ライフサイエンスコーパス: odd electron

1 , despite the potential stabilization of the odd electron by two conjugated triple bonds and unlike t

2 perative that the underlying rules governing odd electron C-C bond forming processes be better unders

3 o comprise increased relative amounts of the odd-electron c-type ions (c+*) and the even-electron z-t

4 led by a composite spin density map (SDM) of odd electron character on the electron density surface,

5 ly access various oxidation states including odd-electron configurations.

6 s the question of pi-delocalization in these odd-electron counterparts.

7 oubled" ESR spectrum diagnostic of complete (odd) electron delocalization.

8 Penning ionization with formation of radical odd-electron doubly charged molecular cation or via high

9 [triple bond]C units in conjugation with the odd electron enhances rather than diminishes stability.

10 up is the acid, (HPX-CO2H)FeIII(OH), because odd-electron homolytic O-O bond cleavage is inhibited.

11 es induce a JT distortion that localizes the odd electron in a single priority S-C antibond, which un

12 Moreover, the delocalization of odd electrons in these radicals has been investigated by

13 S/MS), but unlike CFM-ESI, CFM-EI can handle odd-electron ions and isotopes and incorporates an artif

14 DFT calculations suggest that the odd electron is localized in a smif pi* orbital, i.e., s

15 d a series of b- and y-type ions; CID of the odd-electron Lbeta11(*) product resulted in a wide range

16 e residue, which is easily identified by the odd-electron loss of .SCH(2)CONH(2).

17 rison between the gas-phase fragmentation of odd-electron M+*, [M + H]2+*, and [M - 2H]-* ions of mod

18 lyzed reactions are proposed to also involve odd-electron Ni(I) and Ni(III) oxidation states.

19 o evidence for long-lived organic radical or odd-electron nickel intermediates.

20 CN, CO2Me, CHO, C3HMeBF2O2, and NO2 when the odd electron of the intervalence oxidation level is remo

21 o-9-azabicyclo[3.3.1], NPPh3, and O when the odd electron of the intervalence oxidation level is remo

22 O with CO located on the axis of the d(z)(2) odd-electron orbital (g( ) > g(||) ~ 2).

23 tic of a "cloverleaf" (e.g., d(x)(2)-(y)(2)) odd-electron orbital, with Ni(p) binding two, apparently

24 ation in the C-C-O-C fragment brings the two odd-electron orbitals closer to each other, and the othe

25 ding of potential catalytic applications for odd-electron Pd systems.

26 derstanding of the fragmentation patterns of odd-electron peptide ions produced through various appro

27 lay an important role in the dissociation of odd-electron peptide ions.

28 cleavages are observed, as well as even- and odd-electron products.

29 Unusual odd-electron radical a- and x-ions were observed.

30 on product ion termed Lalpha12, the other an odd-electron radical ion termed Lbeta11(*), which allowe

31 By increasing the field strength about iron, odd-electron reactivity was circumvented via increased c

32 hese reactions occur in place of undesirable odd-electron redox processes that produce hydroxyl radic

33 Odd-electron, redox-active ligands are discussed in the

34 idation of Fe(II) by H(2)O(2), thus avoiding odd electron reduction products of oxygen and therefore

35 roton and (13)C spin densities show that the odd electron resides in a molecular orbital with six hyd

36 In the reduced monomer's ground state, the odd electron resides on the dmb ligand rather than on th

37 Odd-electron silver clusters are found to be especially

38 ox catalysis is a powerful means to generate odd-electron species under mild reaction conditions from

39 photocatalyst and oxygen in the formation of odd-electron species.

40 it is in agreement with the distribution of odd-electron spin electron density from the ESR data and

41 n even electron systems and rapid etching in odd electron systems.

42 The EPR spectrum of the odd-electron Y2@C79N indicates that the spin density lar

43 Here we report that the odd electron z (*) -type ions formed by the electron-bas

44 involves production and isolation of primary odd-electron z(*) ions, followed by radical site initiat