ライフサイエンスコーパス: ground state

1 to a homovalent Mn(IV)(4) core with an S = 3 ground state.

2 s exhibit an antiferromagnetic (S=0) singlet ground state.

3 state is rapidly (2.2 ps) deactivated to the ground state.

4 s, which should be readily extendable to the ground state.

5 mined to lie ~0.5 eV (12 kcal/mol) above the ground state.

6 rmediate compounds exhibit a spin-glass-like ground state.

7 n state ensemble are reduced compared to the ground state.

8 antiferromagnetically coupled, giving an S=0 ground state.

9 lly coupled to the V magnetic moments in the ground state.

10 s complex an Fe(II)-thiyl radical electronic ground state.

11 etastable within the otherwise ferromagnetic ground state.

12 ant of J = +110(12) cm(-1), to give an S = 3 ground state.

13 lly and optomechanically cooled close to the ground state.

14 provide strong evidence for a Cu(II) -NO(.) ground state.

15 guration (S = 5/2) and have a non-degenerate ground state.

16 c state of the molecule in comparison to the ground state.

17 t of the free-ion Dy(III) with a (6) H(15/2) ground state.

18 state energies through a slower decay to the ground state.

19 as simple, consisting of a unique electronic ground state.

20 d dissociation rather than relaxation to its ground state.

21 of an auxiliary energy level coupled to the ground state.

22 between the excited state and the electronic ground state.

23 nds in (#6094)C(68) due to the change in the ground state.

24 n orbitally nearly doubly degenerate S = 1/2 ground state.

25 agnetic phase, and this is the true magnetic ground state.

26 ar molecular ions, often in their electronic ground state.

27 (1)TT state as well as decay pathways to the ground state.

28 4)C(68) fullerene, which possesses a triplet ground state.

29 state S(1) at an energy of 2.3 eV above the ground state.

30 to a variant with an effectively degenerate ground state.

31 ears in the excited state rather than in the ground state.

32 nsfer from the Green Box to fullerene in the ground state.

33 (>70 meV/atom) compared to the wurtzite-type ground state.

34 ymmetric dipolar structure in the electronic ground state.

35 , which lies energetically 1.50 eV above the ground state.

36 d of HSrRuO(3) with paramagnetic metallic as ground state.

37 has charge-transfer (CT) character, and the ground state.

38 ed by the absence of static magnetism in its ground state.

39 t to access with reactions in the electronic ground state.

40 ) and 13-cis/15-syn, after relaxation to the ground state.

41 , affording an overall doublet (S = (1)/(2)) ground-state.

42 will relax, via spontaneous emission, to its ground-state.

43 opological Kondo insulator (TKI) with exotic ground states.

44 quisite for rational engineering of magnetic ground states.

45 t do not possess static pear-shapes in their ground states.

46 cence when the molecules relax back to their ground states.

47 It is not limited to ground states.

48 s is the competition and cooperation between ground states.

49 g to a variety of possible symmetry-breaking ground states(11-17).

50 sulators and other complex quantum many-body ground states(2,3).

51 In the ground-state a two-fold symmetric H-bond and a salt brid

52 nalysis our system, demonstrating single-run ground state accuracies of 98% on randomized MAX-CUT pro

53 have various degrees of aromaticity in their ground state, almost no data are available for their T(1

54 Excited molecules relax back to the ground state along two pathways: After population of a h

55 The ground-state alpha phase of plutonium has an extraordina

56 ample exhibits an out-of-plane ferromagnetic ground state, an in-plane antiferromagnetic state appear

57 rate superpositions of a harmonic oscillator ground state and a number state of the form [Formula: se

58 icture in explaining the observed electronic ground state and emphasize the key importance of trigona

59 e phases that are nearly degenerate with the ground state and may give rise to the pseudogap state fr

60 rt as 3 ps, which intersystem crosses to its ground state and rearranges to form the (6-4) photoadduc

61 n modulates the recovery of rhodopsin to the ground state and rod dark adaptation.

62 A famous example is finding the ground state and the excitations of the two-dimensional

63 sitivity of the qubit transition between the ground state and the first excited state, which recovers

64 ect optical transition between the spin-zero ground state and the spin-one triplet levels(8).

65 omparison of charge distribution between the ground state and the transition state will show how much

66 e pathway for fast decay from the LES to the ground state and thereby preclude detection of the CSS a

67 on hole geometric discrimination between the ground state and transition state or highly precise gene

68 h resembles the driving of atoms between the ground state and various excited states.

69 metal complexes with two degenerate magnetic ground states and are promising for increasing storage d

70 ineering provides the ability to control the ground states and associated phase transition in epitaxi

71 er singles and doubles (NEO-CCSD) method for ground states and the equation-of-motion counterpart (NE

72 romism due to the large dipole moment of the ground states and the transition dipole moment that is i

73 With an aim to achieve a balance between ground-state and excited-state reduction potential of do

74 Herein, we present the results of ground-state and transient absorption spectroscopies as

75 re accurate predictions than the QRM for the ground state, and often for the first excited state as w

76 radio-frequency resonator, cooled it to the ground state, and stabilized Fock states.

77 and non-adiabatic coupling to the electronic ground state are shown to be driven by ballistic S-C bon

78 dynamics reveals that transitions out of the ground state are slower in 1 than in the first reported

79 y of the ferromagnetic and antiferromagnetic ground states, arising from its atomic-scale structural

80 city, combined with Huckel's 4n + 2 rule for ground-state aromaticity, to tailor new potential chromo

81 plex has a doublet spin configuration in the ground state as a result of the strong orbital overlap,

82 om the singly-excited states decaying to the ground state as is the current paradigm.

83 xido complexes that have the same S = 2 spin ground state as those found in nature and then systemati

84 reach, spontaneously, the ferroelectric (FE) ground state at low temperature where a residual Pauling

85 by a transition from a triplet to a singlet ground state at low temperatures.

86 ng to nearly exclusive population of triplet ground state at room temperature, and good thermal stabi

87 obutyne is a transition state in its singlet ground state, based on new coupled cluster and multirefe

88 by which the two co-planar C-H bonds in the ground state become perpendicular to each other in the e

89 pounds that are [4n + 2] pai-aromatic in the ground state, become [4n + 2] pai-antiaromatic in the fi

90 ments, type of magnetic and crystallographic ground state, bond disproportionation and ligand hole ef

91 f not only the exciton's [Formula: see text] ground state but also its excited [Formula: see text] Ry

92 The excited state differs from the ground state by a change in secondary structure, consist

93 red diradical is predicted to have a singlet ground state by theory and variable temperature EPR.

94 an generate a new molecular aggregate in the ground state, called an electron donor-acceptor (EDA) co

95 at fluctuations about the valence bond solid ground state can mediate an attractive interaction that

96 Importantly, the spin ground state changes from S = 1/2 to S = 3 as the OEC is

97 ppression of the transition to a diamagnetic ground state characteristic of U(IV), and in doing so, i

98 (IR) light offers a novel route to carry out ground state chemistry.

99 jority of studies thus far have focused upon ground-state chemistry and rarely consider any more than

100 ally under V-USC, which could play a role in ground-state chemistry.

101 This platform has also allowed us to observe ground-state collisions of laser-cooled molecules both i

102 a stabilization of the ferrous-thiyl radical ground state compared to the five-coordinate ferric-thio

103 quenching was found to be static suggesting ground-state complex formation between betaLG and vitami

104 The computed ground-state complex shows substrate-induced ionization

105 stabilization of a particularly interesting ground state configuration consisting of three embedded

106 of unity along with a 1a(2)1e(4) electronic ground state configuration for the [Mo(3)O(4)F(9)](5-) c

107 th formation of a gapped state with an S = 0 ground-state configuration.

108 minimum and maximum energy bounds as well as ground state configurations corresponding to various typ

109 applications including sensitive metrology, ground state cooling of mechanical motion and slowing of

110 ds the value of 0.6 x 10(13) Hz required for ground state cooling.

111 r back electron transfer and regeneration of ground state Cy, required for photostabilization, or Cy-

112 The inverse DFT problem of mapping the ground-state density to its exchange-correlation potenti

113 st pai* <- pai electronic transition using a ground-state depletion method.

114 Thus, the role of these residues may be ground state destabilization of the enzyme-substrate com

115 ike uracil DNA glycosylase (UDG) can achieve ground state destabilization, by polarizing substrates t

116 to date, wherein the reactivity is driven by ground-state destabilization of the amide bond.

117 rate scope and support a mechanism driven by ground-state destabilization of the carboxylate group be

118 structure reveals precisely why; the triplet ground state diatomic O(2) molecule is paramagnetic and

119 lar dyes and concomitant annihilation of the ground state dipole moment is observed in the UV/vis abs

120 We report triplet ground state diradical 2 with a large singlet-triplet en

121 for achieving such a trait is by increasing ground state diradical character; however, this greatly

122 (6)ArC)Fe(2)(mu-H) has a well-isolated S = 1 ground state, distinguishing it from all other diiron mu

123 that have low electron affinities, through a ground-state doping mechanism that is further amplified

124 Here, we report the complete excited- and ground-state dynamics of the UV form of histidine kinase

125 riment also enable visualization of the rich ground-state dynamics that involve the formation of, and

126 f current progress in quantum algorithms for ground-state, dynamics, and thermal-state simulation and

127 ons, possibly because of Hammond behavior or ground-state effects.

128 rowave dressing to a clock transition of the ground-state electron spin of a silicon carbide divacanc

129 tating novel intermolecular, solvent tunable ground state electronic communication with these guests.

130 xperiments that exploit variable-temperature ground-state electronic absorption spectroscopy unambigu

131 udies of 93 atoms predict drastic changes to ground-state electronic configurations and electronegati

132 el for donor-acceptor systems with localized ground-state electronic distributions.

133 le superconducting and correlated insulating ground states emerge.

134 s, which further elucidate the nature of the ground state energies, frontier orbital characters, exci

135 nation of literature experimental values for ground-state energies and ab initio-calculated energies

136 Computational evaluation of ground-state energies of dihydroineleganolide is used to

137 ivity scale for atoms, based consistently on ground-state energies of valence electrons.

138 the average accuracy of the CIM to find the ground state energy was ~90% for 120 trials.

139 We estimate the ground-state energy of the Transverse Field Ising Model

140 he variational parameters, approximating the ground-state energy with up to 40 trapped-ion qubits.

141 The ground-state energy, kinetic energy, cluster size, and d

142 We find that the ground state ESCs cultured with GSK3-, MEK-inhibitors an

143 We further show that the ground-state ESCs particularly rely on elevated FAO for

144 r FAO inhibition induces bona fide quiescent ground-state ESCs with an intact core pluripotency netwo

145 activating fatty acid oxidation (FAO) in the ground-state ESCs.

146 e pluripotent quiescence specifically in the ground-state ESCs.

147 y minor roles in mESC self-renewal and naive ground state establishment by core sets of dominant plur

148 ed FC excited state differs from that of the ground state, even with a relatively light first row tra

149 Whether a metallic ground state exists in a two-dimensional system beyond A

150 d metals exhibit a diverse set of electronic ground states, few approaches exist for spatially modula

151 avin semiquinone/quinone redox couple, where ground-state flavin semiquinone provides the electron fo

152 F calculations reveal a closed-shell singlet ground state for 4 with a considerable diradical charact

153 y, including an unexpected high-spin S = 3/2 ground state for the 19e(-) derivatized ferrocene anion.

154 The dipole orientation of ground-state Gamma-K interlayer excitons can be flipped

155 r rigidity, which makes deformation from the ground-state geometries unfavorable.

156 rfluoroalkanes compared to alkanes are their ground-state geometries, which are increasingly unsuitab

157 lize the transition state (TS) relative to a ground state (GS).

158 ES relative to the long-lived more abundant ground state (GS).

159 e the distal ligand, while the return to the ground state has been attributed to thermal relaxation.

160 , the impact of nematicity on the electronic ground state has been obscured by superconductivity.

161 c behaviors, and thus the previously invoked ground-state heterogeneity may not be relevant to the ex

162 study the collision of rotationally oriented ground state hydrogen molecules with a lithium fluoride

163 f 1.3 ns, indicating the formation of a new (ground-state) hydrogen-bonded ABZ-H(2)O(2) complex (stat

164 Decay to the ground state in 100 ns is the primary loss pathway for (

165 ion occurs on the S(1)-S(0) evolution to the ground state in 4.8 ps.

166 inversion induces a topologically nontrivial ground state in EuCd(2) As(2) .

167 l-prismatic geometry stabilizes the magnetic ground state in the case of Dy(3+) and results in a larg

168 (11) rubidium atoms, initiated nearly in the ground state in the presence of a magnetic field.

169 an energy of 32.8 +/- 0.3 eV forms the (3)A" ground state in which the HNCO(2+) ion is long lived.

170 g and manipulate the electronic and magnetic ground states in complex oxides.

171 The magnetic ground states in highly ordered double perovskites LaSr(

172 Although magnetic ground states in quantum materials can be theoretically

173 rlap results in strongly coupled, large-spin ground states in the [Ni(4)(NP(t)Bu(3))(4)](+/0) cluster

174 s that any single material has a spin liquid ground state, in the past few years a number of material

175 c fields suggests evidence of spin-polarized ground states, in stark contrast to magic-angle twisted

176 usler phases harbour a variety of electronic ground states, including superconductivity, antiferromag

177 als of low relative Lewis acidity display no ground state interaction with carbonyls.

178 ervation, revealing the specific role of the ground-state intra- and inter-molecular coupling in sele

179 ar ions can be suppressed and ro-vibrational ground state ions can be generated with high purity.

180 ascertain their topological nature, as their ground state is a simple condensate or the vacuum, and o

181 recombination, the return to the planar MbNO ground state is an electronic relaxation from HS to LS t

182 les occupying their rotational and hyperfine ground state is best described by second-order rate equa

183 For finite t', the ground state is consistent with a Luther-Emery liquid wi

184 metals in the +2 oxidation states where the ground state is effectively a (2)S state.

185 e spin chain the continuum is gapped and the ground state is Neel ordered.

186 g the many implications is that the system's ground state is not necessarily highly entangled, which

187 We find that the ferromagnetic ground state is remarkably robust to engineered disorder

188 y the proteasome and returns to its inactive ground state is unknown.

189 pling to the environment is ultra-strong the ground-state is expected to become dressed with virtual

190 laxation, transitions from excited states to ground states, is well studied, but their influence on h

191 stems that maintain them as highly immature, ground-state ISCs marked by a single-cell clonogenicity

192 While benzene is aromatic in its ground state, it is antiaromatic in its lowest paipai* e

193 tically small, escalating steps in which the ground-state keto-isomer is tautomerized to an enol and

194 identical set of states(7), including their ground state, labelled by their total angular momentum J

195 former have insulating and antiferromagnetic ground states, LNO remains metallic and non-magnetic dow

196 ntally different kinetic mechanisms from the ground-state macroscopic phases.

197 wn high temperature realization of a singlet ground state magnet, in which magnetism occurs through a

198 The torsional dependence of the ground state magnetic exchange coupling (J) and the corr

199 ystal structure of an ATP (ADP:BeF(3)-bound) ground-state mimic double-ring mHsp60(14)-(mHsp10(7))(2)

200 rface and surface-induced changes to DMABN's ground-state molecular structure.

201 ar dynamics calculations of the excited- and ground-state molecules, the results provide insights int

202 dynamic noise and eigenvalue dropout to find ground states more efficiently.

203 of the multiconfigurational behavior in the ground state of [Tb(NP(1,2-bis-(t)Bu-diamidoethane)(NEt(

204 A Bose-Einstein condensate is the ground state of a dilute gas of bosons, such as atoms co

205 The ground state of a fermionic condensate is well protected

206 dy the evolution of C4 photosynthesis from a ground state of C3 photosynthesis, we initially construc

207 The PRIS provides sample solutions to the ground state of Ising models, by converging in probabili

208 ically trapped nanoparticle into its quantum ground state of motion from room temperature.

209 Therefore the ground state of strontium-73 must differ from its J (pai

210 te in rubidium-73, which is identical to the ground state of strontium-73.

211 not observed because the transition from the ground state of TCNB(-) (A(u) symmetry) to the QBS (A(g)

212 ses dramatically the distance with the naive ground state of the 2i + LIF ESCs.

213 oscillators (DOPOs) to effectively find the ground state of the Ising Hamiltonian, which can be used

214 nor-acceptor compaction within the activated ground state of the wild type enzyme.

215 probe the chemical nature of the insulating ground state of VO(2), whose properties have been an iss

216 Whether the magnetic ground state of Yb(2)Ti(2)O(7) is a quantum spin liquid

217 What are the ground states of an interacting, low-density electron sy

218 Impurities often play a defining role in the ground states of frustrated quantum magnets.

219 Here we explore the ground states of interacting electrons in an exceptional

220 lay a key role in determining the electronic ground states of materials.

221 We show that the ground states of this system are consistent with previou

222 We explore the problem of projecting the ground-state of an ultra-strong-coupled circuit-QED syst

223 model with a nonmagnetic valence bond solid ground state on a ladder.

224 d triangulene retains its open-shell quartet ground state on the surface.

225 By stabilizing unpaired spin in the ground state, open-shell pai-conjugated molecules can ac

226 port already from screening the polymer film ground state optical properties.

227 The ground-state optimized structure of Pd(0) active catalys

228 rations are required to achieve and maintain ground state or occur as an outcome of 2i signal induced

229 bable, rather than by stabilizing the folded ground state or the cleaved product.

230 In turn, this permits us to compute ground-state phase diagrams for multicomponent systems.

231 which various insulating and superconducting ground-state phases emerge at low temperatures in magic-

232 ctroscopy identifies the chromophore in this ground-state photo-intermediate as being protonated.

233 However, ground state pluripotency in some inbred strain backgrou

234 e role genetic variation plays in control of ground state pluripotency.

235 K and GSK3beta (2i) inhibitors transition to ground state pluripotency.

236 s to open-shell nanographenes with high-spin ground states, potentially useful in carbon-based spintr

237 the fraction of fluorescent molecules in the ground state pretty nearly equals the total concentratio

238 h the arene is held more loosely than in the ground state, primarily through dispersion forces.

239 + sigma2s] reaction symmetry-allowed in the ground state, proceeding through a transition state with

240 iew focuses primarily on carbon tunneling in ground-state processes but also highlights nitrogen tunn

241 asis of atomic orbitals from which all other ground-state properties can be derived.

242 in flexible, entropically rich, and inactive ground states provides a mechanism for utilization of li

243 cular H-transfer that generates zwitterionic ground-state quinones.

244 ate that the PmoD Cu(A) has a pure sigma(u)* ground state rather than the typical equilibrium between

245 Propelling a ground state reaction by mode-specific vibrational excit

246 ming the activation energy and promoting the ground state reaction with negligible heating of the sam

247 We obtain ground-state reaction rates of 2.19 x 10(11) s(-1) at 15

248 s reaction as a paradigm for IR light-driven ground state reactions.

249 We demonstrate that ground-state recovery is mediated by two distinct S(1) d

250 donor strength, systematic elevation in the ground-state reduction potential and decrease in the HOM

251 otoluminescence intensity, together with the ground-state resonant peak of quantum dots appearing in

252 Hydrogen sulfide radicals in the ground state, SH(X), and hydrogen disulfide molecules, H

253 Luttinger liquid is locally heated above its ground state shows superdiffusive behavior (i.e., spread

254 y for the generation of nitrogen-radicals by ground-state single electron transfer with organyl-Ni(I)

255 e classically forbidden transitions from the ground-state singlet to excited-state triplets to gain o

256 ne with an unprecedented high-spin (triplet) ground state, singlet triplet energy gap, DeltaE(ST) = 0

257 Using recently published QM/MM-derived ground-state SLO-substrate complexes for WT and DM, toge

258 usts the orientation of its substrate in the ground state so that the substrate needs to only undergo

259 scopy, we resolved emission into each of the ground-state spin sublevels, a crucial component for spi

260 These compounds display a ground-state spin that can be initialized and read out u

261 In molecular systems, optically addressing ground-state spins would enable a wide range of applicat

262 ations confirm the presence of ferromagnetic ground states that arise from direct exchange between ma

263 ten show a rich variety of quantum many-body ground states that challenge theory(2).

264 s well known that benzene is aromatic in the ground state (the Huckel's rule) and antiaromatic in the

265 ext] and VI[Formula: see text], the magnetic ground state, the band gap, and the Fermi level could be

266 rengths and redox potentials that define the ground-state thermodynamics for C-H bond activation in c

267 The efforts detailed here indicate that the ground-state thermodynamics of C-H bond activation in P4

268 ssociated with the decay from the CSS to the ground state through charge recombination were experimen

269 tion of ferromagnetically coupled large-spin ground states through the elimination of long-range, int

270 Though no bond exists in the ground state, time-dependent density functional theory i

271 conformational rearrangements from a closed ground state to a CD4-bound open state.

272 imentally demonstrate that the jump from the ground state to an excited state of a superconducting ar

273 transitions from the disordered free energy ground state to assembly-competent states.

274 measure the cyclotron frequency ratio of the ground state to the metastable state of the ion with a p

275 e conformational ensemble equilibrium from a ground state toward an active state, which is detected b

276 -altitude observatory(10), of the rotational ground-state transition of HeH(+) at a wavelength of 149

277 We detected two ground-state unprotonated retinal photoproducts, 13-tran

278 cyclopentadienyl) sandwich complex, with the ground-state valence electron configuration of uranium(I

279 e role of structural defects on the magnetic ground state via the diffuse scattering of neutrons.

280 s result is surprising since a Dirac fermion ground state was only recently proposed as an alternativ

281 Here, we show that the properties of the ground-state wavefunction and the holon excitation of th

282 The two states are the 'locked' ground state where the FliJ coiled coil filament experie

283 derate-poor electrochemical potential in the ground state, whereas some of them are characterized by

284 FA(2+) and dianion ANA(2-) have closed-shell ground state, which can be explained by the different in

285 ab initio calculations in the ferromagnetic ground state, which indicates intermediate-strength elec

286 by accessing the energy landscape above the ground state, which may have fundamentally different kin

287 l reactions catalyzed by Pd complexes in the ground state, which mostly proceed through two-electron

288 nvolves the formation of a singlet diradical ground state, which requires multireference methods, the

289 ta and Mek1/2 (2i) instructs a self-renewing ground state whose endogenous inducers are unknown.

290 a low optical gap, and an open-shell singlet ground state with a low singlet-triplet gap.

291 (4)](3+)-alkyl cluster adopts an S = (1)/(2) ground state with g(iso) > 2.

292 ations of 2, 6 and 12 fermionic atoms in the ground state with high fidelity.

293 Cs) cultured in the presence of LIF occupy a ground state with highly active pluripotency-associated

294 that this Mn(IV)(4)O(4) complex has an S = 3 ground state with isotropic (55)Mn hyperfine coupling co

295 epulsive Coulomb interactions, which favours ground states with non-zero electron spin.

296 achieve nearly the accuracy of NEO-CCSD for ground states with significantly lower computational cos

297 100 nm and almost degenerate singlet-triplet ground states with weak antiferromagnetic interactions e

298 e CCS is patterned entirely as a slow, nodal ground state, with a T-box dependent, physiologically do

299 rapid transition from spherical to deformed ground states, with (78)Ni as the turning point.

300 f mirror-symmetry violation in bound nuclear ground states within the mirror partners strontium-73 an