipid entities were
179 aqueous and organic mobile phases were 0.1% formic acid in water and acetonitrile, respectively.
182 mobile phase consisting of solvents A (0.1% formic acid in water), and B (0.1% formic acid in methan
183 different extraction solvents including: A, formic acid in water; B, ammonium hydroxide in water; C,
184 surements of OVOCs, including high levels of formic acid, in the atmosphere (measured by an online hi
185 oom-temperature photocatalytic conversion of formic acid into either hydrogen or carbon monoxide.
190 he solubility of the polymerized material in formic acid is controlled by the degree of graft copolym
191 ach of increasing NAD(P)H and removing extra formic acid is efficient for increasing the production o
194 novel catalytic cycle for the reaction with formic acid is proposed and subjected to a variety of ex
195 le and expensive reducing reagents, and only formic acid is required in the proposed LSDBD chemical v
196 on of CO2 into energy-dense liquids, such as formic acid, is desirable as a hydrogen carrier and a ch
197 iophosphoramidate oligonucleotides with 0.1% formic acid leads to the cleavage of the 3' N-P bond and
199 tiful atmospheric abundance of FA, makes the formic acid mediated hydrolysis reaction a potentially i
201 duction reaction, and oxidation reactions of formic acid, methanol and carbon monoxide) of noble meta
202 r the direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are thoroughly
205 The measured concentrations of acetic acid, formic acid, NO(2), O(3), particulate matter, sulfur dio
207 gen-dependent reduction of carbon dioxide to formic acid offers a promising route to greenhouse gas s
209 The integral heat of molecular adsorption of formic acid on clean Pt(111) at 100 K is 62.5 kJ/mol at
210 d by studying the dissociative adsorption of formic acid on oxygen-presaturated (O-sat) Pt(111) to ma
211 tational results, the oxidation mechanism of formic acid on Pt(111) electrodes modified by the incorp
212 ) postulates and considers the adsorption of formic acid on the catalyst as the rate-determining step
213 at the chemical shift value of an adsorbate (formic acid) on metal colloid catalysts measured by (13)
216 "score." We found that a heavy smear with a formic acid overlay (H+FA) produced optimal MALDI-TOF MS
220 dation, benzoquinone (BQ) reduction, and the formic acid oxidation reaction (FAOR) at a Pt microelect
222 ridium variant Ir(1)/CN electrocatalyses the formic acid oxidation reaction with a mass activity of 1
223 atio) as a better electrocatalyst toward the formic acid oxidation than pure Pd or Pt in 0.1 M KHCO(3
224 reat importance to explore new catalysts for formic acid oxidation that have both ultra-high mass act
225 bes and spheres (including oxygen reduction, formic acid oxidation, and methanol oxidation) were test
226 exhibited enhanced catalytic activity toward formic acid oxidation, with a current density 2.5 and 7.
231 ation, a C(18) column was applied using 0.1% formic acid (pH 3.4) as the mobile phase with detection
233 5 mM naphthalene trisulfonate (NTS) in 0.4 M formic acid, pH 2.0 is developed for detection of UV tra
234 technology or as a cell factory dedicated to formic acid production, which is a commodity in itself a
235 equential in nature (in which the formate to formic acid protonation can be assisted by a negatively
236 ed complexes among the most promising CO2-to-formic acid reducing catalysts developed to date; addres
239 sin and eluted with acidified methanol (0.1% formic acid), resulting in analyte recoveries generally
241 umns and adding TFA as an acid modifier to a formic acid/reversed phase gradient, providing additiona
242 hich, when deleted in combination, predicted formic acid secretion in Saccharomyces cerevisiae under
243 mate dehydrogenase mutant (fdh1 fdh2), while formic acid secretion in wild-type yeast was undetectabl
244 tant strain showed the predicted increase in formic acid secretion relative to a formate dehydrogenas
245 Microbial respiration and production of formic acid showed that Enterobacter sp. had a higher to
246 sp. Microbial respiration and production of formic acid showed that Enterobacter sp. had a higher to
247 ast reaction of syn-MVK-oxide with SO(2) and formic acid, similar to smaller alkyl-substituted CIs, a
248 igand-capped cadmium sulfide nanocrystals in formic acid/sodium formate release up to 116+/-14 mmol H
249 changes in sodium dodecyl sulfate-soluble or formic acid-soluble Abeta pools or Abeta oligomers in Tg
250 ort that the levels of detergent-soluble and formic acid-soluble levels of Abeta and deposition are e
252 monstrated ultra-high concentrations of pure formic acid solutions (up to nearly 100 wt.%) condensed
253 he conductivities of aqueous acetic acid and formic acid solutions were measured from 0.1% to 100% co
256 a lack of (18)O incorporation in the product formic acid, supporting only the Compound I pathway.
257 based on extraction with acetonitrile/water/formic acid, ten-fold dilution and analysis by LC-MS/MS
258 isoning tolerance in the electrooxidation of formic acid than Pt cubes; the oxidation of CO on Pt nan
259 eport a new (13)C-tagging method using (13)C-formic acid that delivers high sensitivity, good quantit
260 ized lignin under mild conditions in aqueous formic acid that results in more than 60wt% yield of low
261 process may produce a few Tg/year of gaseous formic acid, the amount comparable to its primary source
262 otonated, this species preferentially expels formic acid through an O-O cleavage transition state.
263 zyme from Escherichia coli normally oxidizes formic acid to carbon dioxide and couples that reaction
267 egral heat of the dissociative adsorption of formic acid to make monodentate formate (HCOOmon,ad) plu
268 istic studies point to the unique ability of formic acid to mediate the cyclization forming the clusi
269 as eluted with 30% acetonitrile plus 100 muM formic acid to provide sufficient hydrogen ions to ioniz
271 catalytically active for dehydrogenation of formic acid (TOF = 1718 h(-1) and Ea = 31 kJ/mol) and on
272 was performed under mild conditions with the formic acid/triethylamine (5:2) system as the hydrogen s
273 substituted substrates, the more established formic acid/triethylamine system gives superior results.
274 he direct, on-plate formic acid, and ethanol/formic acid tube extraction methods, were evaluated for
275 nes 25-26 were synthesized in one step using formic acid, urea, guanidine carbonate, and phenylisocya
276 er mobile phase (80:20, v/v) containing 0.1% formic acid using isocratic flow at 0.15 mL/min for 13 m
277 We report electrocatalytic oxidation of formic acid using monometallic and bimetallic dendrimer-
278 cetate and hexane in the presence/absence of formic acid, using different extraction times and temper
282 ray and the oxidation current generated when formic acid was collected by active electrocatalytic spo
286 mobile phase (59% water, 40% isopropanol, 1% formic acid) was used to remove the residual surfactant
289 membrane inlet system, and formaldehyde and formic acid were detected by ESI-MS after a derivatizati
291 ation of methanol generates formaldehyde and formic acid which then condense with methanol to form di
292 analysis of the oxygen atoms of the product (formic acid), which exchange with the solvent (water) un
293 fixed potential for the electro-oxidation of formic acid with a commercial Pt/carbon catalyst increas
294 ne of the few catalysts that reduce CO2 into formic acid with high selectivity but at high overpotent
295 ctions of acetic acid, acetic-d3 acid-d, and formic acid with the Ge(100)-2 x 1 surface have been inv
296 l, then an aldehyde, and finally eliminating formic acid with the introduction of a Delta14-15 double
298 electro-oxidation of ethanol, methanol, and formic acid, with mass activities of 1.55 A/mg(Pt) , 1.4