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1 it two-electron chemistry to form the carbon-metal bond.
2 metric chiral ligand that stabilizes a metal-metal bond.
3 ound on the strength of the d(8)-d(10) metal-metal bond.
4  instability against oxidation of the sulfur-metal bond.
5  iodide for a fluoride strengthens the metal-metal bond.
6 e-electron bond is an exceedingly long metal-metal bond.
7 tal orientation and the presence of a metal--metal bond.
8 s our fundamental understanding of f element metal bonds.
9 with unusual and often unprecedented element-metal bonds.
10 the relative weakness of newly formed carbon-metal bonds.
11  the spontaneous formation of covalent thiol-metal bonds.
12 ilize low-valent metal centers through metal-metal bonding.
13 coupling indicate a transition from 3D to 2D metal bonding.
14  kinetically stabilized Ge-metal and Ge-semi-metal bonding.
15 even electronic transitions due to d-d metal-metal bonding.
16 icularly with respect to the nature of thiol-metal bonding.
17 ntermediates, and products through substrate-metal bonding.
18 correlated with the increasing role of metal-metal bonding.
19 e transition metal cluster with direct metal-metal bonding.
20 nderstanding of the electron deficient metal-metal bonding.
21  moiety with systematic shifts caused by the metal bonding.
22 ions lead to hole localization with no metal-metal bonding.
23 ovides a direct experimental probe of ligand-metal bonding.
24 of the TMB ligand framework, forming a metal-metal bonded (1)dsigma*psigma state after 4-5 ps.
25 g carbon-carbon, carbon-hydrogen, and carbon-metal bond activation.
26 l as investigate how coordination number and metal bonding affect the preferred geometry of interacti
27  which seems to correlate with a short metal-metal bond and a higher spin state.
28 ovided a detailed understanding of the metal-metal bonding and electronic transitions that are respon
29          Our analysis shows diminished metal-metal bonding and increased hydrogen bonding at FeFeco's
30 relation between the amounts of C-metal or O-metal bonds and the corresponding bacterial inactivation
31 delta bonding orbital of the quadruple metal-metal bond, and a strong interaction of this orbital wit
32 atory insertion of the ylide into the carbon-metal bond, and protodemetalation, the last step being t
33 n in the presence of hydrogen bonding, metal-metal bonding, and electrostatic interactions.
34 he assumption of inert 4f electrons in metal-metal bonding, and we propose a promising strategy for f
35 structural feature, the largest metal-halide-metal bond angle.
36 metal-metal distances and lower metal-oxygen-metal bond angles than are seen in the more familiar per
37 s can be conjugated to peptides via a carbon-metal bond are described, and selected medicinal applica
38 interactions that preclude significant metal-metal bonding are predicted.
39 pon reaction of 2 with dinitrogen, all metal-metal bonds are broken, steric conflicts are relaxed, an
40 n reactions and/or direct formation of metal-metal bonds are discussed (103 references).
41            Instead of bearing a static metal-metal bond as suggested by structural X-ray diffraction
42 examples of MOFs constructed using phosphine-metal bonds as the sole structural component.
43  possible to observe NMR signals of directly metal-bonded atoms because pronounced rhombicity in the
44 ination polymers with a heterometallic metal-metal bonded backbone.
45                   The expansion of the metal-metal bond becomes the controlling factor for a(b) evolu
46  Heterobimetallic catalysts, bearing a metal-metal bond between a transition metal (TM) and a tin ato
47                   Understanding direct metal-metal bonding between actinide atoms has been an elusive
48                                 Direct metal-metal bonding between lanthanide atoms has been challeng
49               Our results clearly show metal-metal bonding between Tc pairs along the edge-sharing ch
50 uggesting the formation of C-O-metal and C-N-metal bonds between N-doped graphene oxide and spinel ox
51                                        Metal-metal bond breaking that leads to the evolution of catal
52 nal sampling of the complex with constrained metal bonds by force-field-based molecular dynamics (MD)
53                                   This metal-metal bond can be protonated and thus functions like a b
54   Gould et al. report that introducing metal-metal bonding can enhance coercivity.
55  Our results show how the emergence of metal-metal bonding can stabilize giant spin-lattice coupling
56                                        Metal-metal bonded cationic complexes of the [M(2)(DAniF)(n)(M
57 re single electron actinide-lanthanide metal-metal bonds, characterized by structural, spectroscopic
58  However, the role of each residue in carbon-metal bond cleavage has not been well-defined.
59 leads to a dinuclear, acetate-bridged, metal-metal bonded complex of platinum(III); dmso in the prese
60 ther by ATR-FTIR suggesting the formation of metal-bonded complexes at circumneutral to low pHc = -lo
61  this plane could be especially reactive for metal-bonded complexes, as they facilitate a mononuclear
62 e first study of a fluorophore-labeled metal-metal bonded compound, work that opens up new venues for
63 tional theory calculations to identify local metal bonding configurations.
64                           The average ligand-metal bond covalencies obtained from these pre-edges are
65                        The changes in ligand-metal bond covalencies upon redox compared with DFT calc
66 small relative to the large change in ligand-metal bond covalency (30%) observed in the data.
67 ) has been employed to directly probe ligand-metal bond covalency, where it has been found that prote
68  steps that replace several C-H bonds with C-metal bonds, desorb H atoms (H*) from saturated surfaces
69                     We report a stable metal-metal bonded diruthenium complex that spontaneously prod
70    The Mn-Cr complex has an ultrashort metal-metal bond distance of 1.82 A, which is consistent with
71                          Regarding the metal-metal bond distances, we make use of the formal shortnes
72 nce of incorporating an additional adsorbate-metal bonding effect in the calculation is demonstrated
73 that the diiron system has delocalized metal-metal bonding electrons, which seems to correlate with a
74 ddition to metal to forge the initial carbon-metal bond followed by redox-promoted alpha-elimination
75 w set of stable NC sizes with simpler ligand-metal bonding for researchers to explore both experiment
76 ort real-time dynamics of photoinduced metal-metal bond formation acquired from ultrafast time-resolv
77 n halide loss, ligand compression, and metal-metal bond formation to yield a 48-electron Co(I)(3) clu
78 to involve the NHC's ability to induce metal-metal bond formation.
79 rH(2)(Cp*)}] 1, featuring a very short metal-metal bond, has been isolated through an original alkane
80  complexes containing short uranium-group 10 metal bonds have been prepared from monometallic IU(IV)(
81                     Superatoms feature metal-metal bonding; hence, since their discovery 40 years ago
82    As a result the very nature of the carbon-metal bond in the Ni(I)-CO adduct and the molecular back
83 de a multireference description of the metal-metal bond in the simple dimers MeMMMe and PhMMPh (M = C
84 ng conceptual advances in the field of metal-metal bonding in clusters.
85 port for the oxide layer theory of porcelain-metal bonding in dental alloy systems.
86 e elucidation of the mechanism for porcelain-metal bonding in dental systems, because a test capable
87 le experimental tool in the studies of metal-metal bonding in endohedral metallofullerenes and in end
88 als, the semicore p orbitals engage in metal-metal bonding in the B2 phase, facilitating the pressure
89           Here, we study the nature of metal-metal bonding in the ThCr(2)Si(2) structure type by prob
90 ional synergy elucidates the nature of metal-metal bonding in U(2) and U(2)(-).
91  the authenticity of covalent actinide metal-metal bonds in a stable compound and deepens our fundame
92                         Finally, three metal-metal bonds in experimentally characterized compounds ar
93 formation of new species containing actinide-metal bonds in good yields (Th: 6; U: 7); this photolysi
94 fluorine atom significantly alters the metal-metal bonding interactions of Th-Th and Ca-Sc.
95 s for the fundamental understanding of metal-metal bonding interactions.
96 f 4 were performed to characterize the metal-metal bonding interactions; the results indicate a dativ
97                          Understanding metal-metal bonding involving f-block elements has been a chal
98 bridging carbonyl and formation of the metal-metal bond is accompanied by coordination of a phosphine
99 inide-actinide (Th-Th) single electron metal-metal bond is formed inside Th(2)F@I(h)(7)-C(80) upon th
100 nyl and electron-donating ligands, the metal-metal bond is the highest occupied molecular orbital (HO
101                                        Metal-metal bonding is a distinct feature of some refractory m
102                                        Metal-metal bonding is a widely studied area of chemistry(1-3)
103 l aspects of metal-metal bonding, lanthanide-metal bonding is limited to interactions between lanthan
104                                        Metal-metal bonding is used to explain such 'abnormal' behavio
105                         Protonation at metal-metal bonds is of fundamental interest in the context of
106 derstanding the fundamental aspects of metal-metal bonding, lanthanide-metal bonding is limited to in
107 udy reveals the origin of the observed metal-metal bond length disorder, distinctively different for
108                  Furthermore, the average As-metal bond length of the KMnO(4) solids (R(As-Fe/Mn) = 3
109 well as static and dynamic disorder in metal-metal bond lengths can be obtained.
110 dral geometry and essentially bulklike metal-metal bond lengths, even for the smallest (few atom) nan
111 addition, ion-pairing interactions and metal-metal bonding may have a dramatic influence on metalate
112 Samples of 3c enriched in (13)C (99%) at the metal-bonded methyl sites were also prepared and investi
113 ther at a single site (Al) or across a metal-metal bond (Mg-Mg).
114 ound containing triangular clusters of metal-metal bonded Mo atoms, is studied as a potential anode m
115 ation where each compound contains two metal-metal bonded Mo(2)(n+) units linked by a dimethyloxamida
116 eterometallic compounds with a linear, metal-metal-bonded Mo[Formula: see text]Mo-Co chain.
117  that fluorine doping can induce novel metal-metal bonding motifs leading to potentially intriguing m
118 n-bonded network formation and reduced water-metal bonding observed on Pd relative to Ru.
119                       In this case, no metal-metal bonding occurs and, for the first time, IVCT in a
120        H(2) adds reversibly across the metal-metal bond of [(BDI)Ga(H)-Zn(tmeda)(thf)][BAr(4) (F) ] (
121           The electronic structure and metal-metal bonding of 2, 6, 8, and 9 are explored through com
122  group into one of the hydride-bridged metal-metal bonds of 8.
123 ble of detecting differences among porcelain-metal bonds of various qualities is required before the
124 alculations revealed that, indeed, the metal-metal bonding orbitals in the diiron complex are much mo
125 ism in 1, 2, and 3 are attributed to a metal-metal bond order of unity along with a 1a(2)1e(4) electr
126                    (ii) Histidine tautomeric metal bonding patterns in ligating zinc ions are mixed.
127                                        Metal-metal bonds play a vital role in stabilizing key interme
128 cluster compound, those with direct metal-to-metal bonding, previously known as homogeneous molecular
129 rategies that convert inert C-H bonds into C-metal bonds prior to C-C bond formation.
130  the singlet ground state, suppressing metal-metal bond reformation and favoring photoisomerization.
131 s are considered for polymer-metal and metal-metal bonding, respectively.
132 ydrogenation steps, which replace C-H with C-metal bonds, resulting in strong inhibition by H2, also
133  also provides a new approach to probe metal-metal bonding; results for Mn2(CO)10 are provided as an
134                  Unexpectedly, the two metal-metal bonded rhodium centers are capable of engaging in
135               Absolute configurations of the metal-bonded stereocenters in the diastereomerically enr
136 egular TcO6 octahedra and diminish the metal-metal bond strength compared with closely related oxides
137             The data show a trend in uranium-metal bond strength that decreases from 3-Ni down to 3-P
138 tural conformation of natural biopolymers in metal bond strength.
139 ing TcBr(6) octahedra with no apparent metal-metal bond (Tc-Tc = 3.7914(4) A).
140 dination complexes with heterometallic metal-metal bonds that are paramagnetic.
141 isolated in all three cases, have long metal-metal bonds that are unsupported by bridging ligands, th
142 p 14 metal atoms linked by unsupported metal-metal bonds that exploits hemilabile ligands to generate
143 rbital-selective formation of covalent metal-metal bonds that leads to an "exclusion" of correspondin
144                        In the field of metal-metal bonding, the occurrence of stable, multiple bonds
145 en crystallized by exploiting favorable soft-metal bonding to the sulfur of NCS.
146 t have been used for the formation of carbon-metal bonds to electrode surfaces for analyses of single
147 ar covalent actinide double and triple metal-metal bonds under normal experimental conditions has bee
148 ation [Co2Cp2(CO)4] +, 2+, which has a metal-metal bond unsupported by bridging ligands.
149  two d(10) centers so as to deem it a "metal-metal bond" vis-a-vis "metallophilic interaction." Densi
150                                   This metal-metal bond, which minimizes spin density at Ni(1+), is c
151              This strain also weakens the CO-metal bond, which will reduce the energy barrier for cat
152 lic distances that are consistent with metal-metal bonding, while the cobalt centers in Pn*2Co2 (4) e

 
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