ライフサイエンスコーパス: molar mass

1 om the literature values with increasing DNA molar mass.

2 rs, increased water solubility and decreased molar mass.

3 n with an extremely high DM (83%) and a high molar mass.

4 cations are sensitive to the distribution of molar mass.

5 nsive information on both microstructure and molar mass.

6 ncy of TEC increases with increasing polymer molar mass.

7 tical anisotropy as a continuous function of molar mass.

8 ween reaction concentration and experimental molar mass.

9 h different chemical structures but the same molar mass.

10 ime points followed by a gradual decrease in molar mass.

11 ratio of convicilin and vicilin with higher molar mass.

12 g in oligomers as low as 14 % of the initial molar mass.

13 to oxidation of 3 rye starches of different molar mass.

14 e amount of arabinoxylans and their apparent molar mass.

15 reasing domain spacing with increasing total molar mass.

16 ed applications that largely depend on their molar mass.

17 he direct determination of block lengths and molar masses.

18 sotactic and syndiotactic PMMAs of different molar masses.

19 narrow dispersities, and predictable average molar masses.

20 d are more suitable for molecules with small molar masses.

21 vogadro constant requires knowledge of their molar masses.

22 dicating adequate values of derived absolute molar masses.

23 Deconstructable PS of different molar masses (~20-300 kDa) bearing varied amounts of sta

24 the high-molar mass product (number-average molar mass 21.4 kilograms per mole) to a mixture of line

25 duct was obtained with a high-number-average molar mass (26850 g mol(-1)) and low polydispersity inde

26 purification the influence of EPS-dextran of molar mass 3,244,000 g/mol on resistant starch formation

27 , multifunctional complex architectures with molar masses above 11 kDa.

28 t monomer compositions and different average molar masses additionally containing two kinds of end gr

29 Their substitution to alanine decreased high-molar-mass alternan yield by a third, without significan

30 talyzing the synthesis of both high- and low-molar-mass alternans, we searched for structural traits

31 cial for size-based separations of ultrahigh molar mass analytes with low diffusion coefficients.

32 molecular attributes of polymers other than molar mass and aims at improving the overall molecular c

33 terials with a high degree of precision over molar mass and architecture.

34 multidetection system, indicate the uniform molar mass and chemical composition of the conjugate, th

35 of methoxylation, neutral sugar content, and molar mass and compared to citric acid (pH 2.5, 2h at 80

36 e catalyst provides control of the polymer's molar mass and composition by orthogonally activating th

37 The effect of MMA(n) molar mass and composition is also studied.

38 We have studied the effects of polymer molar mass and concentration on the electrophoretic migr

39 , we show that it is possible to recover the molar mass and dispersity of recycled HDPE products usin

40 The weight average molar mass and molar mass distribution obtained at each

41 e glass transition temperatures based on the molar mass and molecular O:C ratio of SOA components, an

42 rm synthetic polymers with precisely defined molar mass and monomer sequence (primary structure) have

43 ty functional block copolymers with targeted molar mass and narrow molar mass distribution using RAFT

44 this study allows the easy identification of molar mass and other structural features of aldehyde and

45 toxoid protein however greatly increased the molar mass and polydispersity of the final conjugates.

46 re diffusion coefficients are independent of molar mass and polymer concentration and are comparable

47 els are colloidal polymer networks with high molar mass and properties between rigid particles, flexi

48 nt in HDC, as evidenced by the fact that the molar mass and radius of gyration obtained by HDC with m

49 ed upper critical fields correlated with BCP molar mass and record surface areas for compound superco

50 alculated from the experimentally determined molar mass and sedimentation coefficient agrees with the

51 epletion at the meniscus reveals its buoyant molar mass and sedimentation coefficient with an accurac

52 The changes include both a decrease molar mass and size as well as an increase in apparent d

53 The method allows for determination of molar mass and size over the size distribution.

54 sample that is broadly polydisperse in both molar mass and size, with strings ranging from two to fi

55 water extractable arabinoxylan with varying molar mass and structure (cross-linked vs. hydrolyzed) i

56 f polymer matrixes appropriately matched for molar mass and the extent of interchain entanglements.

57 allowed the detection of changes in nanogel molar mass and topology as a function of both temperatur

58 ied HA fractions of different weight-average molar mass and with narrow size distributions and Select

59 were counted in solutions of varying polymer molar masses and concentrations and were plotted against

60 , and poly(methyl methacrylate) of different molar masses and in different solvents.

61 uce hydroxyl telechelic PPC with predictable molar masses and narrow dispersity (D < 1.15).

62 a very useful tool for the determination of molar masses and new Mark-Houwink parameters via DOSY.

63 rous determination of macromolecular buoyant molar masses and the thermodynamic study of reversible i

64 th MULTISIG revealed a broad distribution of molar masses and this heterogeneity was further confirme

65 g polyether displays predictable end groups, molar mass, and a low dispersity (D(M)<1.09).

66 assemblies with regards to morphology, size, molar mass, and chemical composition in one experiment.

67 measurements are made of SWNT concentration, molar mass, and size by using UV-vis absorption and mult

68 content, capsid molar mass, encapsidated DNA molar mass, and total capsid and vector genome titer.

69 onjugated to proteins via a one-pot process; molar mass- and grafting density-matched PTGG-lysozyme c

70 Partial breakdown of high molar mass arabinoxylan-protein and arabinoxylan-arabino

71 The aromaticity and asphaltene average molar mass are also correlated with IFT reductions at bo

72 rmore, positive log(g") values (~0.2) at low molar mass are attributed to cyclic subpopulations.

73 lex DNA loading and size, both geometric and molar mass, are key to understanding the transfection pr

74 how to determine the chemical heterogeneity, molar mass averages and distribution, and solution confo

75 at unit allows for direct calculation of the molar mass averages as well as sample polydispersity ind

76 zed by FSCE and MALDI-TOF; the values of the molar mass averages, Mw and Mn, typically agree to withi

77 on multiangle light scattering (SEC/D-MALS), molar mass averages, polydispersities, molar mass distri

78 constraints, we investigate the use of high molar mass biopolysaccharides, present in the mucilagino

79 Measurements and molar mass calculations are performed without any intern

80 es both a structure- and solvent-independent molar mass calibration.

81 r, 94 diffusion coefficients representing 16 molar mass calibrations of the diffusion coefficients in

82 nal grid methods, assures that only a single molar mass can be associated with a given anisotropy mea

83 istributions in molecular properties such as molar mass, chemical composition, and branching.

84 ility or any other characteristic parameter (molar mass, chemical composition, charge density, ...).

85 r DM, was more branched, and showed a higher molar mass compared to HTB carrot serum pectin.

86 Heat-induced structural changes of high molar mass complexes influenced competitive hydration am

87 as been shown that guarana seeds contain low-molar-mass compounds; however, no data have been reporte

88 Reliable knowledge of weight average molar mass, conformation and polydispersity of lignin st

89 , and that MPs and MPt form a complex with a molar mass consistent with a 1:1 heterodimer.

90 ne-based tweezer molecules and soluble, high molar mass copolyimides.

91 sual molar mass evolution profile where high-molar-mass cyclic polymers are produced at early time po

92 High molar mass deconstructable PMMA-based copolymers (dPMMA,

93 The derived equation for the molar masses delivered a very good accuracy for all samp

94 or both polymers, which was supported by the molar mass dependence of both the radius of gyration and

95 DOSY) can produce a universal calibration of molar mass dependences of polymers compared to size excl

96 most comprehensive universal calibration of molar mass dependences will be presented.

97 lations of Kuhn-Mark-Houwink-Sakurada of all molar-mass dependent hydrodynamic estimates show linear

98 In starches of low molar mass, depolymerization occurred mainly through the

99 d superior accuracy of the direct methods of molar-mass determination of the polysaccharide fragments

100 ture-, solvent-, and temperature-independent molar mass determinations for both small and large molec

101 mples and might be one of the best tools for molar mass determinations.

102 8A) induced quasi-complete loss of very-high-molar-mass dextran synthesis, resulting in production of

103 mensional liquid chromatography (2D-LC), the molar mass differences of the separated species were inv

104 rs with molar masses up to 6901 Da, ultralow molar mass dispersities (D </= 1.00002), and unique cont

105 lding excellent block purity and low overall molar mass dispersities (Eth<1.16).

106 r with predictable molecular weights and low molar-mass dispersities.

107 f HCP is intimately tied to small amounts of molar mass dispersity (D); for example, an HCP-forming F

108 ely high monomer conversion (>/=80%) and low molar-mass dispersity (D(M) </= 1.3).

109 Due to the broad molar mass distribution (MMD) and the presumed existence

110 ht scattering in undertaking measurements of molar mass distribution as a function of temperature.

111 e for accurate, easy and fast oligocellulose molar mass distribution determination.

112 ted with tetrahydrofuran, resulting in large molar mass distribution discrimination effects in the MA

113 calculation analogous with the dispersity of molar mass distribution Mw/Mn.

114 The weight average molar mass and molar mass distribution obtained at each temperature agr

115 The molar mass distribution of a polymer sample is a critica

116 mers by capillary gel electrophoresis (CGE), molar mass distribution of end-charged poly-l-alanine by

117 -charged poly-l-alanine by free solution CE, molar mass distribution of evenly charged polyelectrolyt

118 rophoresis (CE) are presented, including the molar mass distribution of poly-L-lysine oligomers by ca

119 n to be an effective method to determine the molar mass distribution of polysaccharides.

120 Here, we report the determination of a molar mass distribution of the oligocellulose synthesize

121 This provides a profile of the molar mass distribution of the original polymer sample t

122 The molar mass distribution of the synthesized oligocellulos

123 polymers with targeted molar mass and narrow molar mass distribution using RAFT polymerization.

124 The oligocellulose molar mass distribution was analyzed using three differe

125 The molar mass distribution was closely dependent on the dig

126 molar mass PET, representative of the entire molar mass distribution, were obtained only when a good

127 0) without compromising the control over the molar mass distributions (D < 1.20), even at an extremel

128 The resulting polymers exhibit narrow molar mass distributions (D approximately 1.1) and high

129 r, such polymer systems typically have broad molar mass distributions and lack the purity and sequenc

130 SEC is widely used to determine molar mass distributions and their dispersities.

131 imentation coefficient distributions c(s) or molar mass distributions c(M).

132 ns, c(M,R(S)), and sedimentation coefficient-molar mass distributions c(s,M).

133 n provides an unbiased scale for determining molar mass distributions of noninteracting species.

134 The absolute molar masses (M(n)) and molar mass distributions of the dendrimers were measured

135 creased linearly with conversion, and narrow molar mass distributions were obtained.

136 ALS), molar mass averages, polydispersities, molar mass distributions, and the distribution of the op

137 irregular backbone connectivities and broad molar mass distributions.

138 ocesses, in analogy to the work performed on molar mass distributions.

139 Molar-mass distributions were determined by coupling siz

140 ditions of thiols to activated alkynes, high-molar-mass elastomers were isolated via step-growth poly

141 e, size-distribution, capsid content, capsid molar mass, encapsidated DNA molar mass, and total capsi

142 Molar masses estimated by a combination of colorimetric

143 When molar masses estimated by indirect methods were compared

144 Special focus lies on molar mass estimates of unimeric polymeric species, self

145 ed parameters such as hydrodynamic shape and molar mass estimates.

146 However, CB6 also exhibits an unusual molar mass evolution profile where high-molar-mass cycli

147 olled polymerization and was able to achieve molar masses exceeding 20 kg mol(-1) with low dispersiti

148 Poly(vinyl ethers) of molar masses exceeding 50 kg mol(-1) can be produced wit

149 llows their separation by factors other than molar mass for molar masses typically higher than 20000

150 erally bimodal with some evidence for higher molar mass forms at higher concentration.

151 High molar mass fractions increased the maximal foam height a

152 Non-volatile substances and molar mass fractions influence sensory perceptions of pa

153 bed for direct molar-mass measurement of low-molar-mass fragments obtained by oxidative cleavage of t

154 Test chemicals range in molar mass from 120 to 1423 g.mol(-1) with log octanol-w

155 method extracts partial specific volume and molar mass from sedimentation velocity data for cases wh

156 elds polymers with predictable compositions, molar mass (from 38-71 kg mol(-1)), and forms dihydroxyl

157 haracterisation confirm the presence of high molar mass (>=2 MDa) polysaccharides in the extracted mu

158 SEs, polyurethanes were synthesized from low-molar-mass hydroxy-telechelic PSEs.

159 usion chromatography separating according to molar mass in the second dimension, thus providing compr

160 in critical activation diameter and average molar mass in three out of five combinations evaluated,

161 In all cases, polymer molar masses increased linearly with conversion, and nar

162 nisotropy and partial specific volume if the molar mass is known.

163 Extended, i.e., recycled, product molar mass is tunable through the ratio of monomer to ol

164 eve an optimal separation and identify a low molar mass limit is particularly described.

165 phoretic DNA separations compared to matched molar mass linear polyacrylamide.

166 rization to provide polymers with controlled molar mass, low dispersity, and targeted alpha-end funct

167 The addition of a small amount of low molar mass LPA or ultrahigh molar mass LPA to the optimi

168 ll amount of low molar mass LPA or ultrahigh molar mass LPA to the optimized nanogel sequencing matri

169 of the ligand is almost entirely monomeric (molar mass M = 45.7 kDa) in dilute aqueous solution with

170 The change in the weight average molar mass M w with loading concentration was consistent

171 th respect to their isotopic composition and molar mass M(Si).

172 equilibrium data indicates a weight average molar mass M(w) of (3.9 +/- 0.8) kDa and (4.2 +/- 0.2) k

173 ation equilibrium indicated a weight average molar mass M(w) of (4.3 0.2) kDa, with minimal concentra

174 t simultaneous heterogeneity in density rho, molar mass M, and particle diameter d.

175 Overlap of data sets of point weight average molar masses M w(r) versus local concentration c(r) for

176 otential below -40 mV and, and polymers with molar mass (M(n)) above 10 kg mol(-1).

177 ork, matched for both polymer weight-average molar mass (M(w)) and the extent of interchain entanglem

178 Absolute values of weight average molar mass (M(w)) determined using sedimentation equilib

179 tion rate (ER) of chemicals as a function of molar mass (M) and vapor pressure (P) that is simpler th

180 re extended conformation in solution in this molar mass (M) regime.

181 determination of molecular properties, i.e. molar mass (M), root-mean-square radius (r(rms)), appare

182 The absolute molar masses (M(n)) and molar mass distributions of the

183 These polymers have typical weight-average molar masses (M(w)) in the range (1.7-2.0) x 10(5) g mol

184 TTC-bCP allowed the preparation of a high-molar-mass (M(n) 135 kg mol(-1)) methyl methacrylate-n-b

185 ) = 160 degrees C (in the limit of very high molar mass, M(n)).

186 aqueous solution with a trace amount of high molar mass material (M 200 kDa).

187 This method offers access to high molar mass materials, as exemplified by poly(tert-butylp

188 n of the optical anisotropy as a function of molar mass may all be determined.

189 Two methods are described for direct molar-mass measurement of low-molar-mass fragments obtai

190 pattern of five of these properties namely: molar mass, melting point, vapour pressure at 20 degrees

191 retical model is provided to generalize this molar mass memory effect.

192 njugate vaccines against serious disease are molar mass (molecular weight), heterogeneity (polydisper

193 MALS, dRI, and dVis provides information on molar mass, molecular size, and molecular topology.

194 of important molecular parameters, including molar mass, molecular size, chemical composition, molecu

195 Weight average molar masses Mw where lower for activated polysaccharide

196 ultaneous optimization of LPA weight-average molar mass (Mw) and concentration for SSCP/HA peak separ

197 onic acid (GalA), neutral sugar composition, molar mass (Mw), viscosity and degree of branching.

198 egrees (20,w) combined with the value of the molar mass obtained by MALDI mass spectrometry (44.2 kDa

199 Variation between the molar masses obtained by the two methods ranged from 5 t

200 from 770 dendrons that exhibits an ultrahigh molar mass of 1.73 x 10(6) g/mol.

201 In solution, sGP has an absolute molar mass of 103 kDa, is monodisperse, and folds into a

202 es of the three nucleoporins, amounting to a molar mass of 12.3 MDa and contributing 256 phenylalanin

203 fficient, s(20,w), of 7.0 S with a predicted molar mass of 213 kg/mol.

204 ne and 3% alpha-(1 -> 3) branches, and had a molar mass of 3.3 x 10(6) g/mol.

205 ral proof for the wheel-like molecule with a molar mass of 3815.4 g/mol.

206 y an ideal one-component model with a fitted molar mass of 40180 +/- 240 Da (without Mg(2+) ions) or

207 We identified the stoichiometry and molar mass of a complex formed during the interaction of

208 hly branched arabinogalactan (type 2) with a molar mass of approximately 1-2.10(5)g/mol, a hydrodynam

209 infection in surface waters may increase the molar mass of dissolved organic compounds relative to su

210 The molar mass of each block was tailored to target material

211 elf-associate plateauing > 1 mg/mL to give a molar mass of g/mol corresponding to ~ (19 +/- 1) mers,

212 Salt concentration did not affect the molar mass of legumin.

213 of the average degree of polymerisation and molar mass of milk saccharides throughout the hydrolysis

214 rmore, the ability to detect and measure the molar mass of multiple separate species enables the meas

215 g and viscous behaviour possesses an average molar mass of Mw=350kg/mol, Mn=255kg/mol.

216 ral polysaccharide fraction shows an average molar mass of Mw=47kg/mol and Mn=28kg/mol and is compose

217 ple variations in the volume fraction and/or molar mass of PEO lead to either polymerization-induced

218 The weight average molar mass of the activated material was considerably re

219 Surface reconstruction rather than molar mass of the adsorbing molecules seemed to determin

220 In addition, sLac treatment reduced the molar mass of the APPL by over 50%, as determined by gel

221 resents only between 0.05 and 4.77% from the molar mass of the dendritic dipeptide.

222 ingle-valued relationship exists between the molar mass of the growing polymer chain and its correspo

223 The molar mass of the linoleic acid overlaid onto the PP-Tan

224 es, or in the form of prior knowledge of the molar mass of the main species.

225 Additionally, the molar mass of the polymers was found to impact their hem

226 is described that allows measurement of the molar mass of the solute within 15 to 30 min after start

227 semble to form micellar-like spheres, with a molar mass of up to 1.1 x 10(6) g/mol, that self-organiz

228 ock and myrcene content of 60-75 mol %, with molar masses of 100-200 kg/mol were prepared by living a

229 are compared regarding the determination of molar masses of block copolymers.

230 ation for LCCC-NMR, and determination of the molar masses of copolymers.

231 The average molar masses of LPA used as DNA separation matrixes were

232 w that this can be used to determine average molar masses of macromolecules and characterize macromol

233 ing starting at 3 months, and weight-average molar masses of scaffold parts were 20% and 14% of their

234 sed to directly determine concentrations and molar masses of the block copolymers from the chromatogr

235 he PE-ester samples with high number-average molar masses of up to 111 kg/mol.

236 For low molar mass oligomers (PET-1), minor discrimination effec

237 d nucleic acids are monodisperse just as low-molar-mass organic compounds are.

238 MALDI spectra of medium molar mass PET, representative of the entire molar mass

239 ry is demonstrated for oligomeric and medium molar mass poly(ethylene terephthalate) (PET).

240 onducted with compositionally asymmetric low molar mass poly(isoprene)-b-poly(lactide) diblock copoly

241 Using this process to make low molar mass polycarbonate polyols is a commercially relev

242 In contrast, efficient catalysts for high molar mass polycarbonates are underinvestigated, and the

243 In contrast, high molar mass polycarbonates, produced from CO(2), generall

244 For PHB, number and weight average molar mass, polydispersity, and oligomer size distributi

245 Information about molar mass, polydispersity, size, shape/conformation, or

246 sed simultaneously and complex blends of low molar mass polyethylene and ethylene-co-1-octene copolym

247 d nanofibrillated cellulose (NFC) and a high molar mass polyethylenimine (PEI) have been prepared via

248 d from pine trees, and used to prepare a low molar mass polymer TPA5 through free radical polymerisat

249 (ROMP), where only trans-SiCH afforded high-molar-mass polymer under enthalpy-driven ROMP.

250 at confer its ability to produce a very-high-molar-mass polymer.

251 : whereas highly entangled solutions of high molar mass polymers provide optimal sequencing performan

252 llenges associated with the analysis of high molar mass polymers with a high degree of branching.

253 However, after depolymerization, low molar mass polyolefins contained some units with differe

254 nated samples support assignment of the high-molar mass product (number-average molar mass 21.4 kilog

255 High-molar-mass products were achieved, and the degree of pol

256 tely unimodal log-normal but broad and large molar mass profiles, confirmed by sedimentation equilibr

257 e branch units per molecule as a function of molar mass provides a unique profile of each branched PL

258 poly(ethylene glycol) (PEG) solutions over a molar mass range from 106 to 22,800 g/mol.

259 The large polysaccharides have a molar mass range of 4.0 x 10(3) to 8.0 x 10(5) g.mol(-1)

260 The series of linear PEGs in the molar mass range of only a few thousand to 50000 g mol(-

261 tering, detecting an absolute weight average molar mass ranging from the size of a monomer to the siz

262 ts that steadily increased in weight-average molar mass, reaching a final maximal steady-state size o

263 effectively repolymerized to generate a high molar mass recycled PE-ester sample.

264 ter extraction at the expense of significant molar mass reduction.

265 stem, covalent chains grow to higher average molar mass relative to chains formed via the same polyme

266 e DSM17330 produces a dextran of the highest molar mass reported to date (~10(9) g/mol).

267 eriodic array, in spite of the fact that its molar mass represents only between 0.05 and 4.77% from t

268 are of EPS dextran limited formation of high molar mass resistant starch in starch pastes during stor

269 tion between the hydrodynamic radius and the molar mass, Rh approximately M(1/d), with a fractal dime

270 From a single analysis, the molar mass, root mean square and hydrodynamic radii, com

271 The approach allows determination of molar mass, root- mean-square radius and apparent densit

272 Soluble, high molar mass samples of these materials were first prepare

273 c separation, directly measures the absolute molar mass, size and concentration of the eluate species

274 vide complete particle analysis based on the molar mass, size, shape, and compactness and their distr

275 acrylamide) homopolymers to quantitate their molar mass, solution conformation, and chemical heteroge

276 of the 1-4 glycosidic bond, whereas in high molar mass starch of degradation processes also the brea

277 ral characterization, if possible with large-molar-mass sugar ligands, would allow confirming this hy

278 ed hyaluronan (HA) of smaller weight-average molar mass than wild-type enzyme (3.6 MDa); the smallest

279 dary calibration with dextran standards gave molar masses that exceeded the SEC-MALLS/RI data by as m

280 excellent DNA sequencing performance of high molar mass, thermoresponsive polymer matrices that exhib

281 complex size growth (mean square radius and molar mass) throughout the DNA/poly-L-lysine polyplex fo

282 ent is more alternating than random at lower molar masses, thus causing the copolymer to adopt a more

283 to generate recycled PS of nearly identical molar mass to the parent material, in good yields (80-95

284 e depolymerization mechanism, effects of its molar mass, topology, and end-group chemistry are examin

285 aration by factors other than molar mass for molar masses typically higher than 20000 g/mol.

286 rategy we have synthesized uniform BCPs with molar masses up to 12.1 kDa on approximately 1 g scale.

287 cyclo[4.4.0]dec-5-ene yields polyesters with molar masses up to 13.6 kg mol(-1) and pendent vinyl sid

288 rative synthetic protocol, co-oligomers with molar masses up to 6901 Da, ultralow molar mass dispersi

289 rty insights, including the benefits of high molar mass urethane oligomers, a high density of urethan

290 the diffusional broadening and the apparent molar mass values of the effective sedimenting particle

291 ance, related to fluorescence efficiency and molar mass, varies with size.

292 hiphilic networks could be achieved when low molar mass versions of both the PFPE-DMA (1 kg/mol) and

293 ples of 3.4-, 5-, and 20-kDa nominal average molar mass were analyzed by FSCE and MALDI-TOF; the valu

294 Natural variants with high molar mass were associated with a gene encoding a putati

295 In this study, 5 polyesters of similar molar mass were synthesized by reacting 1,10-decanediol

296 in length by quantitative 1H NMR, from which molar masses were derived.

297 Absolute molar masses were determined by size-exclusion chromatog

298 surface contacts at rates independent of the molar mass (which was varied by a factor of 30), but dep

299 ter to afford P3H(Me)(2)P with low to medium molar mass, which is then utilized to produce lactones t

300 In contrast, the determination of molar masses with common relative methods based on calib