ライフサイエンスコーパス: metal

1 placed by orthopyroxene, troilite, and minor metal.

2 evolution reaction (HER) catalysts for noble metals.

3 e sum corrected for effects of charge and 5d metals.

4 from focusing on reductions in environmental metals.

5 eristic layered structures composed of noble metal A and strongly correlated BO(2) sublayers.

6 computational evidence that late transition metals adopt the axial position in heterocycles or syncl

7 ept to metamaterials such as microfabricated metal-air hybrids.

8 electrolyte, the interphase between a liquid metal and a liquid electrolyte is directly visualized vi

9 generated through chemical reduction with K metal and characterized by EPR spectroscopy.

10 attributed to SEI formation on both lithium metal and copper (and Cu(+), Cu(2+) reduction).

11 thermal oxidation, supports a wide range of metal and metal oxide active phases.

12 etal ions that we describe, depending on the metal and synthesis temperature used, as random (Co, Cd,

13 h the reducible Ti-LLZTO layer contacting Li-metal and the LLZTO layer contacting cathode.

14 rious substrates-including silicon, ceramic, metal and transparent glass-and show that the water repe

15 roportionation equilibrium between In(I), In metal, and In(III) opens up additional flexibility in pr

16 stabilize the highly reductive lithium (Li) metal anode and the high-voltage cathode for long-life,

17 ords new insights into realizing a stable Li metal anode for high-temperature Li metal batteries with

18 uctured electrodes (V(2) O(5) cathode and Li metal anode) are realized through a combination of impri

19 rolyte system that can stabilize the lithium-metal anode, the solvation behavior of the solvent molec

20 Lithium metal anodes have attracted extensive attention owing to

21 The practical applications of lithium metal anodes in high-energy-density lithium metal batter

22 Potassium (K) metal anodes suffer from a challenging problem of dendri

23 homogeneous plating and stripping of lithium metal anodes.

24 lications in rechargeable batteries based on metal anodes.

25 alysts, in particular those containing noble metals, are frequently used in heterogeneous catalysis,

26 fossilize in the vicinity of archaeological metal artifacts offers the most exquisite preservation t

27 Although salts of such metals as vanadium, niobium, cerium, and manganese were

28 Single-atom catalysts not only maximize metal atom efficiency, they also display properties that

29 n of bond distances between a broad range of metal atoms of different sizes.

30 f these materials is challenging because the metal atoms reside on surfaces that are typically nonuni

31 containing a linear array of more than three metal atoms, and coordination polymers with a heterometa

32 conjugating nanoplastics with functionalized metal (Au)-containing nanoparticles (NPs), thus making t

33 f this review summarizes previous studies on metal-based anticancer agents that cause ER stress.

34 at can be used for the growth of other noble-metal-based delafossites, which are known to be challeng

35 mplement to the current workhorse transition-metal-based methods for catalytic intermolecular C-N cou

36 ng-life, high-energy-density rechargeable Li metal batteries (LMBs).

37 Rechargeable lithium metal batteries are next generation energy storage devic

38 electrolyte interface in solid-state lithium metal batteries can be overcome using this architecture.

39 metal anodes in high-energy-density lithium metal batteries have been hindered by their formation an

40 Currently, all reported liquid metal batteries need to be operated at temperatures abov

41 is different from traditional molten-salt Li metal batteries using a pristine metallic Li anode.

42 table Li metal anode for high-temperature Li metal batteries with a simple battery configuration and

43 Here, highly stable lithium (Li) metal batteries with LCO cathode, through the design of

44 perated for rechargeable high-temperature Li metal batteries.

45 atabase searches resulted in only 13 similar metal binding sites in other proteins, indicative of the

46 Abundant transition metal borides are emerging as substitute electrochemical

47 chrotron X-ray fluorescence imaging of trace metals, both performed with 40 nm spatial resolution, on

48 might be trapped by cysteine cross-links and metal bridges.

49 he other position transforms into a discrete metal carbene complex.

50 and glasses, polymers, metal nanoparticles, metal carbide nanoparticles, and carbon materials.

51 oncave to convex side due to a difference in metal-carbon bonding at the curved surfaces as confirmed

52 articularly, the merger of Earth-abundant 3d metal catalysis and electrooxidation has recently been r

53 rable potential of isonitriles as ligands in metal catalysis utilizing both commercially available bu

54 ctions have traditionally relied on precious-metal catalysts for C-H bond cleavage and, as a result,

55 Engaging two transition metal catalysts for this goal presents a considerable de

56 ster and modulate the mobility of transition metal catalysts in living environs.

57 Recent achievements in transition-metal catalyzed enantioselective functionalizations of c

58 anols, including base-mediated ring-opening, metal-catalyzed C-C insertions and eliminations, oxidati

59 ntary reactivities under radical, ionic, and metal-catalyzed conditions.

60 tter (aka Tsuji-Trost allylic substitution), metal-catalyzed hydrofunctionalization does not require

61 Taken together, this base-metal-catalyzed process provides access to cyclopropyl-c

62 ese findings enrich the available arsenal of metal-catalyzed spirocyclization methods based on the us

63 We cover a wide range of transition-metal-catalyzed, template-directed remote C-H activation

64 of POM properties with different organic and metal cation functionalities, thereby expanding the key

65 with virtually any (bio)organic molecule or metal cation, generating a wide range of materials with

66 Recent work has indicated that other metal cations can substitute for Mg(2+), raising questio

67 veal that, regardless of the metal identity, metal cations occupy preferably octahedral coordination

68 ly-charged [Ge(4) ](4-) units and transition metal cations, in which 3-center-2-electron sigma bondin

69 ayers allows for ion exchange with 3d and 5f metal cations.

70 All-solid-state Li-metal cells with these composite electrolytes demonstrat

71 ical energy and funnel it to the luminescent metal center.

72 taining structures of intact redox states of metal centers derived from zero dose X-ray crystallograp

73 Metal centers in X-ray structures of small organometalli

74 The metal-clad leaky waveguide (MCLW) is an optical biosenso

75 sual example of mutual stabilization between metal clusters and a self-assembled metal-organic cage.

76 oline derivatives using first-row transition-metal cobalt has been demonstrated wherein the pivaloyl

77 uents that engage the ATP phosphates and the metal cofactors.

78 cillary ligands to stabilize late transition metal complexes and are conventionally considered to hav

79 n the perspectives and significance of using metal complexes as ER stress-inducing agents for the tre

80 ase condensations have produced multinuclear metal complexes exhibiting the shape of tetrahedral cont

81 tion method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that c

82 rmaceuticals, agrochemicals, and ligands for metal complexes, but strategies to selectively halogenat

83 In many cases, the metal concentration in end-of-life products is lower tha

84 We find that hot electrons in the metal contact transfer their energy to pre-existing free

85 d can be applied to other moderately soluble metal containing natural, incidental, or engineered NPs

86 In this protocol, metal-containing anions and layered double hydroxides ar

87 Transition metal-containing catalysts are employed, although accomp

88 Bronsted acid/base) near the active site of metal-containing catalysts is an effective way to improv

89 nal class, bioinorganic class, metal ion and metal-containing cofactor, which will serve as a valuabl

90 ed by complex enzyme machineries with unique metal-containing cofactors.

91 This study illustrates specific effects of metal coordination, and the associated electrostatic cha

92 sidues responsible for nucleoside selection, metal coordination, triphosphate binding, and RNA templa

93 adding tungsten carbide nanoparticles to the metal core to arrive at wire lengths more than 30 cm wit

94 drive an increase in the production of many metals, creating new mining threats for biodiversity.

95 Eleven metal-dependent lysine deacetylases (KDACs) have been id

96 ere, we show that Agd3 deacetylates GAG in a metal-dependent manner, and is the founding member of ca

97 cture for the surface metal protrusion to be metal-dependent, but point to an equivalent octahedral-c

98 lk superlattice consisting of the transition metal dichalcogenide (TMD) superconductor 2H-niobium dis

99 optical selection rules(12-14) of transition metal dichalcogenide heterostructures allow us to optica

100 homojunctions in two-dimensional transition metal dichalcogenide materials have been widely reported

101 perovskites and III-V, II-VI and transition metal dichalcogenide semiconductors form the foundation

102 Ta(1.6)Te, derived from a layered transition metal dichalcogenide, are isolated with standard exfolia

103 Transition Metal Dichalcogenides (TMDs) are one of the most studied

104 Atom-thin transition metal dichalcogenides (TMDs) have emerged as fascinating

105 ential of atomically thin layered transition metal dichalcogenides as next-generation channel materia

106 ecisely and that stability is assured at the metal-dielectric interface.

107 nformational effects seen for singly charged metals differ profoundly from binding of multiply charge

108 RS, including TMDs (MX(2) , M = transitional metal, e.g., Mo, W, Re, Sn, or Pt; X = chalcogen, e.g.,

109 M to protect it during the deposition of the metal electrode which requires conditions under which or

110 cal and mechanical stability issues with the metal-electrolyte interface in solid-state lithium metal

111 erromanganese industry, a source of airborne metals emissions.

112 f)(2) ][OTf] with two triflates bound to the metal encapsulated in the crypt.

113 These mechanisms are generalizable to other metal-enriched QD surfaces that have a similar surface s

114 d residues allowed for quantification of the metal evaporation from the three nanomaterials.

115 largely endocytosed in response to non-iron metal excess, unlike IRT1.

116 allic nodes of MUV-10(Ca) enables controlled metal exchange in soft positions for the generation of h

117 obtained at recruitment, as a biomarker for metal exposure from any source.

118 issues associated with the low reactivity of metal fluorides.

119 ion environment from the reducing transition metal fragment.

120 eceptors can be modulated by the coordinated metal fragments and that they can bind chloride 1 to 2 o

121 ecently, aNHCs successfully accomplished the metal-free catalytic formylation of amides using CO(2) a

122 is among the best performances reported for metal-free CO(2) reduction electrocatalysts.

123 Herein, a metal-free domino synthesis of Z-selective alpha,beta-di

124 The metal-free hydrofluorination of alkynes constitutes an a

125 Compared to metal-free oxidation of the substrates, which is caused

126 This makes metal-free perovskites novel candidates for the next gen

127 is the design of a redox stimuli activatable metal-free photosensitizer (aPS), also functioning as a

128 An effective method for transition-metal-free postfunctionalization of thiazolo[3,2-c][1,3,

129 one product cleanly, and faster than in the metal-free reactions.

130 A one-pot, metal-free, double cyclization for the synthesis of bicy

131 high degree of metal-ligand covalency due to metal -> ligand pai-backdonation.

132 for a series of tetraphenylphosphonium (TPP) metal halide hybrids containing distinct metal halides,

133 r evidence of water stability in a lead-free metal halide perovskite, namely DMASnBr(3) , obtained by

134 commonly used as charge-extraction layers in metal-halide perovskite solar cells.

135 iradicals, and the way to think about alkali metal halides, show us the way to integrate simulation w

136 PP) metal halide hybrids containing distinct metal halides, TPP(2) MX(n) (MX(n) =SbCl(5) , MnCl(4) ,

137 ansformation kinetics of GBs in an elemental metal have remained elusive.

138 g specific surface area (SSA) of the natural metal-(hydr)oxide fraction is ~350-1400 m(2)/g, illustra

139 he thermodynamics of paramagnetic transition metal hydride complexes, especially of the abundant 3d m

140 eory) studies reveal that, regardless of the metal identity, metal cations occupy preferably octahedr

141 ffinity chromatography to either immobilized metals (IMAC) or metal oxides, i.e., Fe(3+), TiO(2), or

142 Such embedding of supranano liquid metal in perovskite films leads to a cesium-based ternar

143 e could find a specific gene marker for each metal in the 10-gene marker list.

144 ctal-like structures on the surface of these metals in a controlled (tier, composition, and structure

145 natural chelator of Fe, zinc (Zn) and other metals in higher plants and NA-chelated Fe is highly bio

146 hat reveals the positions of two active site metals in the FEN/EXO domain.

147 nation of hard (titanium) and soft (calcium) metals in the heterometallic nodes of MUV-10(Ca) enables

148 with variable nuclearity, controlled by the metal incorporated.

149 The metal-insulator transition (MIT) in transition-metal-oxi

150 y in the passivating oxide(s) and underlying metal interface exacerbates these challenges.

151 DMI manifests at metallic ferromagnet/heavy-metal interfaces, owing to inversion symmetry breaking a

152 ifier, functional class, bioinorganic class, metal ion and metal-containing cofactor, which will serv

153 ionally, our simulations show that the third metal ion assists the departure, through the mobile arch

154 for engineering such a selective multivalent metal ion binding site into target macromolecules for st

155 orted so far for catalysts based on a single metal ion mechanism.

156 s multiway junctions or pseudoknots in mixed metal ion solutions.

157 imple approach, called UVHis-PAGE, that uses metal ion-loaded and fluorescently labeled chelator head

158 ences of delaying Abeta aggregation via weak metal-ion binding, quantitatively linking the contributi

159 We find that the metal-ion-induced folding can proceed with stereoinducti

160 ughs in substituting precious and rare-Earth metal ions (e.g. Ru, Ir, Pt, Au, Eu) in these applicatio

161 nt luminescence nanoparticles (D-PLNPs) with metal ions (MIs) and for the first time proposed an MIs-

162 nto 3D lattices upon coordination of various metal ions and ditopic, hydroxamate-based linkers.

163 Pt and RE metal ions from the most common hydrated metal salts are

164 esence of heterogeneous spatial sequences of metal ions that we describe, depending on the metal and

165 he contributions of specific interactions of metal ions with monomeric Abeta to their effects on bulk

166 -center containing proteins (homo and hetero metal ions).

167 e ligands, pai-interactions, coordination to metal ions, and few halogen bonds in chloropyrazines.

168 able to form coordination bonds with various metal ions, which can be reduced to metal nanoparticles

169 ive, 'one-pot' coordination of soft and hard metal ions.

170 ctural stabilization of this domain by bound metal ions.

171 In spintronics, the antiferromagnetic metal IrMn has been used as the pinning layer in magneti

172 ce of proper concentrations of intracellular metals is essential for cell fitness and pathogenesis.

173 ide complexes, especially of the abundant 3d metals, is important in the design of electrocatalysts a

174 alt and binder stability, and the transition metal L-edges to gain insights into the oxidation/reduct

175 CLW) is an optical biosensor consisting of a metal layer and a low index waveguide layer on a glass s

176 t coordination environments of the framework metals lead to variations in the linker stacking geometr

177 We analyzed metal levels in erythrocyte samples obtained at recruitm

178 There is also a small reduction in metal-ligand covalency and an attendant increase in the

179 tting of the d-orbitals and a high degree of metal-ligand covalency due to metal -> ligand pai-backdo

180 pH-controlled deposition often leads to low metal loadings or a range of metal species.

181 Although electron transfer involves metal-localized orbitals, investigations of [(P(6)ArC)Fe

182 that it formed by decomposition of a complex metal M oxide (M (4)O(5)) with a stoichiometry of (Fe(3+

183 ariation: elemental substitution on both the metal (M) and carbon/nitrogen (X) sites presents promisi

184 Fatigue damage in metals manifests itself as irreversible dislocation moti

185 , raising questions about the role different metals may play in the maintenance of the ribosome under

186 cies and leads to a mixture of products, the metal-mediated reactions lead to one product cleanly, an

187 re dominated by thermally driven, transition-metal-mediated reactions.

188 h a combination of intra- and intermolecular metal-mediated self-assembly steps.

189 onal nanocatalysts such as carbon materials, metal, metal oxides or dyes.

190 Regarding the metal-metal bond distances, we make use of the formal sh

191 coordination polymers with a heterometallic metal-metal bonded backbone.

192 imes likely contribute to the variability in metal/metalloid levels across studies, making comparison

193 st, the binding properties and solubility of metal-mimosine complexes were assessed through spectroph

194 We examined associations of a metal mixture with general cognition in a cross-sectiona

195 trocatalytic reaction between NH(4)(+) and a metal/nano-catalyst.

196 very challenging to prepare amorphous noble-metal nanomaterials due to the strong interatomic metall

197 various metal ions, which can be reduced to metal nanoparticles (NPs) as a result of thermal anneali

198 amorphous MOF liquids and glasses, polymers, metal nanoparticles, metal carbide nanoparticles, and ca

199 eakening was recently revealed in ultrasmall metal nanoparticles.

200 ies rely on unusual materials such as liquid metals, nanowires, and woven textiles or on optimally co

201 , can be utilized in the design of supported metal NCs highly resistant to sintering.

202 o classes based on the composition of the RE-metal node being RE(iii)-ions, RE(iii)-chains, or RE(iii

203 by anchoring the chromophore to a framework metal node, portending a potential avenue to develop an

204 These in vivo-generated metal NPs represent a biocompatible drug delivery platfo

205 It is observed that transition metal nucleated, high yield growth of carbon nanotubes (

206 are exhaustively catalogued on the basis of metal or organocatalyst.

207 s are thinner and more flexible than typical metal or silicon electrodes, but the arrays described in

208 sters in diverse application areas including metal organic framework design, TM-based catalyst design

209 between metal clusters and a self-assembled metal-organic cage.

210 The resulting metal-organic ferrimagnets feature critical temperatures

211 Herein, we deliberately design a Th-metal-organic framework (MOF) for highly efficient separ

212 a multidentate coordination environment in a metal-organic framework to stabilize discrete inorganic

213 Now, a cationic nanoscale metal-organic framework, W-TBP, is used to facilitate tu

214 orption capacities of nanomaterials, such as metal-organic frameworks (MOF), has been extensively inv

215 Metal-organic frameworks (MOFs) are promising materials

216 y of two-dimensional (2D) layered conductive metal-organic frameworks (MOFs) as drop-casted film elec

217 The emergence of electrically conductive metal-organic frameworks (MOFs) has led to applications

218 Metal-organic frameworks (MOFs), constructed from organi

219 ct engineering can enhance key properties of metal-organic frameworks (MOFs).

220 Nanoscale metal-organic frameworks (nMOFs) are excellent radiosens

221 We recently introduced protein-metal-organic frameworks (protein-MOFs) as chemically de

222 Metal-organic frameworks and porous coordination cages h

223 ch catalysts supported on zeotype materials, metal-organic frameworks, and covalent organic framework

224 xidation, supports a wide range of metal and metal oxide active phases.

225 fficient H doping in green solvent-processed metal oxide films and the promise of high-performance, u

226 Owing to their great stretchability, these metal oxide FNs can be laminated/embedded on/into elasto

227 on laser exposure, MOF crystals shrank while metal oxide nanoparticles formed giving rise to the HP-M

228 he promise of high-performance, ultra-stable metal oxide semiconductor electronics with simple binary

229 tal-insulator transition (MIT) in transition-metal-oxide is fertile ground for exploring intriguing p

230 ic mechanism of this multi-redox reaction on metal-oxide photoanodes remains a significant experiment

231 By combining metal-oxide WD catalysts that are efficient near the aci

232 Mesoporous metal oxides (MMOs) have been demonstrated great potenti

233 The promising P2-layered sodium transition metal oxides (P2-Na(x)TmO(2)) often suffer from structur

234 into charge-ordering phenomena in transition-metal oxides in general.

235 nocatalysts such as carbon materials, metal, metal oxides or dyes.

236 C) removal was achieved when antibiotics and metal oxides were allowed for preequilibration before st

237 ctions are ubiquitous in physics; transition metal oxides(1,2), layered molecular crystals(3) and tra

238 ACs on traditional supports (N-doped carbon, metal oxides, etc.) remains a formidable challenge, espe

239 raphy to either immobilized metals (IMAC) or metal oxides, i.e., Fe(3+), TiO(2), or Ti(4+).

240 achieving giant intrinsic SHE in transition metal oxides.

241 ites, when oxides, allow for face-sharing of metal-oxygen octahedra or trigonal prisms within their s

242 AMP-activated protein kinase deprived of any metal Pd contamination.

243 nge membrane (PEM) fuel cell, platinum-group-metal (PGM)-based catalysts account for ~50% of the proj

244 , Co, Ni, Mn) are the popular platinum group-metal (PGM)-free catalysts for many electrochemical reac

245 Notably, a metal-phthalocyanine fragment was successfully incorpora

246 ibility of developing a family of transition metal polychalcogenides functioning via coupled cationic

247 Metal precursors and organic ligands are separated to re

248 ng force and final structure for the surface metal protrusion to be metal-dependent, but point to an

249 iferromagnetic Cr(2)O(3) crystal and a heavy metal (Pt or Ta in its beta phase).

250 governed by microbial interactions, whereby metal-reducing bacteria are able to reduce soluble U(VI)

251 Here, it is shown that liquid metals render this possible as they offer catalytic acti

252 is the first study to examine the transition-metal resonances directly in MXene samples, and the firs

253 opulations in the member galaxies and a hot, metal-rich gas composing the intracluster medium.

254 This setup has significant flaws related to metal/salt reference electrodes: they are bulky and diff

255 RE metal ions from the most common hydrated metal salts are first atomically embedded into an in sit

256 taining two amines, two dialdehydes, and two metal salts-have been found to self-sort, generating two

257 antly to LLL of sirolimus-eluting absorbable metal scaffolds.

258 nal properties of this remarkable transition-metal-sequestering protein has remained enigmatic.

259 rmeable throughout at those points where the metal sheeting was absent and where the vegetation had o

260 ral host-guest strategy to fabricate various metal single-atom catalysts on nitrogen-doped carbon (M(

261 ly dispersed and nitrogen coordinated single metal sites (M-N-C, M=Fe, Co, Ni, Mn) are the popular pl

262 ssible to tune the O(2) affinity at the open metal sites of MOFs for applications involving the stron

263 he parent oxide, and Ir serves as the active metal species that produces the ex-solved metallic parti

264 en leads to low metal loadings or a range of metal species.

265 Using the ferromagnetic metal SrRuO(3) as a model system, we demonstrate an effi

266 ve been identified, the intersection between metal starvation and other essential inorganic nutrients

267 el-coated balloon angioplasty (N=3543), bare-metal stenting (N= 2045) versus paclitaxel-eluting stent

268 in the DIVA (Drug-Eluting Stents Versus Bare Metal Stents in Saphenous Vein Graft Angioplasty; NCT011

269 bjected to chemically similar but non-native metal substitutions is a long-standing puzzle.

270 breaking and spin-orbit coupling by a heavy metal such as Pt.

271 lements of the periodic table, in particular metals such as Ca, Al, Na, Zn, and Fe and halogens like

272 While some metals such as iron and copper are essential for cellula

273 Li(2) S into a prelithiation agent, forming metal sulfides rather than S(8) after the full charge.

274 Metal template Schiff base condensations have produced m

275 With an in situ reduction of Ti-LLZTO by Li-metal, the interfacial wettability was improved and a mi

276 ncerns associated with the presence of toxic metals, these quantum dots are not well suited for appli

277 n ensure smooth electrodeposition of lithium metal, thus paving the way for practical applications in

278 Modeling the thermodynamics of a transition metal (TM) ion assembly be it in proteins or in coordina

279 tributed to a phase transition from a normal metal to a spin-polarized correlated state.

280 lowed by additional chain walking allows the metal to migrate to the alpha-carbon of the acrylate moi

281 to refine PSB and crack-initiation models in metals to account for gradual and heterogeneous evolutio

282 anic lithosphere destabilizes carbon-bearing metals to form diamond, without disturbing the ambient-m

283 om an N(2) S(2) (4-) cavity holding a single metal, to a binucleating H(2) ema(2-) with bridging sulf

284 The metal-to-ligand charge transfer (MLCT) excited states of

285 y intriguing because they exhibit an unusual metal-to-metal transition.

286 ombination of abiotic (nutrient deprivation, metal toxicity) and biotic (pathogens, herbivores) stres

287 concentration of Ru ions where the insulator-metal transition occurs.

288 ing because they exhibit an unusual metal-to-metal transition.

289 to 2.44 on the band structure and insulator-metal transitions are presented for the first time.

290 , ddh), the urease operon, genes involved in metal transport (feoA, mntH, sirA), anaerobic metabolism

291 ly exemplifies this deficit, as the specific metal used by any family member cannot be predicted.

292 ribute to the ongoing search for ultrastrong metals via materials engineering.

293 orbit coupling arises from a proximate heavy metal, we show that in perpendicularly-magnetized iron g

294 nts on magnetically frustrated heavy fermion metals, we theoretically study the phase diagram of the

295 Metals were measured using inductively coupled plasma ma

296 to place a studied system in proximity of a metal, which induces additional screening and hence supp

297 Li anode require excess electrolytes and Li metal, which significantly reduce the energy density of

298 [Ga(arene)(n) ](+) salts on oxidation of Ga metal with AgOTf in arene solvents.

299 The behaviour of lithium metal within the MIEC channels suggests that the chemica

300 esized that levels of salivary nutrients and metals would correlate with salivary microbiome composit