ライフサイエンスコーパス: isodesmic

1 indicating that aggregation is approximately isodesmic.

2 anic cosolvent, 1-F undergoes cooperative or isodesmic aggregation.

3 ay crystallography, SEM, heterocomplementary isodesmic analysis, 1- and 2D NMR, and dynamic light sca

4 [Chemical structures: see text] Isodesmic and homodesmic equations at the B3LYP/6-311+G(

5 s the CBS-QB3 method, and using a variety of isodesmic and homodesmotic reaction schemes.

6 ctions of oDMSi-BTA sergeant (>25 mol%), the isodesmic assembly of the increasing amounts of sergeant

7 s most closely resembles noncooperative (or "isodesmic") assembly; the polymers are single-stranded a

8 Isodesmic bond separation calculations for the endo isom

9 We find that use of the isodesmic bond separation reaction C(10)H(16) + 14CH(4)

10 The concept of isodesmic bond separation reactions is generalized to al

11 Application of this same isodesmic bond separation scheme to gas-phase adamantane

12 Isodesmic calculations at the B3LYP/6-31G level of theor

13 Isodesmic calculations show that the anti-7-trimethylsil

14 ionic fragments were considerable even when isodesmic comparisons could have canceled electron corre

15 hing stabilization energies are evaluated by isodesmic comparisons of protobranched alkanes with etha

16 Isodesmic computational studies (M062X/6-311+G**) indica

17 zation difference between ethyl and vinyl in isodesmic equation 1.

18 es 3 (n double bonds), which are combined in isodesmic equation 4.

19 Using an isodesmic equation, we find that the thermodynamic stabi

20 ormation of these systems were obtained from isodesmic equations at the HF/6-31G(d) level.

21 lization energy (RSE) scale, developed using isodesmic equations computed at the DFT level, aiming to

22 -benzyne singlet-triplet energy gap and from isodesmic equations, is also examined.

23 ontains pi-delocalization) is computed using isodesmic equations.

24 Isodesmic exchange evaluation for Fe(nor)4 confirmed tha

25 G2 calculations of the theoretical isodesmic hydride-transfer reaction between secondary vi

26 nteracting protein aggregates in terms of an isodesmic, indefinite aggregation equilibrium constant.

27 ve been interpreted by a mechanism involving isodesmic ligand-mediated or ligand-mediated plus ligand

28 ther FtsZ protofilaments are assembled by an isodesmic (linear aggregates in which each bond has an i

29 elf-assemble, oDMSi-BTAs self-assemble in an isodesmic manner.

30 2, which form H-type aggregates following an isodesmic mechanism.

31 This isodesmic model accurately predicts the assembly, disass

32 The isodesmic model can fit the assembly in GDP closely but

33 bly were obtained through the fitting of the isodesmic model to (1)H NMR spectrometry and circular di

34 on addition of good solvent are observed for isodesmic (non-nucleated) systems.

35 and later including the full details of the isodesmic or cooperative supramolecular processes (i.e.,

36 ome controversy over whether the assembly is isodesmic or cooperative.

37 he increased n n* interaction include larger isodesmic polymerization elongation constants in solutio

38 ondii, unexpectedly finding that it exhibits isodesmic polymerization in contrast to the conventional

39 We have developed a model for the isodesmic polymerization that includes GTP hydrolysis in

40 reactions (BSR), defined on the basis of an isodesmic principle, are taken as reference properties f

41 upon cooling to 7 degrees C, via a proposed isodesmic process.

42 ular helical nanotubes via a noncooperative, isodesmic process; the self-assembly of ordered helical

43 s is constructed: isogyric (RC1) superset of isodesmic (RC2) superset of hypohomodesmotic (RC3) super

44 the ring-strain energies with the help of an isodesmic reaction and evaluated structural and spectros

45 The investigation of the isodesmic reaction between strained species and Cp(2)M y

46 The isodesmic reaction between the most stable conformers of

47 The energy of a suitable isodesmic reaction showed the triplet and singlet states

48 Calculations of the energies of isodesmic reactions allow the effect of each of the four

49 Isodesmic reactions allowed the separate examination of

50 ation are calculated based on homodesmic and isodesmic reactions and the G2(MP2,SVP) method with a va

51 riplet energy splittings and the energies of isodesmic reactions are used to assess the amount of bis

52 Isodesmic reactions between [HBEt(3)](-) and selected BX

53 Analyses of isodesmic reactions for singlet 7-carbenanorbornene (4S)

54 Calculated energies of isodesmic reactions give an ASE of ~37 kJ mol(-1) in [18

55 ave been evaluated by computing energies for isodesmic reactions involving the ClNO(4) and ClNO(5) is

56 otentials to calculate the energy change for isodesmic reactions that convert an aromatic ring to an

57 ovalent interactions, natural bond orbitals, isodesmic reactions, and hydration propensities lead to

58 es, nucleus independent chemical shifts, and isodesmic reactions.

59 ving the effect of the tert-butyl groups via isodesmic reactions.

60 the calculation of the energies of relevant isodesmic reactions.

61 sured value K(6) of aminocarbamic acid using isodesmic reactions.

62 thalpies of formation have been deduced from isodesmic reactions: 94.2 +/- 2.0 kcal/mol (C(6)H(5)CHCH

63 s linear higher-order oligomers following an isodesmic self-association model.

64 eement with previous characterization of the isodesmic self-association of SPOP.

65 e 2,15-substituted derivative 1 undergoes an isodesmic supramolecular polymerization forming globular

66 here is the synthesis, characterization, and isodesmic supramolecular polymerization of [3.3]paracycl

67 ethylacetamide and the target amide using an isodesmic trans-amidation process and is calibrated rela

68 Isodesmic-type reactions were used to determine strain e