ライフサイエンスコーパス: intramolecular

1 occurs proceed through an enantiodetermining intramolecular 1,2-migration prior to fluorination.

2 initrogen to form vinyl cations that undergo intramolecular 1,3- and 1,4- hydride transfer processes

3 ityl-(1,9-di-tert-butyl)dipyrrin) facilitate intramolecular 1,3-dipolar cycloaddition as well as C-H

4 Large intramolecular (13)C kinetic isotope effects (KIEs) for

5 istic studies are reported on the inter- and intramolecular [2 + 2] alkene cycloadditions to form cyc

6 nsight into the mechanism of both inter- and intramolecular [2 + 2] cycloaddition reactions.

7 The synthetic approach involves an intramolecular [2 + 2] cycloaddition with concomitant de

8 up in the 2-position gave the products of an intramolecular [2 + 2] photocycloadditon.

9 The key step was an intramolecular [2 + 2]-photocyclization.

10 l rearrangement and a subsequent spontaneous intramolecular [4+2] hetero-Diels-Alder cycloaddition.

11 erazinoindolines through an indium-catalyzed intramolecular 5-exo-dig cyclization of ortho-alkynyl di

12 strate with reconstituted Lit to investigate intramolecular acyl chain transfer.

13 A derivative that upon TzB formation elicits intramolecular acyl transfer to give N-acyl thiazolidine

14 S(N)Ar reaction or a tandem Michael addition-intramolecular Ad(N)E process to furnish a range of phar

15 This cascade features an intramolecular addition of an acyl group-derived enol to

16 This adduct facilitates further intramolecular addition of the alkoxide to the aromatic

17 To determine whether intramolecular adjacency of these functionalities is nec

18 The existence of such an intramolecular agonist was initially indicated by site-d

19 responding enedione, followed by spontaneous intramolecular aldol condensation and leads to the forma

20 ing Baeyer-Villiger oxidation and subsequent intramolecular aldol condensation.

21 addition-intramolecular oxa-Michael addition-intramolecular aldol reactions.

22 h the exclusion of both competing inter- and intramolecular alkene/alkyne hydroboration.

23 the configuration of the axial amine, and an intramolecular alkoxycarbonylation to build the bicyclic

24 ioglycosides into beta-sulfonium ions via an intramolecular alkylation reaction, leading to highly al

25 ur-component reaction, followed by either an intramolecular alkyne hydroarylation and subsequent alke

26 asymmetric induction in an enantioselective intramolecular allylic substitution reaction catalyzed b

27 hat in addition to predicted self-regulatory intramolecular amino acid interactions between the SnoaL

28 ned by the twist of lateral phenyl rings and intramolecular and intermolecular CT transitions.

29 ase spectroscopy, are an increase in (a) the intramolecular and intermolecular deck-to-deck spacing c

30 gh substituents believed to enhance separate intramolecular and intermolecular H-bond interactions.

31 our transient system, to show that multiple intramolecular and intermolecular interactions modulate

32 on of the carboxylate conjugate base through intramolecular anion-binding to a thiourea site.

33 The palladium(0)-catalyzed intramolecular annulation of 12 1,3-disubstituted cyclop

34 ines were prepared in excellent yields by an intramolecular annulation of easily prepared chalcogen-c

35 Cu(I)-catalyzed intramolecular annulation of o-ethynylquinoline-3-carbal

36 H(-) group from the solvent that leads to an intramolecular aromatic O atom insertion into the CH bon

37 autoinhibition is released by disrupting the intramolecular ATPase:CW coupling through the competitiv

38 Concomitantly this intramolecular attraction raises the energy barrier from

39 P53 binding to MDMX disrupts an intramolecular auto-regulatory interaction and enhances

40 owed by reformation of the thiazole ring and intramolecular aza-Michael addition to furnish the title

41 of an aza-Nazarov reagent and its subsequent intramolecular aza-Michael cyclization.

42 heir hetero analogues was synthesized by the intramolecular aza-Wittig condensation of the amido grou

43 intermediate on the aryl ring and subsequent intramolecular B-B bond formation.

44 4)OMe)) with potassium graphite initiates an intramolecular, benzylic C-H amination at room temperatu

45 ese RaS enzymes and find that it installs an intramolecular beta-thioether bond onto its substrate pe

46 nd whose structure allows the restriction of intramolecular bond rotation (RIR) via intra- and interl

47 stituted B,N,B-benzo[4]helicenes 2 a/2 b via intramolecular borylation and sequential B-Mes bond clea

48 the nature of the spacer could modulate the intramolecular BP/Thy photoreactivity, resulting in an e

49 e catalytic conditions of the intermolecular-intramolecular Buchwald-Hartwig amination.

50 rs fused to heterocycles includes inter- and intramolecular buta-1,3-diyne cyclizations with the form

51 d and natural P450 catalysts can promote the intramolecular C-H amination of arylsulfonyl azides with

52 A mild visible-light-induced Pd-catalyzed intramolecular C-H arylation of amides is reported.

53 in-6(7H)-ones was developed via Pd-catalyzed intramolecular C-H arylation.

54 ldipyrrin; py: pyridine) displays productive intramolecular C-H bond amination to afford N-heterocycl

55 The intramolecular C-H borylation of (hetero)arenes and alke

56 hat provide evidence for a unique bifurcated intramolecular C-H interaction.

57 as nitrene precursors towards regioselective intramolecular C-H oxygenations to provide cyclic carbon

58 ing substrate to undergo palladium-catalyzed intramolecular C-H/C-Br bond cross-coupling to produce a

59 Intramolecular C-O coupling is also possible.

60 ompared as chiral inducers in the asymmetric intramolecular carbolithiation of olefinic aryllithiums.

61 tereoselectivity through a rhodium-catalyzed intramolecular carbonyl ylide cycloaddition reaction for

62 ma-lactams in up to 97% yield and 98% ee via intramolecular carbonylnitrene C-H insertion.

63 The reaction pathway involves an intramolecular cascade cyclization of homopropargyl sulf

64 role of orbital delocalization (occurring by intramolecular chalcogen bonding) in determining the con

65 The Intramolecular Chaperone Auto-processing (ICA) domain of

66 erties of isoindigo 6 and 7 exhibit a strong intramolecular charge transfer (ICT) absorption band in

67 t that pai to pai* transitions are dominant, intramolecular charge transfer (ICT) also contributes in

68 Here, we report an intramolecular charge transfer (ICT) dye, DMNDC, as an a

69 eir photoinduced electron transfer (PET) and intramolecular charge transfer (ICT) properties.

70 e including a 0.92 quantum yield ascribed to intramolecular charge transfer and intramolecular throug

71 The optical transitions are based on intramolecular charge transfer, as shown by solvatochrom

72 metric sensor materials due to the effect of intramolecular charge transfer.

73 antum yield remains large due to the lack of intramolecular charge transfer.

74 ivity (CISS) spin-filtering effect during an intramolecular charge-transfer (CT) process.

75 understanding the photophysical data and the intramolecular charge-transfer (ICT) processes of the sy

76 lar solution, DMABN forms an excited twisted intramolecular charge-transfer (TICT) state that emits w

77 Distinct from twisted intramolecular charge-transfer (TICT) states, experiment

78 The design of these intramolecular charge-transfer dyes is based on the conc

79 ies indicate that the formation of a twisted intramolecular charge-transfer species enables the popul

80 et of dyes are optimal candidates to explore intramolecular CISS.

81 ere, we aim in deciphering how protein-bound intramolecular cofactors can facilitate such long-range

82 Here, rhodium-pai bonds are used for intramolecular collapse in order to show that mechanical

83 namic cross-correlation analyses demonstrate intramolecular communication and suggest that specific r

84 have addressed the molecular basis for this intramolecular communication by analyzing the structure

85 f the dipole-bound (DB) electron on the cage intramolecular complexes does not fit into the standard

86 lic oxazolidinone, followed by a sequence of intramolecular condensation, tautomerization, and decarb

87 required to mediate protein oligomerization, intramolecular conformational switch, and protein-target

88 lecules and polymers that combine the linear intramolecular conjugation pathways commonly associated

89 tail regions of the molecule and of the key intramolecular contacts that cause inhibition.

90 Intramolecular contacts were determined between the prot

91 The intramolecular conversion of CO(2) to molecular oxygen i

92 Finally, intramolecular coordination interactions between TPYs an

93 e combination of covalent polymerization and intramolecular coordination-driven self-assembly.

94 nner rim for subsequent folding by selective intramolecular coordination.

95 etail, clearly resolving both the inter- and intramolecular correlations.

96 t is demonstrated that metallacycle-mediated intramolecular coupling of an alkyne and a 1,3-diketone

97 est cyclopropanation reactions involving the intramolecular coupling of two C-H bonds on gem-dialkyl

98 However, except for the intramolecular coupling, trisubstituted alkenes are unsa

99 ene) bridging ligands with sufficiently weak intramolecular coupling.

100 m the polymer backbone and focused on weaker intramolecular cross-links, leading to polymer unfolding

101 ms revealed panchromatic absorption owing to intramolecular CT and near-IR absorbing azaBODIPY.

102 The role of NHC in the intramolecular cyclization and preliminary mechanistic e

103 N-tethered epoxy-indoles that trigger facile intramolecular cyclization followed by an oxidative quen

104 he enol double-bond protonation, followed by intramolecular cyclization involving the interaction of

105 e functionalized in order to undergo further intramolecular cyclization leading to a new class of mac

106 Our synthetic strategy also features an intramolecular cyclization of a N-chloroamine to forge t

107 under mild reaction conditions, followed by intramolecular cyclization of an intermediate formed aft

108 nes has been demonstrated via site-selective intramolecular cyclization of aryl-fused 1,6-diyn-3-ones

109 n, we disclose a method for its formation by intramolecular cyclization of ester-tethered enaminones,

110 An acid-catalyzed intramolecular cyclization of three such indolines gave

111 on lithium bis(trimethylsilyl)amide-mediated intramolecular cyclization of trisubstitued cyclopentane

112 roquinoline frameworks and the base-mediated intramolecular cyclization to establish the spiral quate

113 ormation involves domino imine formation and intramolecular cyclization to form 2-arylcyclopropyl-2,3

114 tituted phenacyl bromide, finally leading to intramolecular cyclization to give a mixture of diastere

115 d by p-toluenesulfonic acid (PTSA)-catalyzed intramolecular cyclization with aldehydes has been devel

116 sed via enamine formation, Michael addition, intramolecular cyclization, and intramolecular iminium i

117 e following 1,5-hydrogen atom translocation, intramolecular cyclization, and rearomatization steps le

118 ,6-diyn-3-ones undergo triflic acid-mediated intramolecular cyclization, leading to benzo[b]fluorenon

119 ASA can undergo intramolecular cyclization, yielding an equilibrium with

120 oss coupling with boronic acids, followed by intramolecular cyclization.

121 hich includes base-mediated Michael addition/intramolecular cyclization/[1,5]-H shift/cleavage of CS(

122 cesses have been selected such as inter- and intramolecular cyclizations, including carba-, oxa-, thi

123 of asymmetric induction are achieved in the intramolecular cycloadditions using a C (2)-symmetric ch

124 modeled by protein engineering to permit the intramolecular cyclopropanation of a broad spectrum of h

125 Importantly, this structure shows a unique intramolecular cysteine disulfide bond in the ATP-bindin

126 d and activated in every catalytic cycle via intramolecular dehydration/cyclization.

127 A concept for intramolecular denitrogenative C(sp(3))-H amination of 1

128 An intramolecular Diels-Alder reaction and an enone-olefin

129 The effect of a variety of parameters on the intramolecular Diels-Alder reaction was investigated, in

130 ative demetallation leading to a spontaneous intramolecular Diels-Alder reaction.

131 d membrane signal peptidase that requires an intramolecular disulfide bond for in vitro activity.

132 tion at cysteine 213, which is engaged in an intramolecular disulfide bond, leads to butterfly-shaped

133 uggest that not all interruptions of D2 loop intramolecular disulfide bonding lead to haploinsufficie

134 ulfide isomers of three peptides bearing two intramolecular disulfide bonds but different cysteine co

135 oth kinase and phosphatases are sensitive to intramolecular disulfide formation in their catalytic su

136 Upon oxidation, this cysteine forms an intramolecular disulphide bond with a vicinal "backdoor"

137 Recent models suggest that intramolecular docking of the MIDAS domain onto the AAA

138 entially, our approach is based on provoking intramolecular "domain swap." The results show that the

139 Charge-transfer-based materials with intramolecular donor-acceptor structures are attractive

140 d conditions, followed by a deprotection and intramolecular double ring-closing condensation reaction

141 additional hydrophobic surface and that the intramolecular dynamics of the protein are significantly

142 However, its slow intramolecular electron transfer (IET) rate from the FAD

143 , and the high TOF is achieved through rapid intramolecular electron transfer (IET) to the native int

144 merism (VT) involves a reversible stimulated intramolecular electron transfer between a redox-active

145 n the use of separated ETMs, indicating that intramolecular electron transfer between the hydroquinon

146 e in the molecular dipole moments induced by intramolecular electron transfer can introduce a macrosc

147 licated a concerted PCET mechanism involving intramolecular electron transfer from tyrosine to Ru(bpy

148 e presence of a divalent cation improved the intramolecular electron transfer.

149 ase from RSNOs by serving as Lewis acids for intramolecular electron-transfer, redox-innocent Lewis a

150 ltitude of synthetic procedures reported for intramolecular electrophilic C-H borylation contain many

151 To date, intramolecular electrophilic C-H borylation is utilised

152 Less prevalent intramolecular electrophilic C-H borylation reactions th

153 a vinylogous Michael addition followed by an intramolecular enamine aldol condensation.

154 By comparison, related intramolecular ET rate constants in very similar constru

155 simulations totaling 32.7 mus and cell-based intramolecular fluorescence resonance energy transfer (F

156 A subsequent intramolecular fluoride displacement reaction provides a

157 t PTP-3 is upstream of SYD-2 to regulate its intramolecular folding.

158 considered generally to have weak inter- and intramolecular forces compared to alkanes, explaining th

159 Intramolecular FRET analysis in living nematodes demonst

160 bsorbing (water-soluble) antenna followed by intramolecular-FRET/TBET energy transfers.

161 Via an intramolecular Friedel-Crafts cyclization, a dihydrobenz

162 e (RSO(2)Na), and (iii) the CuBr(2)-mediated intramolecular Friedel-Crafts cyclizative dehydration.

163 nverted to an imidate radical that underwent intramolecular H-atom transfer (HAT).

164 ononuclear [CuOH](1+) core is stabilized via intramolecular H-bonds between the H-donors of the ligan

165 meranz-Fritsch-type cyclization with a final intramolecular Heck reaction.

166 stereoselective aza-Michael addition and an intramolecular Heck-type reaction lead to the formation

167 thesis of both bruceol and isobruceol was an intramolecular hetero-Diels-Alder reaction of an o-quino

168 partate of the J-domain perturbs a conserved intramolecular Hsp70 network of contacts that crosses do

169 antioselective, radical-based method for the intramolecular hydroamination of alkenes with sulfonamid

170 The first example of Cp*Co(III)-catalyzed intramolecular hydroarylation of allyl aryl ethers using

171 ort a catalytic, light-driven method for the intramolecular hydroetherification of unactivated alkeno

172 usions and suggested that the presence of an intramolecular hydrogen bond between the oxygen of the d

173 le species is arrested by the presence of an intramolecular hydrogen bond.

174 tautomer is stabilized by a strong N-H...O=C intramolecular hydrogen bond.

175 , which reveals differences in the levels of intramolecular hydrogen bonding between each of the cycl

176 plex compared to POP-pNH(2) -Py owing to the intramolecular hydrogen bonding between the amino group

177 by theoretical calculations demonstrate that intramolecular hydrogen bonding can stabilize Boat, wher

178 Intramolecular hydrogen bonding formed by 1,10-diamide s

179 c simulations which confirm a persistent key intramolecular hydrogen bonding.

180 We also identified intramolecular hydrogen bonds within pyrazine ligands, p

181 ASA derivative, confirming the importance of intramolecular hydrogen bonds.

182 s show that the cage structure contains rare intramolecular hydrogen-hydrogen (C-H...H-C) bonding int

183 therefore essential to reduce or even avoid intramolecular hydrogen/deuterium migration, which cause

184 We propose a successive decarboxylation and intramolecular hydroxylation mechanism forming 2HG in a

185 Intramolecular imine photocyclization has been explored

186 el addition, intramolecular cyclization, and intramolecular iminium ion cyclization steps.

187 S, P-IID, is described, which operates by an intramolecular indicator displacement (IID) mechanism.

188 (RIAs), DimerDye disassembly assays (DDAs), intramolecular indicator displacement assays (IIDAs), al

189 HTN1L-specific C-terminal motif counters the intramolecular inhibition and allows SHNT1L to bind acti

190 Akt appears to be autoinhibited by an intramolecular interaction between its N-terminal plecks

191 ching frequency (nu(NO)) is sensitive to the intramolecular interaction between the pendant ligand an

192 vealed that the R1060C mutation disrupts the intramolecular interaction between the POLD1 CysB motif

193 donors of the central urea moiety through an intramolecular interaction led to improved potency in wh

194 rther domain analysis revealed an unexpected intramolecular interaction that might control Rspo2 sign

195 ted nuclear export, and TRIB1 displaces this intramolecular interaction to induce nuclear retention o

196 We find that the inhibitory intramolecular interaction within DIAPH1 is disrupted by

197 g of disease-causing mutations near sites of intramolecular interaction.

198 -inhibited state stabilized by electrostatic intramolecular interactions between the intrinsically di

199 Lastly, we characterized intramolecular interactions between ZAR1 subdomains that

200 complete, understanding of the influence of intramolecular interactions on the properties of aromati

201 RM) domains of U2AF2 mediates autoinhibitory intramolecular interactions to reduce nonproductive bind

202 uctures disclosed that the C-tail engages in intramolecular interactions with the DNA binding groove

203 ecruitment of Ste20p to the plasma membrane, intramolecular interactions, and interaction with the GE

204 Furthermore, investigations regarding intramolecular interactions, by means of steady-state an

205 The strong intermolecular and intramolecular interactions, combined with CT, allow for

206 It is clear that planarizing intramolecular interactions, which exist between the per

207 ng the beneficial thiophene-benzothiadiazole intramolecular interactions, while further extending the

208 lso conducted, supporting the involvement of intramolecular interactions.

209 By contrast, the intramolecular iron-catalyzed [2 + 2] cycloaddition of 1

210 nt radical recombination was corroborated by intramolecular isotope labeling experiments and theoreti

211 e basal junction is recognized by a four-way intramolecular junction in Drosha, triggered by the Belt

212 results showed greater (p < 0.05) inter- and intramolecular lipid disorder in the frankfurters with E

213 A luciferin comprising an intramolecular "lock" was identified as a viable light-e

214 The second involves an intramolecular mechanism for q modulation.

215 2 is shown to form via intramolecular metal-metal cooperative phenyl group C(sp

216 cally low-lying reaction channel involves an intramolecular Michael addition leading to the experimen

217 ted sulfonyl furans through a cascade S(N)2'-intramolecular Michael reaction, followed by aromatizati

218 Whereas intramolecular MIDAS docking appears to require a treatm

219 the presence of K(+) and [18]crown-6 induces intramolecular migration of the alkenyl group from N' to

220 atures mCPBA-mediated amine oxidation and an intramolecular Mitsunobu reaction to form the tetrahydro

221 ive IF-TTF units in close proximity promotes intramolecular mixed-valence interactions.

222 ive intermolecular N-benzylation followed by intramolecular N-arylation and oxidation.

223 ceeds via selective S-alkylation followed by intramolecular N-cyclization enabling the formation of C

224 ies that can bind amine substrate triggering intramolecular N-H heterolysis.

225 (sp(2))-H/C(sp(3))-H coupling followed by an intramolecular N-H/C(sp(3))-H dehydrogenative coupling t

226 This novel cascade reaction features an intramolecular N2-arylation of pyrazoles with allenes at

227 tify a critical and evolutionarily conserved intramolecular network connecting the ligand to the core

228 The applicability of an intramolecular Nicholas reaction for the preparation of

229 small carbenes results more from stabilizing intramolecular non-covalent interactions in the secondar

230 t of donor (D)/acceptor (A) units presenting intramolecular noncovalent interactions.

231 DFT calculations suggest a mechanism with intramolecular nucleophilic aromatic substitution and re

232 f AA in CW-based oleogels caused to form new intramolecular or intermolecular hydrogen bonding, and i

233 al Knoevenagel condensation-Michael addition-intramolecular oxa-Michael addition-intramolecular aldol

234 e-stage Lewis acid-catalyzed stereoselective intramolecular oxa-Michael reaction, E-selective ring-cl

235 ergonic directed oxypalladation, followed by intramolecular oxidative addition and reductive eliminat

236 c S-aryl-Pd-X unit by taking advantage of an intramolecular oxidative addition strategy.

237 ntanedione; (b) a chemo- and stereoselective intramolecular oxidative cyclization; and (c) a complexi

238 trogen of 2-aminoheteroarenes followed by an intramolecular oxidative N-S/N-Se bond formation.

239 ally derived synthetic strategy relied on an intramolecular palladium-catalyzed coupling reaction to

240 of c-MYC oncogene has the ability to form an intramolecular parallel G4 structure.

241 charge transport through intermolecular and intramolecular paths in single-molecule and single-stack

242 a metal-nitrosyl species, facilitated by an intramolecular pendant thiol proton.

243 acked chromophores and geometrically favours intramolecular photochemical [2 + 2] cycloadditions, dis

244 A BF(3).OEt(2) catalyzed intramolecular Povarov reaction was used to synthesize 1

245 pathways and yields of many photo-initiated intramolecular processes.

246 he DCA radical anion followed by barrierless intramolecular proton transfer leads to the final produc

247 on by Schiff bases through 1,2-addition, 1,4-intramolecular proton transfer, Huisgen 1,3-dipolar cycl

248 In this case, we postulate an initial intramolecular proton-coupled electron-transfer step yie

249 cant advances have recently been achieved in intramolecular radical reactions, the governing of asymm

250 on of allyl ethers and amines and subsequent intramolecular reaction with nucleophiles.

251 cular cyclization in addition to its cognate intramolecular reaction, underscoring its versatility as

252 ous cyclopent-2-enones were less prone to an intramolecular reaction.

253 yclases that, instead, assemble terpenes via intramolecular rearrangements of a single substrate.

254 ramp) in multiple conformations revealed the intramolecular rearrangements required for alternating a

255 ism of conformational control of BFL-1 by an intramolecular redox switch.

256 hanistic studies show the oxidative addition/intramolecular reductive elimination likely to be the lo

257 xes [L(Ph)(Ni(II)-H)(2)](-) (3) are prone to intramolecular reductive H(2) elimination, and an equili

258 tically active species with an unprecedented intramolecular relationship between the cationic Au(I) c

259 HSF1 is tightly regulated via intramolecular repressive interactions, post-translation

260 eometric structure of organic molecules with intramolecular resolution using high resolution scanning

261 X36 and examine the remodeling of inter- and intramolecular RNA quadruplex structures.

262 rget site masking is caused by heterogeneous intramolecular RNA-RNA interactions, which can conceal t

263 This behavior shows that intramolecular rotation is restricted at and near the mi

264 how that the conventional restriction of the intramolecular rotation mechanism cannot fully account f

265 ochromic by means of coupling the rate of an intramolecular rotation, which depends on the mechanics

266 These restricted intramolecular rotations at and near the microdroplet pe

267 r), and two room-temperature atroposelective intramolecular S(N)Ar cyclizations for sequential CD (8:

268 eed through either a tandem Michael addition-intramolecular S(N)Ar reaction or a tandem Michael addit

269 derived from p190RhoGAP; rather, it makes an intramolecular salt bridge to an aspartic acid.

270 We further identified inter- and intramolecular salt-bridge interactions of Orai subunits

271 en carried out, showing the critical role of intramolecular second coordination sphere effects exerte

272 n the formation of an intermediate A with an intramolecular [SH...ON-Fe] interaction.

273 the relative strengths of these noncovalent intramolecular sigma-sigma interactions via temperature-

274 hese surprising results in the context of an intramolecular signal transduction accounting for many p

275 ll unknown precisely how TALI is involved in intramolecular signal transmission.

276 r dynamics simulations, SS-RJW100 attenuates intramolecular signalling important for coregulator recr

277 of a conventional IC pathway, an unexpected intramolecular singlet fission (iSF) process is responsi

278 stems and is driven, in part, by the role of intramolecular solvation of the charge site(s) on these

279 as synthesized with systematic variations in intramolecular spacing between catechol and cationic fun

280 lication of Raman spectroscopy in discerning intramolecular (ssRNA and ssDNA) and intermolecular (RNA

281 Making use of intramolecular stabilization by a ferrocene substituent,

282 acted with an N-heterocyclic carbene, and an intramolecular Stetter reaction proceeded smoothly to gi

283 These significant differences result from intramolecular substituent effects.

284 The demonstration of intramolecular synergy between LPMOs and hydrolytic enzy

285 nique compact structure on the basis of four intramolecular thioether bridges with reversed stereoche

286 cribed to intramolecular charge transfer and intramolecular through-space conjugation.

287 Homoconjugation and intramolecular "through-space" charge transfers are mole

288 molecules with two anchors transited from an intramolecular to an intermolecular path when the degree

289 intercepted retro-Nazarov reaction utilizing intramolecular tosyl migration to generate a reactive ox

290 M (N and C) with fluorescent probes and used intramolecular TR-FRET to assess interlobe distances whe

291 Lit is a unique example of an intramolecular transacylase differentiated from that cat

292 e integral membrane protein Lit (lipoprotein intramolecular transacylase) from the opportunistic noso

293 ked Ube2N~ubiquitin conjugate, catalyzing an intramolecular transglutamination reaction, covalently c

294 he first time, triplet decorrelation through intramolecular triplet diffusion was observed following

295 thesis of highly substituted beta-lactams by intramolecular Tsuji-Trost allylation is reported.

296 We report the intramolecular Tsuji-Trost reaction of Ugi adducts to gi

297 eveloping a Rh(I)-catalyzed enantioselective intramolecular Type II cyclization of alkynes via C-C ac

298 Rate constants for intramolecular tyrosine oxidation were measured using th

299 Intermolecular and intramolecular variants of the reaction are described, a

300 theory (DFT), enabling the assignment of all intramolecular vibrational modes.