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1 ar cycloaddition as well as C-H amination to furnish 1,2,3-dihydrotriazole and substituted pyrrolidin
2 tization reaction sequence to preferentially furnish 1,2,4-trisubstituted pyrroles instead of the exp
3 alyzed semireduction of conjugated enynes to furnish 1,3-disubstituted allenes using water as the pro
5 genation, epoxidation, or dihydroxylation to furnish 2,3,6-tridesoxy, 2,3-anhydro-6-desoxy, or 6-deso
6 action with various arene diazonium salts to furnish 2,3-unsaturated aryl C-glycosides in moderate to
8 yrrole-2-carbonitriles with copper(II)-salts furnished 2,2'-bipyrroles as well as 5,5'-bis(5-cyano-1-
9 he thiol proton in cysteine with m-carborane furnished 2-amino-3-(1,7-dicarba-closo-dodecacarboranyl-
10 ent removal of the carbamate directing group furnishes 2-arylated estrone, estradiol, or estriol depe
12 ium-catalyzed cyclizative coupling reactions furnished 3,6-dihydro-2H-pyrans through a chemo- and reg
14 rtiary sp(3)-C center of spiro-epoxyoxindole furnishes 3-fluoro-3-hydroxymethyloxindoles, whereas TBA
15 cridine N-oxides also reacted with arynes to furnish 4-(2-hydroxyaryl)acridines, albeit in moderate y
17 wed by N-sulfonation of one indole moiety to furnish 6-bromo-3-(6-bromo-1H-indole-3-carbonyl)-1H-indo
18 diated photoprotection in cyanobacteria, and furnish a basis for understanding the physiological rele
19 he C-B bonds could also be functionalized to furnish a diverse set of highly substituted cyclobutanes
20 els in conjunction with MeOH/CO(2) served to furnish a generic modifier (0.2% NH(4)OH, 5% H(2)O in Me
21 mouse neurons, astrocytes, and microglia to furnish a global portrait of the cellular anatomy of ser
22 dergo electron redistribution with borane to furnish a heteroatomic group 13 ring exhibiting a sigma-
23 non-symbolic ratio processing abilities can furnish a more expansive account of numerical cognition
25 rmation of the nasolacrimal groove, and they furnish a powerful resource for those investigating the
28 el addition-intramolecular Ad(N)E process to furnish a range of pharmacophoric, diverse, spiroannulat
29 udy, we used synthetic methodologies able to furnish a series of stereochemically defined phosphinic
32 cessfully employed in this transformation to furnish a variety 3-keto-isoquinolines in very good yiel
33 scale, which could be further elaborated to furnish a variety of enantiopure trisubstituted cyclopro
34 -gamma-lactones can be further elaborated to furnish a variety of enantiopure trisubstituted cyclopro
35 ent, Brook rearrangement can be triggered to furnish a wide range of cyclobutenes with exceptional di
36 e reacted smoothly at ambient temperature to furnish a wide range of propargylamines in high yields (
37 e biosynthesis of these natural products has furnished a diverse array of halogenation biocatalysts,
38 reported ((Ar)L)FeCl with potassium graphite furnished a low-spin (S = 1/2) iron complex ((Ar)L)Fe wh
40 itation of promiscuous flavoenzymes has thus furnished a previously unknown biocatalytic reaction.
41 lactam, resulted in 5-exo cyclizations which furnished a series of 2,5-dimethyl-1-((3R,4'S)-2H-spiro[
42 activation reactions of EH(3) with 1, which furnished a silyl nickel(II) complex through NH(3) activ
44 ometric amount of 1-azidoadamantane (AdN(3)) furnished a three-coordinate, diamagnetic Co(III) imide
46 article analysis of homopolymer partitioning furnishes a basis for understanding the symmetry breakin
49 unit of a Gb5 pentasaccharide backbone that furnishes a Neu5Acalpha(2,6)GalNAc-linked hexasaccharide
52 hydrolysis of 1-methylcytosine, for which it furnishes a satisfactory kinetic model and a probable me
53 col is operationally simple and scalable and furnishes a series of high-value 2-alkenylheteroarenes i
55 Oxidation of proline to 5-hydroxyproline furnishes a versatile intermediate that can be transform
56 through an aromatic iminium intermediate and furnishes a wide range of 2-substiuted 2H-thiochromenes
57 nd aldehydes, whereas CF(3) radical addition furnishes a wide range of gem-difluoroalkenes through be
58 framework of bounded evidence accumulation, furnishing a platform for the study of such multi-stage
59 g insight into host-pathogen dialog that may furnish actionable targets for antiparasite therapies or
60 s a powerful method to determine CMCs, as it furnishes additional information on the enthalpy and ent
63 oxo-scissoring of a wide range of alkenes to furnish aldehydes and/or ketones in high yield using a l
64 he unusual and rapid cyclization reaction to furnish all new carbazole compounds through installation
65 with retention of the diazo functionality to furnish alpha-cyclic-alpha-diazo compounds that are them
69 a catalytic isocyanide reductive coupling to furnish an alkene product (4) in a transformation that h
70 lphosphines (PCy(3) and PEt(3)) surprisingly furnish an aminophosphonium substituted by a zwitterioni
71 s that employ Grignard reagents are shown to furnish an array of nonracemic chiral organoboronic este
73 rately, the Black/Leff operational model has furnished an extremely valuable method of quantifying dr
74 f this alcohol with a C1-C19 carboxylic acid furnished an open C1-C25 macrolactone precursor, but thi
78 particles supported on activated carbon and furnishes arenes and phenols in high yields without hydr
79 e, and fast at or below ambient temperature, furnishing arylamines in moderate-to-good yields and wit
80 (HR) water, i.e. moisture content in the wet furnish at the transition between constant rate part and
83 yl anions, which can be processed further to furnish beta-substituted, alpha,beta-disubstituted, or a
84 cation, isomerization, and lactamization, to furnish bicyclic 2-pyridones in up to 98% yield with ret
85 perform 3D spectroscopic microimaging and to furnish biologically interpretable, quantitative, and dy
86 l is intercepted by bis(catecholato)diboron, furnishing boronic esters from a diverse range of struct
87 C-F bond in partially fluorinated arenes, to furnish borylation products under catalyst-, metal-, and
88 e reaction proceeds in a kinetic resolution, furnishing both epoxide and thiirane in high yields and
89 the expected HWE product, aromatic aldehydes furnished butenolides, resulting from the dimerization o
92 dicare Provider Utilization and Payment Data furnished by the Centers for Medicare and Medicaid Servi
93 dicare Provider Utilization and Payment Data furnished by the Centers for Medicare and Medicaid were
95 The results were in agreement with those furnished by UV-vis spectrometry and endorsed by statist
96 l-, heteroaryl-, and alkenylboronic acids to furnish C(3) aryl-, heteroaryl-, and alkenyl-substituted
98 lation and quenching with an electrophile to furnish C6-substituted derivatives which, in the presenc
99 d aniline products or intramolecular ones to furnish carbazole-4-carboxylates in mostly good to excel
102 ates that bear geminal dimethyl substituents furnished chiral amines that feature a quaternary stereo
104 and other imaging modalities is promising to furnish complementary information for accurate cancer di
105 ed stereospecific C-H arylation chemistry to furnish complex scaffolds primed for DEL synthesis, and
106 nded portrait of the ligandable proteome and furnishes compounds that can illuminate protein function
107 ation of terminal and internal 1,3-enynes to furnish corresponding dienylboronates in high efficiency
110 sors tethered by a simple phenoxy linker and furnishes cycloadducts with a prominent structural motif
112 h SeO(2) in the presence or absence of water furnishes di- and trioxidized cyclopentenones, respectiv
113 winds provide an important energy source for furnishing diapycnal mixing primarily through the genera
114 demethylases of N6-methyladenosine (m6A) but furnish different major products, N6-hydroxymethyladenos
115 ansformation of the P- and As-analogues of 1 furnishes directly the respective side-on Si=E Ni comple
118 ly efficient oxidative annulation of alkynes furnished diversely substituted pyran[2,3,4- de]chromene
119 e penultimate core acid 2 with sulfonamide 3 furnishes drug substance 1 with consistently high qualit
120 ing to functionalized biaryls and ultimately furnishing drug-like small molecules, as well as late st
122 l of a considerable amount of water from the furnish during processing, necessitating thorough unders
126 ns of a single proline-containing tripeptide furnish eight tripeptides, each having different unnatur
127 oup via 5-exo-tet or 6-exo-tet cyclizations, furnishing either pyrrolidine or piperidine, respectivel
128 egiodivergent arylations of cycloalkanols to furnish enantioenriched dysideanone's analogues are perf
131 ary N-alkoxycarbonyl- N-aryl-beta-enaminones furnished exclusively the trans-hexahydrocarbazol-4-ones
132 on/N-acyliminium ion cyclization sequence to furnish four of the five requisite rings and three of th
134 cy of the oxygen reduction reaction (ORR) is furnished from a systematic electrochemical study by usi
135 he enol double bond and the amide bond, thus furnishing fully substituted 5-isoxazolone derivatives.
136 nd alkenyl acetates are well tolerated, thus furnishing functionalized Csp(2)-Csp(3) coupling product
138 ctive annulation of 1,4,2-dioxazol-5-ones to furnish gamma-lactams in up to 97% yield and 98% ee via
139 ligand discovery with chemical proteomics to furnish global portraits of reversible small-molecule/pr
140 ing outcomes of treatment for type 1 HRS and furnishes guidance for the design of future dose-ranging
141 lly design photocatalytic water-splitting to furnish [H] or [D] and isotope alkanol-oxidation by phot
143 -[1,4]-sigmatropic rearrangement to directly furnish heterocyclic products with net retention at the
144 molybdenum monoaryloxide chloride complexes furnish higher-energy (Z) isomers of trifluoromethyl-sub
145 on for the case of methacrylates and styrene furnishing higher molecular weight copolymers with minim
146 table for electron-deficient aryl chlorides, furnishing higher yields than the corresponding aryl bro
151 grains on the surface of the grinding stone furnished information about the tool handling, confirmin
152 aromatic aldehydes with 2-halobenzyl halides furnishes intermediates that can be cyclized to 1,2-disu
153 ctionalization of a wide array of olefins to furnish iodination products as single stereoisomers.
155 enol ethers were used to trap the radicals, furnishing ketones after successive single-electron oxid
157 -electron reduction of ((tbs)L)Fe(3)(thf)(1) furnishes [M][((tbs)L)Fe(3)] ([M](+) = [(18-C-6)K(thf)(2
160 and mtDNA copy number, which are required to furnish mature eggs with an adequate supply of mitochond
161 ith hyperpolarized [(13)C]-Glyc in rat liver furnished metabolic products, [(13)C]-labeled pyruvate a
165 the development of reflectins as materials, furnish molecular-level insight into the mechanistic und
167 ich reaction and subsequently derivatized to furnish more than one protected beta(2)-homologous amino
169 nding assays, we show that the MHC-Ib family furnishes multiple binding partners for murine CD8alphaa
172 dine is a (7e + 7H(+)) oxidative cascade and furnishes N-pyridinecinnolinyl radical ((Py)Cn(*)).
177 is highlighted through transformations that furnish other desirable derivatives and a concise synthe
180 ced cores enhances their optical properties, furnishing particles with center emission wavelengths be
181 ded for viral assembly and on the other hand furnish peptides that exhibit broad-spectrum virocidal a
182 yzed asymmetric allylic alkylation reaction, furnishing phosphinates with high enantio- and diastereo
183 pplications in transition-metal chemistry to furnish pincer complexes or "pogo stick" type compounds.
185 mall N(6)-cycloalkyl and 3-halobenzyl groups furnished potent dual acting A1AR agonists and A3AR anta
186 t of the cerebellum in tic production; (iii) furnishes predictions on the amount of tics generated wh
187 transformation proceeds in moderate yield to furnish previously unreported and structurally diverse N
189 to the desymmetrization of meso 1,2-diols to furnish products with three stereogenic centers and a te
191 ylzinc reagents with internal alkenes, which furnishes products with three contiguous all-carbon seco
192 f substituted tetralone-derived nucleophiles furnishing products bearing a newly formed vicinal terti
195 lysis of catalytic voltammograms can quickly furnish qualitative evidence of precatalyst transformati
196 literature on GO systems in organic solvents-furnish quantitative explanations for the empirically un
198 oteins and the cell lipid envelope that have furnished rapid and selective diagnostic strategies and
201 labeling of the desferroxamine B conjugates furnished scV/Zr, scVR1/Zr, and scVR2/Zr tracers with hi
203 e show that fragment hits can be advanced to furnish selective ligands that affect the activity of pr
204 ing of the resulting beta-aminoboronic acids furnishes selective and cell-active inhibitors of the (o
205 proach for mitigating malicious attacks, and furnish self-healing to reconstruct failed infrastructur
207 ion reactions with diazoacetate derivatives, furnishing sp(2) -sp(3) coupled products with moderate-t
210 d the naphthoquinone headgroup of the former furnishes stronger binding interactions with the pocket,
212 %), while the reaction with secondary amines furnish sulfuramidimidoyl fluoride products (8 examples,
213 eous C-C homocoupling at room temperature to furnish symmetrical (bis)aryls in good yields under mild
214 ative allylation of few products is shown to furnish synthetically viable enantioenriched 2-oxindoles
215 window onto a system's dynamics, and should furnish tests of the neutral hypothesis that are more po
216 r a one-pot trimetallic orthogonal catalysis furnish tetrahydrocyclohepta[b]indoles, and a one-pot qu
217 mpatible with allenes in place of alkynes to furnish tetrasubstituted alkenyl halides, showcasing the
219 nalyzed two real phenotypes (hair length and furnishing), that are fixed in certain breeds to charact
220 5-exo-dig cyclization in a domino fashion to furnish the 2-iminothiazolidine derivative in excellent
221 ent, as an E/Z mixture of cinnamyl chlorides furnish the anti-chlorocyclopropane product in high dias
225 r-Napieralski cyclization/reduction cascades furnish the cis- and trans-fused azadecalin subunits pre
227 react with racemic alpha-branched amines to furnish the corresponding enantioenriched enaminone and
230 resonance (EPR) imaging data sets that will furnish the distribution maps and the spectral signature
232 d enolate coupling reaction was then used to furnish the final E ring and complete the total synthesi
233 ia a physiologically stable oxime linkage to furnish the first semisynthetic bacterial-based immunoge
234 d to the ring closing metathesis reaction to furnish the gem-difluoromethylene containing cyclopenten
236 the two silylene subunits are regenerated to furnish the isolable bis(silylene)-stabilized N(I) compl
237 ides is reported under ambient conditions to furnish the medicinally important 1,4-disubstituted-5-ar
238 th various ketones at ambient temperature to furnish the optically active functionalized (2-azidophen
240 acid additives and under mild conditions to furnish the target species, including those derivatized
241 ecially for late-stage functionalization, to furnish the targeted compounds through frequently used a
244 (R)- or (S)- tetrahydrofuran-2-carboxamides furnished the corresponding (2R,3R) and (2S,3S) C3-aryla
245 ethers obtained from ynones to sulfinimines furnished the corresponding beta-sulfinamido ynones in a
246 l-3-ones and ortho-halo aryl carboxaldehydes furnished the corresponding chromone fused pyrazoles, in
247 4-(tert-butyl)benzene N(3)(C(6)H(4)-p-(t)Bu) furnished the corresponding four-coordinate organoazide-
248 N(C6H4-p-(t)Bu)) (2) with potassium graphite furnished the corresponding high-spin (S = (5)/2) imido
249 ular cyclization/nucleophilic addition at C7 furnished the corresponding tetrahydro-5 H-benzo[ c]fluo
250 ium-catalyzed cross-coupling with haloarenes furnished the desired trisubstituted imidazole scaffolds
251 3.1]nonane (9-BBN) as a potential Lewis acid furnished the first boryl(silyl)germylene complex 6, pos
253 ilibrated thermodynamic <-> kinetic enolates furnished the highly regioselective functionally rich 1,
257 protected adenine, followed by deprotection, furnished the target nucleoside FMCA (12) in high yield.
258 hols in the absence of any external oxidants furnished the tetrasubstituted alkene as the major produ
259 triosyl trichloroacetimidate donor unit then furnished the undecasaccharide harboring a D3-arm extens
260 nt of 1a with one or two molecules of Xyl-NC furnished the unique (silyl)(imido)silene 3a and the C=C
263 xygenation of A with N(2) O at -60 degrees C furnishes the deep blue 1,2-disiloxydiarsene, [LZnOSi(L'
265 tolerates a variety of functional groups and furnishes the desired products in high yields (up to 92%
266 order in strongly correlated metals commonly furnishes the development of unconventional superconduct
267 ructurally different diazocarbonyl compounds furnishes the donor-acceptor cyclopropane-fused benzoxa[
268 yclic carbene=C[((i) Pr)NC(Me)]2 ) with N2 O furnishes the first Si-metalated iminosilane, [DippN=Si(
270 for a subsequent variographic analysis that furnishes the newly designed quantitative global heterog
271 reaction proceeds under mild conditions and furnishes the oxysulfonylated products in moderate to ex
272 ent triketone reacts at room temperature and furnishes the pyrazine or bis-pyrazine-containing conden
274 ion accompanied by a C-H activation reaction furnishing the 7-hydro-7-borabenzo[de]anthracene derivat
275 ence of a Pd(OAc)2/Dpephos catalytic system, furnishing the fused indolo[2,1-a]phthalazines in high y
276 resence of a PdBr2/DPEphos catalytic system, furnishing the novel biheterocycles based on quinolin-4-
277 bonates are competent electrophilic partners furnishing the products in excellent enantioselectivity
278 e reaction tolerates a wide range of alkynes furnishing the products in high yields and excellent ena
281 es and thioamides underwent thiocyanation to furnish thiocyanated thiazoline and oxazoline derivative
282 bes the organocatalytic methods available to furnish THPs as well as the application of these methodo
283 etric amount of various alkyl azides (N(3)R) furnished three-coordinate Co(III) alkyl imidos ((Ar)L)C
284 istic studies reveal that the anti-isomer is furnished through concurrent Pd(II)(SOX) catalyzed C-H a
286 f-assembly approach that has the prospect of furnishing unprecedented heterometallic bicyclic archite
287 ses, recognizing them in fossilized bone can furnish us with important information on dinosaurs' phys
288 The whole of the obtained kinetic data has furnished useful information on the high nucleophilic re
290 nes with alkyl hydroperoxides is reported to furnish various peroxycarbonyls and 1,3-haloperoxygenate
291 ters bearing gamma-propargylic C-H bonds and furnishes versatile products in good yields and excellen
293 havior of a wood-CNF particulate system (wet furnish) was studied through pressure filtration tests,
294 significant effect on the dewatering of wet furnish where dewatering rate significantly increased at
295 ective C-H alkylation of aniline derivatives furnished with a pyrimidine auxiliary is herein reported
296 oad, and C-H functionalization products were furnished with excellent levels of enantioselectivity.
298 demands of embryogenesis, mature oocytes are furnished with vast amounts of mitochondria and mtDNA Ho
299 The corresponding beta-hydroxyamides can be furnished with yields up to 92% and an enantiomeric exce
300 tes in BF(3).OEt(2)-catalyzed crotylation to furnish (Z)-delta-boryl-syn-homoallylic alcohols with go