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1 sic conditions; statistical versus selective formylation).
2 ohol groups in the anthocyanin available for formylation.
3 a selective and efficient pathway for the N-formylation.
4 native to the available methods for aromatic formylation.
5 e less-known, such as O-ubiquitination and N-formylation.
6 ed by catalytic hydrogenation and subsequent formylation.
7 xidation, and a directed aromatic lithiation-formylation.
8 stability of the product, and regioselective formylation.
9 was converted into (+)-geissoschizine (1) by formylation.
10 d attached to the tRNA is also important for formylation.
11 h lysine was an extremely poor substrate for formylation.
12 which contains the critical determinants for formylation.
13 tive effect of the acceptor stem mutation on formylation.
16 previously reported transformations, such as formylation and amine substitution, the available scope
17 ukaryotic protein synthesis does not involve formylation and deformylation at the N-terminus, there h
18 Protein synthesis in bacteria involves the formylation and deformylation of the N-terminal methioni
20 tion in the presence of a ketone followed by formylation and finally acid-catalyzed methanolysis comp
21 (CO)] (R = Ph/ i-Pr/Cy/ t-Bu) for both amine formylation and formamide hydrogenation, only catalyst R
22 erminal methionine removal, acetylation, and formylation and four forms of the carbonic anhydrase-zin
23 aryl moiety via combination of the Bouveault formylation and hydride reduction has been optimized usi
24 The principal modifications included lysine formylation and methionine sulfoxidation both of which o
25 ed with methionine, was a good substrate for formylation and was, consequently, quite active in initi
27 C-C bond formations via cascade alkylation, formylation, annulation, and aromatization to make subst
30 n the insertion loop (which are defective in formylation) are not protected by the initiator Met-tRNA
31 ionalization reactions such as halogenation, formylation, carboxylation, nitration, sulfonation, and
32 ted with lysine is a very poor substrate for formylation compared with the same tRNA aminoacylated wi
33 enynol substrate as well as a one-pot Rieche formylation/cyclization/deprotection sequence to efficie
34 ong a reaction sequence involving a tandem N-formylation/decarboxylation that may have a mechanistic
35 cherichia coli MTF, which compensate for the formylation defect of a mutant initiator tRNA, lacking a
36 or mutations in MTF which compensate for the formylation defect of the mutant tRNA aminoacylated with
37 ects MTF against trypsin cleavage, whereas a formylation-defective mutant initiator Met-tRNA, which b
38 mnant without any functional role in protein formylation/deformylation and validates PDF as an excell
40 m easily accessible enamino keto esters by a formylation followed by in situ intramolecular cyclizati
41 thanes have been investigated: (1) Vilsmeier formylation followed by selective removal of the unwante
42 ng O-mycoloylation, pyroglutamylation, and N-formylation, for mycomembrane-associated and -secreted O
43 specific recognition of the determinants for formylation in the acceptor stem of the initiator tRNA.
45 fMet), and tRNA(fMet) shows that there is no formylation in vivo of the mitochondrial initiator Met-t
46 he initiator tRNA is not known, but in vitro formylation increases binding of Met-tRNA(f)(Met) to tra
52 hat catalyzes the ATP- and formate-dependent formylation of 5-aminoimidazole-4-carboxamide-1-beta-D-r
53 inolone-3-sulfonamide intermediates features formylation of a beta-ketosulfonamide employing dimethyl
56 sfully accomplished the metal-free catalytic formylation of amides using CO(2) and the catalytic redu
57 t exhibited high catalytic efficiency in the formylation of amines (turnover frequency up to 204 h(-1
59 groups have generally employed the Vilsmeier formylation of an acid-resistant copper or nickel porphy
64 n of the inversion as being rate-determining formylation of cis-enolate 27 from a mixture of rapidly
65 e excellent selectivity and yields towards N-formylation of diverse amines with CO(2) and H(2) under
67 urT transformylase, catalyzes an alternative formylation of glycinamide ribonucleotide (GAR) in the d
68 ons in purine biosynthesis by catalyzing the formylation of glycinamide ribonucleotide through a cata
69 rp, conversion of Ser to dehydroalanine, and formylation of His) were observed in alphaA-crystallin f
78 modification of chromatin proteins, the N(6)-formylation of lysine that appears to be uniquely associ
79 n contrast, isopropyl group inversion during formylation of menthone with NaOMe and HCO(2)Et led, by
80 is used directly in purine biosynthesis and formylation of Met-tRNA and indirectly in the biosynthes
81 MTF, but not of an inactive mutant, leads to formylation of methionine attached to the yeast cytoplas
82 e, we report the selective electrochemical N-formylation of methylamine using methanol as both reagen
84 rmylmethionyl-tRNA, which indicates that the formylation of mitochondrial Met-tRNA specifies its part
85 is discovered to be highly reactive for the formylation of morpholine, leading to the formation of N
86 able approach for the photoinduced oxidative formylation of N,N-dimethylanilines using a phenalenyl-b
87 erocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen
88 ive MgCl(2)-mediated Casnati-Skattebol ortho-formylation of phenol, Wittig methylenation, acryloylati
89 In addition, 5 mol % of 2 catalyzed the N-formylation of secondary and primary amines by carbon di
90 es the N-10-formyltetrahydrofolate-dependent formylation of the 4''-amine of UDP-L-Ara4N, generating
91 nique properties of E. coli initiator tRNA - formylation of the amino acid attached to the tRNA and b
92 noacylation of the tRNA, (iii) the extent of formylation of the aminoacyl-tRNA to formylaminoacyl-tRN
93 esis in yeast mitochondria can occur without formylation of the initiator methionyl-tRNA (Met-tRNA(fM
96 ionyl-tRNA transformylase results in partial formylation of the mutant tRNA and activity of the formy
98 us, the G4: C69 base pair contributes toward formylation of the tRNA and protein synthesis in E. coli
99 tive low-valent, metal-free catalyst for the formylation of thiols using CO(2) via nucleophilicity an
103 cal oxidation and that their modification by formylation or acetylation greatly enhances their subseq
105 ings a key structural determinant to predict formylation patterns is identified: the precise glucosyl
107 istinct from widely used palladium-catalyzed formylation processes, this reaction proceeds by a two-s
109 that the 1,2-boronate rearrangement for the formylation reaction could be temperature-controlled, th
113 ed levels of global cytosine methylation and formylation, reduced cytosine hydroxymethylation, decrea
114 age of an electronically directed metalation/formylation sequence followed by condensation with methy
115 s of carefully orchestrated steps: addition, formylation, tautomerization, and dehydration, with CuCN
116 meno[3,4-c]pyridines was achieved via a Duff formylation that is attended by an unusual cyclization r
119 amined, the slowest rate of serine/threonine formylation was found for 50% H2O/33% 2-propanol/17% for
120 rtho-selectivity, whereas unprecedented para-formylation was observed for other electron-rich aromati
122 st stereospecific boronate rearrangement and formylation were utilized for the practical asymmetric s
123 boronate rearrangement followed by a robust formylation with an in situ generated DCM anion has been
124 lithium, followed by carbonation with CO2 or formylation with N-formylpiperidine and subsequent depro
126 The solvent-free, metal-free mild method of formylation, with the absence of tedious work-up steps a