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1   The B-H bond activation process produces P-hydrido-1,3,2-diazaphospholene intermediate 2, which exh
2                                    Ruthenium hydrido ammonia halide ion pair intermediates [cis-(PMe(
3            Thus, complexes that contain both hydrido and phosphanido functionalities are of great int
4   A DFT study has shown that the phosphonium hydrido borate zwitterion 10 is formed exergonically in
5 ambient temperature to yield the phosphonium/hydrido borate zwitterion 5.
6 y studies and isolation of an original trans-hydrido(boryl)iron complex, Fe(H)(Bpin)(dmpe)2, allowed
7                       An alternative Rh(III) hydrido-boryl complex, which has been independently synt
8 nomeric H-B-9-BBN with nitriles leads to the hydrido-bridged diborylimine intermediate; a subsequent
9 of the fluorine atom in hydrolysis versus mu-hydrido bridging.
10             Cationic cobalt(II) bisphosphine hydrido-carbonyl catalysts that are far more active than
11 gnificantly more active than known ruthenium hydrido-carbonyl phosphine or NHC complexes.
12 lkylidene complexes include the formation of hydrido-carbonyl-chloride derivatives in the presence of
13 pling reactions are catalyzed by a ruthenium hydrido chloride complex (1), supported by a chelating P
14 s with HCl to furnish two isomeric dirhodium hydrido-chloride complexes, Rh(2)(II,II)(tfepma)(2)(CN(t
15 hat proceeds via an isolated a-hydroxylalkyl hydrido complex (3).
16                     The mixed-valence diiron hydrido complex (mu-H)Fe2(pdt)(CO)2(dppv)2 ([H1](0), whe
17 irst example whereby a low-valent main-group hydrido complex facilitates metalation of sp(3) C-H bond
18    A novel heterobimetallic tantalum/iridium hydrido complex, [{Ta(CH(2)(t)Bu)(3)}{IrH(2)(Cp*)}] 1, f
19 itions (1.5 bar, 298 K), in forming bridging hydrido-complex 6.
20                             The tungsten(IV) hydrido compounds react with iodoform to afford the corr
21  species are now known for a wide variety of hydrido compounds.
22  oxides, these adducts react with H2 to give hydrido derivatives [(CO)(CNBAr(F)3)2Fe(H)(pdt)Ni(dxpe)]
23 nd NMR characterization of activated rhodium-hydrido dicarbonyl species were carried out.
24 n the absence of H2, reaction of the rhodium-hydrido dicarbonyl with allylbenzene allowed further det
25  an otherwise elusive and highly reactive Fe-hydrido (Fe-H) intermediate.
26 ified, e.g., by isolating an elusive anionic hydrido germanate and exploiting it for challenging bond
27   This review covers low oxidation state and hydrido group 2 complexes and their role in the reductio
28  E2 and S(N)2 products, along with ruthenium hydrido halide complexes including the ruthenium fluorid
29 a weak acid to 2 allowed us to intercept the hydrido-halide intermediate [(PN)(2)Zr(I)(H)] (X = Cl, I
30 o-ligand hydrogen transfers (through an iron-hydrido intermediate) to form CpFeC(2)H(3)(+) and CpFeC(
31 nyl Pt(II) cations, via Pt(IV)-methyl-phenyl-hydrido intermediates.
32  assigned as a Ni(III)-Fe(II) species with a hydrido ligand in the bridging position between the two
33 e bridging hydrido ligands, and one terminal hydrido ligand on one of the two platinum atoms.
34 ng {AuPPh3} group was replaced by a bridging hydrido ligand to yield the unsaturated dirhenium comple
35 milar to 11 but contains one triply bridging hydrido ligand, two edge bridging hydrido ligands, and o
36     It contains a Pt-Os bond with a bridging hydrido ligand.
37 nusually large degree of spin density on the hydrido ligand.
38                                    The three hydrido ligands are bridging ligands across each of thre
39                                          The hydrido ligands in 2-4 bridge the platinum-rhenium bonds
40 easonable yields, but the elimination of all hydrido ligands to yield 1 was achieved only under the m
41                                  Some of the hydrido ligands were expelled from 4 in the form of hydr
42 y bridging hydrido ligand, two edge bridging hydrido ligands, and one terminal hydrido ligand on one
43 four metal atoms with two dynamically active hydrido ligands.
44 oms with a Pt-Pt bond and four edge bridging hydrido ligands.
45  consequent Fe-Ir and Ir-Ir bonds bridged by hydrido ligands.
46 nyl ligands from 11 and the addition of four hydrido ligands.
47 contains a triangular PtRe2 cluster with two hydrido ligands; one bridges a Pt-Re bond, and the other
48 e C-H bond dissociation and the formation of hydrido methyl complexes, H-Aux(+) -CH3 .
49 this medium, although some distinct carbonyl/hydrido/methyl or acetato species were also observed.
50    Instead, Fe-bound formaldehyde is a metal-hydrido mimic, a locked, inhibited form analogous to tha
51 titatively generated an unexpected dinuclear hydrido Ni complex with a four-membered planar Ni2Si2 co
52 easured in wastewater and human blood (e.g., hydrido-PFCAs), and five compounds associated with aqueo
53 1,6-diyne or 1,6-enyne substrates to afford (hydrido)Rh(III)-based metallocyclopentadiene and metallo
54 f one of the borane ligands and afforded the hydrido (sigma-B-H)-boryl bis(sigma-B-H)-borane complexe
55 V) acts as a hydride transfer agent, and the hydrido silicate key intermediate is isolated.
56                            In this process, (hydrido)silyl amines, generated in situ by dehydrogenati
57                                             (Hydrido)silyl ethers that are formed in situ by hydrosil
58                                             (Hydrido)silyl ethers, generated in situ by dehydrogenati
59 silylation of arene C-H bonds directed by a (hydrido)silyl group.
60 ca-supported low-coordinate heterobimetallic hydrido species [=SiOTa(CH(2)(t)Bu)(2){IrH(2)(Cp*)}], 5,
61 lytic cycle at which a highly reactive metal-hydrido species is formed.
62 y occurred, the reaction of HCHO with the Fe-hydrido species would lead to methanol, release of which
63  most prevalent in highly reactive alkyl and hydrido species.
64 ving a third series of oligomers with a beta-hydrido substituent at the anomeric carbon.
65 rresponding Tp'Re(O)(diolato) complex (Tp' = hydrido-tris-(3,5-dimethylpyrazolyl)borate) was measured
66  intermediate is directly converted into the hydrido vinyl product via an intramolecular sp(2) C-H bo
67 2) (R = Me, Ph), to afford the corresponding hydrido zirconocene diazenido complexes have been measur
68 ulted in rapid N H bond formation to yield a hydrido zirconocene hydrazido compound concomitant with