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1 multaneous co-sorption of As(V) and Sb(V) to jarosite.
2 d in Sb(V) being sequestered by newly formed jarosite.
3 ring the transformation of schwertmannite to jarosite.
4 s ferric arsenate (AFA), schwertmannite, and jarosite.
5 etic behavior for the AV(3)(OH)(6)(SO(4))(2) jarosites.
7 rts per trillion to 100 parts per billion in jarosite, a sulfate-rich mineral associated with liquid
10 3(OH)6(SO4)2, along with the selenate-capped jarosite analogues of potassium, KFe3(OH)6(SeO4)2, and r
11 at the Tl L3-edge, partly Tl(I)-substituted jarosite and avicennite (Tl2O3) were identified as Tl-be
12 h secondary Mn (birnessite) and Fe minerals (jarosite and goethite), which together accounted for nea
14 Cu, and Zn are associated with metal-bearing jarosite and other minerals (e.g., clays, Fe-(oxy)hydrox
15 unity identified the ferric sulphate mineral jarosite and possible relicts of gypsum at the Meridiani
16 A four-step extraction procedure to quantify jarosite and schwertmannite separately with various solu
17 ification of the fractions of Tl(III), Tl(I)-jarosite and Tl(I)-illite in bulk samples based on XAS i
22 isms controlling As(V) and Sb(V) sorption to jarosite at pH 3 (in dual and single metalloid treatment
23 loped for the preparation of a new series of jarosites, AV(3)(OH)(6)(SO(4))(2) (A = Na(+), K(+), Rb(+
24 f K-jarosite is expected to be key to future jarosite-based soil Pb remediation method development.
26 that Fe(2+)-induced transformation of As/Sb-jarosite can increase Sb mobility and exert major influe
27 nt a new approach for the preparation of the jarosite class of compounds, which for the past several
33 vironment and Tl is readily released from Tl-jarosite during both abiotic and biotic dissolution.
36 ce and supports the ice-weathering model for jarosite formation on Mars, highlighting the geologic im
38 ot proceed to completion, and that following jarosite formation, arid conditions must have prevailed.
40 perature resulted in increased conversion to jarosite-group minerals, but addition of potassium (K) j
41 hat relies on converting soil Pb and As into jarosite-group minerals, such as plumbojarosite (PLJ) an
42 examined the dissolution of synthetic Tl(I)-jarosite, (H(3)O)(0.29)Tl(0.71)Fe(2.74)(SO(4))(2)(OH)(5.
44 ter in hydrated minerals, such as gypsum and jarosite, has numerous applications in studies of recent
46 is needed to verify that schwertmannite and jarosite in the pit sediment do not convert to goethite,
50 results indicate, for the first time, that K-jarosite may successfully convert soil Pb to PLJ without
53 n of a new series of stoichiometrically pure jarosites of the formula, AV(3)(OH)(6)(SO(4))(2) with A
55 of abiotic Fe(2+)-induced transformation of jarosite on the mobility, speciation, and partitioning o
57 V) during the dissolution of synthetic Pb-As jarosite (PbFe(3)(SO(4),AsO(4))(2)(OH)(6)) by Shewanella
58 ound Sb(V), while highlighting the role that jarosite plays in controlling the Sb(V) mobility and fat
60 ining magnetostructural correlations for the jarosites possessing various interlayer cation and cappi
65 ctions included Sb(V) incorporation into the jarosite structure via partial Sb(V)-for-Fe(III) substit
66 ia bidentate corner-sharing complexes on the jarosite surface when Sb(V) was absent or present at low
67 te minerals (including magnesium sulfate and jarosite) that constitute several tens of percent of the
68 tic techniques on the magnetic properties of jarosites, the V(3+) jarosites were also prepared accord
69 AFe3(OH)6(SO4)2 (A = Na+, K+, Rb+ and NH4+) jarosites, these compounds provide a framework for probi
70 entojarosite, AgFe3(OH)6(SO4)2, and thallium jarosite, TlFe3(OH)6(SO4)2, along with the selenate-capp
71 (10 and 20 mM) rapidly (<10 min) transformed jarosite to a green rust intermediary, prior to the subs
72 trigger the Fe(2+)-induced transformation of jarosite to more stable Fe(III) minerals, such as goethi
73 ions; therefore, we probed the potential for jarosite to remediate Pb via intercalation by reacting p
78 roup minerals, but addition of potassium (K) jarosite was most critical to Pb and As bioaccessibility
79 magnetic properties of jarosites, the V(3+) jarosites were also prepared according to the nonredox t
81 ion by reacting presynthesized potassium (K)-jarosite with aqueous Pb and/or Pb-contaminated soil at
82 ave been proposed to explain the presence of jarosite within Martian surficial sediments, including t