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1 icarbonyl (glyoxal) or C(2)-hydroxycarbonyl (glycolaldehyde).
2 adicals, a crucial intermediate in producing glycolaldehyde.
3 s: 4-hydroxy-2-nonenal, malondialdehyde, and glycolaldehyde.
4 experiments, starting with formaldehyde and glycolaldehyde.
5 ase activity toward beta-hydroxypyruvate and glycolaldehyde.
6 ford, MA) was nonenzymatically glycated with glycolaldehyde.
7 amples with (13)C- and (2)H-labeled forms of glycolaldehyde.
8 inobenzene protected against the toxicity of glycolaldehyde.
9 rin to 6-hydroxymethyl-7,8-dihydropterin and glycolaldehyde.
10 the substrate, HOCl generates high yields of glycolaldehyde.
11 species for the selective oxidation of EG to glycolaldehyde.
13 on of the truncated substrate piece [1-(13)C]glycolaldehyde ([1-(13)C]-GA) in D(2)O, a 25-fold increa
14 the deuterium exchange reactions of [1-(13)C]glycolaldehyde ([1-(13)C]GA) to form [1-(13)C,2-(2)H]GA
17 organic aerosol production was observed for glycolaldehyde, acetaldehyde, and formaldehyde only at e
18 ylglyoxal, glyceraldehyde, dihydroxyacetone, glycolaldehyde, acetaldehyde, glyoxal, glyoxylic acid, a
20 ine ammonia-lyase reveal that treatment with glycolaldehyde also results in formation of an ethanesem
21 Activated neutrophils converted L-serine to glycolaldehyde, an alpha-hydroxyaldehyde which mediates
22 onstitutional chemical relationships between glycolaldehyde and beta-mercapto-acetaldehyde, and the c
23 membrane-like matrix, was cross-linked with glycolaldehyde and control and cross-linked matrices com
24 onucleotide precursor-is readily formed from glycolaldehyde and cyanamide, so is 2-aminothiazole form
26 rmation, the important nucleotide precursors glycolaldehyde and glyceraldehyde in a stable, crystalli
27 that simple two- and three-carbon molecules (glycolaldehyde and glyceraldehyde), in the presence of a
28 the sugar building blocks for the synthesis--glycolaldehyde and glyceraldehyde--could be shown to der
29 ed 10 aldehydes, including the sugar-related glycolaldehyde and glyceraldehyde--two species considere
31 )K(GA) for reactions of the substrate pieces glycolaldehyde and HPO3(2-) have been determined for wil
33 (cat)/K(m))DHAP] and of the substrate pieces glycolaldehyde and phosphite dianion (k(cat)/K(HPi)K(GA)
35 l was approximately 10 times more toxic than glycolaldehyde and was more toxic to the SOD-null strain
36 nd low-NO conditions include hydroxyacetone, glycolaldehyde, and 2,3-dihydroxy-2-methyl-propanal (DHM
37 ally as well as in combination with glyoxal, glycolaldehyde, and acetaldehyde at elevated temperature
38 ius 1 mm) containing iron(III), oxalic acid, glycolaldehyde, and ammonium sulfate (pH approximately 3
39 mixture of Nalpha-tert-butoxycarbonyllysine, glycolaldehyde, and glyceraldehyde could produce the Nal
40 e aldehydes (e.g., glyoxylate, formaldehyde, glycolaldehyde, and glyceraldehyde) in water were invest
42 rate constant (kcat/Km)obsd for turnover of glycolaldehyde, and the dependence of (kcat/Km)obsd on [
47 as targets for superoxide was examined using glycolaldehyde as the simplest sugar and using superoxid
48 tmosphere by reaction with (*)OH and O2 with glycolaldehyde being identified as a previously unconsid
49 carboxylic acids from tetroses, trioses, and glycolaldehyde, but cannot readily catalyze retro-aldol
50 activation of hlGPDH-catalyzed reduction of glycolaldehyde by FPO3(2-) to -3.0 kcal/mol for activati
51 a give kcat/Km = 185 M-1 s-1 for turnover of glycolaldehyde by TIM that is saturated with phosphite d
52 chilles tendon fibroblasts were treated with glycolaldehyde-derived advanced glycation end-products (
53 atoms on TiO(2) enable the reduction of the glycolaldehyde desorption barrier, thereby facilitating
55 or competing mechanisms-sequential losses of glycolaldehyde/ethenediol molecules from the reducing en
56 thane) and minor products (ethanol, glyoxal, glycolaldehyde, ethylene glycol, acetaldehyde, ethane, a
57 were prepared from 2 by a condensation with glycolaldehyde followed by tandem reductive amination of
58 istent with CO(2)RR product distribution, as glycolaldehyde formation during CO(2)RR is limited, whic
59 2-)) activated hydride transfer from NADL to glycolaldehyde (GA) catalyzed by glycerol-3-phosphate de
60 se in k(cat)/K(m) for isomerization of bound glycolaldehyde (GA), although the dominant observed prod
61 s no detectable activity toward reduction of glycolaldehyde (GA), or activation of this reaction by 3
63 ction of carbonyl compounds glyoxal (GO) and glycolaldehyde (GLA) with pyridoxamine (PM), a potent po
64 DHAP) and of the neutral truncated substrate glycolaldehyde (GLY) by glycerol 3-phosphate dehydrogena
65 for the synthesis-cyanamide, cyanoacetylene, glycolaldehyde, glyceraldehyde and inorganic phosphate-a
68 ng the release of formaldehyde, formic acid, glycolaldehyde, glyoxal, acetic acid, glycolic acid, gly
69 d hydroxynonenal) or carbohydrate oxidation (glycolaldehyde, glyoxal, and methylglyoxal) covalently m
74 st step or steps of the catalytic process on glycolaldehyde hydrate generate an intermediate that und
75 ion proceeds by a radical mechanism, and the glycolaldehyde hydrate is expected to be converted initi
77 followed the order methylglyoxal > glyoxal > glycolaldehyde = hydroxyacetone, likely caused by the sp
78 methods to ionize known pyrolysis products: glycolaldehyde, hydroxyacetone, furfural, 5-hydroxymethy
79 o the atmospheric budgets of hydroxyacetone, glycolaldehyde, hydroxymethyl hydroperoxide, formic acid
80 ave been developed; alkynyl boronates add to glycolaldehyde imine to afford allylic hydroxyl allenes,
83 ceraldehyde by reaction of formaldehyde with glycolaldehyde is catalyzed under prebiotic conditions t
86 alysis of the inactivated complex shows that glycolaldehyde is transformed into a cis-ethanesemidione
87 rmose reaction, formaldehyde is converted to glycolaldehyde, its dimer, under credible prebiotic cond
88 e Tbb TIM and monoTIM-catalyzed reactions of glycolaldehyde labeled with carbon-13 at the carbonyl ca
89 Product distributions for the reaction of glycolaldehyde labeled with carbon-13 at the carbonyl ca
90 C(2)-hydroxycarbonyl intermediate, such as a glycolaldehyde-like compound, as confirmed by adding gly
92 ber explore the reactive uptake of gas-phase glycolaldehyde onto aqueous seed aerosol containing iron
94 w aldol condensation of dihydroxyacetone and glycolaldehyde phosphate with an initial k(cat) of 1.6 x
95 ge to the enediolate of dihydroxyacetone and glycolaldehyde phosphate, followed by rotation of the al
99 prebiotic model of sugar synthesis involving glycolaldehyde self-condensation, we demonstrate that ho
101 uctose-6-phosphate a physiological donor and glycolaldehyde the best non-phosphorylated acceptor.
102 The ions were shown to be glycopyranosyl-glycolaldehydes through chemical synthesis of their stan
104 esults indicate that the reaction pathway of glycolaldehyde to produce syngas can be enhanced by supp
106 omer of polyethylene terephthalate (PET)) to glycolaldehyde using atomically dispersed Pd species sup
109 The reactive uptake and aqueous oxidation of glycolaldehyde were examined in a photochemical flow rea
110 th slope and intercept effects versus varied glycolaldehyde were produced, indicating that TPCK react
111 dihydroxy acetone, and the two carbon sugar glycolaldehyde, were similarly toxic in an O-2-dependent
112 selective Petasis borono-Mannich reaction of glycolaldehyde with primary or secondary amines and boro
113 small aldehydes (glyoxal, methylglyoxal, and glycolaldehyde) with ammonium sulfate and amines are com