ライフサイエンスコーパス: heterolytic cleavage

1 ut the hydrogen molecule is activated toward heterolytic cleavage.

2 peroxyanion and a peroxide activated toward heterolytic cleavage.

3 ide toward the proximal oxygen, facilitating heterolytic cleavage.

4 t the rate-limiting step in the reaction was heterolytic cleavage.

5 th the presence of the substrate retards the heterolytic cleavage and gives rise to homolytic O-OH cl

6 c cleavage via traditional Fenton chemistry, heterolytic cleavage, and nucleophilic attack.

7 ct formation cis to the ReX bond followed by heterolytic cleavage at the electrophilic rhenium center

8 orating oxygen vacancies not only drives the heterolytic cleavage, but also the homolytic cleavage of

9 ane was experimentally determined versus the heterolytic cleavage energy of hydrogen in acetonitrile,

10 issociation pathways: retrocycloaddition and heterolytic cleavage (generating a trityl cation in the

11 DFT studies reveal that this heterolytic cleavage is actually initiated by an homolyt

12 kcal/mol larger Marcus intrinsic barrier for heterolytic cleavage of 1-F than for cleavage of 1-Cl is

13 adical anion as a critical step, followed by heterolytic cleavage of a carbon-halogen bond.

14 le mechanism for biaryl formation involves a heterolytic cleavage of an aryl C-N bond and release of

15 uggest a formal stepwise mechanism involving heterolytic cleavage of an aryloxysulfur species to give

16 oxygenase (HO) enzymes could proceed through heterolytic cleavage of an iron(III)-hydroperoxo interme

17 and electrons originate from the metal (via heterolytic cleavage of an M-H bond).

18 and 4-chlorophenyltrimethylsilane caused the heterolytic cleavage of aryl-chlorine bonds to give the

19 abstraction by the ferriheme-peroxo base and heterolytic cleavage of arylhydroxylamines render molecu

20 Heterolytic cleavage of dihydrogen into a proton and a h

21 Heterolytic cleavage of H(2) by 3 at room temperature fo

22 le) based on the DFT calculations shows that heterolytic cleavage of H(2) can occur from (eta(2)-H(2)

23 dride complexes that can be generated by the heterolytic cleavage of H(2) gas to form B-H bonds.

24 3-H(2)](+) is consistent with intramolecular heterolytic cleavage of H(2) mediated by the pendant ami

25 utational studies indicate a low barrier for heterolytic cleavage of H(2).

26 bide as energetically viable relative to the heterolytic cleavage of H(2).

27 Such data signify a heterolytic cleavage of H(2)O(2) with HRP as pristine na

28 es in nature use hydrogen as a fuel, but the heterolytic cleavage of H-H bonds cannot be readily obse

29 cently been proposed to interpret the facile heterolytic cleavage of H2 by frustrated Lewis pairs (FL

30 We show how the rate of reversible heterolytic cleavage of H2 can be controlled, spanning 4

31 he dihydrogen complex and the product of the heterolytic cleavage of H2 in a functional model of the

32 We report the facile, reversible heterolytic cleavage of H2 in a manganese complex bearin

33 method involves measuring the equilibrium of heterolytic cleavage of H2 in the presence of a base, an

34 groups on N and P), have been developed for heterolytic cleavage of H2 into a proton and a hydride,

35 r 1a has been measured (49.5(1) kcal/mol) by heterolytic cleavage of H2 with Et3N in CH3CN.

36 The products of heterolytic cleavage of H2, Mo hydride complexes bearing

37 providing a design principle for controlling heterolytic cleavage of H2.

38 Our results rule out a substrate-assisted heterolytic cleavage of H2O2 en route to Cpd I.

39 l role in catalysis, acting as a base in the heterolytic cleavage of hydrogen.

40 r, Q203V PGHS-1 and PGHS-2 mutants catalyzed heterolytic cleavage of peroxides and exhibited native C

41 PGHS POX catalyzes heterolytic cleavage of primary and secondary hydroperox

42 n of charged species (even as spectators) or heterolytic cleavage of small molecules should be though

43 Direct stand breaks result from heterolytic cleavage of the adjacent C3'-carbon-oxygen b

44 consistent with an ionic mechanism involving heterolytic cleavage of the allylic C-N bond, followed b

45 deformylated substrate complex indicate that heterolytic cleavage of the C-C bond in the enzyme envir

46 Complex 4 effects the heterolytic cleavage of the C-H of phenylacetylene to yi

47 roton sources like MeOH and PhOH, the facile heterolytic cleavage of the C-OH bond in intermediate II

48 utases, which catalyze homolytic rather than heterolytic cleavage of the carbon-cobalt bond, can use

49 d by competing backward SET and irreversible heterolytic cleavage of the carbon-hydrogen bond at the

50 sm where the rate-limiting step changes from heterolytic cleavage of the carbon-oxygen bond in the al

51 (Co1+Cbl) species, which can be obtained by heterolytic cleavage of the Co-C bond in methylcobalamin

52 Heterolytic cleavage of the Co-C bonds is much more favo

53 strate for the reaction to proceed, with the heterolytic cleavage of the glycosidic C-O bond.

54 bending; (2) The bent nitrosyl promotes the heterolytic cleavage of the H-H bond and protonation of

55 ts Lewis acidic iron(II) centre promotes the heterolytic cleavage of the H-H bond and this non-redox

56 Controlling the heterolytic cleavage of the H-H bond of dihydrogen is cr

57 tion is less common due to the difficulty in heterolytic cleavage of the H-H bond.

58 city represents the free energy required for heterolytic cleavage of the metal-hydride bond to releas

59 major product of the reaction, demonstrating heterolytic cleavage of the methylcobamide carbon-cobalt

60 um hydride/cyanide species and isobutene via heterolytic cleavage of the N-Bu(t) bond.

61 A reaction mechanism of a heterolytic cleavage of the NOCF3 bond followed by recom

62 lyses point towards a mechanism in which the heterolytic cleavage of the O-O bond is triggered by a p

63 A significant amount of heterolytic cleavage of the O-O bond of cumene hydropero

64 ydroperoxoferri-HO (D140A) instead undergoes heterolytic cleavage of the O-O bond, ultimately yieldin

65 to the hydroperoxy intermediate resulting in heterolytic cleavage of the peroxide O-O bond and format

66 These radicals then undergo heterolytic cleavage of the phosphate group to yield alk

67 (4a) proceeds via a sigma-adduct followed by heterolytic cleavage of the Si-H bond and transfer of si

68 could be initiated either by homolytic or by heterolytic cleavage of this bond.

69 Heterolytic cleavage of this tyrosine radical at the Cal

70 onal models of FLP chemistry, which invoke a heterolytic cleavage pathway.

71 nds up with H(2) coordination and subsequent heterolytic cleavage, regenerating the gold(I)-hydride a

72 rate could be converted: oxidative addition, heterolytic cleavage, sigma-bond metathesis, electrophil

73 ond cleavage were clearly identified: a fast heterolytic cleavage (tau = 108 ps) was observed in prot

74 hosphate leaving group is then expelled in a heterolytic cleavage to give a contact alkene radical ca

75 a hydroxyl radical and Cu(II)OH rather than heterolytic cleavage to yield water and a Cu(II)-O(*-) s

76 Motifs that display heterolytic cleavage typically separate according to non