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1  a trityl radical (tris( p- tert-butylphenyl)methyl radical).
2  a pyramidal C(3v) anion to the planar D(3h) methyl radical.
3 Me scission of the alkoxy radicals to form a methyl radical.
4 gmented to give the (2,2-diphenylcyclopropyl)methyl radical.
5 ore sensitive in detecting the production of methyl radical.
6 para-positions of tris(2,4,6-trichlorophenyl)methyl radical.
7 e methyl ligand can be better described as a methyl radical.
8 atter undergoing decarboxylation to generate methyl radicals.
9 a a mechanism that involves the formation of methyl radicals.
10 s the reaction, as evidenced by the detected methyl radicals.
11 kel-mediated cross-coupling of substrate and methyl radicals.
12 aved by the iron oxide-mediated formation of methyl radicals.
13 anticipated trends: 0 <or= F(C) <or= 0.3 for methyl radical, 0.4 for ethyl radical, 0.57 for n-propyl
14 on the reactivity of the 5-(2'-deoxyuridinyl)methyl radical (1) and 5-(2'-deoxycytidinyl)methyl radic
15                        A 5-(2'-Deoxyuridinyl)methyl radical (1) was independently generated from thre
16 nyl radical (3) and 2-methylenecyclopentyl-1-methyl radical (1) were measured using the PTOC-thiol co
17 hotolysis of 2 generates 5-(2'-deoxyuridinyl)methyl radical (1), the reactive intermediate that resul
18 )methyl radical (1) and 5-(2'-deoxycytidinyl)methyl radical (2) was studied.
19 tic studies indicate that HAT is mediated by methyl radical-a previously unexplored HAT agent with di
20  This study explores the fundamental case of methyl radical addition reaction (MRAR) to monosubstitut
21 ne strongly lowers the activation energy for methyl radical addition.
22 ine coupling constants similar to the 4-POBN/methyl radical adduct found in aqueous solution.
23 ttacked by the hydroxyl radical to produce a methyl radical; administration of CsA with [(12)C]DMSO p
24 mation and its subsequent decomposition into methyl radical and a free electron may hold important co
25 ection of two new stratospheric species, the methyl radical and diacetylene, gaseous species present
26 a (Tp*)Ni(II)(acac) cocatalyst that captures methyl radical and engages in concurrent outer-sphere S(
27 22 nm(-2)) that photolytically dissociate to methyl radicals and n-doped nanocrystals.
28 al preference for loss of aryl radicals over methyl radicals and that the selectivity for aryl vs met
29 ysis of CpW(CO)3Me has been shown to produce methyl radicals and to cleave DNA in a single-stranded m
30 dependent generation of 5-(2'-deoxycytidinyl)methyl radical, and our results demonstrate that this ra
31  to provide the 4-boryl-2(5H)-furanone and a methyl radical; and 4) hydrogen abstraction from the NHC
32 h 3(@crypt) leads to the formation of a free methyl radical, as shown by EPR reaction trapping.
33                          Consistent with the methyl radical-based mechanism, there was no evidence fo
34                               If a source of methyl radicals can be established, then the selective o
35 ), we explored the gas-phase reaction of the methyl radical (CH(3)(*)) with the aromatic and resonanc
36 rface (AWI) of microdroplets to generate the methyl radical (CH(3).).
37 st direct experimental evidence of gas-phase methyl radicals (CH(3) (.) ) in the ODHP reaction over b
38 l radicals (*OH), and thus activate CH(4) to methyl radicals (*CH(3)).
39 s primary product yields and elucidates that methyl radical (.CH(3)) is a common intermediate in HCN
40                                The loss of a methyl radical converts the CB(11)Me(12)(*) radical into
41 *(2)Yb(4Me,4H-bipym)PdMe(2), 5, in which the methyl radical couples with the bipym radical.
42            However, strategies that leverage methyl radical for C(sp(3)) methylation remain underdeve
43 phoxide via homolytic bond cleavage leads to methyl radical formation and finally to methane in high
44                                              Methyl radical formation was further confirmed using [(1
45 using dimethyl sulfoxide (DMSO) demonstrated methyl radical formation, revealing the production of hy
46 e uncover its crucial role as a trap for the methyl radical formed after the N-O bond cleavage of O-a
47 king it significantly less reactive than the methyl radical formed by SAM photolysis.
48                  Under anaerobic conditions, methyl radicals formed by fragmentation of the autocatal
49  thymidine methyl group, 5-(2'-deoxyuridinyl)methyl radical, forms interstrand cross-links with the o
50 ts that the iron oxide-mediated formation of methyl radicals from methyl-substituted substrates is a
51  alkyl halides (chlorides and bromides) with methyl radical generated photocatalytically from benzald
52                                   Notably, a methyl radical, generated from peroxide, was confirmed b
53  systematic DFT study (ZORA-(U)OLYP/TZ2P) on methyl radical (H(3)C(*)) additions to H(2)C=X substrate
54 e independently generated 5-(2'-deoxycytidyl)methyl radical (I) in single- and double-stranded oligod
55 N) spin-trapping experiments aimed to detect methyl radical in biological systems, the nitroxides for
56 is finding is consistent with an almost free methyl radical in the highest transition state.
57 h a single transition state by transfer of a methyl radical, in contrast to previously proposed react
58 drogen-atom reabstraction by an intermediate methyl radical is proposed.
59 adicals and that the selectivity for aryl vs methyl radical loss is dependent on the identity of the
60 vored aryl radicals remains competitive with methyl radical loss.
61 hoxybenzene anion show peaks for consecutive methyl radical losses, a feature that establishes the 1,
62 density functional theory predictions of the methyl radical mechanism.
63 trapyrrole that promotes catalysis through a methyl radical/Ni(ii)-thiolate intermediate.
64 ught to involve either methyl-nickel(III) or methyl radical/Ni(II)-thiolate intermediates.
65 f thymine and 5-methylcytosine to give the 5-methyl radical of the pyrimidine bases.
66                                          The methyl radical produced by the hydroxyl radical represen
67 ciently formed via a rapid 1-indenyl radical-methyl radical reaction.
68 nces (anti-clumping) in ethane produced from methyl radical recombination.
69 o involve a one-electron transfer, producing methyl radicals that incorporated into the GAC.
70 s on time scales ranging from <or=0.5 ns for methyl radical to 2.3 ns for adenosyl, the largest radic
71 dical is proposed to subsequently transfer a methyl radical to IB, thus launching the formation of b-
72 m solves the challenge of otherwise dominant methyl radical-triggered side reactions brought about by
73 ,6-dichlorophenyl)-bis(2,4,6-trichlorophenyl)methyl radical (TTM-Cz).
74 ith the (*)OH scavenger Me(2)SO, which forms methyl radical upon reacting with (*)OH.
75 from a substrate C-H bond or generation of a methyl radical via B-methyl scission.
76 trimethyl orthoformate serves as a source of methyl radical via beta-scission from a tertiary radical
77 ctional 2-Methoxyethanol (2ME) biofuel using methyl radical was introduced.
78  of an isolable diamino(4-diarylboryl-phenyl)methyl radical was observed.
79                                              Methyl radicals were detected during ultrasonication by
80 gible, and QT photooxidizes DMSO, generating methyl radicals which initiate the RAFT polymerization o
81 ethyl-coenzyme M (methyl-SCoM) to generate a methyl radical, which abstracts a hydrogen atom from coe
82            Hydroxyl radical oxidizes DMSO to methyl radical, which forms relatively stable nitroxides
83 nitase and xanthine/xanthine oxidase yielded methyl radical, which was detected by ESR spin trapping.
84                        Cross coupling of the methyl radical with 4-cyanopyridine installs a 4-pyridin