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1 dation to forge the C-N bond of the tertiary isonitrile.
2 azaborinine derivatives by treatment with an isonitrile.
3 rms an imidoyl radical intermediate from the isonitrile.
4 ith the bulky, yet conformationally flexible isonitrile.
5 n treated with 2 equiv of 2,6-dimethylphenyl isonitrile.
6 verse labeling and release applications with isonitriles.
7  of multicomponent reactions and convertible isonitriles.
8 nerated from the reactions of thioacids with isonitriles.
9 amily of proteins that produce small organic isonitriles.
10 s of a reaction between carboxylic acids and isonitriles.
11 otal synthesis of N-methylwelwitindolinone D isonitrile (1) has been achieved in 17 steps from a read
12 the natural product (+/-)-welwitindolinone A isonitrile (1) is described.
13 cyanate (2a), (-)-N-methylwelwitindolinone C isonitrile (2b), and (-)-3-hydroxy-N-methylwelwitindolin
14 he example reaction of beta-galactopyranosyl isonitrile (7) with a protected aspartic acid under micr
15                      (99m)Tc-methoxyisobutyl isonitrile (99(m)Tc-MIBI) single-photon emission compute
16 f typical donor ligands (carbon monoxide, an isonitrile, a nitrile, THF-d8,) it forms the respective
17 hereby assembling a long-chain gamma-hydroxy isonitrile acid skeleton.
18 = hypersilyl, (Me(3)Si)(3)Si) with different isonitriles afforded a series of five-membered N(2)P(2)C
19  occur when the ligand is nitrile, carbonyl, isonitrile, alkene and eta(6)-arene.
20  small molecule substrates (e.g., aldehydes, isonitriles, alkynes) to afford their cooperatively boun
21      By the careful choice of amino acid and isonitrile, an optional access to all possible enantiome
22 thesized in racemic form by employing indole-isonitrile and ammonium acetate in the Ugi 4-center-3-co
23 g system of the hapalindoles from cis-indole isonitrile and geranyl pyrophosphate through a presumed
24 ed to pai-bonded carbocycle and sigma-bonded isonitrile and hydrocarbyl derivatives.
25 ctively with N,N-dibromoarylsulfonamides and isonitrile and in the presence of K(2)CO(3).
26 ependent (Fe/2OG) enzymes to construct vinyl isonitrile and isocyanoacrylate moieties found in isonit
27 rmodynamical stability of the nitrile versus isonitrile and silanitrile versus isosilanitrile isomer
28        Here, we present the reaction between isonitriles and chlorooximes as a ligation that proceeds
29 nd N-terminal peptides, mediated by hindered isonitriles and hydroxybenzotriazole, gives rise to pept
30                        The latter react with isonitriles and singlet carbenes giving (phosphino)phosp
31  used for click chemistry, azides, nitrones, isonitriles, and nitrile oxides are the most popular.
32 lement of multicomponent reactions for which isonitriles are known and offer the desirable trait of g
33 o not have the objectionable odors for which isonitriles are typically known, making them more access
34  we report on the utilization of convertible isonitriles as effective synthetic tools for the ligatio
35 sts recognized the considerable potential of isonitriles as ligands in metal catalysis utilizing both
36 Stable asymmetric tetrazines that react with isonitriles at rate constants as high as 57 L mol(-1) s(
37 ones are essentially unknown as reactants in isonitrile-based multicomponent reactions.
38                     One focus of the work is isonitriles bearing perfluorinated alkyl groups that ena
39                                              Isonitriles, being competent sigma-donors, show a strong
40                                              Isonitrile biosynthesis was restricted for over a decade
41  Until recently only one route was known for isonitrile biosynthesis, a condensation reaction that br
42 lds are prepared via addition of 1-adamantyl isonitrile (C=NAd) across the alkylidyne in complexes [(
43 l-1,10-phenanthroline and ptolICN=para-tolyl isonitrile, called TRIP.
44            Selective addition of radicals to isonitriles can be harnessed for initiating reaction cas
45 we show that the chemical energy inherent to isonitriles can be harnessed to activate nucleoside phos
46 onitriles proceed via an insertion of CO and isonitrile carbon into the B-Li bond followed by isomeri
47 center with isonitrile, whereas insertion of isonitrile carbon occurred at the B-Bi bond in 10 which
48 until the end of the last century, few metal-isonitrile catalyzed processes were known.
49  by relieving PdtaS/R-mediated repression of isonitrile chalkophore biosynthesis.
50 led through extension of recently discovered isonitrile chemistry to the domain of alpha,beta-unsatur
51 rein our recent explorations in the field of isonitrile chemistry.
52  dual-labeling experiments revealed that the isonitrile-chlorooxime ligation is orthogonal to the str
53 hibited a ~80-fold increase in reactivity to isonitriles compared to dimethyltetrazine with high orth
54 n aryl migration process, producing a eta(1) isonitrile complex.
55  the special properties and attributes metal-isonitrile complexes offer towards their application in
56 aninol, where amino groups are acylated with isonitrile-containing fatty acyl chains.
57            N-alkylisonitrile, a precursor to isonitrile-containing lipopeptides, is biosynthesized by
58 trile and isocyanoacrylate moieties found in isonitrile-containing natural products.
59 rboxylic acid isonitrile couplings, thioacid isonitrile couplings at ambient temperature, and isonitr
60 tility of microwave-mediated carboxylic acid isonitrile couplings, thioacid isonitrile couplings at a
61 ed with the results of 99mTc-methoxyisobutyl isonitrile, CT, MRI, or histology.
62 ty and different functional groups including isonitrile-(D)-tyrosine, N-formyl tyrosine, and phloreti
63            Moreover, the reactions of 3 with isonitrile derivatives RNC: under heating conditions gav
64 and the N-benzyl group and conversion of the isonitrile-derived amide (the Ugi product) into the corr
65 he strategy relies on the use of convertible isonitriles-derived from Fukuyama amines-and peptide car
66                          Applications of the isonitrile/Diels-Alder logic to the IMDA reaction, as we
67 n done for complexes of nitriles, carbonyls, isonitriles, dinitrogen, Fischer carbenes, alkenes, alky
68 valuation of the DICA stereoisomer with both isonitriles equatorial.
69  instances of photochemical rearrangement of isonitriles, facilitated by energy transfer catalysis un
70 utational investigations of the mechanism of isonitrile formation by ScoE, an unprecedented reaction
71  ScoE have previously been reported, yet the isonitrile formation mechanism remains obscure.
72 of a-ketoglutarate binding, the mechanism of isonitrile formation, and how the structure of ScoE has
73  propose a plausible molecular mechanism for isonitrile formation.
74 zymes, Sav607, ScoE and SfaA, which catalyze isonitrile formation.
75 ized by decarboxylation-assisted -N=C group (isonitrile) formation by using N-alkylglycine as the sub
76                                   ScoE forms isonitrile from a glycine adduct, with both the nitrogen
77  biosynthesis of the key gamma-hydroxy epoxy isonitrile functional group.
78 , the striking architectures and the unusual isonitrile functional groups of the isocyanoterpenes hav
79 or product is actually paerucumarin, a novel isonitrile functionalized cumarin.
80 duce rhabduscin, an amidoglycosyl- and vinyl-isonitrile-functionalized tyrosine derivative.
81 ever, we find that 14 and 2,6-dimethylphenyl isonitrile give instead a 2,5-diazahafnacyclopentane tha
82 ling (2CC) reaction of carboxylic acids with isonitriles gives rise to various N-formylamides.
83 release through covalent modification of the isonitrile group of kupyaphores.
84 y this class of enzymes, installation of the isonitrile group represents a novel reaction type for Fe
85 let carbenes giving (phosphino)phosphinidene-isonitrile (&gt;P-P<--:CNR) and -carbene adducts (>P-P<--:C
86                  A new family of unsaturated isonitriles has been prepared by the base-promoted ring-
87 ling (2CC) reaction of carboxylic acids with isonitriles have been investigated.
88 hermore, the photochemical rearrangements of isonitriles have been supported by computational studies
89      Furthermore, we identify an Mtb-encoded isonitrile hydratase, which can possibly mediate intrace
90                         Isocyanide (formerly isonitrile) hydratase (EC 4.2.1.103) is an enzyme of the
91 tration of reactants, arranging the acid and isonitrile in the appropriate orientations, isolating in
92 , depending on pH) and chemoselectively with isonitriles in the presence of biological nucleophiles,
93 encumbered tetrazines react selectively with isonitriles in the presence of strained alkenes/alkynes,
94  synthesis of (-)-N-methylwelwitindolinone C isonitrile, in addition to the total syntheses of the 3-
95  net O-H and C-H addition across, as well as isonitrile insertion into, the terminal platinum-amido l
96 sequential imine formation, decarboxylation, isonitrile insertion, and hydrolysis to afford the produ
97 n alternative pathway employed by nature for isonitrile installation.
98 boxylation-assisted desaturation to complete isonitrile installation.
99 ocol of alcohols and amines through a common isonitrile intermediate.
100                           In both cases, the isonitrile intermediates are then loaded onto an acyl ca
101            They share a conserved pathway to isonitrile intermediates that involves a bifunctional th
102 le, the reaction with a second equivalent of isonitrile is also observed for smaller substituents.
103  l-proline or pipecolic acid, aldehydes, and isonitriles is described.
104 polypeptides on solid phase via mediation by isonitriles is described.
105                                              Isonitrile ligands, which can be both innocent or non-in
106 s underlines the biocompatibility of the AMI-isonitrile ligation, and simultaneous one-pot triple-pro
107  of the nonribosomal biosynthetic pathway of isonitrile lipopeptides.
108  using combined native chemical ligation and isonitrile-mediated activation strategies.
109                                 The scope of isonitrile-mediated amide bond-forming reactions is furt
110 itrile couplings at ambient temperature, and isonitrile-mediated couplings of carboxylic acids and th
111 , aggregation-prone sequence, we advanced an isonitrile-mediated ligation method.
112 his study, we compared 99mTc-methoxyisobutyl isonitrile (MIBI) with 201Tl scintigraphy for the detect
113 on the steric bulk of the substituent at the isonitrile, migration of a Hyp group was observed, resul
114 usly constructs the spiro-oxindole and vinyl isonitrile moieties.
115                                          The isonitrile moiety is an electron-rich functionality that
116                                          The isonitrile moiety is found in marine sponges and some mi
117 ucleophilic addition of an alkanethiol to an isonitrile moiety, 5-exo cyclization, followed by nucleo
118                      Radical addition to the isonitrile moiety, 5-exo-trig cyclization, and Cu-cataly
119 ived from long-chain acids with a rare epoxy isonitrile moiety, the complexity of which renders the t
120 soxazolecarboxylic acid, and the convertible isonitrile N-(2-{[(tert-butyldimethylsilyl)oxy]methyl}ph
121 notetrazoles have been developed by treating isonitriles, N,N-dibromoarylsulfonamides, and sodium azi
122 suggests that the reactions with CO and aryl isonitriles proceed via an insertion of CO and isonitril
123 allow tuning the structures of tetrazine and isonitrile reactants for application in bioorthogonal li
124 ver the silanitrile and the nitrile over the isonitrile reaction products are favored, respectively.
125         We have investigated the reaction of isonitriles (RNC) with electronically unsaturated diene
126 enced the metagenome and transcriptome of an isonitrile sesquiterpenoid-containing sponge of the orde
127 ional 201TI and hexakis 2-methoxy-2-isobutyl isonitrile studies are less accurate as compared to FDG
128 ynthesis was restricted for over a decade to isonitrile synthases, a family of enzymes catalyzing a c
129                                          The isonitrile-tethered ACP is subsequently processed by pol
130 ent approach based on the combination of the isonitrile-tetrazine (4+1) cycloaddition and the Ugi fou
131 rm stable imine conjugates even with primary isonitriles that are otherwise rapidly hydrolyzed.
132          Depending on the substituent of the isonitrile, the reaction with a second equivalent of iso
133 to contribute to background oxidation of the isonitrile, thereby explaining the improved performance
134 ms that are bridged with L = benzene bis-1,4-isonitrile to form polymer strands.
135 a thioacid, which presumably reacts with the isonitrile to generate a thio-formimidate carboxylate mi
136 droboration product is trapped with CO or an isonitrile to give the respective cyclic zwitterionic bo
137 ic acid function reacts with small aliphatic isonitriles to form N-acyl formamides inside the cavity.
138            Recent developments in the use of isonitriles to furnish secondary and tertiary amide bond
139        3 reacted with CO (1 atm) and various isonitriles under ambient condition, and mechanistic stu
140      Live-cell imaging of cell-surface-bound isonitriles underlines the biocompatibility of the AMI-i
141 ty of tetrazines and their reactivity toward isonitriles, we hypothesized that substituents that are
142 lecule coordinating to the metal center with isonitrile, whereas insertion of isonitrile carbon occur
143 d in 6 was achieved by the treatment with an isonitrile, which led to the formation of a base-stabili
144  from an aldehyde, a secondary amine, and an isonitrile with excellent asymmetric induction.
145          On the contrary, in the reaction of isonitriles with 1, planar five-membered heterocycles (3
146                               Thermolysis of isonitriles with carboxylic acids provides, in one step,
147 ion complexes are applied to the reaction of isonitriles with carboxylic acids.
148 fferences in reactivity between nitriles and isonitriles within our protocol.
149 hermolysis, carboxylic acids can couple with isonitriles without an external catalyst to form N-formy

 
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