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2 s(-1), DeltaH(double dagger) = 17.6 +/- 3.0 kJ mol(-1), DeltaS(double dagger) = -143 +/- 11 J mol(-1
3 N), and calculated heat of formation (-421.0 kJ mol(-1)), combined with its calculated superior deton
9 .59 kJ mol(-1)), enthalpy (DeltaH(0) = 18.05 kJ mol(-1)), and entropy (DeltaS(0) = 68.92 J/K/mol) wer
12 in energy density from 0.34 +/- 0.09% at 0.1 kJ/cm(3) (68 degrees C) to 2.23 +/- 0.04% at 7.0 kJ/cm(3
15 eal a solution Lewis acidity of 3 (FIA=262.1 kJ mol(-1) ) that is higher than that of the landmark Le
18 on enthalpies are Delta H(*)(app) = 43 +/- 1 kJ mol(-1) irrespective of active site location, confini
19 ior, DeltaDelta H degrees (R - S) = -5 +/- 1 kJ/mol and - TDeltaDelta S degrees (R - S) = 3 +/- 1 kJ/
20 nthalpy of adsorption (Deltahads = -73 +/- 1 kJ/mol), with a larger than expected entropic penalty fo
26 asurement of NHC desorption energy (158+/-10 kJ mol(-1)) and confirmation that the NHC sits upright o
30 croorganisms, with available energies of -10 kJ/mol for acetate oxidation and -20 kJ/mol for hydrogen
34 calcium content levels (ca. 6.5-30 mg Ca/100 kJ) were prepared in accordance with the guidelines of C
35 coupling, which can be as large as 1 eV (100 kJ mol-1), leads to the formation of new hybrid states,
36 ducts, with Ng binding energies of 80 to 100 kJ mol(-1) , contain B-Ng bonds with a substantial degre
38 eef briskets were subjected to shockwave (11 kJ/pulse) and were sous vide-cooked at 60 degrees C for
41 y consumption of 483 kWh per ton of Cl2 (124 kJ molCl2 (-1) ) which is about 50-55 % of state-of-the-
42 ergy (Ea) requirements ranged from 51 to 125 kJ mol(-1), with wood-derived PyOM having the highest Ea
48 activation energies of the process span 135 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for
51 (DeltaH()) for H2O formation increase by 14 kJ mol(-1) when Pd cluster diameters increase from 0.7 t
52 n phase reaction is decreased by 162 and 140 kJ mol(-1) according to calculations done with the SMD a
56 ime of 240 s at Ultraviolet-C dosage of 2.15 kJ/m(2) was observed to provoke a considerable increase
58 gy required to phosphorylate organics is ~15 kJ/mol, requiring either very low water activities or re
62 possesses even higher toughness (Gamma ~ 155 kJ m(-3) ), which is 40% higher over that of (silica) =
64 etric work capacity during contraction (2.17 kJ kg(-1)), which is over 50 times that of the same weig
65 entropies, which varied from 92.05 to 99.17 kJ/mol, 88.83 to 95.94 kJ/mol, -35.58 to -4.81 J/mol K,
66 th verified stabilization energies below -17 kJ/(mol Si), comparable to or better than known OSDAs fo
67 coupling low heat of adsorption (-10 to -17 kJ mol(-1) (alkene) ), high alkene:alkane selectivity (4
68 rogen abstraction (15-lipoxygenation) was 17 kJ/mol lower than for arachidonic acid 12-lipoxygenation
71 ocess span 135 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for neat and recycled PE, respecti
72 ctivation energies in the range of 96 +/- 19 kJ/mol are determined, with Pt leading to the lowest ene
73 scopy showed an enthalpy of activation of 19 kJ mol(-1) and a approximately 2.5-fold kinetic isotope
74 d observation of a corrin triplet (E(T) =190 kJ mol(-1) ) and was found to be an excellent photo-sens
78 rbon was exothermic (Delta H = -14.4 +/- 3.2 kJ mol(-1) for T = 20-94 degrees C) and followed the Fre
79 rgy of stabilization (DeltaG(0)) of 32 +/- 2 kJ.mol(-1) For holoBcII, a first non-cooperative transit
83 e acceptors) changes by only approximately 2 kJ mol(-1) across the AnO2(2+) series, indicating that t
84 2) ) with peak energy and power density of 2 kJ m(-2) (6.2 MJ m(-3) or 1.7 mWh cm(-3) ) and 150 kW m(
85 on nor after UV-C treatment with a dose of 2 kJ/L, which is sufficient for the inactivation of microo
89 an isosteric heat of adsorption as low as 20 kJ mol(-1) for carbon dioxide, which could bring a disti
95 termined the triplet energy of HDA to be 217 kJ mol(-1), whereas a complementary method based on trip
97 in water from HVED pre-treated peels at 218 kJ/kg and in aqueous glycerol from pre-treated peels at
98 , decreasing the heat of adsorption by 19-22 kJ molH2-1 while inducing an additional entropy loss of
99 .42 kJ mol(-1); [Formula: see text] = -32.22 kJ mol(-1); [Formula: see text] = -31.84 kJ mol(-1)).
101 ergies of the process span 135 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for neat and recyc
102 transitions in A(1)R-G279S(7.44) (73 +/- 23 kJ/mol) than in wild-type A(1)R (135 +/- 4 kJ/mol) or in
108 J/2.5 h) and resting energy expenditure (243 kJ/d) and an anorexigenic appetite-sensation profile.Pro
109 prompting).Mean energy (difference: -567.25 kJ; 95% CI: -697.95, -436.55 kJ; P < 0.001), saturated f
110 activation directly at the MSI (E(app) ~ 25 kJ/mol) and significantly slower heterolytic H(2) activa
112 xhibit fracture energy, Gamma, of up to 2500 kJ m(-2) , exceeding the toughest existing materials.
113 si-phases (qF: 268 +/- 31 kJ, qL: 263 +/- 26 kJ, P = 0.31) but was 5 +/- 7% higher during DRY than du
114 kJ/mol to 226 kJ/mol, and 188 kJ/mol to 268 kJ/mol, for neat and recycled PE, respectively, and the
115 ct was only observed in water media after 27 kJ/cm(3) by FRAP (47 degrees C) and DPPH (86 degrees C)
119 ize 2000 distorted geometries to within 0.28 kJ mol(-1) of the corresponding ab initio energy, and 50
120 alculated to be Delta(vap)H = 91.27 +/- 0.28 kJ/mol compared to Delta(vap)H(corr) = 91.44 kJ/mol for
125 two HgCN molecules was calculated to be 296 kJ mol(-1) and that for CNHg-HgNC into two HgNC molecule
126 Pa, relatively small amounts of energy (<0.3 kJ/g) are absorbed by the compression of these MOFs.
127 resin was exothermic (DeltaH = -6.3 +/- 1.3 kJ/mol) and spontaneous (DeltaG = -39.7 +/- 0.1 to -43.2
128 +/- 1.10 x 10(4) M(-1) and DeltaG of -100.3 kJ mol(-1) in comparison to a Ka 0.41 x 10(3) +/- 0.09 M
130 nd exchange having barriers of 17.8 and 19.3 kJ/mol for cyclopentene and cyclohexene, respectively.
131 eF as weak ligand for binding (DeltaH = -2.3 kJ/mol; -TDeltaS = -19.5 kJ/mol) but not as substrate fo
134 cluster 4H(2-) (232 +/- 4 kJ mol(-1), -46.3 kJ mol(-1)) the latter is found to react significantly f
138 ng energy of CO2 to benzyl thiolate of -66.3 kJ mol(-1), consistent with the experimental observation
139 strongly exothermic process (DeltaH = -80.3 kJ/mol; -TDeltaS = 37.9 kJ/mol, Kd = 39 nm) whereby the
140 )) values were determined to be 45.9 x 10(3) kJ/kg-mol and 18125.95 min(-1), respectively using the A
141 on resulted in higher DIT ( approximately 30 kJ/2.5 h) and resting energy expenditure (243 kJ/d) and
143 The frameworks exhibit a significant (30 kJ.mol(-1)) variation in the enthalpy of formation depen
145 , Purple Haze and Nutri Red processed at 303 kJ/kg completely increased Caco-2 cells resistance towar
147 differ between quasi-phases (qF: 268 +/- 31 kJ, qL: 263 +/- 26 kJ, P = 0.31) but was 5 +/- 7% higher
148 of formic acid (TOF = 1718 h(-1) and Ea = 31 kJ/mol) and one-pot reactions of formic acid, 2-nitrophe
149 50 kJ mol(-1), 111.174 kJ mol(-1) and 93.311 kJ mol(-1) of activation energy values were found for L(
150 significant enhancements in catalysis (10-32 kJ mol(-1) in barrier lowering) when the catalyst was pr
151 m temperature and activation energy of 30-32 kJ mol(-1) expanding the recently introduced family of l
153 At the strongly binding Cu(I) sites (32 kJ mol(-1)) nuclear quantum effects result in higher ads
154 ee molecules (DeltaG(25 degrees C)(0)=-29.35 kJ mol(-1)), and the binding constant was 1.39 x 10(5) M
156 al phenolic content increased >56% at 3.6-36 kJ/cm(3), indicating production of phenolic compounds.
157 ed better protection to vitamin E (E(a) = 36 kJ/mol), whereas SD-M provided better protection for alp
158 shorter lengths from treatments at 27 and 36 kJ/cm(3) (47 degrees C) compared to 3.9 and 7.0 kJ/cm(3)
162 desorption with an energy consumption of 374 kJ.mol(-1) CO(2) and a CO(2) purity higher than 95%.
163 with glucose-to-duodenum [-22%, -988 +/- 379 kJ (mean +/- SEM), Tukey's post hoc, P < 0.05]; and incr
165 nergy intake were 55 kJ (95% CI, -284 to 395 kJ) at 12 months and 143 kJ (95% CI, -241 to 526 kJ) at
168 trations, with DeltaG(0) value of 65 +/- 1.4 kJ.mol(-1) These combined data highlight the importance
169 ieved accuracy (estimated uncertainty +/-1.4 kJ/mol), the ab initio energies become useful benchmarks
172 3 kJ/mol) than in wild-type A(1)R (135 +/- 4 kJ/mol) or in A(1)R-Y288A(7.53) (184 +/- 24 kJ/mol).
173 electrochemical energy consumption of 155.4 kJ mol(-1) or 0.98 kWh kg(-1) of CO(2) and a CO(2) captu
174 t of adsorption can also be tuned from -16.4 kJ/mol for CPM-200-Sc/Mg to -79.6 kJ/mol for CPM-200-V/M
175 tion free energy (BDFE) of 5H(2-) (230 +/- 4 kJ mol(-1)) and the free energy DeltaG degrees PCET for
176 for the homoleptic cluster 4H(2-) (232 +/- 4 kJ mol(-1), -46.3 kJ mol(-1)) the latter is found to rea
177 the energy absorption typically reaches 3-4 kJ/g; for comparison, the energy release in the explosio
178 the isosteric heat of adsorption (21.9-30.4 kJ/mol) for these CPMs is as low as about one-third of t
179 horter 2.347 angstrom Zn-Zn bond in the 37.4 kJ mol(-1) higher energy isocyanide CNZnZnNC, and a long
180 opants can affect the internal energy (-39.4 kJ mol(-1) with humidity in a nitrogen plasma and +15.7
182 rees PCET for the reaction with TEMPO (-48.4 kJ mol(-1)) are very similar to values for the homolepti
183 The corresponding linear triple bond is 50.4 kJ/mol less stable in vacuo according to the calculation
185 ver the range 111-117 degrees C (DeltaH = +4 kJ.mol(-1)) via a melt-recrystallization process, with t
186 n state for racemization by approximately 40 kJ mol(-1) , thereby facilitating the observed dynamic k
188 % higher in DRY than HUM [263 (39), 248 (40) kJ; P < 0.01] in conjunction with equivalent autonomic r
190 ound in winter (17.48 +/- 3.98 MJ d(-1), 402 kJ kg(-0.75) d(-1)) and the highest in summer (25.87 +/-
191 ) for binding ( [Formula: see text] = -33.42 kJ mol(-1); [Formula: see text] = -32.22 kJ mol(-1); [Fo
192 attraction raises the energy barrier from 42 kJ/mol for unsubstituted DBCOD to 68 kJ/mol for diamide-
193 ormation requires an activation energy of 42 kJ/mol, which is substantially lower than those of exist
194 r between phases [EF: 257 (37), ML: 255 (43) kJ, P = 0.62], but was 7 (9)% higher in DRY than HUM [26
203 text]) was found to be in the range of 45~49 kJ/mol, which was about 20% larger than that between the
204 ding (DeltaH = -2.3 kJ/mol; -TDeltaS = -19.5 kJ/mol) but not as substrate for reduction or oxidation.
205 rge difference in adsorption enthalpy of 2.5 kJ mol(-1) between D2 and H2 results in D2-over-H2 selec
210 GPa and specific energy dissipation of 325.5 kJ/kg, surpassing previously reported values at similar
211 ss spectrometry indicated that a loss of 4-5 kJ/mol/protomer in the N3 domain that is peripheral to t
215 action energy was found to vary by about 7.5 kJ mol(-1) on going from a phenyl-phenyl to an anthracen
216 ees C=0.94+/-0.14 min(-1) and Ea,l=178+/-8.5 kJ/mol, and a stable fraction, representing 58+/-2%, wit
219 ng of the barrier to unfolding in G37R by >5 kJ/mol(-1) over the other variants, consistent with expe
220 rent activation energy (Eapp) of 56.5 (+/-5) kJ mol-1 and is kinetically limited by desorption of mol
223 plemented DraE (DraE-sc) by approximately 50 kJ mol(-1) in an exclusively thermodynamic manner, i.e.
224 igher in energy than the tri-keto form by 50 kJ mol(-1) which must be more than compensated by enhanc
228 th an associated moderate energy input of 54 kJ/mol, typical for the full CO2 desorption in conventio
229 erence: -567.25 kJ; 95% CI: -697.95, -436.55 kJ; P < 0.001), saturated fat (difference: -2.37 g; 95%
230 timated differences in energy intake were 55 kJ (95% CI, -284 to 395 kJ) at 12 months and 143 kJ (95%
234 rved free adsorption energy of -52.7 +/- 0.6 kJ/mol, PAH adsorption was found to be surprisingly less
238 getic penalty per rotor of approximately 5-6 kJ mol(-1) was observed in less strained situations wher
240 ith this surface stabilizes the protein by 6 kJ mol(-1) , a value that is in good agreement with theo
242 ium ion 5 with binding energies of 57 and 62 kJ/mol for cyclopentene and cyclohexene, respectively, w
243 derate enthalpic barrier of approximately 62 kJ/mol, to give H2 and an antiferromagnetically coupled
244 ted, with an activation energy as high as 63 kJ mol(-1) in DMSO-d(6) solution (DFT prediction for a m
248 lectric fields (PEF) (1.4-1.7 kV/cm, 653-695 kJ/kg) and heating (60 and 80 degrees C for 10 min) at d
253 ination of the activation (E(A) = 50.3 +/- 7 kJ/mol) and deactivation (E(D) = 62.23 +/- 3 kJ/mol) ene
255 Eapp), across the techniques applied, of 8.7 kJ mol-1, within the temperature range investigated (276
256 exhibiting an overall activation energy of 7 kJ mol(-1), which was estimated in vacuum at the B3LYP/6
258 e olefin binding enthalpies, below 55 and 70 kJ/mol for ethylene and propylene, respectively, indicat
259 gn with DeltaHpart becoming endothermic (+70 kJ/mol) and entropically favored (DeltaSpart = +240 J/(m
263 est negative values ofDeltaH degrees (-11.74 kJ/mol) andDeltaS degrees (-8.08 J/K.mol) led to the mos
271 al cycle to yield DeltaHf,298K = (325 +/- 8) kJ mol(-1), ca. 10 kJ mol(-1) below the previous value.
273 owers the fragmentation barrier by around 80 kJ mol(-1) in the gas phase, while a negative charge has
275 genetic risk group versus control group 0.85 kJ/kg/d (95% CI -2.07 to 3.77, p = 0.57); phenotypic ris
277 f rotation, DeltaG(double dagger)298 = 82-86 kJ mol(-1), were determined by (1)H NMR for 12a, 12d, 12
281 activation energy of 0.665, 2.650 and 13.893 kJ/mol for vacuum, and 1.089, 4.923 and 14.142 kJ/mol fo
282 The calculated barrier (DeltaG( ) = 107.9 kJ/mol; at the M06L/6-311+G(d,p)/SDD level of theory) fo
284 cess (DeltaH = -80.3 kJ/mol; -TDeltaS = 37.9 kJ/mol, Kd = 39 nm) whereby the thioimide adduct is form
285 ll ligands bound, is lower by only about 8.9 kJ/mol than that of the Michaelis or apo complex conform
287 ndard free energy change of approximately -9 kJ/mol, which is a large contribution to the delicate ba
288 The Delta(soil-air)U values were 328 and 90 kJ/mol for chlorpyrifos in the absence and presence of f
289 ,f show high rotational barriers of up to 92 kJ mol(-1), unlike those of (1R)-2e,f and with much lowe
291 d from 92.05 to 99.17 kJ/mol, 88.83 to 95.94 kJ/mol, -35.58 to -4.81 J/mol K, respectively (R(2) > 0.
292 ary carbocations were calculated as 76 to 97 kJ/mol and enthalpies for subsequent charge migration to
293 lk fibres achieving an impact strength of 98 kJ m(-2), which is twice that of purely carbon-fibre rei
294 ome, objectively measured physical activity (kJ/kg/day), and also measured several secondary outcomes
295 C-H bond cleavage is 9.5 kilojoule per mole (kJ/mol) lower than the binding energy of the adsorbed pr
296 ., 1.05 [0.89-1.23] and 0.92 [0.71-1.18] per kJ/m(2) for center-level monthly mean UVR for the 13- to
299 31 [95% confidence interval = 1.05-1.63] per kJ/m(2)) and minimum (1.25 [1.06-1.47] per kJ/m(2)) UVR