ライフサイエンスコーパス: isomerize

1 nd may be set by the proportion of rhodopsin isomerized.

2 Light isomerizes 11-cis-retinal in a retinal rod and produces

3 Rhodopsin becomes activated when light isomerizes 11-cis-retinal into an agonist, all-trans-ret

4 Absorption of a photon isomerizes 11cRAL to all-trans-retinaldehyde (atRAL), br

5 he intramolecularly sensitized precipiton 2Z isomerized 250 times faster (k(2Z-->2E) = 1.0 x 10(-3) s

6 -one (MIO)-dependent family of catalysts and isomerizes (2S)-alpha-phenylalanine to (3S)-beta-phenyla

7 Attempts to isomerize 4 to the thermodynamically favored C,C-dialkyl

8 asis of the covalent bond between enzyme and isomerized 5-FU we propose a Michael addition mechanism

9 GLO1 is a Zn(2+)-dependent enzyme that isomerizes a hemithioacetal, formed from glutathione and

10 cyclin E, mutational data suggest that Pin1 isomerizes a noncanonical proline-proline bond, with the

11 rapeutic strategies based on targeting the D-isomerized Abeta, rather than natural L-Abeta.

12 Compound 1 was shown to slowly isomerize about the C-36/C-37 double bond when stored in

13 that c-Fos represents a novel target for the isomerizing activity of Pin1 and support a role for Pin1

14 pcF and CpcE/PecF were used to show that the isomerizing activity that converts phycocyanobilin to ph

15 ive precursor for mechanistic studies of the isomerizing alkoxcarbonylation of methyl oleate.

16 al studies on the overall catalytic cycle of isomerizing alkoxycarbonylation reveal the steric conges

17 le, retinal G protein-coupled receptor (RGR) isomerizes all-trans retinal to 11-cis retinal in the re

18 n in vivo and in vitro, and that it does not isomerize along other double bonds, suggesting that it f

19 ral transitions needed for RNA polymerase to isomerize and engage with the DNA template strand.

20 AzoAMP-3 does not isomerize and exhibits emission (Phi(fl) = 0.0008) at 77

21 ests that the cyclized beta-silyl cation can isomerize and then reopen to a classical aryl-stabilized

22 aged proteins by recognizing and methylating isomerized and racemized aspartyl residues in aging prot

23 ligand binding, this intramolecular agonist isomerizes and induces structural changes in the 7-trans

24 Upon absorption of light, the chromophore isomerizes and the character of the photoproducts (e.g.,

25 hore, retinal, that upon absorption of light isomerizes and thereby triggers biological functions ran

26 be modified, peptide bonds can be cleaved or isomerized, and disulfide bonds can be cleaved.

27 junctions formed through catalysis by XerD, isomerized, and were converted by XerC to reaction produ

28 Highly cracked and isomerized archaeal lipids and bacterial lipids, structu

29 ates on an ultrafast time scale, rather than isomerizing as it does on a lower surface.

30 es and alkenes are facilely oligomerized and isomerized at high conversions (>97 %), mimicking the tr

31 The disilenyl germylene 5b isomerizes at 40 degrees C to the NHC-adduct of the corr

32 ctivity of ATR is downregulated by Pin1 that isomerizes ATR from cis-isomer to trans-isomer at the ph

33 CPD can then isomerize back to DHP upon irradiation with UV light or

34 of the enzyme in the "F" form, which slowly isomerize back to the E form.

35 % of molecules in the trans configuration to isomerize before binding.

36 Moreover, the full-length constructs isomerized before ADP release, which has not been observ

37 itially forming a van der Waals complex that isomerizes below the energy of the reactants and eventua

38 annels are allosteric membrane proteins that isomerize between C(losed) and O(pen) conformations.

39 states is promoted by a "Janus" ligand that isomerizes between binding modes that favor Mn(3+) or Mn

40 echanism by which this protein assembles and isomerizes between closed- and open-channel conformation

41 e-step binding mechanism where actomyosin VI isomerizes between two conformations, one competent to b

42 aintains an affinity for large substrates by isomerizing between the open and closed states with nucl

43 he brains of these embryos often become left isomerized: both sides of the brain develop morphology a

44 to pyramidalization at a carbon atom of the isomerizing bridging double bond.

45 The hydroximoyl chlorides 1Eaand 2Ea only isomerize by the nucleophilic catalysis mechanism.

46 s have shown that polyunsaturated lipids are isomerized by alkanethiyl radicals (S(*)) in a cycle pro

47 ll-trans-retinaldehyde must be chemically re-isomerized by an enzyme pathway called the visual cycle.

48 monstrated that the imine double bond can be isomerized by light (365 nm LED) during the reaction lea

49 rate vision requires that opsin chromophores isomerized by light to the all-trans form be replaced wi

50 sodium amide monomers, whereas 1-pentene is isomerized by trisolvated monomers.

51 Results suggest that it isomerizes by cleavage of either the C1-C2 or C1-C3 bond

52 This condition is also effective to isomerize C38-epi-halichondrins into C38 natural halicho

53 hat impulsively driven protein motion by the isomerizing chromophore during the 200 fs primary transi

54 ne/threonine residues in target proteins and isomerizes cis isomers to more stable trans configuratio

55 Expression of aconitase, which isomerizes citrate into isocitrate, is controlled by sev

56 protein that oxidizes and, more importantly, isomerizes complex disulfide connectivity in substrates.

57 The isomerized compounds are excellent ligands for Co(II) ce

58 -H...O horizontal lineC in the Z moieties of isomerized compounds.

59 The thresholds for isomerizing conformer A to all six other conformations d

60 s that inactivate OASS and produce the fully isomerized CSC.

61 We found that Ess1 preferentially binds and isomerizes CTD heptad-repeat (YSPTSPS) peptides that are

62 Individuals with a symmetric, right-isomerized dHb also exhibit increased freezing.

63 contrast, larvae that have a symmetric, left-isomerized dHb, or in which just the left dHb-IPN projec

64 ng the product distributions of expected and isomerized Diels-Alder adducts.

65 sylation reactions using a prop-1-enyl donor isomerized directly from an allyl glycoside.

66 lfide isomerase (PDI) oxidizes, reduces, and isomerizes disulfide bonds, modulates redox responses, a

67 developed highly stereoselective methods to isomerize electron-deficient propargylic alcohols to E-e

68 nched oligoethylene molecule was achieved by isomerizing ethoxycarbonylation and alternatively cross

69 nterestingly, of those trajectories that did isomerize, every one of them violated conventional trans

70 mputational data predict AzoAMP-1 should not isomerize following S(2)<--S(0) excitation because of th

71 e the B-chromophores toward a bleached trans isomerized form.

72 cultures were identified as the reduced and isomerized forms of the isoxazole SMX moiety.

73 f a bond remotely located in relation to the isomerizing fragment.

74 n makes it sterically possible for Tyr106 to isomerize from a solvent exposed configuration to a buri

75 duction in solution, owing to its failure to isomerize from cis to trans, the same could not be inves

76 Photon absorption causes the chromophore to isomerize from the 11-cis- to all-trans-retinal configur

77 nic acid sodium salt thus synthesized can be isomerized from its trans to its cis form reversibly in

78 a dropped from 7 to 4-5 and the muconic acid isomerized from the cis,cis (ccMA) to the cis,trans (ctM

79 rystal structure features a chromophore that isomerized from trans to cis but the surrounding pocket

80 , the retinal protonated Schiff base (RPSB), isomerizes from its native all-trans form to a 13-cis fo

81 In addition, hGFAT2 is able to isomerize fructose-6-phosphate into glucose-6-phosphate

82 assign to a metastable state that failed to isomerize fully.

83 ceptor-channels are allosteric proteins that isomerize ('gate') between conformations that have a low

84 olite that contains tin (Sn-Beta) is able to isomerize glucose to fructose in aqueous media with high

85 ential oil from Saaz variety and tetra-hydro isomerized hop extract (tetra hop), were established usi

86 are synaptic ion channels that spontaneously isomerize (i.e., gate) between resting and active confor

87 mechanism to generate a borane complex that isomerizes if necessary to place the alkyl group cis to

88 dodecadienal; these primary products readily isomerize in an aqueous medium to the corresponding 6E-

89 e click amino acid (F-PSCaa) was designed to isomerize in response to visible light.

90 These intermediates can isomerize in situ to yield a eta(1) nitrile complex.

91 The resultant azobenzene bridge isomerized in response to light, thereby changing the co

92 composes to form unrearranged carbene, which isomerizes in 5 ps.

93 ic carbon-bearing molecules that dynamically isomerize, interconverting between enantiomers without c

94 that the reaction proceeds through a rapidly isomerizing intermediate.

95 V23, may play an important enzymatic role in isomerizing intermolecular disulfide bonds during eggshe

96 e reaction, but under prolonged heating they isomerize into 7a H-indolium ylides, followed by a barri

97 g DNA, DnaC hydrolyzes ATP, allowing DnaB to isomerize into a topologically closed, pre-translocation

98 ex (RPc), where DNA is double stranded, must isomerize into an open promoter complex (RPo), where the

99 s decomposition, isoxazole was also found to isomerize into several products: 2-formyl-2H-azirine, 3-

100 e significant consequences on its ability to isomerize into the corresponding extended duplex (ED) fo

101 Here, we found that NHPI can be isomerized into isatoic anhydride by an unusually facile

102 d 2,2'-disubstituted terminal alkenes can be isomerized into the more stable internal (Z)- and (E)-al

103 nducting; however, this intermediate rapidly isomerizes into a tighter, fully inhibitory receptor-inh

104 rate-channeling activity, indicating that it isomerizes into the active state under assay conditions.

105 rm in the presence of the Lewis acid center, isomerizes into the acyclic form of fructose, and finall

106 The cis-enediolate quantitatively isomerizes intramolecularly to the trans-enediolate in C

107 that can further react to predominantly form isomerized isoAsp residues upon rehydration (imbibition)

108 f the PTP, the recombinant truncated AaIPPI1 isomerized isopentenyl pyrophosphate (IPP) to dimethyl a

109 attach phycoerythrobilin and simultaneously isomerize it to phycourobilin.

110 way that phosphorylates the C-4 hydroxyl and isomerizes it to a C-3 hydroxy compound, which is catabo

111 s-retinal (a vitamin A derivative) and light isomerizes it to all-trans-retinal, which activates the

112 of the alpha-subunit of phycoerythrin II and isomerizes it to phycourobilin.

113 photon by a rhodopsin or cone-opsin pigment isomerizes its 11-cis-retinaldehyde (11-cis-RAL) chromop

114 e (SAM), and pyridoxal 5'-phosphate (PLP) to isomerize L-alpha-lysine to L-beta-lysine.

115 Lactate racemase, which isomerizes L- and D-lactate, is composed of the LarA pro

116 oerythrocyanin alpha-subunit phycocyanobilin isomerizing lyase, PecE/PecF, from Noctoc sp. PCC 7120.

117 To isomerize M6P to F6P requires a rotation of its C2-C3 bo

118 A flash causing a few hundred isomerized melanopsin molecules in a retina is sufficien

119 early demonstrated that ACO is in fact a non-isomerizing member of the CCE family.

120 gradient created by binding of Arr2 to photo-isomerized metarhodopsin.

121 The synthetic utility of isomerizing metatheses is demonstrated by various new ap

122 Overall, the concept of isomerizing metatheses promises to open up new synthetic

123 d further carbonylation are slow compared to isomerizing methoxycarbonylation of monounsaturated fatt

124 local effective temperature at which a photo-isomerizing molecule attacks its orientationally confini

125 Liberated CypD then isomerizes multiple proteins including p53 (causing p53

126 with the opposite regiochemistry to deliver isomerized N(2)-acyl-2-aminoimidazoles with broad substr

127 terized in the context of the loosely folded isomerized native-like state {N(iso)} predicted in simul

128 currents from adult mouse muscle AChRs that isomerize normally without agonists but have only a sing

129 nsfer an H* back to the metal, generating an isomerized olefin, or (2) add intramolecularly to a doub

130 ing such highly active catalyst systems, the isomerizing olefin metathesis becomes an efficient way t

131 n irradiated with 415 nm; however, it cannot isomerize on Ag surfaces, unless higher energy light is

132 The hydroximate 2Zb may be isomerizing only by iminium ion rotation.

133 le and unloadable conformations subsequently isomerizes or resets the configuration of the nucleotide

134 siae regulates RNA polymerase II (pol II) by isomerizing peptide bonds within the pol II carboxy-term

135 ation site by comparing the MS/MS spectra of isomerized peptides with and without (18)O incorporation

136 The isomerized permeate was subsequently purified to a lactu

137 Ess1 is proposed to control transcription by isomerizing phospho-Ser-Pro peptide bonds within the CTD

138 ned a mystery because the effect of a single isomerized pigment molecule in cones, unlike that in rod

139 Rod absolute threshold corresponded to 12-15 isomerized pigment molecules (R*) in image fields of 800

140 HcmA I90V and I90A mutant enzymes could also isomerize pivalyl- and isovaleryl-CoA, albeit at >10 tim

141 with an indium cocatalyst and Bronsted acid isomerize primary and secondary propargylic alcohols in

142 ferent selectivity toward main metathesis or isomerized products.

143 e (Tyr or Trp) in a position adjacent to the isomerizing proline (if one is not already present) and

144 d plant carotenoid isomerase (CRTISO), which isomerizes prolycopene to all-trans-lycopene.

145 l proliferation, and differentiation through isomerizing prophosphorylated substrates.

146 By isomerizing pSer/Thr-Pro bonds, Pin1 can regulate the co

147 The azirines isomerize quantitatively either into isoxazoles under ca

148 of alphaA- and alphaB-crystallin that mimic isomerized residues deviated from native behavior in all

149 that antibodies containing either one or two isomerized residues were not effective in inhibiting EGF

150 Light isomerizes rhodopsin's retinal chromophore and triggers

151 motifs used by sigma factors to melt DNA and isomerize RNA polymerase to form functional open promote

152 A class I lyase-like family of aminomutases isomerizes (S)-alpha-arylalanines to the corresponding b

153 tase from Chondromyces crocatus (CcTAM) that isomerizes (S)-alpha-tyrosine to (R)-beta-tyrosine.

154 Thus, the isomerizing self-metathesis of oleic and other fatty aci

155 mu-N(2)) as an isolable kinetic product that isomerizes sequentially upon heating into the trans,cis

156 I from becoming trapped with substrates that isomerize slowly.

157 n essential protein that can peptidyl-prolyl-isomerize small phosphopeptides.

158 In contrast, the oxiranyl derivative isomerized smoothly.

159 Some members also isomerize specific double bonds in their substrates to y

160 However, red cone pigment isomerizes spontaneously 10,000 times more frequently th

161 all-trans-retinal which, upon illumination, isomerizes stereospecifically to the 11-cis isomer.

162 ienol ring by protonating C(8) to produce an isomerized structure.

163 rd oxygen and water as well as a tendency to isomerize substrates and react with internal olefin prod

164 framework tin or titanium Lewis acid centers isomerizes sugars, e.g., glucose, via reaction pathways

165 pattern found in frequency-domain spectra of isomerizing systems.

166 (5-FU), reveals a covalent bond between the isomerized target base and tyrosine 140.

167 ose that FKBP51 can use the Hsp90 complex to isomerize tau, altering its phosphorylation pattern and

168 The prolyl isomerase Pin1 binds and isomerizes tau and has been implicated in protecting aga

169 al(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position.

170 jaundice may be managed with phototherapy to isomerize the biosynthetic 4Z,15Z-bilirubin-IXalpha to m

171 ective epoxidation/deoxygenation sequence to isomerize the C(13,14) olefin, and a biomimetic quinone-

172 ement of the blocks and therefore Mcm10 must isomerize the CMG-DNA complex to achieve the bypass func

173 deprotection/reprotection step concurrently isomerize the conjugated chromophore to the all-E isomer

174 stoichiometric amount of reduced species can isomerize the entire mixture.

175 ains and use ATP hydrolysis-driven energy to isomerize the RNA polymerase-sigma(54) complex during tr

176 ger loop, and active-center side chains that isomerize the triphosphate of bound NTP and two Mg(2+) i

177 -A NPs convert X-rays into UV radiation that isomerizes the azobenzene groups, which allows controlle

178 erein we describe a system that specifically isomerizes the retinylidene protonated Schiff base both

179 Importantly, Pin1 isomerizes the serine118-proline119 bond from a cis to t

180 h PDI and ERp72 reduce Py, ERp57 principally isomerizes the virus in vitro, a reaction that requires

181 inear pentenes via hydrogen bonding, rapidly isomerizing the double bond.

182 , the amine 8a was obtained and found not to isomerize thermally to the anticipated atropisomer 8b (i

183 Monosubstituted carbodiimides isomerize thermally to the corresponding cyanamides (e.g

184 ile none of the mutant enzymes is capable of isomerizing these substrates, the R207Q (single and doub

185 isomerization conditions, (Z)-7 can readily isomerize to (E)-7.

186 dehydro[10]annulene (2), a molecule known to isomerize to 1,5-didehydronaphthalene (4) above -50 degr

187 estigation suggests that 3-butenenitrile can isomerize to 2-butenenitrile, a conjugated nitrile, befo

188 S4-symmetric structure and then subsequently isomerize to a T-symmetric tetrahedron for better accomm

189 nitrosamine intermediate, CH3NHNO, which can isomerize to an alkyldiazohydroxide, CH3NNOH, and furthe

190 rming ureate ligands, which upon thermolysis isomerize to bridging carbodiimides.

191 derive from endoperoxide intermediates that isomerize to D/E-ring forms or that are reduced to F-rin

192 mic compound ajmaline, or alternatively, can isomerize to form perakine, an alkaloid with a structura

193 Specific ligand complexes, however, slowly isomerize to give a high-affinity complex.

194 lable starting materials, have been found to isomerize to high E/Z ratios after storage at -20 degree

195 Previously, we hypothesized that dGh could isomerize to iminoallantoin (dIa) via a mechanism simila

196 , RNA polymerase must change conformation or isomerize to its active form.

197 gest O-alkylated cation 16 does not directly isomerize to N-alkylated cation 18; instead, it reverts

198 ecified early in the transcription cycle and isomerize to other forms slowly.

199 s complete Diels-Alder reaction and does not isomerize to Q.

200 The resulting 1-pyrazolines isomerize to regioisomeric 2-pyrazolines (a or b) or und

201 ions (13+ to 6+) yield products that rapidly isomerize to structures that have smaller collision cros

202 cal test of whether an inactive filament can isomerize to the active state.

203 All nitrile imines isomerize to the corresponding carbodiimides both therma

204 cal anion of the Z isomer is able to rapidly isomerize to the corresponding E configured counterpart

205 initial encounter reaction, and subsequently isomerize to the final tertiary fold in a second slower

206 Fluorescent DCCs, formed by this enzyme, isomerize to the respective NDCCs in weakly acidic mediu

207 rane(5) anion derived from 9-BBN is found to isomerize to two regioisomeric species via a proposed me

208 -phosphate (MTR 1-P) and adenine; MTR 1-P is isomerized to 1-methylthio-d-xylulose 5-phosphate (MTXu

209 On rapid heating, the resulting carbenes isomerized to 2,4-didehydroadamantanes by intramolecular

210 undergoing the aza-Prins cyclization rapidly isomerized to a planar enamine intermediate, the alkaloi

211 ion, the chromophore 11-cis retinal is first isomerized to all-trans retinal, followed by conversion

212 n, contains an 11-cis retinyl moiety that is isomerized to all-trans upon light absorption.

213 On absorption of light, 11-cis-retinal is isomerized to all-trans-retinal, constituting a one-way

214 ost opsins is 11-cis-retinaldehyde, which is isomerized to all-trans-retinaldehyde by absorption of a

215 (i) Allylic hydroperoxides may be isomerized to alpha,beta-epoxyalcohols by a heterolytic

216 (IDH2) to form isocitrate, which can then be isomerized to citrate.

217 These isomerized to diastereomeric hydroxymethylphosphonamidat

218 a normal diet, indicating that MAA could be isomerized to FAA in the absence of MAAI.

219 ecular disulfide bond with C207 that must be isomerized to form the active C207-C207 intermolecular b

220 sted and Lewis acid sites is that glucose is isomerized to fructose at low temperatures, while direct

221 (S)-alpha-arylalanine was enantioselectively isomerized to its corresponding (R)-beta-product.

222 HP)-O-P=C=NHC in which the PCO unit has been isomerized to OPC.

223 e-1,4-dicarboxylate (10), which subsequently isomerized to produce trans-1,2-cyclohexanebis-alpha-acr

224 The initial all-trans-form isomerized to the 13-cis isomer more rapidly at 80 degre

225 by BCMO1, part of the 9-cis-double bond was isomerized to the all-trans-stereoisomer, yielding all-t

226 fmDMAPP) are alternate substrates, which are isomerized to the corresponding IPP derivatives.

227 he third last residue is posttranslationally isomerized to the d configuration.

228 , neuropeptides that have the second residue isomerized to the D-isoform are distinguished from their

229 inal metathesis conditions while the Z-diene isomerized to the E-isomer.

230 lytic, in which the hydroperoxy substrate is isomerized to the epoxyalcohol or keto product.

231 ing of the rapid formation of a complex that isomerized to the final charge-transfer complex.

232 at the minor-bis-adduct of Gd(3)N@I(h)-C(80) isomerized to the major-adduct, a possible second additi

233 he metastable isomer of a photoswitch can be isomerized to the more stable one catalytically upon red

234 Under UV irradiation, the SP was isomerized to the open merocyanine (MC) form, causing th

235 one-pot fashion, an allyl glycoside is first isomerized to the reactive 1-prop-en-yl glycoside interm

236 e product, vinylacetyl-CoA, which is further isomerized to the thermodynamically stable normal produc

237 However, the S-isomer is rapidly isomerized to the trans-trans-2,4-conjugated diene.

238 Erythrose 4-phosphate is epimerized and/or isomerized to threose 4-phosphate, which is subsequently

239 +/- 1 cal mol(-1) K(-1)), which subsequently isomerizes to (eta(2)-O(2))V(N[(t)Bu]Ar)(3) (3) (DeltaH(

240 14 then isomerizes to 15, thus connecting low- and high-temperat

241 ylnitrene 35 to 1-cyanoindene 36, which then isomerizes to 3- and 2-cyanoindenes 12 and 13.

242 acid or conditions, to give [t-H3](+), which isomerizes to [t-H3'](+), wherein all PMe(3) ligands are

243 1,2,4-triazin-4(3H)-ol (4-OH), which rapidly isomerizes to a 3,4-dihydro-1,2,4-triazine-based nitrone

244 mu-1,2-O2(2-))](2+) (2(P)) that subsequently isomerizes to a bis-mu-oxodicopper(III) complex, [{((DMM

245 on of an initial collision complex (EI) that isomerizes to a highly stable complex (EI*) from which I

246 se separation is induced when the precipiton isomerizes to a low-solubility form.

247 ontains non-native structure that rearranges/isomerizes to a more native-like species.

248 s rapidly dissociate, whereupon the antibody isomerizes to a nonbinding isomer.

249 the cation radical of 1g, which sequentially isomerizes to a novel sigma-radical with an O,O 3e bond

250 ever, the first intermediate is unstable and isomerizes to a second intermediate, which was isolated.

251 disubstituted pi-allylruthenium complex that isomerizes to a thermodynamically more stable monosubsti

252 nducting channel intermediate, which rapidly isomerizes to a tighter complex.

253 e isomeric a(7)-PhobPH has been detected but isomerizes to a(5)-PhobPH rapidly in the presence of wat

254 that 6 forms via a carbene complex (1d) that isomerizes to aminomethyl complex 7d.

255 Allenyl carbinol ester 3 isomerizes to an E,Z mixture of the corresponding diene

256 ives formation of a tetramer, mR1(4a), which isomerizes to an inactive form, mR1(4b), and ATP binding

257 This complex isomerizes to an open complex, ED(o1), in an energetical

258 t 300 degrees C, bicyclo[4.2.0]oct-2-ene (1) isomerizes to bicyclo[2.2.2]oct-2-ene (2) via a formal [

259 egrees C, the kinetically formed allylborane isomerizes to give the thermodynamic allylborane 12E wit

260 1:1), a readily available starting material, isomerizes to high E/Z ratios by storage at -20 degrees

261 ations, the initial collision complex either isomerizes to its cis-form or undergoes a hydrogen atom

262 In room light, marinomycin A slowly isomerizes to its geometrical isomers marinomycins B and

263 pyrene (DHP) is a deep-colored compound that isomerizes to light-brown cyclophanediene (CPD) upon irr

264 o-C(2)B(10)H(12) isomerizes to m-C(2)B(10)H(12) upon heating at 400 degre

265 carbene Ph-C-R and different LiCN species or isomerizes to PhCRCNLi in the presence of LiX (X = Cl, I

266 the Rho-RNA species PR1, which subsequently isomerizes to PR2 with a rate constant 21 s(-1).

267 The first form, Q*, either reacts with Cp or isomerizes to Q, a form that is significantly less react

268 photon, the covalently bound 11- cis-retinal isomerizes to the all- trans form, enabling rhodopsin to

269 nterior of the visual receptor rhodopsin and isomerizes to the all-trans configuration following abso

270 This radical isomerizes to the beta-Lys* radical (state 4(Lys*)), whi

271 lly found in the outermost layer of skin and isomerizes to the cis isomer upon exposure to UV radiati

272 cinnamate attached to the active-site serine isomerizes to the cis isomer which then rapidly lactoniz

273 nerates an isotoluene-type intermediate that isomerizes to the isolated aromatic product upon exposur

274 lled abnormal C-5 NHC lithium complex slowly isomerizes to the normal C-2 NHC, and the process can be

275 )-CHCHC(6)H(4)S)Mo(PMe(3))(4), which rapidly isomerizes to the olefin-thiophenolate and 1-metallacycl

276 n the trigonal bipyramid, which subsequently isomerizes to the thermodynamic isomer with axial chlori

277 y formed E isomer in solution (CDCl3) slowly isomerizes to the Z isomer, indicating greater stability

278 olesterol to previtamin D that spontaneously isomerizes to vitamin D.

279 transporter from binding substrate and from isomerizing to an inward-facing conformation.

280 We find that the enthalpic barrier for N2O4 isomerizing to trans-ONO-NO2 is 43.9 kcal/mol, ruling ou

281 The pseudouridine synthases isomerize (U) in RNA to pseudouridine (Psi), and the mec

282 e of the propensity of these alkyl groups to isomerize under the reaction conditions.

283 (Me(3)Si)(2)CNN isomerizes upon addition of traces of [Me(3)Si](+) ions

284 The pseuoduridine synthases (psi synthases) isomerize uridine (U) to pseudouridine (psi) in RNA, and

285 A subfamily of PUSs, a class of enzymes that isomerize uridine to pseudouridine in noncoding RNAs, su

286 molog of pseudouridine (Psi) synthase, which isomerizes uridine to Psi in noncoding RNAs.

287 Monosilylated divinyl ethers can be isomerized using a cationic iridium(I) catalyst followed

288 (2) collision complex, which is also able to isomerize via a hydrogen shift to the SiNCHCH(3) interme

289 nalized by the ability of the ortho ester to isomerize via an intermediate benzylic cation and examin

290 bacterial and vertebrate rhodopsins start to isomerize via distinct implementations of the same bicyc

291 hrough a short-lived CO(4) intermediate that isomerizes via a symmetric CO(4) transition state contai

292 rangement indicates that the primary product isomerizes via an associative mechanism in DNA.

293 The cis-HCCHBS intermediate either isomerizes via hydrogen atom shift from the carbon to th

294 Depending on the nature of the isomerized VOCs, their next generation oxidation forms h

295 photoswitches, as well as photoswitches that isomerize with red and near-infrared light.

296 The double bond geometry can be optionally isomerized with I(2) to furnish the all-(E)-species.

297 lectron-rich substituents can be effectively isomerized with red light (630-660 nm), a wavelength ran

298 bond is more flexible at the methyl end and isomerizes with shorter correlation times.

299 that, upon S0-S1 excitation, gas-phase CHBr3 isomerizes within 100 fs into the BrHCBr-Br species, whi

300 f a BF(2)-azo complex that can be induced to isomerize without the need of deleterious UV light.