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1 CO(2)D gives ring-opened products as well as methylenecyclopropane.
2 ly weak allylic C-H bonds (99.3 kcal/mol) of methylenecyclopropane.
3 ine catalyst and the intrinsic reactivity of methylenecyclopropanes.
4 for the sigmatropic rearrangement of alkenyl-methylenecyclopropanes.
5 unimolecular rearrangement of 2,2-dichloro-1-methylenecyclopropane (1) to (dichloromethylene)cyclopro
6 a)-C(beta) ring cleavage reaction, 1-amino-2-methylenecyclopropane-1-carboxylic acid (2-methylene-ACC
9 atalyzed reaction of ethyl diazoacetate with methylenecyclopropane 19, obtained from 2-bromo-2-bromom
15 dipolar cycloadditions, a thermally promoted methylenecyclopropane acetal cycloaddition, and a Pd-cat
17 a and 11b derived from 2,2-bis(hydroxymethyl)methylenecyclopropane analogues 1a, 1b, 2a, and 2b were
18 - and E-stereoisomers of (1,2-dihydroxyethyl)methylenecyclopropane analogues of 2'-deoxyadenosine and
20 important for synthesis of antiviral purine methylenecyclopropane analogues of nucleosides, is also
24 hly strained spiro[2,3]hexane skeletons from methylenecyclopropanes and a broad selection of alpha,be
25 chael addition followed by ring expansion of methylenecyclopropanes and nucleophilic attack of an ena
27 lytic asymmetric synthesis of axially chiral methylenecyclopropanes by a [2 + 1]-cycloaddition of an
28 tablished for 26,27-DHZ, suggesting that the methylenecyclopropane can serve as a lead structure for
31 enhancements in a series of aryl-substituted methylenecyclopropanes correlate with sigma(+) values.
32 rine (30) with 24 + 25 afforded (Z)- and (E)-methylenecyclopropane derivatives 26 + 27 and 31 + 32.
33 cular Diels-Alder furan cycloaddition, and a methylenecyclopropane dienophile was used for a stereose
36 n intramolecular strain-promoted Diels-Alder methylenecyclopropane (IMDAMC) reaction provided a pivot
37 of 1-methylcyclopropene relative to isomeric methylenecyclopropane is ascribed to its weak ring C-H b
38 ion of a second pair of geminal fluorines to methylenecyclopropane lowers the barrier to rearrangemen
39 a new reaction of reductive isomerization of methylenecyclopropanes (MCPs) to vinylcyclopropanes (VCP
40 ntermediate, (2) the relief of strain in the methylenecyclopropane moiety provides the thermodynamic
43 thylsilylcyclopropyl alkyl ketones also gave methylenecyclopropane products derived from trimethylsil
45 ains open as to whether the silver-catalyzed methylenecyclopropane rearrangement proceeds via an arge
46 The three triazole groups all enhance the methylenecyclopropane rearrangement rate and are therefo
50 New nucleoside analogues 14-17 based on a methylenecyclopropane structure were synthesized and eva
51 ddition, and a Pd-catalyzed cycloaddition of methylenecyclopropane to an oxabicyclo[3.3.0]octenone.
53 ylthio)benzene), di- and trivinylarenes, and methylenecyclopropanes with primary amines R' 'NH(2) (R'