ライフサイエンスコーパス: mol

1 fe; peak B(T) >= 30 mg/dL and B(T) /A >= 1.0 mol:mol were equally predictive of perinatal brain injur

2 /(mol h atm) with AO incorporation up to 4.0 mol % and 1.6 mol %, respectively.

3 The reactions are promoted by 5.0 mol % of a readily available monodentate phosphoramidite

4 ol/L +/- 0.8) compared with that in NWM (8.0 mol/L +/- 0.8) in the healthy volunteers (P < .001 for b

5 Among all, 0.002 mol L(-1) SNP concentration was superior to lengthen sto

6 prusside (SNP) 0.000, 0.001, 0.002 and 0.003 mol L(-1) were investigated on pear fruit cv. Patharnakh

7 lysts, with catalyst loading as low as 0.005 mol %.

8 results in catalyst loadings as low as 0.01 mol % (100 ppm) and reaction temperatures as low as room

9 vent-free conditions with very low (0.1-0.01 mol %) catalyst loading.

10 of 800 h(-1) at low catalyst loading (0.025 mol %, 70 degrees C, 30 bar CO(2)).

11 ities for iodide (EC(50) =0.042 mum or 0.028 mol % relative to lipid), whcih is transported 10 times

12 ld of PAA under UV(254) (Phi = 0.88 +/- 0.04 mol-Einstein(-1)) was determined via simultaneously quen

13 In the presence of 0.05 mol % CdS QDs, which have an emission spectrum that over

14 d Cu(OAc)(2) as catalysts with as low as 0.1 mol % loading, providing protected alkyl, alkenyl and ar

15 tivities in the presence of as little as 0.1 mol % of a chemoselective peptidic catalyst.

16 an even with low catalyst loadings (0.01-0.1 mol %).

17 raffin impregnated graphite electrode in 0.1 mol dm(-3) HClO(4) and KNO(3) aqueous electrolytes using

18 ms of the number (n = 2) and yields (0.9-5.1 mol %) of metabolites.

19 ram scale with catalyst loadings as low as 1 mol %.

20 The catalyst loading can be as low as 1 mol%.

21 etic data point out that the bulky diol at 1 mol L(-1) in combination with 18-crown-6 is able to prod

22 vely low concentrations of catalyst (i.e., 1 mol %).

23 Using low catalyst loadings (<1 mol percent), benzene and other functionalized arenes we

24 digestion time of 14 min, concentration of 1 mol L(-1) HNO(3) and 2.5 mL of H(2)O(2).

25 es of diluted absorbing solutions (5 mL of 1 mol L(-1) HNO(3)) were possible, allowing the use of low

26 The results show that RCGs (1 mol %) were capable of hosting and catalyzing various wa

27 In aqueous solutions, 1 mol % of glycoclusters to substrates was efficient at ac

28 cts are formed in up to 93% yield using 5-10 mol % ZrCl(4).

29 AgPF(6) (10 mol %) served as the silver source, PhI=NNs as the nitre

30 (31), but not with DPPC-d(62), whereas at 10 mol% melatonin, phase separation was observed in both sa

31 The targeting liposomes containing 10 mol% GM-modified lipids increased the accumulation of th

32 ve reactions, high catalyst loadings of >=10 mol % are still common and either due to low reactivity

33 Hence, after 24 h of incubation, 10 mol % of C(12)EO(8) or 50 mol % of OG in the membrane su

34 Notably, 10 mol % Sb-doped (GeTe)(0.95)(SnSe)(0.025)(SnS)(0.025) exh

35 mployed as the sensitizer at a loading of 10 mol % in small-scale reactions and of 2.5 mol % on a lar

36 In the presence of 10 mol% of the phenylimine rhodium precatalyst and 4 atm of

37 f 462 K, in single leg TE device based on 10 mol % Sb-doped (GeTe)(0.95)(SnSe)(0.025)(SnS)(0.025).

38 nderwent smoothly in the presence of only 10 mol % organocatalyst, the intra-molecular C-H arylation

39 lines to PIFA and trifluoroacetic acid or 10 mol % Sc(OTf)(3) triggers nitrenoid formation, followed

40 Subsequently, 10 mol % Sb-doped (GeTe)(0.95)(SnSe)(0.025)(SnS)(0.025) exh

41 (2+) binding to SLBs containing more than 10 mol % PS induces extensive reordering of the bilayer.

42 An increase to 10 mol% of the modified lipid resulted in further enhanceme

43 ed at ambient conditions by alloying with 10 mol % AgBiSe(2).

44 (f) = B(3,5-C(6)H(3)(CF(3))(2))(4)]; 1.0-100 mol % loadings, avg 32.6% (X = Cl) or 14.0% (X = I) for

45 a new 2TfO(-)B(C(6)F(5))(4)(-) salt (1.1-100 mol % loadings; avg 31.0% for 24 common analytes), inclu

46 Only 0.62-100 mol % loadings are required (avg 14.5 or 11.6% for 24 an

47 er from TMSCF(3) (1), mediated by TBAT (2-12 mol %) or by NaI (5-20 mol %), has been investigated by

48 we assess abiotic H(2) sources (~6 x 10(12) mol H(2)/y) and sinks (~4 x 10(12) mol H(2)/y) and then

49 x 10(12) mol H(2)/y) and sinks (~4 x 10(12) mol H(2)/y) and then attribute the net difference (~2 x

50 en attribute the net difference (~2 x 10(12) mol H(2)/y) to microbial consumption in order to balance

51 es higher than its kernel) and pistachio (13 mol/kg, 630 times higher) makes them good candidates to

52 ugar alcohols in (0.01, 0.05, 0.09 and 0.13) mol kg(-1) nicotinic acid((aq)) (vitamin B3) solutions h

53 trite (from 1.15 x 10(-14) to 4.94 x 10(-13) mol m(-2) s(-1)).

54 ereas leakage remains below 10% for up to 14 mol % of C(12)EO(8) and 88 mol % of OG.

55 mple addition, enabling detection of 10(-14) mol of ATP within 10 min.

56 -16) mol/L, K(a, allicin) = 5.0227 x 10(-15) mol/L, K(a, sanshool) = 1.7832 x 10(-15) mol/L.

57 15) mol/L, K(a, sanshool) = 1.7832 x 10(-15) mol/L.

58 per, were K(a, capsaicin) = 3.5206 x 10(-16) mol/L, K(a, allicin) = 5.0227 x 10(-15) mol/L, K(a, sans

59 .28 or 0.74 mol/kg fructose and 0.17 or 0.19 mol/kg lactose with an enzymatic activity of 2.0 or 2.8

60 evels (up to 97% ee) at an unusually low 0.2 mol % catalyst loading.

61 in toluene, with catalyst loadings 0.05-0.2 mol %, without additives.

62 ination conditions are mild, requiring 0.1-2 mol% catalyst loading and operational at room temperatur

63 ower mean UTE measure was found in NAWM (7.2 mol/L +/- 0.8) compared with that in NWM (8.0 mol/L +/-

64 >= 60 degrees C), low catalyst loadings (>=2 mol%), and innocuous terminal reductants (polymethylhydr

65 unts of tris(pentafluorophenyl)borane (10-20 mol %) are employed to afford the C=C coupled products (

66 ediated by TBAT (2-12 mol %) or by NaI (5-20 mol %), has been investigated by in situ/stopped-flow (1

67 nsted acids or substoichiometric amounts (20 mol %) of Lewis acids is attributed to the close proximi

68 rge asymmetry of bacterial membranes with 20 mol % of 1-palmitoyl-2-oleoyl-sn-glycero-3-phospho-rac-g

69 rations, corresponding to zeptomole (10(-21) mol) amounts encapsulated in individual droplets.

70 olic-rich extracts prepared form walnut (255 mol/kg Trolox, measured by DPPH, 1500 times higher than

71 optimal conditions revealed to be pH 7.3/0.3 mol.L(-1) NaCl yielded 46.83% and 59.16% of total protei

72 zed by the [Ru(p-cymene)Cl(2)](2) complex (3 mol %) and exhibited a broad reaction scope with differe

73 RE-NMR spectroscopy as 0.056 +/- 0.003 dm(3) mol(-1) s(-1) at 298 K and is comparable to that determi

74 thermal (1)H NMR (k = 0.050 +/- 0.003 dm(3) mol(-1) s(-1)) and UV measurements (k = 0.053 +/- 0.001

75 d UV measurements (k = 0.053 +/- 0.001 dm(3) mol(-1) s(-1)).

76 0.3) x 10(-7) mol m(-2) and 420 +/- 30 m(3) mol(-1), respectively.

77 alt concentration were -31.6 and -34.4 cm(3)/mol, respectively, indicating a higher rigidity of Tg.

78 ectrolyte at a superhigh concentration of 31 mol kg(-1) exhibits a wide electrochemical window of 3.3

79 very small amount of PdCl(2)(PPh(3))(2) (0.4 mol %) as a catalytic precursor and without the need for

80 ion reactions catalyzed by [Ir(cod)Cl](2) (4 mol %) to provide 2-substituted indoles (up to 70% yield

81 y compounds have been recorded in 1 x 10(-4) mol kg(-1) nicotinic acid((aq)) solutions.

82 the concentration ranges: 5.10(-6)-1.10(-4) mol L(-1) by HPLC-UV and 1.10(-7)-5.10(-5) mol L(-1) by

83 ing a 3.5 x 10(-5) mol L(-1) to 8.0 x 10(-4) mol L(-1) linear range with a limit of detection of 5.1

84 In a range as wide as 5 x 10(-7)-1 x 10(-4) mol L(-1), a linear relationship is well established, an

85 ied from the attenuation data was 3 x 10(-4) mol/m(2)s and decreased to 3 x 10(-5) mol/m(2)s after 24

86 -H arylation catalytic system composed of 40 mol % each of the catalyst and the additive (4-dimethyla

87 mates indicate the GoM open (- 0.06 +/- 0.45 mol C m(-2) year(-1)) and coastal (- 0.03 +/- 1.83 mol C

88 s with 82% yield for the Heck product at 0.5 mol % loading of Pd catalyst; no product forms at this l

89 han 2 h with very low palladium loading (0.5 mol %).

90 ct of pH (6-9) and NaCl concentration (0-0.5 mol.L(-1)) on sunflower protein extraction was studied t

91 10 mol % in small-scale reactions and of 2.5 mol % on a larger scale.

92 ectivity (47; 29), and uptake capacity (>2.5 mol(alkene) mol(-1) (Cu3) ).

93 The methodology utilizes 0.5-5 mol % TMPhen-nickel as the catalyst, which, when activat

94 to 60 h(-1), affording full conversion at 5 mol% catalyst loading in approximately 20 min with these

95 At 5 mol% melatonin, we observed phase separation in samples

96 catalyzed by a few dirhodium carboxylates (5 mol %) under a balloon pressure of oxygen.

97 Targeting liposomes containing 5 mol% GM-modified lipids enhanced the uptake of the probe

98 ess proceeds with DABSO in the presence of 5 mol % RuCl(2)(PPh(3))(3) in methanol at 100 degrees C.

99 sing CuI and low catalyst loading (down to 5 mol %).

100 ) mol L(-1) by HPLC-UV and 1.10(-7)-5.10(-5) mol L(-1) by GC-MS techniques.

101 tric measurements, displaying a 3.5 x 10(-5) mol L(-1) to 8.0 x 10(-4) mol L(-1) linear range with a

102 10(-4) mol/m(2)s and decreased to 3 x 10(-5) mol/m(2)s after 24 h because of increasing diffusion lim

103 composed of DPPC: DSPC: DSPE-PEG2K (85:10:5, mol%) with 100 mM FeSO(4) as the trapping agent inside.

104 of incubation, 10 mol % of C(12)EO(8) or 50 mol % of OG in the membrane suffice for virtually comple

105 nd highest C(2) H(2) -capture amount of 4.54 mol L(-1) , thus outperforming most previous benchmark m

106 Samples with at least 0.56 mol of CO(2) per mol of ZIF-8 display a large, broad ano

107 ith AO incorporation up to 4.0 mol % and 1.6 mol %, respectively.

108 SCB in an ethylene-hexene copolymer (EH, 3.6 mol % H) in 3.5 min with 0.5 mug of sample.

109 loaded in the supported bilayers with ~0.6% mol/mol (protein/lipid) concentration corresponding to 3

110 ge with a limit of detection of 5.1 x 10(-6) mol L(-1).

111 composite sorption capacities of up to 0.62 mol CO(2) kg(-1) and recorded breakthrough curves in a f

112 for As, Cd, Hg and Pb, respectively, when 7 mol L(-1) HNO(3) was used as the absorbing solution.

113 were determined to be (9.1 +/- 0.3) x 10(-7) mol m(-2) and 420 +/- 30 m(3) mol(-1), respectively.

114 eated with 10(-8) mol/L estradiol +/- 10(-7) mol/L medroxyprogesterone acetate (MPA) +/- 1 IU/mL thro

115 of lactulose was determined as 1.28 or 0.74 mol/kg fructose and 0.17 or 0.19 mol/kg lactose with an

116 n 10 days to PFOA/PFOS at yields of 3.4-20.8 mol % by day 21 and several infrequently reported PFAS s

117 proton density was found in MS lesions (3.8 mol/L +/- 1.5), and a slightly lower mean UTE measure wa

118 aPAA hydrogels having 60% ionization and 4.8 mol % N',N'-methylenebisacrylamide as the cross-linker r

119 OD, S/N = 3) is well defined as 4.7 x 10(-8) mol L(-1).

120 ll (TDC) monolayers were treated with 10(-8) mol/L estradiol +/- 10(-7) mol/L medroxyprogesterone ace

121 At a molar loading of 5.93x10(-8) mol cm(-2) , it exhibits a Faradaic efficiency of 96 % a

122 m(-2) year(-1)) and coastal (- 0.03 +/- 1.83 mol C m(-2) year(-1)) ocean are approximately neutral in

123 10% for up to 14 mol % of C(12)EO(8) and 88 mol % of OG.

124 oped NMC (NMCAM) of identical Ni content (89 mol%) synthesized in-house.

125 concentration of redox moiety (2.92 x 10(-9) mol cm(-2)) and heterogeneous electron transfer rate con

126 ruits endophilin to membranes composed of 95 mol% of zwitterionic lipids via the SH3 domain.

127 presented for samples containing up to 0.99 mol of CO(2) per mol of ZIF-8.

128 ; 29), and uptake capacity (>2.5 mol(alkene) mol(-1) (Cu3) ).

129 We identified the ratio of 0.10 umol heme b mol(-1) POC as the cut-off between heme b replete and he

130 exhibited a mean value of 0.44 mumol heme b mol(-1) POC.

131 m); ratio of radioactivity to total mass; Bq/mol) of a radiotracer dose and the time-course of carrie

132 s free energy of unfolding of g(nu) ~100 cal/mol per amino acid.

133 +/- 0.5 kcal/mol; DeltaS*= -24.3 +/- 1.7 cal/mol.K) were measured using Eyring analysis, implying a h

134 flavonoids with molecular mass of 250-320 g/mol have high potential of anticholinesterase activities

135 cyclic siloxanes (molecular weight 162-410 g/mol) as PISTOL-based oxygen reporters by characterizing

136 nker, and PEG length between 1000 and 5000 g/mol.

137 thylene with M(n) values up to 4.1 x 10(6) g/mol.

138 ighest molar mass reported to date (~10(9) g/mol).

139 (-11.74 kJ/mol) andDeltaS degrees (-8.08 J/K.mol) led to the most excellent stability at 100 degrees

140 by overcoming a barrier of 0.28+/-0.02 kcal mol(-1) .

141 (eta(5)-C(5)Me(5))Rh((Me)PhI)H and 51.1 kcal mol(-1) for (eta(5)-C(5)Me(5))Rh(ppy)H.

142 n unsigned errors are 2.3, 1.7, and 2.1 kcal mol(-1).

143 on of alkoxyl radicals are as low as 13 kcal mol(-1).

144 ns the NH...pai interactions from 12-15 kcal mol(-1) in "naked" cations to 5-9 kcal mol(-1) in the sa

145 iplicity with a binding energy of -3.20 kcal mol(-1) has been computed at the UCCSD(T)-F12a/aug-cc-pV

146 rgy (BDFE(C-H) ~ 29 kcal mol(-1) and 25 kcal mol(-1), respectively) cf. BDFE(Fe-H) of 56 kcal mol(-1)

147 taG) to ring inversion calculated at 27 kcal mol(-1) .

148 issociation free energy (BDFE(C-H) ~ 29 kcal mol(-1) and 25 kcal mol(-1), respectively) cf. BDFE(Fe-H

149 4-didehydropyridine (PA = 213.4 +/- 3.3 kcal mol(-1)) even though the latter biradical has one radica

150 pyridine has a larger PA (215.3 +/- 3.3 kcal mol(-1)) than 3,4-didehydropyridine (PA = 213.4 +/- 3.3

151 fast (80 ms) and strong (-10.1 +/- 0.3 kcal mol-1).

152 s so that PA magnitudes higher than 300 kcal mol(-1) are now feasible for nonphosphorous neutral orga

153 ents the lowest absorption energy (-363 kcal mol(-1)) and largest contact area (4034.1 angstrom(2)).

154 nglet-triplet splitting by +4.5 +/- 0.4 kcal mol(-1) from ortho-benzyne.

155 olar (40.7 kcal mol(-1)) to polar (47.4 kcal mol(-1)).

156 tives are computed to be higher than 50 kcal mol(-1), while the barriers for the formation of alkoxyl

157 -1), respectively) cf. BDFE(Fe-H) of 56 kcal mol(-1) for [Fe(III)(eta(5)-Cp*)(dppe)H](+).

158 quivocally show that it is simply the 6 kcal mol(-1) higher proton affinity of F(-) that enables this

159 ormation were -12.36, -8.10, and -10.61 kcal mol(-1), respectively.

160 ifferences DeltaDeltaG(293 K) up to 0.7 kcal mol(-1) between diastereoisomeric complexes, is explaine

161 ions reveals that the cis isomer is 0.7 kcal mol(-1) more stable than the trans isomer.

162 (30) values ranging from nonpolar (40.7 kcal mol(-1)) to polar (47.4 kcal mol(-1)).

163 bond dissociation free energies of 51.8 kcal mol(-1) for (eta(5)-C(5)Me(5))Rh((Me)PhI)H and 51.1 kcal

164 possesses a low activation energy (10.8 kcal mol(-1)) and a high turnover frequency (483 and 1336 hr(

165 kcal mol(-1) in "naked" cations to 5-9 kcal mol(-1) in the salts.

166 tal guest binding affinities (MAD = 1.9 kcal mol(-1)) and identify the catalytic Diels-Alder proficie

167 tum chemical accuracy (errors below 1 kcal . mol(-1)) on test data.

168 for many molecules are limited to 2-3 kcal . mol(-1) with presently-available functionals.

169 energy barrier for phosphorolysis by 10 kcal.mol(-1).

170 latively low-stability dispersion (<1.2 kcal.mol(-1)).

171 that has a free-energy barrier of 6.65 kcal.mol(-1).

172 tion of the energy of activation of 6.9 kcal.mol(-1), which is not sufficient for the reaction to tak

173 associative interactions (DeltaG ~ -1.0 kcal/mol) have limited their use in aqueous self-assembly to

174 ) and the wild type (WT) mADA (Ea = 5.0 kcal/mol) were selected for HDX-MS experiments.

175 ues with standard error of roughly 0.05 kcal/mol.

176 .5 kcal/mol for Pd(2)(II,III) and <-9.1 kcal/mol for Pd(III)(2).

177 on (HAA) of strong C-H bonds (BDE ~ 100 kcal/mol).

178 /mol and root mean square error of 1.11 kcal/mol, comparable with the accuracy of previously publishe

179 state was determined to lie ~0.5 eV (12 kcal/mol) above the ground state.

180 metric transition state (TS) (E(a) = 17 kcal/mol).

181 terfacial stabilization by -1.3 +/- 0.2 kcal/mol is observed experimentally, in good agreement with o

182 nsertion in these complexes is ca. 19.2 kcal/mol.

183 f o-alkylphenyl ketones in excess of 20 kcal/mol when the solvent is methanol and by over 30 kcal/mol

184 rnal field has effects of ca. 10 and 20 kcal/mol, respectively.

185 igh gas-phase proton affinity (PA = 258 kcal/mol), and a preference for electron-poor alkenes.

186 nation of N(2) with a barrier of ca. 26 kcal/mol.

187 tion strength for the -CF(2)H group (~3 kcal/mol).

188 activation energy barriers of ~10 +/- 3 kcal/mol.

189 the solvent is methanol and by over 30 kcal/mol for [EMIM][BF(4)].

190 The strain energy of ca. 30 kcal/mol was predicted for the latter compound, which was hig

191 e pairs yielded an overall RMSD of 0.32 kcal/mol when compared with experimentally derived parameters

192 LCT) state with an energy of 1.6 eV (38 kcal/mol).

193 an root mean square error of about 0.4 kcal/mol for most methods.

194 ctive gamma-arylation is favored by 3.4 kcal/mol, and both findings are in agreement with the reporte

195 a total solvation energy gain of -35.4 kcal/mol.

196 mide 40 with an activation energy of 43 kcal/mol.

197 t-triplet energy gap (DeltaE(S-T) = -45 kcal/mol), a high gas-phase proton affinity (PA = 258 kcal/mo

198 free energy of Pd dimerization as <-4.5 kcal/mol for Pd(2)(II,III) and <-9.1 kcal/mol for Pd(III)(2).

199 ethylpiperdine-N-hydroxide, BDFE = 66.5 kcal/mol in THF), forming the hydroperoxide species HP and TE

200 hydride addition to the si-face is 1.5 kcal/mol lower than that to the re-face, with a predicted ee

201 an elevated activation energy (Ea = 7.5 kcal/mol) and the wild type (WT) mADA (Ea = 5.0 kcal/mol) wer

202 ractions, each with large energies (3-5 kcal/mol).

203 de species HP was calculated to be 73.5 kcal/mol, employing the thermodynamic square scheme and Bordw

204 tion parameters (DeltaH* = 13.4 +/- 0.5 kcal/mol; DeltaS*= -24.3 +/- 1.7 cal/mol.K) were measured usi

205 he more substituted alpha-carbon is 3.6 kcal/mol lower than that to the beta-carbon, thus favoring th

206 um albumin ranged from -7.30 and -10.62 kcal/mol.

207 oronate complexes (strain energy ca. 65 kcal/mol), which were prepared by reacting boronic esters wit

208 re exceptionally high at 103.4 and 91.7 kcal/mol, respectively, which are the highest condensed phase

209 was experimentally estimated to be 18.7 kcal/mol.

210 s and the t-butyl group amounts to 10.8 kcal/mol in the gas phase.

211 erting a small stem-loop (DeltaG = -4.8 kcal/mol) in the middle of the mRNA 5' untranslated region (U

212 ies, with a mean unsigned error of 0.86 kcal/mol and root mean square error of 1.11 kcal/mol, compara

213 able to cleave sp(3) C-H bonds up to 87 kcal/mol to afford rate constants and kinetic isotope effects

214 1 with a root-mean-square-error of 1.93 kcal/mol, which was significantly better than the other metho

215 inyl ethers) of molar masses exceeding 50 kg mol(-1) can be produced within 1 h without elaborate rea

216 s, 0.2% carboxymethyl cellulose (CMC) 700 kg mol(-1) as the dispersing agent, probe sonication for 1

217 able compositions, molar mass (from 38-71 kg mol(-1)), and forms dihydroxyl telechelic chains.

218 ues were determined to be 45.9 x 10(3) kJ/kg-mol and 18125.95 min(-1), respectively using the Arrheni

219 is, resulting in production of only 10-13 kg/mol polymers.

220 25 degrees C are as high as 4208 and 535 kg/(mol h atm) with AO incorporation up to 4.0 mol % and 1.6

221 or a model compound in the vacuum: 90-100 kJ mol(-1) ).

222 hase reaction is decreased by 162 and 140 kJ mol(-1) according to calculations done with the SMD and

223 upling low heat of adsorption (-10 to -17 kJ mol(-1) (alkene) ), high alkene:alkane selectivity (47;

224 ing the hydrogen bond is found to be 6-20 kJ mol(-1) .

225 kJ mol(-1); [Formula: see text] = -32.22 kJ mol(-1); [Formula: see text] = -31.84 kJ mol(-1)).

226 cm(-1) and a low activation energy of 29 kJ mol(-1) as determined by impedance spectroscopy.

227 with a low reaction-energy barrier (47.3 kJ mol(-1) ).

228 ter 2.347 angstrom Zn-Zn bond in the 37.4 kJ mol(-1) higher energy isocyanide CNZnZnNC, and a longer

229 ectrochemical energy consumption of 155.4 kJ mol(-1) or 0.98 kWh kg(-1) of CO(2) and a CO(2) capture

230 or binding ( [Formula: see text] = -33.42 kJ mol(-1); [Formula: see text] = -32.22 kJ mol(-1); [Formu

231 nate formation: DeltaG(*) = +92.6 +/- 2.5 kJ mol(-1).

232 ergonic ( DeltaG (r) <0), yielding ~30-50 kJ mol(-1) .

233 , with an activation energy as high as 63 kJ mol(-1) in DMSO-d(6) solution (DFT prediction for a mode

234 ibiting an overall activation energy of 7 kJ mol(-1), which was estimated in vacuum at the B3LYP/6-31

235 adsorption enthalpy (DeltaH(ads)) of +71 kJ mol(-1).

236 rs the fragmentation barrier by around 80 kJ mol(-1) in the gas phase, while a negative charge has a

237 kJ mol(-1); [Formula: see text] = -31.84 kJ mol(-1)).

238 y (873 kJ mol(-1)) compared to NH(3) (854 kJ mol(-1)).

239 ecause of its higher proton affinity (873 kJ mol(-1)) compared to NH(3) (854 kJ mol(-1)).

240 n1)(*)~54.14,DeltaG(dHSA-RESAn1)(*)~73.97 KJ mol(-1)).

241 the stable complex ( [Formula: see text] KJ mol(-1)), and the rate of association was faster than th

242 [Formula: see text] , [Formula: see text] KJ mol(-1)).

243 that a minimum energy consumption of 164 kJ.mol(-1) CO(2) could be achieved.

244 The frameworks exhibit a significant (30 kJ.mol(-1)) variation in the enthalpy of formation dependin

245 reatinine, and glutamine was 72.2 +/- 0.4 kJ.mol(-1).

246 degrees values of 0.64, 56.55, and -10.00 kJ/mol, respectively.

247 The 9 and 14 kJ/mol magnitudes of the effects for 3HB6H and HPAH-C(2), r

248 required to phosphorylate organics is ~15 kJ/mol, requiring either very low water activities or react

249 vation energies in the range of 96 +/- 19 kJ/mol are determined, with Pt leading to the lowest energy

250 (DeltaG = -39.7 +/- 0.1 to -43.2 +/- 0.2 kJ/mol) between 14 and 43 degrees C.

251 ansitions in A(1)R-G279S(7.44) (73 +/- 23 kJ/mol) than in wild-type A(1)R (135 +/- 4 kJ/mol) or in A(

252 /mol) or in A(1)R-Y288A(7.53) (184 +/- 24 kJ/mol).

253 ng site with a binding free energy of -24 kJ/mol.

254 tivation directly at the MSI (E(app) ~ 25 kJ/mol) and significantly slower heterolytic H(2) activatio

255 ulated to be Delta(vap)H = 91.27 +/- 0.28 kJ/mol compared to Delta(vap)H(corr) = 91.44 kJ/mol for the

256 tion for alpha + beta carotene (E(a) = 29 kJ/mol).

257 C and intrinsic stability DeltaGu = 24.3 kJ/mol) and a sub-optimal immunogenicity profile.

258 sin was exothermic (DeltaH = -6.3 +/- 1.3 kJ/mol) and spontaneous (DeltaG = -39.7 +/- 0.1 to -43.2 +/

259 mol) and deactivation (E(D) = 62.23 +/- 3 kJ/mol) energies of hydrolysis.

260 better protection to vitamin E (E(a) = 36 kJ/mol), whereas SD-M provided better protection for alpha

261 e isosteric heat of adsorption (21.9-30.4 kJ/mol) for these CPMs is as low as about one-third of that

262 J/mol) than in wild-type A(1)R (135 +/- 4 kJ/mol) or in A(1)R-Y288A(7.53) (184 +/- 24 kJ/mol).

263 with an activation energy of 81.1 +/- 1.4 kJ/mol.

264 raction raises the energy barrier from 42 kJ/mol for unsubstituted DBCOD to 68 kJ/mol for diamide-sub

265 ation requires an activation energy of 42 kJ/mol, which is substantially lower than those of existing

266 mol compared to Delta(vap)H(corr) = 91.44 kJ/mol for the reference correlation.

267 activation mediated by water (E(app) ~ 45 kJ/mol).

268 t]) was found to be in the range of 45~49 kJ/mol, which was about 20% larger than that between the wa

269 of the barrier to unfolding in G37R by >5 kJ/mol(-1) over the other variants, consistent with expecta

270 C and intrinsic stability DeltaGu = 63.5 kJ/mol).

271 respectively 38.2, 24.7, 38.0, 38.2, 41.5 kJ/mol.

272 ssociation free energies that are over 50 kJ/mol below those of their keto equivalents.

273 and with an activation energy of about 50 kJ/mol.

274 dative stability (activation energy 105.6 kJ/mol).

275 m 42 kJ/mol for unsubstituted DBCOD to 68 kJ/mol for diamide-substituted DBCOD.

276 tion of the activation (E(A) = 50.3 +/- 7 kJ/mol) and deactivation (E(D) = 62.23 +/- 3 kJ/mol) energi

277 negative values ofDeltaH degrees (-11.74 kJ/mol) andDeltaS degrees (-8.08 J/K.mol) led to the most e

278 -third of that for peroxo-MOF-74-Fe (66.8 kJ/mol).

279 6 mJ/m(2) and E(a) was quantified as 32.8 kJ/mol.

280 e Delta(soil-air)U values were 328 and 90 kJ/mol for chlorpyrifos in the absence and presence of form

281 Up to 92 kJ/mol of thermal energy was stored in the compounds, demon

282 The binding constant (10(4) L mol(-1)), complex stoichiometry (1:1), and thermodynamic

283 r the macrocycle-monomer complex (K = 10.5 L mol(-1)) is much larger than for other comparable haloge

284 ) and an affinity constant of 9.85 . 10(6) L mol(-1).

285 ns from normally cultured cells was 1.1 mmol/mol tyrosine and decreased significantly in the presence

286 rranean diet (-0.8 mmol/mol; -1.2, -0.4 mmol/mol).

287 35 U/mL) in 54.1%, and serum HbA1c > 48 mmol/mol in 94.3% of the individuals.

288 lobin greater than or equal to 6.5% (48 mmol/mol) (odds ratio = 1.08 per 0.1 stress hyperglycemia rat

289 ple with type 2 diabetes (HbA(1c) >= 48 mmol/mol) at 2 hospital sites in Dublin between October 15th,

290 ol/L, glycated haemoglobin (HbA1c) <=53 mmol/mol (<=7.0%), systolic blood pressure <140mm Hg, or <130

291 ent within 12 months of HbA1c >7.5% [58 mmol/mol]), were estimated using multivariable logistic regre

292 lobin with the Mediterranean diet (-0.8 mmol/mol; -1.2, -0.4 mmol/mol).

293 glycated haemoglobin of up to 9.5% (80 mmol/mol) on a maximum of two oral glucose-lowering drugs wit

294 G30) grown under ambient (aCO(2), 400 mumol mol(-1)) and elevated CO(2) (eCO(2), 620 mumol mol(-1))

295 l(-1)) and elevated CO(2) (eCO(2), 620 mumol mol(-1)) were assessed.

296 Samples with at least 0.56 mol of CO(2) per mol of ZIF-8 display a large, broad anomaly from 70 to 2

297 mples containing up to 0.99 mol of CO(2) per mol of ZIF-8.

298 O(2) concentrations (e[CO(2) ]) by +150 umol/mol.

299 ncentration and prevalence of ZPP >= 80 umol/mol heme at 6 mo, malaria incidence over 12 mo).

300 ined as zinc protoporphyrin (ZPP) >= 80 umol/mol heme, were randomly assigned to receive a 3-mo cours