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1 or improvement is greater than in the mature hydroformylation.
2 as demonstrated by the industrially relevant hydroformylation.
3 propanal) cm(-3) h(-1) in gas-phase ethylene hydroformylation.
4 ht the complex kinetics of Rh(BDP) catalyzed hydroformylation.
5 ure is largely focused on polymerization and hydroformylation.
6 noxide and hydrogen) and ethylene via tandem hydroformylation.
7 o larger reaction schemes, as in homogeneous hydroformylation.
8 onversion of ethylene to propanal via tandem hydroformylation.
9 e formed selectively under the conditions of hydroformylation.
10 acts as a proton shuttle to enable transfer hydroformylation.
11 ating the feasibility of elementary steps in hydroformylation.
12 med to be intermediates in rhodium-catalyzed hydroformylation.
13 s that are generally assumed to be active in hydroformylation.
14 om the same alkene 4 by catalytic asymmetric hydroformylation.
15 f regioselectivity and enantioselectivity in hydroformylation.
16 onds to the substrate, allowing for directed hydroformylation.
17 gth of reaction intermediates and have lower hydroformylation activation energy barriers compared to
20 L1 and L2 in the highly selective asymmetric hydroformylation (AHF) of the challenging substrate 2,3-
21 - and enantioselectivities in the asymmetric hydroformylation (AHF) of three heterocyclic olefins.
24 ons, including cobalt- and rhodium-catalyzed hydroformylation and an Ireland-Claisen rearrangement.
25 nd Ru3(CO)12 or Ru(methylallyl)2(COD) direct hydroformylation and hydrogenation of alkenes to alcohol
27 cades this abundant gas has been employed in hydroformylation and Pausen-Khand catalysis, amongst man
28 he principles of tandem catalysis related to hydroformylation and represents a key step toward the ra
29 ted the active catalyst that mediates alkene hydroformylation and subsequent aldehyde hydrogenation.
31 the substrate ligand interaction is dynamic, hydroformylations are catalytic in ligand and do not req
33 tivity and enantioselectivity of aryl alkene hydroformylation as catalyzed by rhodium complexes of th
36 tions, including (asymmetric) hydrogenation, hydroformylation, C-H activation, oxidation, radical-typ
37 ), which were subsequently used for ethylene hydroformylation catalysed by the nearby Pt-SiO(2) inter
39 sphine)](BF(4)), x = 1-3, is a highly active hydroformylation catalyst system, especially for interna
40 (I)-AsCM-102 is an air-stable and recyclable hydroformylation catalyst, which is more active than its
44 of recent conflicting reports regarding the hydroformylation catalytic activity derived from cationi
45 inyl esters via a cascade reaction including hydroformylation, condensation with a primary amine, and
47 nes, alkynes, and dienes in fewer steps than hydroformylation does, the latter has some advantages at
48 indolizidine skeleton by Rh-catalyzed domino hydroformylation double cyclization and sequential stere
49 on seems to have an advantage as compared to hydroformylation due to the high activity and selectivit
50 However, the electrochemical analogue of hydroformylation (electro-HFN), which uses protons and e
54 mediates relevant to cobalt-catalyzed alkene hydroformylation have been isolated and evaluated in fun
55 covalently attached to the substrate during hydroformylation; however, similar to traditional asymme
60 talyst with high activity and selectivity in hydroformylation is challenging but essential to allow t
63 is the first example in which the asymmetric hydroformylation of 1 is both regio- and enantioselectiv
65 he highly enantioselective rhodium-catalyzed hydroformylation of 1,1-disubstituted olefins has been d
67 However, optimal regio- and enantioselective hydroformylation of 2,3-dihydrofuran (up to 3.8:1 alpha-
69 e original industrial catalysts used for the hydroformylation of alkenes through reaction with hydrog
70 ng high enantioselectivity in the asymmetric hydroformylation of allyl cyanide and the conjugate addi
71 to be the best overall ligand for asymmetric hydroformylation of allyl cyanide with up to 80% ee and
75 g first the formation of an aldehyde through hydroformylation of an olefin and then the production of
77 as well as the regio- and diastereoselective hydroformylation of disubstituted olefins is reported.
81 , has been applied to the diastereoselective hydroformylation of homoallylic alcohols to afford delta
84 aphospholane ligands catalyze the asymmetric hydroformylation of N-vinyl carboxamides, allyl ethers,
89 hodium bis(diazaphospholane) (BDP) catalyzed hydroformylation of styrene is sensitive to CO concentra
94 nd results in unprecedented selectivities in hydroformylation of terminal and internal alkenes functi
95 that promotes branch and diastereoselective hydroformylation of terminal olefins as well as the regi
96 es involve (i) an extremely linear-selective hydroformylation of the terminal alkene moiety of a dehy
98 applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes.
99 ise disfavored beta-aldehyde products in the hydroformylation of vinyl 2- and 3-carboxyarenes, with c
100 and their application in the regioselective hydroformylation of vinyl and allyl arenes bearing an an
102 ieved in the rhodium-catalyzed isomerization-hydroformylations of internal olefins compared with its
103 been achieved in the Rh-catalyzed asymmetric hydroformylations of styrene derivatives and vinyl aceta
105 ative application of the sequence asymmetric hydroformylation/oxidation/alkyne hydroacyloxylation tha
108 otocols relied on a rhodium catalyzed linear hydroformylation process, the alternative approach was b
109 cently alternative routes to the traditional hydroformylation processes that used potentially toxic c
110 spectroscopy for fast in-line monitoring of hydroformylation products directly within the segmented
111 intermediates and thus achieves the highest hydroformylation rates among supported Rh-based catalyst
112 d within a ZSM-5 zeolite to enhance ethylene hydroformylation rates and selectivity while maintaining
115 tures representing the various stages of the hydroformylation reaction of propene in supercritical CO
116 the directing group strategy accelerates the hydroformylation reaction such that the reaction is perf
121 ains the experimentally observed iso-favored hydroformylation regioselectivity due to pore confinemen
123 tanding catalyst for efficient heterogeneous hydroformylation, RhZn intermetallic nanoparticles.
127 ns reveals that the ethylene present for the hydroformylation step slows down initial methanol decomp
128 O)2(BDP)] [BDP = bis(diazaphospholane)] with hydroformylation substrates vinyl acetate, allyl cyanide
129 oil can be used to produce aldehydes through hydroformylation, taking advantage of the olefin functio
130 dies on the mechanism of a rhodium-catalyzed hydroformylation that is selective for branched aldehyde
132 The Rh-WO(x) pair sites catalyse ethylene hydroformylation through a bifunctional mechanism involv
133 nd-free heterogeneous catalysts for ethylene hydroformylation to produce C(3) oxygenates is of import
136 decomposition are poised to directly undergo hydroformylation upon migration from one catalytic inter
137 ) Hydroesterification requires pure CO while hydroformylation uses syngas, a mixture of CO and H2.
140 ve production of aldehyde through the tandem hydroformylation was also observed on propylene and 1-bu
141 ngle atom catalysts (SACs) for heterogeneous hydroformylation was investigated both theoretically and
142 on a cyclohydrocarbonylation (CHC) driven by hydroformylation was set up toward the efficient diaster
143 1,2-disubstituted alkenes undergo effective hydroformylation with 89-97% ee and complete conversion
144 ssible to reduce the temperature of ethylene hydroformylation with a solid catalyst down to 50 degree
146 yl benzyl ether followed by enantioselective hydroformylation yields the beta(3)-aminoaldehyde with 7