ライフサイエンスコーパス: glycosidic

1 Millingtonine is a glycosidic alkaloid that exists as a pair of pseudo-enan

2 The well-defined conformation of glycosidic and aglyconic bonds in alpha-, beta-, and gam

3 ic glycans, the DHB@MNPs generate diagnostic glycosidic and cross-ring cleavage ions, enabling on-spo

4 Both glycosidic and cross-ring cleavages are promoted by hydr

5 r five model glycans, ISD produced extensive glycosidic and cross-ring cleavages in the positive ion

6 splay extensive fragmentation including both glycosidic and cross-ring cleavages with the extent of s

7 oss, and that produced complete sets of both glycosidic and cross-ring fragment ions.

8 separated Hep/HS isomers generated extensive glycosidic and cross-ring fragments for confident isomer

9 acterization and found to produce a range of glycosidic and proteolytic enzymes.

10 f topology, influence of ligand binding, and glycosidic angle rearrangements seen between RNA and DNA

11 C-glycosidic antagonists may serve such a purpose.

12 wine odorant aglycones from odourless grape glycosidic aroma precursors previously isolated from whi

13 extract in order to determine the effect on glycosidic aroma precursors.

14 Thus, this study proved a change in the glycosidic aroma profile in grapes after the oak applica

15 CID and HCD generated mainly glycosidic B/Y and C/Z cleavages of the oligosaccharides

16 lavonol 3-o-sophorosides, characterized by a glycosidic beta-1,2-linkage, to the pollen surface of Ar

17 re due to the metabolic instability of the O-glycosidic bond (O-mannosides).

18 from the double-stranded DNA, cleaves the N-glycosidic bond and leaves the C1' hydrolyzed abasic sug

19 in a high number of distance restraints per glycosidic bond and, consequently, a well-defined struct

20 bose moiety of the substrate and cleaves the glycosidic bond at the very last stage.

21 acetolysis susceptible, indicative of a 1,6 glycosidic bond between CPS and the GlcNAc C-6.

22 rns in terms of preferential cleavage of the glycosidic bond between O- and fructose C2 in both inuli

23 es early stage assembly of the acidic labile glycosidic bond between sugar and 2-methylchromone aglyc

24 in three-stranded DNA via hydrolysis of the glycosidic bond between the crosslinked base and deoxyri

25 s (GH) are enzymes that mainly hydrolyze the glycosidic bond between two carbohydrates or a carbohydr

26 oiety, but may also involve migration over a glycosidic bond between two different saccharide units.

27 city of the alpha-face on replacement of the glycosidic bond by the hydroxylamine linkage.

28 veling mechanism), hydroxymethylene-assisted glycosidic bond cleavage (HAGBC mechanism), and Maccoll

29 e kinetics and thermodynamics of gas-phase N-glycosidic bond cleavage induced by nucleophilic attack

30 by its insertion into the active site where glycosidic bond cleavage is catalyzed.

31 NDTs catalyze N-glycosidic bond cleavage of 2'-deoxynucleosides via a co

32 n maintaining genome integrity by catalyzing glycosidic bond cleavage of 8-oxoguanine (oxoG) lesions

33 genic 8-oxoguanine (oxoG) lesion, catalyzing glycosidic bond cleavage of oxoG to initiate base excisi

34 RCL is an enzyme that catalyzes the N-glycosidic bond cleavage of purine 2'-deoxyribonucleosid

35 -ethenoadenine (A) lesion, and the rate of N-glycosidic bond cleavage was identical to that of the wi

36 sion deoxyribose participate in catalysis of glycosidic bond cleavage.

37 ylation of crystalline cellulose, leading to glycosidic bond cleavage.

38 ergy barrier and largest exothermicity for N-glycosidic bond cleavage.

39 re known to resist the glycosidase-catalyzed glycosidic bond cleavage; however, the synthesis of such

40 The glycan-specific ions mainly arose from glycosidic bond cleavages (B, Y, C, and Z ions) in addit

41 vatized glycans predominately generates C1-O glycosidic bond cleavages retaining the charge on the re

42 acts to yield abundant cross-ring cleavages, glycosidic bond cleavages, and combinations of these typ

43 all possible heparin/HS sequences solely by glycosidic bond cleavages, without the need to generate

44 sociated with the nucleophilic cleavage of N-glycosidic bond constitutes a major factor contributing

45 excited anion radical that undergoes N1-C1' glycosidic bond dissociation rather than relaxation to i

46 ines by reversible homolytic scission of the glycosidic bond following the dictates of the Fischer-In

47 s a control element in enzymic processes for glycosidic bond formation and hydrolysis are discussed.

48 Formidable challenges include glycosidic bond formation between ribose and the canonic

49 a modification not directly involved in the glycosidic bond formation, 6F-N-acetyl-d-galactosamine (

50 g protecting groups on the donor favor alpha-glycosidic bond formation.

51 containing the characteristic ribose-ribose glycosidic bond formed during poly(ADP-ribosyl)ation.

52 onfiguration is retained following gas-phase glycosidic bond fragmentation during tandem mass spectro

53 ism in which the key amino acids driving the glycosidic bond hydrolysis act as catalytic acid/base an

54 Previous studies show that N-glycosidic bond hydrolysis follows a stepwise (S(N)1) me

55 the active site by exclusively impairing the glycosidic bond hydrolysis step.

56 produced by mammals capable of cleaving the glycosidic bond in chitin.

57 the anomeric effect for introduction of an O-glycosidic bond in order to direct the introduction of a

58 s the polyoxygenated saccharide and a labile glycosidic bond in the nucleosides, these reactions can

59 and two hydrogen bond acceptors because the glycosidic bond is C-C rather than C-N as in uridine.

60 te transition state in which cleavage of the glycosidic bond is coupled to the transfer of a proton f

61 size that the cause of the lability of the N-glycosidic bond is due to the combined steric and electr

62 This is due in part to cleavage of the glycosidic bond occurring prior to the peptide backbone

63 lity of the deficient variants to cleave the glycosidic bond of beta-NAD(+) into nicotinamide and ADP

64 glucuronidase, an enzyme that hydrolyzes the glycosidic bond of glucuronides to generate the parent c

65 at LytB cleaves the GlcNAc-beta-(1,4)-MurNAc glycosidic bond of peptidoglycan building units.

66 ine DNA glycosylase (Tdg), which cleaves the glycosidic bond of the bases to give potentially harmful

67 Nucleosides fragmented at the N-glycosidic bond provide nucleobase and/or ribose or 2'-d

68 ein, we disclose that compounds having the O-glycosidic bond replaced with carbon linkages had improv

69 on on the mannoside phenyl ring ortho to the glycosidic bond results in large potency enhancements se

70 N-glycosidic bond scission is then facilitated by a backbo

71 ase cleavage is dependent on the intrinsic N-glycosidic bond stability.

72 Cleavage of the N-glycosidic bond that connects the nucleobase to the back

73 In contrast, the beta-D-GlcNAc-(1-->3)-D-Gal glycosidic bond that connects the two Le(x) trisaccharid

74 demonstration of the anomeric memory of the glycosidic bond upon fragmentation.

75 ts unexpected lability with respect to its N-glycosidic bond when compared with its corresponding can

76 xist in anti or syn conformations around the glycosidic bond when paired opposite to U or G in the co

77 r to direct the introduction of a bridging C-glycosidic bond with the desired stereochemistry.

78 which selectively cleaves the nicotinamide's glycosidic bond yielding (tz)ADP-ribose.

79 tivities: N-glycosylase (hydrolysis of the N-glycosidic bond) and AP lyase (elimination of the 3'-pho

80 h a 3-OH group and a 4-OH group (or alpha1-4-glycosidic bond) at the acceptor subsite +1 for the cata

81 Due to the lability of the glycosidic bond, 8-nitrodG cannot be incorporated into o

82 n by the C2-alkoxide, an essentially cleaved glycosidic bond, and a slight shortening of the endocycl

83 ering by the value of the Psi angle for this glycosidic bond, are populated in solution.

84 f uracil-DNA glycosylase hydrolysis of the N-glycosidic bond, converting 2'-deoxyuridine in DNA to an

85 The wild-type enzyme cleaves the N-glycosidic bond, leaving the ribose ring in the flipped

86 ed in cellular DNA due to instability of the glycosidic bond, particularly at purines and various oxi

87 Following cleavage of the glycosidic bond, the liberated hemiacetal spontaneously

88 of the l-histidine through a hydrolyzable N-glycosidic bond.

89 sidue and thereby facilitate cleavage of the glycosidic bond.

90 lting in a Schiff base intermediate at the N-glycosidic bond.

91 ell characterized in cells due to its labile glycosidic bond.

92 protein Ser or Thr residues via an O-linked glycosidic bond.

93 the hyaluronic acid polymer at the beta-1,4 glycosidic bond.

94 talysis to achieve selective cleavage of the glycosidic bond.

95 can retain the anomeric configuration of the glycosidic bond.

96 uite indirect because of the lability of the glycosidic bond.

97 products from DEA-mediated cleavage at the N-glycosidic bond.

98 Y active site modulate the lability of the N-glycosidic bond.

99 repeating unit incorporates a 1,2-cis-alpha-glycosidic bond; the problematic 1,2-trans-galactosidic

100 uanosine adopts a syn conformation about the glycosidic bond; thermal melting studies and molecular m

101 fferences in the hydrolytic stability of the glycosidic bonds and in the susceptibility of monosaccha

102 ing cycle, which likely includes energy from glycosidic bonds and other sources.

103 degrees of conformational change around the glycosidic bonds and subsequently alter its function as

104 catalyze the highly specific biosynthesis of glycosidic bonds and, as such, are important both as dru

105 n of SEC and FTIR data showed that alpha-1,6-glycosidic bonds are more frequently split in pressurize

106 pore cortex PG and catalyzes the cleavage of glycosidic bonds between N-acetylmuramic acid (NAM) and

107 One of these LPMOs cleaves glycosidic bonds by oxidation of the C1 carbon, whereas

108 ght also assist in the formation/cleavage of glycosidic bonds by stabilizing positively charged oxoca

109 nsition states are late with largely cleaved glycosidic bonds coupled to pyranosyl ring flattening ((

110 on is reversed by hydrolases that cleave the glycosidic bonds either between ADP-ribose units or betw

111 isotope effect (EIE) for heterolysis of the glycosidic bonds in 5'-methylthioadenosine and in 2-(p-n

112 G and AlkA are therefore able to hydrolyze O-glycosidic bonds in addition to N-glycosyl bonds.

113 Cellulase enzymes cleave glycosidic bonds in cellulose to produce cellobiose via

114 dicating the ability of MGIIa_P to hydrolyse glycosidic bonds in complex sugars in PRE.

115 nsertion and subsequent elimination to break glycosidic bonds in crystalline cellulose.

116 To achieve cleavage of the glycosidic bonds in host glycans, S. pneumoniae deploys

117 e ability to perform selective hydrolysis of glycosidic bonds in mogroside V, converting it to siamen

118 Challenges in the assembly of glycosidic bonds in oligosaccharides and glycoconjugates

119 opening polymerization to generate multiple glycosidic bonds in one simple chemical step, allowing u

120 structurally related enzymes that hydrolyze glycosidic bonds in pectin, and are important extracellu

121 enzymes that catalyze oxidative cleavage of glycosidic bonds in polysaccharides in the presence of a

122 s (LPMOs) catalyze the oxidative cleavage of glycosidic bonds in recalcitrant polysaccharides, such a

123 e of electrons to oxidize the C1 position of glycosidic bonds in starch substrates, but not in cellul

124 ases (LPMO10s) use redox chemistry to cleave glycosidic bonds in the two foremost recalcitrant polysa

125 The stereoselective formation of 1,2-cis-glycosidic bonds is challenging.

126 ncorrelated rotations are observed about the glycosidic bonds of a partially de-methyl-esterified dec

127 talline cellulose and hydrolyze the beta-1,4-glycosidic bonds of cellulose to produce fermentable sug

128 s suggested that phenolic hydroxyls, but not glycosidic bonds of melanoidin-bound phenolics are cleav

129 yses reveal that correlated rotations around glycosidic bonds of monosaccharide subunits at and immed

130 that catalyse the endohydrolysis of beta-1,4-glycosidic bonds of partially acetylated chitosan to rel

131 soamylase is essential to debranch alpha-1,6-glycosidic bonds of starch, yielding linear amylodextrin

132 he fungus Trichoderma reesei that hydrolyzes glycosidic bonds on cellulose randomly.

133 human methylpurine DNA glycosylase cleaves N-glycosidic bonds on RNA and that human apurinic/apyrimid

134 acid with alternating beta-1,4 and beta-1,3 glycosidic bonds that can be repeated 20,000 or more tim

135 Glucosidases are enzymes that hydrolyze beta-glycosidic bonds to release non-reducing terminal glucos

136 ermore, lysozyme catalyzed the hydrolysis of glycosidic bonds to the end of the linear substrate but

137 enzymes that catalyze oxidative cleavage of glycosidic bonds using molecular oxygen and an external

138 ttention owing to their abilities to disrupt glycosidic bonds via oxidation instead of hydrolysis and

139 saccharides linked through 1,3- and 1,4-beta glycosidic bonds with subtle differences in structure th

140 Ltgs cleave the glycosidic bonds within bacterial peptidoglycan allowing

141 fragment ions predominantly from cleavage of glycosidic bonds without breaking the peptide bond.

142 atalytic itineraries" during the cleavage of glycosidic bonds, illustrating the relationship between

143 nitial substrate; with increasing numbers of glycosidic bonds, less glucose is formed.

144 ses have broad specificity for hydrolysis of glycosidic bonds, potentially increasing their functiona

145 ectivity in the formation of 1,2-cis-2-amino glycosidic bonds, the glycosylation reaction is hampered

146 ither cross-ring cleavages or rupture of the glycosidic bonds, thereby allowing an unambiguous assign

147 de thioglycosides containing 1,2-cis-2-amino glycosidic bonds, via cationic nickel-catalyzed glycosyl

148 ion 1175-1157cm(-1), linked with breakage of glycosidic bonds, were the most useful for diagnostic mo

149 g the backbone are linked, through alpha-1,3-glycosidic bonds, with fucose branching at C-2, and one

150 ote the stereoselective formation of 1,2-cis-glycosidic bonds.

151 s of enzymes responsible for the cleavage of glycosidic bonds.

152 , that are linked by amide, ether, ester, or glycosidic bonds.

153 the LPMO mechanism for oxidative cleavage of glycosidic bonds.

154 oxygen for subsequent oxidative cleavage of glycosidic bonds.

155 es may utilize in catalyzing the cleavage of glycosidic bonds.

156 accharide residues covalently linked through glycosidic bonds.

157 ternatively linked by alpha-1,3 and beta-1,4 glycosidic bonds.

158 control selectivity during the formation of glycosidic bonds.

159 , for example, that Cel7A cleaves about four glycosidic bonds/s during processive hydrolysis.

160 linked GalNAc polymers that lack significant glycosidic branching and may be connected by glycine pep

161 l chain C-O, C-N, and C-C bond cleavages and glycosidic C-O and cross ring cleavages, thus providing

162 n-covalent CH-pai bonds along alpha-(1 -> 4) glycosidic chains.

163 a proof of concept to interrogate sp(3)-rich glycosidic chemical space for novel biological activity,

164 d two abundant ions consistent with B- and C-glycosidic cleavages corresponding to the loss of the Fu

165 e oligo-porphyrans, with many cross-ring and glycosidic cleavages.

166 y integrating XB-catalyzed construction of a glycosidic compound collection, and evaluating these ana

167 ymorphisms of G-quadruplexes relate to these glycosidic conformational patterns and the lengths of th

168 erved when replacing guanines with different glycosidic conformations.

169 on among species were assigned as kaempferol glycosidic conjugates, with kaempferol-3-O-[glucopyranos

170 cones show higher bioavailability than their glycosidic counterparts and thus may have greater potenc

171 ations, and the release of aromas from their glycosidic counterparts in model cherry juices.

172 ose B, as well as a viable sequencing of the glycosidic couplings.

173 strong sensitizer, so this compound and its glycosidic derivative can contribute to the allergic pot

174 of model systems, comprising a wide range of glycosidic donor/aromatic complexes.

175 The disappearance of the C-glycosidic ellagitannins over time can occur even in abs

176 e oak extract were assimilated and stored as glycosidic forms in both cultivars.

177 vonols are accumulating in a large number of glycosidic forms.

178 Positive ion ESI-MS generates B/Y-type glycosidic fragment ions under collisional-induced disso

179 s, and the subsequent NETD produced abundant glycosidic fragments, allowing the characterization of b

180 e charge results in the generation of C-type glycosidic fragments, highly informative A-type cross-ri

181 ed oligopeptide tree structure appended with glycosidic groups at its multiple N-termini were investi

182 eported two classes of orally bioavailable C-glycosidic inhibitors of the Pseudomonas aeruginosa lect

183 e production of beta-glucosidase and convert glycosidic isoflavones in aglycones.

184 a nonreducing end GlcNAc that has a beta1-6-glycosidic link and that are analogous to either N-glyca

185 For the alpha-O-GalNAc-Ser derivative, the glycosidic linkage adopts a high-energy conformation, ba

186 tions from AF4, carbohydrate composition and glycosidic linkage analysis for the dominating populatio

187 GlycoSeq employs rules of glycosidic linkage as defined by glycan synthetic pathwa

188 flight mass spectrometry confirmed a direct glycosidic linkage between CPS and PG and showed that a

189 s involved were the synthesis of the 1,2-cis-glycosidic linkage between galactose and the linker (spa

190 sing on-tissue acid hydrolysis to cleave the glycosidic linkage between the polysaccharide (core and

191 potent purine nucleoside antibiotic with a C-glycosidic linkage between the ribosyl moiety and the py

192 er truncation or changing stereochemistry of glycosidic linkage between the tetrasaccharide and the t

193 trehalose oxygen atoms most distant from the glycosidic linkage fluctuated around 7.5 x 10(-14) m(2)/

194 A novel type of cross-link involving a S-glycosidic linkage formed by reacting an abasic site in

195 ) that sulfur-for-oxygen substitution in the glycosidic linkage fundamentally alters the energeticall

196 ds a disaccharide that closely resembles the glycosidic linkage in the polylegionaminic acid from the

197 The library includes glycosidic linkage information for three hexoses (glucos

198 ubstrates yet remains highly specific in the glycosidic linkage it creates.

199 encompasses the construction of an extensive glycosidic linkage library built from synthesized standa

200 n-bond acceptor at the position ortho to the glycosidic linkage may not be required.

201 ygromycin B identified an orientation of one glycosidic linkage of hygromycin B consistent with metal

202 The glycosidic linkage positions are often determined by per

203 accharide sequencing, and monosaccharide and glycosidic linkage quantitation.

204 dihedral angles has been determined for each glycosidic linkage relevant for the conformational prefe

205 A direct glycosidic linkage to PG was also demonstrated for serot

206 terized and revealed that in the complex the glycosidic linkage torsion angles between the two reduci

207 antigen mimics, the derivative bearing the S-glycosidic linkage was conjugated to gold nanoparticles

208 free energy landscapes obtained for the same glycosidic linkage within different oligosaccharides.

209 ural substrates harboring the Fucalpha1-2Gal glycosidic linkage, a xyloglucan-derived nonasaccharide,

210 meric form, including the anomericity of the glycosidic linkage, demonstrating the power of this tool

211 uctural information, including sugar pucker, glycosidic linkage, hydrogen bonding patterns and stacki

212 n, regiochemistry and stereochemistry of the glycosidic linkage.

213 was connected to the sequence by a beta(1-6) glycosidic linkage.

214 y known enzymes to be able to hydrolyze this glycosidic linkage.

215 the inversion of the configuration of the N-glycosidic linkage.

216 t high concentration was key to making the C-glycosidic linkage.

217 ons by means of O -> S/Se replacement at the glycosidic linkage.

218 d change the orientation and dynamics of the glycosidic linkage.

219 des composition (stereoisomers), the type of glycosidic linkages (connectivity) and the anomeric conf

220 ent position is diversified to fit different glycosidic linkages and monosaccharide residues.

221 nt structural conformation i.e. variation in glycosidic linkages and sulphate group orientation.

222 led to the selective hydrolysis of flavonol glycosidic linkages and the inducible degradation of fla

223 enzyl, and p-bromobenzyl ethers, esters, and glycosidic linkages are stable to these reaction conditi

224 glycoconjugates bearing the 1,2-cis-2-amino glycosidic linkages because the saccharide thioglycoside

225 ymers of different lengths containing labile glycosidic linkages between monomer units necessitating

226 monosaccharide composition, the position of glycosidic linkages between monosaccharides, and the pos

227 an be characterized by the torsion angles of glycosidic linkages between relatively rigid carbohydrat

228 matic detection and annotation of sugars and glycosidic linkages between sugar units and to proteins,

229 y, the anomericity and regiochemistry of the glycosidic linkages carry important biological informati

230 ry (LC-MS/MS) method for the quantitation of glycosidic linkages derived from disaccharides, oligosac

231 Stereoselective formation of glycosidic linkages has been the prime focus for contemp

232 complementary specificities to hydrolyze the glycosidic linkages in agarose, a linear polymer compris

233 The extensive characterization of glycosidic linkages in carbohydrates remains a challenge

234 Glycoside hydrolases (GHs) cleave glycosidic linkages in carbohydrates, typically via inve

235 Cellulases hydrolyze beta-1,4 glycosidic linkages in cellulose, which are among the mo

236 Cellobiohydrolases processively hydrolyze glycosidic linkages in individual polymer chains of cell

237 is a paradigm for the study of other unusual glycosidic linkages in model and parasitic organisms.

238 n and a reducing agent to oxidatively cleave glycosidic linkages in polysaccharides.

239 Challenging glycosidic linkages including alpha-gluco, beta-manno, a

240 de thioglycosides containing 1,2-cis-2-amino glycosidic linkages is challenging.

241 An immense variety of sugars and glycosidic linkages leads to an almost unlimited diversi

242 enzyme known to catalyse hydrolysis of the O-glycosidic linkages of ADP-ribose polymers, thereby reve

243 aride composed of partially acetylated 1-->4 glycosidic linkages of N-acetylgalactosamine and N-acety

244 ignificant modulation of geometry around the glycosidic linkages of the FPX constituent monosaccharid

245 s ability to catalyze the hydrolysis of beta-glycosidic linkages once endocytosed, whereas equal conc

246 C-H protons is indicative of the position of glycosidic linkages or other substituents and can be rea

247 fficient and stereoselective construction of glycosidic linkages remains one of the most formidable c

248 at NcAA13 and MtAA13 more frequently oxidize glycosidic linkages separated by multiples of a helical

249 te alternating beta-(1-->5) and beta-(1-->6) glycosidic linkages using a single active site.

250 xtend this study to the synthesis of various glycosidic linkages using different sugar series.

251 imultaneous identification of over 90 unique glycosidic linkages using ultrahigh-performance liquid c

252 trols stereoselective formation of 1,2-trans-glycosidic linkages via the arming participation effect.

253 ferases was performed, and the nature of the glycosidic linkages was determined by NMR.

254 While monosaccharide compositions and glycosidic linkages were analyzed by GC-MS, hydrodynamic

255 ctive than aglycones, polyphenols with (2,1) glycosidic linkages were more effective than those with

256 ransferase in the GT41 family that creates N-glycosidic linkages with glucose and galactose at aspara

257 rocycles, melamine and barbituric acid, form glycosidic linkages with ribose and ribose-5-phosphate i

258 can show that the torsions of the different glycosidic linkages within the GPI tetrasaccharide can b

259 types, sugar types, chemical modifications, glycosidic linkages, and anomeric states.

260 ha-glucan with (alpha1-->3) and (alpha1-->6) glycosidic linkages, and was similar in structure to a p

261 By catalysing the breakdown of beta-1, 4-glycosidic linkages, beta-glucosidases produce free ferm

262 sis of their monosaccharide building blocks, glycosidic linkages, chain length, as well as additional

263 Of the two possible glycosidic linkages, chemically, 1,2-trans linkage is re

264 ain of xylose residues connected by beta-1,4 glycosidic linkages, has remained elusive.

265 The use of alkali influenced the glycosidic linkages, molecular mass and thermal stabilit

266 To prevent hydrolysis of acid-labile glycosidic linkages, optimal reaction conditions that ma

267 Moreover, glycans with unique glycosidic linkages, particularly from prokaryotes, whic

268 families acting on both axial and equatorial glycosidic linkages, respectively.

269 ansferase family members to catalyze beta1-2 glycosidic linkages.

270 an-II, cleaving all but 1 of its 21 distinct glycosidic linkages.

271 ight on gas-phase dissociation mechanisms of glycosidic linkages.

272 g is an exo-alpha-neuraminidase that cleaves glycosidic-linked sialic acids.

273 Thermal treatment of the glycosidic mixture at native pH of fruit gave furanoid c

274 By HPLC-ESI-MS analyses of glycosidic mixtures and GC-MS analyses of volatiles rele

275 minal sugar and/or the type of linkage among glycosidic moieties in the mechanism of absorption of fl

276 residue was found to be too distant from the glycosidic oxygen (>4.3 A) to serve directly as a genera

277 thuss proton shuttle between Glu-796 and the glycosidic oxygen, permitting this residue to serve as t

278 riables, such as coordination numbers of the glycosidic oxygen, yielded a variety of chemical reactio

279 oned between the catalytic acid/base and the glycosidic oxygen.

280 nsted acidic OH-defect sites and constrained glycosidic oxygens (i.e., those juxtaposed adjacent to t

281 eral acid/base Glu-288 nearest the predicted glycosidic position, whereas the open conformation possi

282 PMO1s and PMO2s hydroxylate glycosidic positions C1 and C4, respectively.

283 Whereas the glycosidic precursors do not impair the sensory properti

284 Hydrolysis of these glycosidic precursors frees the volatile aroma compounds

285 The aim of this work was to identify the glycosidic precursors of the key volatile compounds resp

286 ships among odour-active volatiles and their glycosidic precursors were also proposed.

287 Glycosidic precursors were isolated from juice by adsorp

288 ntargeted approach with 3 custom-synthesized glycosidic precursors.

289 ne bearing redox-active osmium complexes and glycosidic residues (lactose) is used to create a self-a

290 peating ADP-ribose units linked via a unique glycosidic ribose-ribose bond, and is synthesized from N

291 SoArsAB also activated DMB to its alpha-N-glycosidic ribotide.

292 ad synthetic methods for the construction of glycosidic scaffolds and glycoconjugates of biological a

293 ereas the extracellular domain carries two N-glycosidic side chains.

294 This work aimed to define the glycosidic simple phenolic profile of a large selection

295 piperidine ring of the iminosugar and the C-glycosidic structure of alpha-D-GlcNAc.

296 Presence of alpha and beta-glycosidic structures such as glucans and glucan-protein

297 After a glycan search is complete, each glycosidic torsion angle distribution is displayed in te

298 ous flip-over reaction coordinate (i.e., the glycosidic torsion angle) is unable to resolve the inter

299 The analysis of the glycosidic torsional angles and the pair interaction ene

300 The changes in glycosidic torsional linkage and the receptor conformati