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1 ource (blue LED), and a sustainable oxidant (molecular oxygen).
2 transformations of mercury in the absence of molecular oxygen.
3 lective reaction of an amine/borane FLP with molecular oxygen.
4 ctions can be carried out in the presence of molecular oxygen.
5 photoexcited electrons in the perovskite and molecular oxygen.
6 dations, all involving stepwise reduction of molecular oxygen.
7 mediates light-induced oxidation of water to molecular oxygen.
8 nts during the Archean eon in the absence of molecular oxygen.
9 cur before an irreversible reductive step at molecular oxygen.
10 ility to oxidize methane into methanol using molecular oxygen.
11 of superoxide anion to hydrogen peroxide and molecular oxygen.
12 reducing equivalents without involvement of molecular oxygen.
13 case can catalyze electrooxidation of H2O to molecular oxygen.
14 l product, is reported from (-)-myrtenal and molecular oxygen.
15 ), is actively dissipated in the presence of molecular oxygen.
16 fer from one or more light-excited donors to molecular oxygen.
17 lowed by the strongly favorable reduction of molecular oxygen.
18 nteraction between neutral gold clusters and molecular oxygen.
19 single-site catalysts for the activation of molecular oxygen.
20 radical reactions of organic compounds with molecular oxygen.
21 mely, the ability to convert superoxide into molecular oxygen.
22 y transferring aldehyde-derived electrons to molecular oxygen.
23 achieve selective four-electron reduction of molecular oxygen.
24 plays very little role in the reaction with molecular oxygen.
25 trates using NADPH as the electron donor and molecular oxygen.
26 oxidation when irradiated in the presence of molecular oxygen.
27 lfide isomerase (PDI) and passing them on to molecular oxygen.
28 trolled factors immediately upon exposure to molecular oxygen.
29 on oxidation of ubiquinol in the presence of molecular oxygen.
30 cal species generated upon the activation of molecular oxygen.
31 species via a light-activated reaction with molecular oxygen.
32 he catalytic oxidation of water that evolves molecular oxygen.
33 ates and upon reduction can be reoxidized by molecular oxygen.
34 ompeting with the primary electron acceptor: molecular oxygen.
39 record of the clumped-isotope composition of molecular oxygen ((18)O(18)O in O(2)) trapped in polar f
40 ,22R-dihydroxycholesterol in the presence of molecular oxygen ((18)O2), and coupled assays were used
41 ides can be produced only in the presence of molecular oxygen(3), reactive oxygen species(4,5) or by
42 under anaerobic conditions in the absence of molecular oxygen abrogates Sup35 protein damage and supp
46 lative energies of the transition states for molecular oxygen addition to C9, C5, and C14 (where spin
47 he experimental values for HO* reactions and molecular oxygen addition, and a factor of 5 for peroxyl
51 occurs by hydrogen-transfer from Fl(red) to molecular oxygen, allowing radical coupling of the forme
52 capabilities for phototrophy, scavenging of molecular oxygen, anaerobic respiration, and fermentatio
55 ing dioxygenases requiring for activity both molecular oxygen and 2-oxoglutarate that, under normoxia
60 alpha-MnO2 nanotubes easily accommodated the molecular oxygen and exhibited excellent catalytic activ
62 ineralize manganese oxides in the absence of molecular oxygen and high-potential photosynthetic react
63 phenyliodonium diacetate in the presence of molecular oxygen and N-hydroxyphthalimide or N-hydroxybe
66 olol and honokiol radicals do not react with molecular oxygen and produce no superoxide radical under
69 ltaneous resonant two-photon dissociation of molecular oxygen and resonant two-photon pumping of the
70 made, pointing to a mechanism in which both molecular oxygen and the olefinic substrate coordinate t
71 adventitious electron transfer from nNOS to molecular oxygen and thereby preventing accumulation of
72 he quantum yields were enhanced by excluding molecular oxygen and thermally activated delayed fluores
74 d by experiments performed in the absence of molecular oxygen and with the use of (18)O-labeled water
76 T), a treatment that uses a photosensitizer, molecular oxygen, and light to kill target cells, is a p
78 ational studies on the reactions with water, molecular oxygen, and the superoxide radical anion suppo
79 a capability to reduce Fe(III) minerals and molecular oxygen, and thereby generating Fenton chemistr
81 Here, electrochemical side reactions with molecular oxygen are shown to occur during organic elect
83 glutarate-dependent dioxygenases that deploy molecular oxygen as a co-substrate to catalyse the post-
87 tertiary amines to tertiary amides by using molecular oxygen as a sole oxidant using a Pd/C catalyst
92 coupled with the use of abundant atmospheric molecular oxygen as an oxidant and low catalyst loading
95 c metabolism therefore makes use of reactive molecular oxygen as co-substrate of oxygenases to hydrox
97 lized in the blue bottle experiment, deplete molecular oxygen as long as a sacrificial reduction comp
98 rational bands of nitric oxide, hydroxyl and molecular oxygen as signatures of nitrogen, oxygen, and
99 site and one catalytic residue, and utilizes molecular oxygen as source for the hydroxyl group oxygen
100 drastic reduction in oxidase activity using molecular oxygen as the electron acceptor and a small in
102 utyl-p-benzoquinone enables efficient use of molecular oxygen as the oxidant, high reaction yields, a
106 inates position C4 in a reaction implicating molecular oxygen, as demonstrated with labeling experime
108 the title compound involves the splitting of molecular oxygen by carbene-stabilized diphosphorus.
109 l gold clusters (Au(n); 4 </= n </= 21) with molecular oxygen by probing the highly characteristic O-
110 rate how light-triggered SiNc reactions with molecular oxygen can be potentially sensed and discuss t
111 genous or xenobiotic small molecules such as molecular oxygen, cellular metabolites, or polyaromatic
114 cysteine makes it vulnerable to oxidation by molecular oxygen; consequently, organisms that live in o
115 o-hydroxylation of L-tyrosine to L-DOPA by a molecular oxygen dependent pathway in the presence of di
117 roxylation is catalyzed by a membrane-bound, molecular oxygen-dependent, and ferredoxin-dependent act
118 -phenylindeno[2,1-alpha]phenalene (ipp) with molecular oxygen derived from air, yielding 12-hydroxy-7
121 hanges in proportion to the concentration of molecular oxygen dissolved in plasma or interstitial tis
122 e surface are a significant redox partner to molecular oxygen due to the strong hybridization between
125 the biofuel and the biooxidant, glucose and molecular oxygen, each readily available in human lachry
126 Specifically, the controlled exposure to molecular oxygen efficiently deprotonates terminal alkyn
127 ow that pyrite burial could have resulted in molecular oxygen export exceeding local Fe(2+) oxidation
129 In contrast to GFP, which requires only molecular oxygen for chromophore maturation, phytochrome
132 es (LPMOs) have a unique ability to activate molecular oxygen for subsequent oxidative cleavage of gl
134 to effect the challenging task of utilizing molecular oxygen for the selective epoxidation of cycloo
135 ploys the reaction of iodoalkyl radical with molecular oxygen: for instance, CH2I + O2 --> CH2OO + I.
138 abolism lead to the release of l-lactate and molecular oxygen from the tissue into the gut lumen.
139 water oxidation, but catalysts that produce molecular oxygen from water are needed to avoid excessiv
140 lkyl-substituted diazenes in the presence of molecular oxygen generates an unexpectedly complex produ
141 er drug with light, which in the presence of molecular oxygen, generates cytotoxic reactive oxygen sp
144 urfaces with direct propylene epoxidation by molecular oxygen have not resolved these problems becaus
146 on of a bare palladium cluster Pd(6)(+) with molecular oxygen in an octopole ion trap under multicoll
147 y reports the incorporation of (18)O-labeled molecular oxygen in azinomycin biosynthesis including bo
148 between redox-active conjugated polymers and molecular oxygen in electrochemical devices for bioelect
149 this review article, we consider the use of molecular oxygen in reactions mediated by polyoxometalat
151 ations, we investigate here the migration of molecular oxygen in the bc1 complex in order to identify
152 both confirmed the requirements for DHP and molecular oxygen in the catalytic generation of 5,5'-Br2
153 ing of singlet oxygen, but do not react with molecular oxygen in the ground state, i.e., triplet stat
155 The balance between sources and sinks of molecular oxygen in the oceans has greatly impacted the
159 ive low-temperature oxidation catalysts with molecular oxygen, in stark contrast to the nobility of t
160 ) is not reduced by Mn(II) in the absence of molecular oxygen, indicating that substrate oxidation re
161 a sustained electron flow is maintained with molecular oxygen instead of carbon dioxide serving as th
163 PH oxidase to convert substantial amounts of molecular oxygen into superoxide, which, after dismutati
165 ogen peroxide by radical chain reductions of molecular oxygen into water in buffers leads to hinge de
170 The intramolecular conversion of CO(2) to molecular oxygen is an exotic reaction, rarely observed
179 ng to these results and due to the fact that molecular oxygen is the only known physiological electro
182 Singlet oxygen, the lowest excited state of molecular oxygen, is an intermediate often involved in n
187 interaction between the neutral polymer and molecular oxygen leading to a reduction in electron mobi
190 and that electron shuttling through CNTs to molecular oxygen may be a potential mechanism for DNA da
191 ring, and end-game manipulations featuring a molecular oxygen mediated gamma-CH oxidation, a Stetter
192 pe II photosensitization reactions, in which molecular oxygen mediates the radicalization of proteins
201 lmalonate), which was used to detect singlet molecular oxygen O2((1)Deltag) production in water.
202 so results in direct enzymatic conversion of molecular oxygen (O2 ) to reactive oxygen species (ROS)
203 f biological detection by optical sensing of molecular oxygen (O2) are reviewed, with particular emph
204 ears to be mediated during the activation of molecular oxygen (O2) by reduced flavoenzymes, forming s
206 rbon monoxide (CO) and the infrared inactive molecular oxygen (O2) products are readily detected from
209 w widely appreciated that nutrients, such as molecular oxygen (O2), modulate skeletal muscle formatio
210 n rich terrestrial-type exoplanets including molecular oxygen (O2), ozone (O3), water vapor (H2O), ca
211 ing reactions, we investigated the role that molecular oxygen (O2), solvent and light-source (CF lamp
215 e phosphorescence is effectively quenched by molecular oxygen, optical sensors operating in a wide ra
216 ditions but could be enhanced by exposure to molecular oxygen or by the addition of alternative elect
219 high activities for the electroreduction of molecular oxygen (oxygen reduction reaction, ORR), which
222 gger critical metabolic pathways to detoxify molecular oxygen produced by photosynthesis, thereby per
223 ubsequent quenching of the triplet states by molecular oxygen produces singlet oxygen ((1)O2), which
224 lysts that promote the oxidation of water to molecular oxygen, protons, and "energized" electrons, an
226 such as hydrogen peroxide (H2O2) or singlet molecular oxygen, rather than free-radical species, perf
228 Interactions between biological pathways and molecular oxygen require robust mechanisms for detecting
230 360 mV (vs. Ag/AgClsat) in the presence of a molecular oxygen saturated electrolyte with current dens
232 Prolyl hydroxylase enzymes (PHD1-3) are molecular oxygen sensors that regulate hypoxia-inducible
234 pper-catalyzed alkene aminooxygenation where molecular oxygen serves as both oxidant and oxygen sourc
235 e combustion reactor between water vapor and molecular oxygen so that only hydrogen isotope compositi
236 ns to an atmosphere which became enriched in molecular oxygen spurred the development of a layered sy
237 henotypes are invariant within this range of molecular oxygen suggesting that ESR1 mutations confer a
238 T1 Cu species only formed in the presence of molecular oxygen, suggesting the T1 Cu intermediate is a
239 , which is different from isolated atomic or molecular oxygen surface structures, was observed with i
241 umbrella term for an array of derivatives of molecular oxygen that occur as a normal attribute of aer
242 graded in the gut lumen, which gives rise to molecular oxygen that supports the aerobic respiration o
244 ited state ensembles against deactivation by molecular oxygen though quenching and photooxidation mec
246 cal processes, including the biosynthesis of molecular oxygen (through the photosystem II complex) an
247 emperature without the rigorous exclusion of molecular oxygen, thus making this newly developed Ir-ph
248 on to 15 aromatic compounds; (2) addition of molecular oxygen to 65 carbon-centered aliphatic and cyc
249 or a dominant delivery channel that shuttles molecular oxygen to a specific region of the active site
250 intermediates may be trapped via exposure to molecular oxygen to afford oxygen-containing adducts.
254 (P(Ar)(tBu)2)2] (1, Ar=naphthyl) reacts with molecular oxygen to form Pd(II) hydroxide dimers in whic
255 rhenium(V), (ONO(Cat))ReO(PPh3), reacts with molecular oxygen to give triphenylphosphine oxide and th
256 asm; instead, the four-electron reduction of molecular oxygen to harmless water ensures that the acti
259 ycle pathway involving reversible binding of molecular oxygen to iridium, which contributes to the ai
260 prene reacts with hydroxyl radicals (OH) and molecular oxygen to produce isoprene peroxy radicals (IS
261 ectron transport chain, which is captured by molecular oxygen to produce reactive oxygen species (ROS
262 copper oxidases that couple the reduction of molecular oxygen to proton translocation across the bact
264 the quenching of palladium-benzoporphyrin by molecular oxygen to transduce the local oxygen concentra
265 ine oxidase enzyme superfamily which utilize molecular oxygen to transform amines to imines that are
267 dase (CcO), which catalyzes the reduction of molecular oxygen to water in the mitochondrial and bacte
268 pe quinol oxidases catalyze the reduction of molecular oxygen to water in the respiratory chain of ma
269 chondria and bacteria catalyzes reduction of molecular oxygen to water, and conserves much of the lib
273 h more versatile redox chemistry, biospheric molecular oxygen triggered the selective fixation of the
274 can be directly converted to methanol using molecular oxygen under mild conditions in the gas phase,
277 A material capable of rapid, reversible molecular oxygen uptake at room temperature is desirable
278 as a photoredox catalyst in the presence of molecular oxygen using visible light and, when it was us
279 tly split carbonate into carbon monoxide and molecular oxygen via a low-energy pathway needing no sac
280 oposals have been made for the activation of molecular oxygen via both a Cu(II)-aminoquinol catalytic
283 ithium intercalated into Li(x)V(2)O(5) while molecular oxygen was reduced to form lithium peroxide on
287 ding py and pz orbitals are degenerate as in molecular oxygen, which has singly occupied orbitals.
289 of a small organic molecule, luciferin, with molecular oxygen, which is catalysed by the enzyme lucif
290 cotinamide adenine dinucleotide phosphate to molecular oxygen, which leads to the production of super
291 ion of gem-difluoroalkenes using phenols and molecular oxygen, which retains both fluorine atoms and
292 s become active sites for oxidizing water to molecular oxygen, which was investigated with the photoc
294 ransfer from the Breslow intermediate to the molecular oxygen with formation of a radical couple that
297 mitochondria could occur by the reaction of molecular oxygen with the ferrous CL:cyt c complex in ad
299 intramitochondrial [NAD(+) ]/[NADH] pool to molecular oxygen, with irreversible reduction of oxygen