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1 orresponding to LUMO energy levels as low as fullerenes).
2 roups, in the double cyclopropanation of [60]fullerene.
3 ivatives on carbon nanomaterials such as [60]fullerene.
4 urring through the inherent chirality of the fullerene.
5 alternating rings on the surface of the [60]fullerene.
6 is insufficient to switch the MX inside the fullerene.
7 addition reactions or the making of pristine fullerenes.
8 he interaction between CNTs and encapsulated fullerenes.
9 led by varying the weight percentages of the fullerenes.
10 Fs) often differs from that in neutral empty fullerenes.
11 on fillers consisting of graphene flakes and fullerenes.
12 s of metal complexes and metal surfaces with fullerenes.
13 lead towards a useful methodology to purify fullerenes.
14 tices of quantum dots, p-block clusters, and fullerenes.
15 her small clusters such as nanomaterials and fullerenes.
17 thesis of a new perylenediimide-thiazole non-fullerene acceptor capable of delivering a power convers
18 s, from 2.79 % to 10.51 % for devices with a fullerene acceptor in the active layer, and from 3.89 %
19 rom 3.89 % to 11.04 % for devices with a non-fullerene acceptor in the active layer, demonstrating th
20 R = alkyl substituent) blended with the non-fullerene acceptor ITIC-Th and analyze the effects of su
21 hology measurements by replacing the typical fullerene acceptor with endohedral fullerene Lu3N@PC80BE
22 and self-assembly of thiadiazole-derived non-fullerene acceptors (NFAs) is very critical for elucidat
24 ls using a ternary approach, wherein two non-fullerene acceptors are combined with both a scalable an
29 owever, the single-junction STOPVs utilizing fullerene acceptors show relatively low PCEs of 4%-6% du
30 nventional electron-deficient-core-based non-fullerene acceptors with near-infrared absorption lead t
31 e-property relationships of a library of non-fullerene acceptors, highlighting the important chemical
32 lk heterojunctions between polymer donor and fullerene acceptors, which provide a model system to und
33 of D18-based OSCs is compared with three non-fullerene acceptors, Y6, IT-4F, and IEICO-4Cl, and their
41 ro-hydrophosphination reaction into free [60]fullerene and sec-phosphine borane amino ester compound.
43 with advances in the synthesis of pure boron fullerenes and atom-thin layers, motivates an exploratio
45 capsule 1(8+) in the selective separation of fullerenes and endohedral metallofullerenes (EMFs) remai
48 tercalation into PAHs differs from that into fullerenes and graphite, in which the cation sites are p
49 lytic behavior, involving the combination of fullerenes and low-dimensional (LD) nanohybrids, is curr
52 es that can exceed the device performance of fullerenes and provide opportunities to improve upon the
53 rs by using the specific interaction between fullerenes and saccharides in liquid chromatography (LC)
54 sorbents include activated carbon, biochar, fullerenes, and carbon nanotubes, with applications such
55 ental molecular building block in graphenes, fullerenes, and carbon nanotubes-is facilitated by a bar
56 etal clusters or purely nonmetal cages, like fullerenes, and even noncovalent aggregates such as wate
57 reactions between the two electron-accepting fullerenes, and for kinetics that are influenced by the
58 ive energies of a large number of isomers of fullerene anions, C(2n)(q) (2n = 68-104; q = -2, -4, -6)
61 ereby yielding materials in which metals and fullerenes are brought together in ordered arrangements.
62 Multi-functionalization and isomer-purity of fullerenes are crucial tasks for the development of thei
68 icipated that this data will position chiral fullerenes as an exciting material class for the growing
69 l electrolyte system, exploiting derivatized fullerenes as both anolyte and catholyte species in a se
70 tation of specific carbohydrates by using 3D fullerenes as controlled biocompatible carbon scaffolds
71 We focus mainly on investigations regarding fullerenes as well as endohedral metallofullerenes in en
74 A new method for the functionalization of fullerenes based on the reaction between in situ generat
77 e determine that replacing the commonly used fullerene-based electron acceptor with a perylene diimid
78 signed hosts are able to associate up to two fullerene-based guest molecules and present association
79 y review the synthetic approaches to prepare fullerene-based hybrids with LD (0D, 1D, and 2D) materia
87 yses were performed on Shroom3 in mice using fullerene-based siRNA delivery, which demonstrated that
89 ing the efficiencies of fullerene-based, non-fullerene-based, and ternary organic solar cells (OSCs)
90 ar orientation, boosting the efficiencies of fullerene-based, non-fullerene-based, and ternary organi
91 The regio- and stereocontrolled synthesis of fullerene bisadducts is a topic of increasing interest i
92 mall molecule acceptor into a P3HT-based non-fullerene blend increases the device efficiency up to 7.
94 ss transition temperature of ternary polymer/fullerene blend thin films and their constituents, which
95 trafast charge transfer processes in polymer/fullerene blends have been intensively studied but much
100 rmation are not optimal for the formation of fullerenes, but instead, curved carbon structures coales
101 ally, the hydrophosphination reaction of [60]fullerene by the sec-phosphine borane compounds was perf
104 CNB1 demonstrates selective encapsulation of fullerene C(70) over C(60), with a large association con
105 In addition, the encapsulation of bis-aza[60]fullerene (C(59)N)(2) within a supramolecular coordinati
106 = 0, 3, 5), were constructed by linking the fullerene (C(60)) and bis(3,4,5-trimethoxyphenyl)aniline
107 s (MWCNTs), reduced graphene oxide (RGO) and fullerene (C(60)), and show similar effects upon complex
109 h epoxy and hydroxy groups on the surface of fullerenes (C(60)) and thereby improve the solubility of
110 Box exhibits strong recognition of pristine fullerenes (C(60/70)), with the noncovalent ground and e
111 of isolated water molecules encapsulated in fullerene-C(60) cages by time-domain terahertz (THz) spe
112 terpret the superstructure composing aqueous fullerene C60 nanoparticles prepared by prolonged stirri
113 formation of aminomethylated derivatives of fullerene C60 with high yields (80-90%) and selectivity
115 articular, we focus on dendrimers as well as fullerene C60-with a unique symmetrical and 3D globular
119 g of the three-dimensional potential between fullerene (C60) molecules in different relative orientat
121 superatom molecular orbitals (SAMOs) of the fullerene cage as a means of Li activation, thereby bypa
122 ture, ultimately leading to the closed-shell fullerene cage C60(-) as preprogrammed by the precursor
123 fullerene CH(4) @C(60) , in which each C(60) fullerene cage encapsulates a single methane molecule, h
124 The addition of solubilizing addends to the fullerene cage results in a large number of isomers, whi
125 e of the addends, and (iv) the variations in fullerene cage stability with the progressive addition o
126 nation of the unique encapsulation effect of fullerene cages and the variable oxidation states of act
128 ther the typically favored [6,6]-addition in fullerenes can be shifted to the [5,6] bonds in (#6094)C
129 2F]T polymers are particularly promising non-fullerene candidates for "all-polymer" BHJ solar cells.
131 nt metal-based nanoparticles or nanocarbons [fullerene, carbon nanotubes (CNTs), and graphenes] with
132 he most recent carbon nanostructures, namely fullerenes, carbon nanotubes, and graphene, have receive
134 adducts is a topic of increasing interest in fullerene chemistry and a key point for the full exploit
135 contribute not only to the basic science of fullerene chemistry but would also be used towards effec
136 ohedral fullerenes is an important aspect of fullerene chemistry, since the experimentally formed str
138 at the heterojunction and/or the presence of fullerene clusters guarantee efficient CT dissociation a
139 -layer compression of the negatively charged fullerene clusters, and the nC60s and nHOFs alike displa
140 miscibility between this particular polymer:fullerene combination and to co-crystallization of Lu3N@
141 lamide functionalised reduced graphene oxide-fullerene composite and double layered acrylamide functi
144 o models is comparable with that observed in fullerene-containing materials, which are generally cons
145 l fullerenes in contrast with their pristine fullerene counterparts, (ii) the appearance of more pent
147 terials, mixed metal complexes and clusters, fullerenes, dendrimeric nanocomposites, polymeric materi
151 h gain is presented based on the polymer and fullerene derivative incorporating inorganic quantum dot
152 value lower than those of the PSCs based on fullerene derivative or organic small molecule acceptors
153 er the nonfullerene acceptor EH-IDTBR or the fullerene derivative, [6,6]-phenyl C71 butyric acid meth
157 fabricated with either [60]PCBM or [70]PCBM fullerene derivatives as acceptor, the efficiency of cha
158 rate dilute conditions (0.03 M) leads to [60]fullerene derivatives as epimeric mixtures ( approximate
159 icancer effects of a series of water-soluble fullerene derivatives bearing amino acid (F1-F7) and thi
160 t to the vast majority of known cytostatics, fullerene derivatives do not show any significant acute
162 tion of protein corona on the surface of [60]fullerene derivatives is changing the landscape of their
165 ion pattern, represent the first examples of fullerene derivatives which combine central, axial, and
166 hilic substitution reactions to generate new fullerene derivatives, which can potentially lead to a w
169 from consisting of molecularly mixed polymer-fullerene domains to consisting of both molecularly mixe
173 t efficient polymer-acceptor alternatives to fullerenes (e.g. PC61 BM or its C71 derivative) are base
174 ate clusters are reminiscent of redox-active fullerenes (e.g., C60(n), where n = +1, 0, -1, -2, -3, -
175 d on Borromean rings, dodecaamine cages, and fullerenes, each of which carrying a defined number of c
178 physical properties of these cages and their fullerene-encapsulated adducts were studied in depth.
180 otifs are utilized as recognition motifs for fullerenes, facilitating novel intermolecular, solvent t
183 ong the best performance so far reported for fullerene-free organic photovoltaics and is inspiring fo
184 e, we exploit strong coupling by embedding a fullerene-free organic solar cell (OSC) photo-active lay
186 ture for so long time is rarely reported for fullerene-free OSCs, which might be due to the unique un
187 rativity in binding pairs of anions from the fullerene-free parent: in one case, positive cooperativi
188 egioselectivity in the DA reaction of hollow fullerenes from the usual [6,6] bond to the [5,6] bond i
190 molecular diodes on the basis of endohedral fullerenes (fullerene switching diode, FSD), encapsulate
191 immature Ty3 particles revealed an irregular fullerene geometry previously described for mature retro
192 ate charge transport through graphene/single-fullerene/graphene hybrid junctions using a single-molec
193 d excited state interactions that occur upon fullerene guest encapsulation characterized by a range o
195 f this system with respect to the parent C60 fullerene have been analyzed in detail by using the acti
197 e unique physical and chemical properties of fullerenes have offered new opportunities to tailor both
199 The interaction of gas phase endohedral fullerene Ho3N@C80 with intense (0.1-5 x 10(14) W/cm(2))
200 ggregation kinetics of nC60 and higher-order fullerene (HOF) clusters, i.e., nC70, nC76, and nC84, wa
202 bilized by an allylic group cycloadds to [60]fullerene in an efficient manner and with a good diaster
206 f non-IPR (isolated pentagon rule) exohedral fullerenes in contrast with their pristine fullerene cou
207 -isomer, and particularly single-enantiomer, fullerenes in organic electronic materials and devices a
209 electronics based on numerous sub-nanoscale fullerenes in the large family of carbon allotropes is a
210 significantly changed the characteristics of fullerene including its particle size and surface charge
211 that the interactions between saccharide and fullerene increase with the increase units of the saccha
212 hat the electron-accepting properties of the fullerenes inside the capsules were altered depending on
214 e electronically active sites at the polymer/fullerene interfaces in model bulk-heterojunction blends
215 -in which the central alkyne scaffold of [60]fullerene is connected to 12 sugar-containing [60]fuller
217 he regioselectivity of chemical additions to fullerenes is a major goal in the field of reactivity of
218 standing the relative stability of exohedral fullerenes is an important aspect of fullerene chemistry
219 tabilization of anionic transition states on fullerenes is shown to accelerate disfavored enolate add
220 t systems for the noncovalent recognition of fullerenes is unprecedented, in part because archetypal
221 heterostructures, including the role of the fullerenes, is addressed to provide an in-depth understa
222 ival or surpass the corresponding values for fullerenes, ITIC-0F, and ITIC-4F, and track a positive c
224 namics and enhance the optical response of a fullerene layer, enabling hybrid magneto-molecular optoe
225 lamide functionalised reduced graphene oxide-fullerene layer-by-layer assembled dual imprinted polyme
227 single molecule switch using the endohedral fullerene Li@C(60) that displays 14 molecular states whi
228 allofullerenes, formed by encaging Gd inside fullerenes like C80, can exhibit enhanced proton relaxit
232 Finally, the various applications of the fullerene-like NPs of WS2 and NTs formed therefrom are d
234 The powerful electron accepting ability of fullerenes makes them ubiquitous components in biomimeti
235 consisting of p-type polymers and n-type non-fullerene materials, which is passivated using nickel fo
240 ide functionalised reduced graphene oxide or fullerene molecules, which yielded very inferior sensiti
243 hyperthermia as an adjunctive therapy to [60]fullerene nanoparticle-based drug delivery systems in ta
244 g affinity exceeding 10(8) M(-1) despite the fullerene not fully entering the cavity of the host (X-r
246 ible approach to the successful oxidation of fullerenes (oxC(60)) and the formation of highly hydroph
247 he retro-hydrophosphination reactions of [60]fullerene/phosphine borane compounds offer a promising n
248 ation of large hydrophobic guests, including fullerenes, polycyclic aromatic hydrocarbons, and steroi
249 quantum dot-sensitized solar cells, polymer-fullerene polymer solar cells, organometal halide perovs
250 solved experimental data obtained on polymer:fullerene, polymer:polymer, and small-molecule blends wi
253 The power conversion efficiencies of non-fullerene PSCs have now reached over 15 %, which is far
256 ry both the fullerene substitution and donor/fullerene ratio which allow us to control both aggregate
257 fore, the essential molecular details of the fullerene recognition and binding process into the coord
259 the nitrogen atom and the CH fragment in the fullerene reduces the interaction between the deformed r
260 nt insights into the formation of all carbon fullerenes reveal that conditions in charcoal formation
263 ide functionalised reduced graphene oxide or fullerene, single layered acrylamide functionalised redu
266 istic effects of binary mixtures composed of fullerene soot and organic co-contaminants as malathion,
267 s similar to that found in thermally treated fullerene soot indicates that they share a nanostructure
268 Fullerene extracts are easily available from fullerene soot, but finding an efficient strategy to obt
269 the toxicity of three carbon nanomaterials (fullerene-soot, multiwall carbon nanotubes, and graphene
277 iodes on the basis of endohedral fullerenes (fullerene switching diode, FSD), encapsulated with polar
278 S protein effectively lowered the amounts of fullerene taken up by Caco-2 cells, which are derived fr
282 gulene are predisposed to cocrystallize with fullerenes, thereby yielding materials in which metals a
283 sting that the effect of the coordination of fullerene to one face of our supramolecular platform was
287 In the case of cages loaded with C60 or C70 fullerenes, ultrafast host-to-guest electron transfer wa
288 r use in hydrophosphination reactions of [60]fullerene under phase-transfer catalysis has demonstrate
289 d so far has only been reported for solvated fullerenes under compression. Here, a report on the crea
290 rene is connected to 12 sugar-containing [60]fullerene units (total 120 mannoses)-exhibit an outstand
292 that a supramolecular complex of saccharide-fullerene was formed through CH-pai and/or OH-pai intera
294 , a photochemical desulfinylation of an open fullerene, was completed, even though it is inhibited by
295 ir conductance, and via heteroatom doping of fullerene, which introduces transport resonances and inc
297 renylstyrenes based on the reaction of C(60) fullerene with terminal acetylenes and EtMgBr in the pre
299 study thus provides key strategies to design fullerenes with large chiroptical responses for use as c
300 predict the relative stability of exohedral fullerenes without the need for electronic structure cal