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1 -/C-glycosides), and apigenin (exclusively C-glycosides).
2 etween phloroglucinol and a para-diazophenyl glycoside.
3 zed hydrofunctionalization of the enol ether glycoside.
4 ective for the formation of the equatorial C-glycoside.
5 des to their aglycones, but did not affect C-glycosides.
6 gars in hemiacetal form, rather than typical glycosides.
7 nts perform better than di- or trisaccharide glycosides.
8 empferol 3-O-arabinoside and other flavonoid glycosides.
9 d provides efficient access to alpha-1,2-cis glycosides.
10 ystems were established for the synthesis of glycosides.
11 ptake assays based on (14)C-labeled flavonol glycosides.
12 o inhibit inflammasome activation by cardiac glycosides.
13 es to the free N,N-diacetyllegionaminic acid glycosides.
14 focused on determination of steviol and its glycosides.
15 h as nicotine, phenolamides, and diterpenoid glycosides.
16 allowed the selective installation of alpha-glycosides.
17 mediates for the synthesis of functionalized glycosides.
18 is of trans-1,2-, cis-1,2-, and 2-deoxy-beta-glycosides.
19 acid, as well as phenylethanoid and iridoid glycosides.
20 ycone libraries prepared from isolated plant glycosides.
21 on their composition and content of flavonol glycosides.
22 lyze tannin compounds, depsides and phenolic glycosides.
23 xycinnamic acid amides (HCAAs) and flavonoid glycosides.
24 leasing volatile aglycones from non-volatile glycosides.
25 Disaccharides afforded novel pyrrolo-glycosides.
26 stereospecific construction of beta-linked C-glycosides.
27 from flavone copigmentation was observed for glycosides.
28 ilability relative to typical cereal grain C-glycosides.
29 both donors in the formation of exemplary O-glycosides.
30 tereoselective synthesis of 1,2-trans-beta-O-glycosides.
31 in the mechanism of absorption of flavonoid glycosides.
33 es of ellagic acid, 12 flavanols, 4 flavonol glycosides, 1 flavone, 17 hydroxybenzoic acids and 7 hyd
35 nce and target-site insensitivity to cardiac glycosides(16), culminating in triple mutant 'monarch fl
38 renylated coumarins (2 and 3) and a marmesin glycosides (4) from Micromelum minutum methanol bark ext
39 nes (range 57-137 mug/g) were dominated by O-glycosides (50-68%), present as derivatives of tricin (e
40 es, flavonol-3-O-(dihydrophaseoyl, cinnamoyl)glycoside-7-O-rhamnosides and flavonol-3-O-(malonyl)glyc
41 onol-glycosides, and flavonol-3-O-(cinnamoyl)glycoside-7-O-rhamnosides, flavonol-3-O-(dihydrophaseoyl
43 mentation, clustered in flavonol-3-O-di-/tri-glycosides-7-O-rhamnosides and other flavonol-glycosides
45 g products can be readily derivatized into C-glycoside analogues of beta-glycoconjugates, including C
49 imes wine-like concentration, Gewurztraminer glycosides and geranyl glucoside gave significant fruity
51 enzyme that can selectively hydrolyze mogrol glycosides and promote the conversion of the natural swe
53 constants for spontaneous hydrolysis of aryl glycosides and their analogous valienyl ethers were foun
55 igenin-C-glycosides, three methoxyluteolin-C-glycosides and three tricin-O-glycosides some of which h
56 exclusively O-glycosides), chrysoeriol (O-/C-glycosides), and apigenin (exclusively C-glycosides).
58 ophiles, including complex natural products, glycosides, and amino acids were beta-mannosylated and b
59 lycosides-7-O-rhamnosides and other flavonol-glycosides, and flavonol-3-O-(cinnamoyl)glycoside-7-O-rh
60 th flavonol glycosides, flavones and flavone glycosides, and hydroxycinnamic acids representing 67.6,
61 ccurs via the analogous mechanisms found for glycosides, and through a very similar transition state.
65 at many noncanonical nucleotides and related glycosides are formed much more easily than the canonica
66 l by the European Commission (2011), steviol glycosides are increasingly used as high-intensity sweet
70 identify two withanolides and one fatty acyl glycoside as tentative metabolites to differentiate gold
71 ing an assay employing unnatural nitrophenyl glycosides as activated donors, resulted in the discover
74 tation patterns between the isolated saponin glycoside at m/z 1445.64 [M + formic-H](-) equivalent to
75 uiterpenes, iridoid monoterpenes, cyanogenic glycosides, benzoic acid derivatives, benzoquinones and
80 synthesize 2-deoxysaccharides with specified glycoside bond stereochemistry using a nucleophilic carb
81 mental stages on canopy, yield, and free and glycoside-bound terpenes of the berry were investigated
82 reducing carbohydrates; 3) HAGBC occurs for glycosides but not at the reducing end of cellodextrins;
83 iana resulted in small amounts of kaempferol glycosides but not myricetin glycosides, suggesting that
84 ls like polyphenols, saponins, and steroidal glycosides, but its crop is greatly affected by drought.
86 Chemical syntheses of oligosaccharides and glycosides call utilization of many protecting groups th
87 e precisely controlled, both alpha- and beta-glycosides can be synthesized from the same starting mat
88 showed for the first time that grape-derived glycosides can contribute perceptible fruity flavour, pr
89 roach to stereoselective synthesis of C-aryl glycosides capitalizing on the highly stereospecific rea
90 at it is able to catalyze formation of the C-glycoside carboxyhydroxypyrazole ribonucleotide (CHPR) f
91 hydroxycinnamic acid derivatives, flavonoid glycosides, carotenoids and chlorophylls in the leaves o
93 sent as derivatives of tricin (exclusively O-glycosides), chrysoeriol (O-/C-glycosides), and apigenin
99 nal modeling of the relative energies of the glycoside-derived boronic esters provides results that a
101 The method is tolerant of a wide range of glycoside donors and acceptors, and its versatility is e
102 ated the sensory significance of monoterpene glycosides during tasting, by retronasal perception of o
103 portant factors contributing to the "cluster glycoside effect" observed in carbohydrate-lectin intera
104 g key motif for the molecular recognition of glycosides, either by protein binding domains, enzymes,
105 ion of a wide range of complex substituted O-glycoside esters in good to excellent yields with an exc
111 ated through Orbitrap LC-MS/MS with flavonol glycosides, flavones and flavone glycosides, and hydroxy
114 isolated, structurally related cyanidin-3-O-glycosides from black carrot were investigated in aqueou
116 lation reactions and the reactivity of donor glycosides has been tuned to affect stereoselective glyc
117 lting in the formation of HCAAs and flavonol glycosides have been characterized, it is unclear how th
118 roved to be general, and a variety of aryl O-glycosides have been prepared in good to excellent yield
119 Escherichia coli 120, as its p-methoxyphenyl glycoside, have been achieved using a one-pot sequential
120 of sugar gamma-lactones into highly valuable glycosides having a quaternary anomeric position substit
123 ng protein sequence space has revealed a new glycoside hydrolase (GH) family (GH164) of putative mann
124 substrate, we identified and characterized a glycoside hydrolase 109 (GH109) that is active on blood
127 glycanases are part of the large and diverse glycoside hydrolase 16 (GH16) family and are often lipop
128 ns (ZgAgaC) that is distantly related to the glycoside hydrolase 16 (GH16) family beta-agarases and b
130 ype A-antigen, along with a new subfamily of glycoside hydrolase 31 (GH31) that specifically cleaves
131 tive sugar-binding pockets characteristic of glycoside hydrolase 70 (GH70) glucansucrases that are kn
132 his array for detecting exo- and endo-acting glycoside hydrolase activity using commercial enzymes, a
134 reveal the first instance of an FMN-binding glycoside hydrolase and suggest a potential link between
135 s of specific gene families belonging to the glycoside hydrolase category reflected contrasting ecolo
136 known multicatalytic enzymes contain several glycoside hydrolase domains and one or more carbohydrate
140 two distant bacterial phyla, which belong to glycoside hydrolase family 16 and cleave the beta-1,4 li
141 physiological roles of the four C. japonicus glycoside hydrolase family 3 (GH3) members on diverse be
144 ng forces underlying specificity patterns in glycoside hydrolase family 5, we quantitatively screened
146 H. jecorina Cel7A, cellobiohydrolase I, from glycoside hydrolase family 7, is the workhorse enzyme of
147 Microbial alpha-glucans produced by GH70 (glycoside hydrolase family 70) glucansucrases are gainin
153 d function necessitate the creation of a new glycoside hydrolase family, GH166, whose structural and
156 hydrolase domains from Sph3, an A. fumigatus glycoside hydrolase involved in GAG synthesis, and PelA,
157 -mannosidase (MANEA) is the sole endo-acting glycoside hydrolase involved in N-glycan trimming and is
158 urated uronic acid, is removed from AGP by a glycoside hydrolase located in family GH105, producing t
159 , we show that recombinant Ega3 is an active glycoside hydrolase that disrupts GAG-dependent A. fumig
160 ay, the alpha-galactosidase Aga (a family 36 glycoside hydrolase), can cleave alpha-(1->3)-linked gal
163 The independent activities of PUL-encoded glycoside hydrolases (GHs) and surface glycan-binding pr
172 propose a scheme of sequential action by the glycoside hydrolases encoded by the beta-mannan PUL and
175 linear alpha-Gal epitope can be processed by glycoside hydrolases in family GH110, whereas the presen
176 enes, in particular a strong upregulation of glycoside hydrolases involved in mannan degradation.
177 he nature of such a reaction intermediate in glycoside hydrolases operating via substrate-assisted ca
178 endent enzymes (EC 1.14.99.53-56) that, with glycoside hydrolases, participate in the degradation of
179 mulated 284 putative fucoidanases, including glycoside hydrolases, sulfatases and carbohydrate estera
183 onstrate the superiority of an apramycin-5-O-glycoside in reducing the bacterial burden in vivo.
184 Stevioside is the most prevalent steviol glycoside in Stevia rebaudiana plant leaves, but it has
185 nsist of two hydrophobic chains and an alpha-glycoside in which the 2'-OH group is in the cis orienta
188 Although flavonoid sophorosides are common glycosides in brassica vegetables, red raspberries and o
189 strain-release glycosylation generates O, N-glycosides in excellent anomeric selectivity exceeding H
190 tertiary alcohols affords the corresponding glycosides in excellent yield and good to excellent equa
191 eptors and leads to their corresponding O/ N-glycosides in good to excellent yields with regeneration
192 -suppressing functions of anticancer cardiac glycosides in human glioblastomas and glioma cancer stem
194 rtook comprehensive screening of secoiridoid glycosides in leaf extracts of trees tolerant and suscep
197 agment restored the accumulation of flavonol glycosides in pollen grains to wild-type levels, corrobo
201 opyranosyl ester) is one of the main steviol glycosides in stevia leaves known for its hydrolytic ins
202 iciently promoted the formation of 2-deoxy S-glycosides in the presence of thiols, probably by in sit
204 eport an unexpected diversity of secoiridoid glycosides in UK trees and higher levels of secoiridoid
205 tral conditions and gave the corresponding C-glycosides in up to 95% yield with moderate to excellent
206 Suppression of autosis by ouabain, a cardiac glycoside, in humanized Na+,K+-ATPase-knockin mice reduc
208 edominantly developed diversity in flavonoid glycosides, including 7-O-methyltransferase activity.
209 ve concentrations of twenty-six monoterpenyl glycosides, including nine new putatively identified com
210 catannin C, flavonoids; phloretin, quercetin glycoside, indolamine; punigratane, and phenolic acid; c
213 significant bioconversion of the isoflavone glycosides into their corresponding bioactive aglycones
214 eta-CIP) species, the formation of the alpha-glycoside is necessarily preceded by a bimolecular alpha
215 anoside acid (AG-G), 3-indolyl-(2R)-O-beta-d-glycoside lactic acid (ILA-G) and epi-DPA-3'-O-beta-gluc
220 ses by preparing valienyl ethers to serve as glycoside mimics that are capable of allylic rather than
222 ctive syntheses of more complex monosulfated glycosides, namely, a 3'-sulfolactose derivative and 3'-
225 raparinux is a fully O-sulfated alpha-methyl glycoside of heparin pentasaccharide motif known to inte
229 vonol glycosides in black beans were the 3-O-glycosides of kaempferol, quercetin and myricetin; pinto
230 th the position and extent of sulfation of a glycoside often playing important roles in determining t
232 h different affinities either delphynidine-3-glycoside or delphynidine-3-rutinoside, therefore explai
234 High contents in anthocyanins, flavonol-3-O-glycosides, phenolic acids and flavan-3-ols were found i
237 ins showed deglycosylation of the isoflavone glycosides present in soy drink and appearance of the ag
238 pounds, such as flavanols, flavonol mono-/di-glycosides, proanthocyanidin dimers, and phenolic acids.
241 into the stereoelectronic effects governing glycoside reactivity will eventually enable the concepti
242 ulfame potassium and sucralose), one steviol glycoside (rebaudioside A), and high fructose corn syrup
243 ile the significance of aromatic stacking on glycoside recognition is well stablished, its impact on
244 on of high abundances of HCAAs and flavonoid glycosides reinforce cell walls to contain the pathogen
246 ite plasma membrane (PPM) to the amphipathic glycoside saponin and engenders digestive vacuoles (DVs)
248 oor aqueous solubility of some minor steviol glycosides (SGs) has prevented their potential widesprea
249 roved better suited for generating 2-deoxy O-glycosides, significantly broadening the scope of the ap
251 hoxyluteolin-C-glycosides and three tricin-O-glycosides some of which have not been reported in sugar
253 7-O-rhamnoside were the three major flavonol glycosides, stachyurin and casuarinin were the most abun
254 osylation, the site-selective acylation of S-glycosides streamlines oligosaccharide synthesis and wil
255 active site, but the FEL of corresponding O-glycoside substrate reveals a preference for a Michaelis
257 s alpha-glycosidase can react with unnatural glycosides such as 6-azido-6-deoxy-d-glucose/glucosamine
258 t highly selective entry into KDO equatorial glycosides such as are found in the capsular polysacchar
259 lowing the conversion of chitin into complex glycosides, such as C5-modified sialosides, through the
260 s of kaempferol glycosides but not myricetin glycosides, suggesting that myricetin was limiting.
263 crocins, a complex mixture of apocarotenoid glycosides that accumulate in intracellular vacuoles and
264 s are hydrolase-resistant mimics of O-linked glycosides that can serve as valuable probes for studyin
265 release glycosylation defines a new class of glycosides that inhibit the hedgehog signaling pathway t
266 of all reaction partners involved: the donor glycoside (the electrophile), the activator (that genera
267 tentative identification of seven apigenin-C-glycosides, three methoxyluteolin-C-glycosides and three
268 -selective acylation at the C2 position of S-glycosides through dispersion interactions between the a
269 rch flies' retained small amounts of cardiac glycosides through metamorphosis, a trait that has been
270 s of a substituent at the anomeric carbon in glycosides to adopt axial configuration when the anomeri
271 sequence enables conversion of the protected glycosides to the free N,N-diacetyllegionaminic acid gly
275 y and adverse events associated with cardiac glycosides use in humans and that targeted anti-inflamma
276 ed on methyltitanium, preparation of a vinyl glycoside via Isobe C-alkynylation-rearrangement/reducti
277 its; however, the presence of the pyrimidine glycosides vicine and convicine (v-c) in its seeds limit
285 ce as active as aglycones, and the peracetyl glycosides were, in most cases, equipotent with aglycone
286 The effects of these two factors on aroma glycosides, which can change the aroma profile of beer o
288 Among these drugs are plant-derived cardiac glycosides, which have been used by various cultures ove
289 related herbivorous insects to toxic cardiac glycosides, which primarily occurs via a small subset of
290 r selective for the formation of the axial C-glycoside, while the pseudaminic acid donor was selectiv
291 ups on the donor favor the formation of beta-glycosides, while poorly reactive nucleophiles and elect
292 icetin; pinto beans contained kaempferol 3-O-glycosides, while red kidney beans contained quercetin 3
293 t compounds, which were matched with saponin glycosides, while triterpenoids and steroids occurred in
294 the isolation of a norlanostane-type saponin glycoside with antitrypanosomal activity of 98.9% inhibi
295 ss of defense compounds comprising bioactive glycosides with a steroidal or triterpenoid aglycone bac
296 A-B (1-2) represent a new class of diterpene glycosides with a tetracyclo [7.5.0.0(1,10).0(5,9)] tetr
297 acceptors favor formation of 1,2- trans-beta-glycosides with both d- gluco and d- galacto donors, whe
298 acceptors favor formation of 1,2- cis-alpha-glycosides with d- galacto donors but are unselective wi
299 te the chemical requirements of triterpenoid glycosides within a new binding pocket to characterize t
300 iety of noncanonical nucleotides and related glycosides would have been present on the prebiotic Eart