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1 -top research into large-scale production of hydrogen.
2 s a natural abundance of only ~0.016% of all hydrogen.
3 , then dissociated by ions to produce atomic hydrogen.
5 cases how strain can be used to modulate the hydrogen absorption capacity and HER activity of palladi
6 apidly and accurately predict major sites of hydrogen abstraction in the metabolism of drug-like mole
8 ads led to photoproducts arising from formal hydrogen abstraction or Paterno-Buchi (PB) photoreaction
13 they can remove a small (a few Earth masses) hydrogen and helium envelope on timescales of several bi
15 polished and unpolished BDD electrodes, with hydrogen and oxygen surface terminations, it is determin
16 trochemistry including the adsorbed/absorbed hydrogen and/or the premonolayer palladium oxide redox p
17 diastereoisomeric complexes, is explained by hydrogen- and halogen-bonding, as well as dispersion int
18 cess that involves dissociation of molecular hydrogen at catalytically active graphene ripples, follo
19 the dissociation and metallization of solid hydrogen at megabar pressures almost a century ago(2), s
20 sp(3))-H halogenation sequence by sequential hydrogen atom abstraction (HAA) and radical capture.
23 graphy; and deuterium isotope effects on the hydrogen atom abstraction by the adenosyl radical were u
24 udies reveal that catalysis proceeds through hydrogen atom abstraction followed by radical rebound, a
25 ion of dG(N1-H)(.) via dG(N2-H)(.) following hydrogen atom abstraction from dG is unlikely to be a ma
29 consistent with these observations involving hydrogen atom addition to the ipso position of the pheny
31 ve hydrogen atom transfer (cHAT), where each hydrogen atom donated to the alkene arrives from a diffe
32 ble-light-absorbing reagent and electron and hydrogen atom donor to promote the desulfonylation react
33 proach to radical hydrogenation: cooperative hydrogen atom transfer (cHAT), where each hydrogen atom
34 prise, the mechanism suggests intermolecular hydrogen atom transfer (HAT) chemistry is at play, rathe
35 onstration of the oxidizing ability of S via hydrogen atom transfer (HAT) from TEMPO-H (2,2,6,6-tetra
37 e to both single electron transfer (SET) and hydrogen atom transfer (HAT) reactions, thus covering al
38 ediate 8 are detailed, enlisting late-stage, hydrogen atom transfer (HAT)-mediated free radical bond
44 generally two types of reactions occur: (a) hydrogen-atom transfer (HAT) from a donor to the peroxyl
45 canonical radical reactions-cobalt-mediated hydrogen-atom transfer and copper-promoted radical cyana
47 ydrogen atoms reveal that the segregation of hydrogen atoms at the grain boundaries, rather than the
48 ional theory calculations support up to 0.48 hydrogen atoms per formula unit of ([Formula: see text])
49 haracterization and atomic-scale tracking of hydrogen atoms reveal that the segregation of hydrogen a
51 lectronic-structure-based descriptor for the hydrogen-binding strength: Delta(dp) , the local interba
52 atoms into the inhibitor scaffold can act as hydrogen bond acceptor sites to the serine hydroxyl.
53 ested that the presence of an intramolecular hydrogen bond between the oxygen of the directing group
54 ence of structural interfaces on the spatial hydrogen bond density, the effect of nanofiber size and
55 We identified a novel and highly effective hydrogen bond donor (HBD)-organic acid pair that can fac
59 P(2) and the underlying substrate was due to hydrogen bond formation, which outcompeted electrostatic
60 demonstrate that the strength of this short hydrogen bond is reinforced following protonation of a n
61 ent metal amide complexes featuring extended hydrogen bond networks can undergo tunable, high-enthalp
63 substantially weakens the homolytic nitrogen-hydrogen bond strength of a Bronsted acidic anilinium te
68 H in catalysis by providing an indispensable hydrogen bond; preliminary computational analysis furthe
70 ure-activity analysis reveals that the three hydrogen-bond contacts with fluoride are not equal in te
71 second optimization step, masking one of the hydrogen-bond donors of the central urea moiety through
72 ater-surface bonding and the ease with which hydrogen-bond exchange can occur (either through a class
76 The cocrystals are composed of a tetratopic hydrogen-bond-acceptor molecule synthesized in the solid
78 miconductive, proton-conductive, microporous hydrogen-bonded organic framework (HOF) derived from phe
79 by assuming a nitrene C-H insertion within a hydrogen-bonded silver complex in which a single C-H bon
81 oth Y731 and Y356 with interfacial water and hydrogen-bonded water chains appear critical for effecti
84 auxiliaries that form robust intermolecular hydrogen bonding and are tethered to naphthalic anhydrid
86 conformation (including disruption of strong hydrogen bonding and novel conformer formation) and any
87 ies show that charge-charge interactions and hydrogen bonding between the suramin sulfonated groups a
88 calculations demonstrate that intramolecular hydrogen bonding can stabilize Boat, whereas electron re
89 y comparison to control structures that lack hydrogen bonding capability, resulting in lower surface
90 Our results reveal generic backbone-backbone hydrogen bonding constraints as a determining factor in
92 de dihedral angles accompanying transannular hydrogen bonding in the [3.3]paracyclophane and (b) mono
95 his process, which highlights the ability of hydrogen bonding phase-transfer catalysts to couple two
96 erine show 5hmC-specificity that mirrors the hydrogen bonding potential of the side chain (C-H < S-H
97 ent of water in hydrophobic pores alters its hydrogen bonding structure and related properties such a
98 of information on exact proton locations and hydrogen bonding structures in a bona fide metalloenzyme
99 to form new intramolecular or intermolecular hydrogen bonding, and improve the thermal behavior and c
100 The addition of ancillary groups (e.g., hydrogen bonding, Bronsted acid/base) near the active si
101 01 angstrom or less, even in the presence of hydrogen bonding, metal-metal bonding, and electrostatic
102 ding of cellulose, including the key role of hydrogen bonding, the dependence of structural interface
103 tage is that the footprint reflects SASA and hydrogen bonding, whereas one drawback is the labeling i
105 uations of interfacial water, as well as the hydrogen-bonding interactions and conformational motions
106 e conformational flexibility of Y731 and the hydrogen-bonding interactions of both Y731 and Y356 with
109 ed with IR spectroscopy to study how alkanol hydrogen-bonding networks confined within hydrophobic an
110 re of the motor for recognition of different hydrogen-bonding organocatalysts a greater than 10-fold
112 in structural behavior follows directly from hydrogen-bonding restrictions and suggests that the prot
113 olidinyl)-1,4-benzodioxanes bearing a small, hydrogen-bonding substituent at the 7-, 6-, or 5-positio
115 the foundation for future studies concerning hydrogen bonds and halogen bonds in close proximity.
117 were occupied in the BSA-CYG complex through hydrogen bonds and van der Waals forces with the binding
119 table periodic structures with non-canonical hydrogen bonds in some regions and non-canonical stackin
123 The introduction of an optimal amount of hydrogen bonds significantly strengthens the resultant e
125 of high densities of coordination bonds and hydrogen bonds to achieving a high PCM energy density, a
127 ) complex forms one and two gold-ion-induced hydrogen bonds with the water molecules in interfacial a
129 to water's high polarity and ability to form hydrogen bonds, has severely hampered the development of
130 ysis elucidate the contributions of Hoogsten hydrogen bonds, sugar, and phosphate moieties to the spe
131 the heterolytic activation of strong element-hydrogen bonds, which enables broad compatibility of car
132 tive rotamer featuring two ammonium-boronate hydrogen bonds, which enables phosphate coordination to
140 pidermidis or Staphylococcus hominis yielded hydrogen, but no methane, authentifying observational da
141 ne sources (e.g., petroleum) by inert carbon-hydrogen (C-H) bond activation using classical chemical
142 nantioselective functionalizations of carbon-hydrogen (C-H) bonds represent a promising pathway towar
144 a strong need for careful quality control in hydrogen compound-specific stable isotope analysis (CSIA
147 vs. RHE and a record high half-cell solar-to-hydrogen conversion efficiency of 4.33% under AM 1.5 G s
148 re the H-bonding properties of peripheral NH hydrogens could serve as anchors to tailor the organizat
154 , chemical exchange saturation transfer, and hydrogen-deuterium exchange experiments show that the va
155 the rate of trypsinolysis and the extent of hydrogen-deuterium exchange in local secondary structure
157 differential scanning calorimetry (DSC), and hydrogen-deuterium exchange mass spectrometry (H/D excha
158 2S) has been accomplished through the use of hydrogen-deuterium exchange mass spectrometry (HDX-MS).
159 d trypsinolysis mass spectrometry (LTMS) and hydrogen-deuterium exchange mass spectrometry (HXMS) are
167 dynamics in the presence of substrates using hydrogen/deuterium exchange mass spectrometry, complemen
170 ues were obtained at 33 backbone amides from hydrogen/deuterium fractionation factors by nuclear magn
171 M(-1) s(-1) (THF, -80 degrees C); thus, the hydrogen/deuterium kinetic isotope effect (KIE) = 6, con
172 esence of UV light, a photosensitizer, and a hydrogen donor, this "polyMOC" material can be reversibl
173 is crucial to the deployment of sustainable hydrogen economy but is currently constrained by the lac
174 h a BiVO(4) photoanode, achieving a solar-to-hydrogen efficiency of 1.5% with stability over 10 h und
175 y of 15.1 mA cm(-2) at 1.23 V vs. reversible hydrogen electrode (RHE) with an onset potential of 0.55
176 ic efficiency (99% at -580 mV vs. Reversible Hydrogen Electrode (RHE)), small onset overpotential (<9
177 12500 h(-1) at -0.95 V versus the reversible hydrogen electrode (RHE), with a FE for formate of 96 %
178 centimetre (at 1.5 volts versus a reversible hydrogen electrode) and a cathodic-side (half-cell) ethy
181 echanism, as further supported by monitoring hydrogen elimination from radical a-ions produced by UVP
183 ctron transfer to Pd clusters translate into hydrogen evolution activity optima at different residual
184 llography, X-ray photoelectron spectroscopy, hydrogen evolution experiments, electrospray ionization
185 s the rate of CO(2) reduction and suppresses hydrogen evolution from proton reduction, leading to Far
186 mixed metal/B layers, such as (110), promote hydrogen evolution more efficiently for x = 0.6, support
187 ammetry, which demonstrates the variation of hydrogen evolution reaction (HER) activity across Pt gra
188 switched between Pt species and LiCoO(2) for hydrogen evolution reaction (HER) and oxygen evolution r
191 s are emerging as substitute electrochemical hydrogen evolution reaction (HER) catalysts for noble me
192 efficient and low-cost electrocatalysts for hydrogen evolution reaction (HER) in alkaline media is c
193 ls and its exceptional activities toward the hydrogen evolution reaction (HER) in aqueous electrolyte
194 n with TiO(2)-based systems, rather than the hydrogen evolution reaction (HER), which is generally in
204 evels and diffuse subapical levels of sodium hydrogen exchanger 3 and SGLT1, which regulate transport
206 Preliminary mechanistic study reveals that hydrogen gas is released during the reaction, and both l
207 a simple anaerobic system now represented by hydrogen gas-evolving hydrogenase (MBH) where protons ar
208 ts as a single-chromophore photocatalyst for hydrogen-gas generation and operates with irradiation wa
210 o distinctive fluid chemistries as molecular hydrogen (H(2) ) and hydroxyl ions (OH(-) ) are produced
211 aerobic respiration using microbiota-derived hydrogen (H(2)) as an electron donor and fumarate as an
214 of the carbon-bound non-exchangeable (CBNE) hydrogen in mono and disaccharides has been developed to
215 explain the many unusual properties of dense hydrogen, including a rich and poorly understood solid p
218 atmosphere of N(2) and is highly active for hydrogen isotope exchange at (hetero)aromatic hydrocarbo
219 Subjective digestive symptoms and breath hydrogen (measuring LM) were recorded regularly over 3 h
220 pathways, including heterotrophy, sulfur and hydrogen metabolism, denitrification, and fermentation.
222 t-melting temperature-dependent diffusion of hydrogen occurring above the melting region, where water
226 osolic FdsABG formate dehydrogenase from the hydrogen-oxidizing bacterium Cupriavidus necator H16 bot
227 siderable proton conduction, as confirmed by hydrogen permeation experiment, remarkable hydration beh
228 roxide radical anion (superoxide dismutase), hydrogen peroxide (catalase), hydroxyl radicals (mannito
229 burst of reactive oxygen species (ROS), with hydrogen peroxide (H(2) O(2) ) as the most abundant form
230 the mutual presence of glutathione (GSH) and hydrogen peroxide (H(2) O(2) ) with high specificity on
231 of the active material, such reactions yield hydrogen peroxide (H(2) O(2) ), a reactive side-product,
232 on, we report on the development of a unique hydrogen peroxide (H(2) O(2) )-sensing motif and its cap
237 dismutation of virus-mediated generation of hydrogen peroxide (H(2)O(2)) we developed a model of int
239 wounding stimulates the rapid production of hydrogen peroxide (H(2)O(2)).(1)(,)(2) This then acts as
241 chemistry and produce reactive radicals from hydrogen peroxide activation have been extensively studi
243 d both the TGF-beta1-dependent production of hydrogen peroxide and the presence of myeloperoxidase (M
244 usly added as well as endogenously generated hydrogen peroxide decreases spermathecal contractility b
246 on of energy-dissipating ion channels, while hydrogen peroxide distributes oxidative stress to sensit
249 uminescence assay and a device for measuring hydrogen peroxide in the exhaled breath condensate of as
250 sted by the finding that elevation of ROS by hydrogen peroxide increased Src phosphorylation, while R
251 CM is able to effectively convert endogenous hydrogen peroxide into oxygen and then elevate the produ
252 This study examines whether an increase in hydrogen peroxide is sustained posttreatment and potenti
255 UV irradiation, oxygen plasma and vaporized hydrogen peroxide treatments, measured with EGA and HPC.
257 l agents (bleomycin, doxorubicin, topotecan, hydrogen peroxide, UV, photosensitized reactions) and fr
258 efective mutant had increased sensitivity to hydrogen peroxide-induced stress, was inhibited in its a
263 FSAs [keto-perfluorooctane sulfonate (PFOS), hydrogen-PFOS, and unsaturated PFOS] appeared to be more
267 indicates atmospheric venting from refinery hydrogen plants, landfill working surfaces, composting s
269 both aerobic (oxygen producing) and hypoxic (hydrogen producing) photosynthesis in daylight under air
272 bits a superior visible-light photocatalytic hydrogen production rate (~212 umol h(-1) /0.02 g cataly
273 for the first time that the surface-adsorbed hydrogen, rather than the hydride encaged in the C12A7 e
274 Methodology of nucleophilic substitution of hydrogen (S(N)(H)) was first applied for the direct modi
276 However, the exact nature of the reactive hydrogen species and the role of electride support still
277 the correlation between the pore volume and hydrogen storage capacity is examined and two empirical
278 al equations are rationalized to predict the hydrogen storage capacity of MOFs with different pore ge
279 s (MOFs) are promising materials for onboard hydrogen storage thanks to the tunable pore size, pore v
281 rotein increases gut bacterial production of hydrogen sulfide (H(2)S), indole, and indoxyl sulfate.
283 studies suggest that the cellular effects of hydrogen sulfide are mediated in part by sulfane sulfur
286 e cystathionine gamma lyase (CSE), generates hydrogen sulfide-related sulfane sulfur compounds (H(2)S
287 by investigating cardioprotective effects of hydrogen sulphide (H(2) S) and underlying mechanisms.
288 perfusate: saline vehicle (control); sodium hydrogen sulphide (NaHS); NaHS plus glibenclamide, an an
289 may need to be resolved by forming a global hydrogen taskforce in order to translate bench-top resea
290 ELT process are converted back to water and hydrogen; thus, the chemical and corrosive activity of w
293 ntermediates or transition states favors the hydrogen transfer reaction from rhodium to carbon to for
294 on transfer and, on the other hand, improved hydrogen transfer to the radical species in the solution
297 configuration and enhances the adsorption of hydrogen, which impedes the hydrogen evolution reaction.
299 donor results in the catalytic production of hydrogen with 170 +/- 5 turnovers in 24 hours and an ini