ライフサイエンスコーパス: organo

1 ng Ala and organic parts: "cyclo-{-(Ala)(n) -organo-}".

2 In drained soils, organo-Al complexes were positively associated with soil

3 In contrast, reactive organo-Al in drained soils facilitates C storage via agg

4 Soil moisture, organo-Al, and reactive Fe explained most of the variati

5 In this review, we describe a number of organo- and hydrogels formed through the assembly of nuc

6 luorination were enabled most prominently by organo- and transition-metal catalysis.

7 Metal-, organo-, and proton-catalyzed carbonyl-olefin/alkyne met

8 However, organo-arsenic (MMA, 48% and DMA, 19%) was the more domi

9 nic was performed by previous degradation of organo-arsenic species, followed by a reduction.

10 monstrates the premise that incorporation of organo(arsines) into MOF scaffolds is a safer and more c

11 ne {PhC((t)BuN)(2)}Si{B(NDippCH)(2)} with an organo-azide proceed through a Si(IV)-Si(II)-Si(IV) seri

12 rmed from readily available arylimidates and organo azides by Rh(III)-catalyzed C-H activation/C-N bo

13 ynthetic approach involving the reactions of organo azides with a potassium aluminyl reagent.

14 joins an allylic acetate, and indole and an organo-B(pin) species to provide substituted indoles and

15 nt influence on stability and isolability of organo-Bcat compound classes and lay the groundwork for

16 hodology for forming synthetically versatile organo-boronate esters and boron containing bioactives.

17 eogenic elements exploiting either metal- or organo-catalysis are the principal approaches to efficie

18 undamental knowledge gained in both bio- and organo-catalysis for asymmetric biocatalysis.

19 the reactive intermediates in Bronsted acid organo-catalysis.

20 e base BEMP turned out to be the most active organo-catalyst compared with guanidine and amidine base

21 evelopment of a synthetically viable aqueous organo-catalyst.

22 C-Computational Identification of POtential (Organo)Catalysts), which discovered a chiral 2-aminoDMAP

23 openium ions in terms of their broad use as (organo)catalysts, ligands, redox-flow batteries, and app

24 presence of thiols as biologically relevant (organo)catalysts.

25 cholate through a combination of metal-free organo-catalytic living ring-opening polymerization and

26 This organo-catalyzed [5 + 1] annulation features a broad sub

27 aternary-substituted thiazolines through the organo-catalyzed halocyclization of sulfonate thioimidat

28 The first organo-catalyzed synthesis of imidazolidin-2-ones and im

29 spatial parameter in the use of the charged organo-cation guest in the zeolite synthesis.

30 -dimethylhept-3-yl)phenol) into soil-derived organo-clay complexes was investigated.

31 Isolated organo-clay complexes were separated into humic subfract

32 )CH2C(CH3)2CN (R1*)) that proceed on to form organo-cobalt complexes (TMP)Co-CH(OAc)CH3 (4, Co-R2) an

33 erate exchanges of radicals in solution with organo-cobalt complexes are deduced from (1)H NMR studie

34 nge of organic radicals between solution and organo-cobalt complexes is experimentally observed and t

35 interchange of the latent radical groups in organo-cobalt porphyrin complexes with freely diffusing

36 dies for the formation and transformation of organo-cobalt species in this system.

37 Top SOC predictors were roots, the ratio of organo-complexed iron (Fe) to aluminum (Al), water stabl

38 l transformation of nano-ZnS to adsorbed and organo-complexed Zn species.

39 ived from thermodynamic results for (TSPP)Rh-organo complexes in aqueous solution for Rh-CDO, Rh-CH(R

40 Photoredox catalysts are metallo- or organo-compounds capable of absorbing visible light, res

41 molecule has broad implications in terms of organo-copper chemistry, biological methane oxidation, a

42 Here we report a cationic organo-copper cluster [Cu(4)(PCP)(3)](+) (PCP = 2,6-(PPh

43 The catalytic relevance of the high-valent organo-Cu(III) has been demonstrated by the C-C bond-for

44 ereoselective synthesis of boron-stereogenic organo-derivatives is highly desirable.

45 FETPY, an organo-diiron(I) complex, showed strong cytotoxicity acr

46 e/separation, water purification, catalysis (organo-, electro-, and photocatalysis), and electrochemi

47 In this work, we introduce an organo-erbium spin qubit in which narrow (megahertz-scal

48 roups to be incorporated into redox-inactive organo-f-block compounds.

49 ve surface charge, water stable aggregation, organo-Fe complexation, and root inputs were key SOC pro

50 to the Fe site such that the formation of an organo-Fe intermediate seems improbable.

51 oethite, and their corresponding OMCs, i.e., organo-ferrihydrite (O-Fh) and organo-goethite (O-Goe) o

52 Additionally, the formation of 8-membered organo(fluoro)phosphate rings in lithium ion battery ele

53 Since the high toxic potential of organo(fluoro)phosphates has emerged interest in safety

54 tween chloride ion and specifically designed organo-fluoro alicycles.

55 Likewise, the introduction of organo-functional groups makes mesoporous silicas highly

56 ganisation and hierarchical self-assembly of organo-functionalised hybrid polyoxometalates (hereafter

57 ing from heterogeneous catalysis and surface organo-functionalization to medical implants.

58 In this review, recent developments in organo-functionalized graphene and printed biosensor tec

59 orylation and activation of c-jun during the organo-genesis of the liver.

60 g OMCs, i.e., organo-ferrihydrite (O-Fh) and organo-goethite (O-Goe) on NPs mobility under varying en

61 species of formula c-(MR)(3) (M = Al-Tl; R = organo group).

62 A series of bimetallic organo-group 4 "constrained geometry" catalysts and binu

63 pathways analogous to those established for organo-group 4 and actinide complexes.

64 hey provide a good alternative to the use of organo-halide reagents in traditional cross-coupling rea

65 ross-coupling of organosilicon reagents with organo halides and pseudo-halides has developed over the

66 with measurements of total and extractable (organo)halogen (TX and EOX, respectively; where X = F, C

67 our genomes inferring that these Archaea are organo-heterotrophic and autotrophic acetogens.

68 ain aromaticity, PyH2 is a potent recyclable organo-hydride donor that mimics important aspects of th

69 ly reduced the benzimidazolium cation to its organo-hydride form in quantitative yield, demonstrating

70 ally, new prospects are identified for metal-organo-hydride systems as catalysts for organic transfor

71 is critically surveyed and the use of metal-organo-hydride systems in electrochemically-, photochemi

72 of CO(2) by a recyclable benzimidazole-based organo-hydride, whose choice was guided by quantum chemi

73 he hydride donor properties--hydricities--of organo-hydrides and how these are affected by metal ions

74 The coordination chemistry of organo-hydrides is critically surveyed and the use of me

75 c, photochemical or chemical regeneration of organo-hydrides such as NAD(P)H, including for driving e

76 chemistry of organic donors of hydride ion--organo-hydrides--such as dihydronicotinamides, other dih

77 ) by sustainable, recyclable, and metal-free organo-hydrides.

78 t an easy-to-synthesize thermally responsive organo-/hydro-gel that features covalently bound 10-phen

79 d anisotropic proteins are superior to other organo-/hydrogel systems.

80 mechanical anisotropy and microstructure of organo-hydrogels and adipose tissues, allowing the forma

81 n cancer cell migration and demonstrate that organo-hydrogels are particularly relevant tools to deve

82 udy these processes, we developed biomimetic organo-hydrogels that recreate structural, mechanical, a

83 ancer cells present invasive tropism towards organo-hydrogels, replicating the behaviour observed in

84 ovalently incorporate PDA nanoparticles into organo-/hydrogels via radical cross-linking, yielding tu

85 I(-) to I(2) or hypoiodide (HOI) leading to organo-I formation.

86 tically reduced to I(2) or HOI leading to an organo-I formation.

87 ion, that could enhance iodide oxidation and organo-iodine formation in soils and sediments.

88 quantification of surface coverage using the organo-iodines formed during modification.

89 s this challenge, we designed supramolecular organo-ionic (ORION) electrolytes that are viscoelastic

90 l potential, we synthesized a library of six organo-Ir(III) half-sandwich [(eta(5)-Cp(X))Ir(N N)Cl](+

91 We present a new class of organo-iridium drug candidates bearing a structural feat

92 Organo-lead halide perovskite solar cells have emerged a

93 Organo-lead halide perovskite solar cells have gained en

94 Organo-lead halide perovskite solar cells represent a re

95 tandem hydrosilylation with mixed main-group organo-Lewis acid (LA) catalysts [Al(C6F5)3 + B(C6F5)3]

96 Zn), and (iv) by transmetalation reactions (organo-Li and Mg transmetalations with ZnCl(2) or ZnO(Pi

97 review highlights the use of functionalized organo-Li, -Mg and -Zn reagents for the construction and

98 ure using the layered silicate magadiite and organo-magadiite modified with polyethylenimine (PEI).

99 or bottom-up syntheses employing low valent organo-main group element sources.

100 skite family, which combines solid-state and organo-main-group chemistry.

101 uch as the isolation of catalytically active organo-manganese(I) complexes, 1,3-dienyl-intermediates,

102 The catalytic mechanism of the organo-mediated Beckmann rearrangement has been modeled

103 enthalpies of the extractant and respective organo-metal complexes, analogous to the additivity prin

104 crystalline minerals and coprecipitation of organo-metal complexes, as well as C loss via anaerobic

105 Solar cells based on organo-metal halide perovskites have gained unprecedente

106 s, that were identified as sulfate-, oxide-, organo-metal-, and chloride-based compounds.

107 ocatalysis, NHC-organocatalysis, cooperative organo/metal catalysis, bifunctional organocatalysis, di

108 tween the Bragg-plasmon mode supported by an organo-metallic array and molecular excitons in the form

109 h-density storage of genetic information and organo-metallic materials processing.

110 xcellent catalytic activity for alkyl, aryl, organo-metallic substituted aldehydes and reducing sugar

111 We demonstrate this for organo-metallic vapor phase epitaxy of (0001) GaN.

112 Substrate binding occurs at a complex organo-metallocluster called FeMo-cofactor (FeMo-co).

113 of fertilization practices, mineral (M) and organo-mineral (OM), on molecular composition of Nero di

114 oils, with progressively poorer agreement in organo-mineral and organic soils.

115 no CaCO3, suggesting a strong role of Ca in organo-mineral assemblage formation.

116 ervations, we present a structural model for organo-mineral associations based on the coordination of

117 Colloidal organo-mineral associations contribute to soil organic m

118 ic processes could have abiotically produced organo-mineral associations displaying morphological and

119 However, direct investigation of organo-mineral associations has been hampered by a lack

120 eochemical, and mineralogical composition of organo-mineral associations in a chert sample from the c

121 The role of organo-mineral associations in regulating glyphosate ret

122 tics of subsized fractions of fine colloidal organo-mineral associations in soils and explores the im

123 able insights into the potential pathways of organo-mineral associations involving Mn-oxides and thei

124 Our results show that organo-mineral associations mainly form at medium curvat

125 To obtain the organo-mineral associations necessary for the study of b

126 usions about the origin of most Paleoarchean organo-mineral associations therefore requires further c

127 Given the ubiquity of organo-mineral associations, the shift toward AMPA forma

128 ering congruency influences the formation of organo-mineral associations, thereby modulating the acce

129 a new step in the high-resolution imaging of organo-mineral associations, while shedding further ligh

130 g and/or oxidizing organic molecules through organo-mineral associations.

131 nic molecules, at least temporarily, through organo-mineral associations.

132 and aluminosilicates with organic matter in organo-mineral associations.

133 diversity, consistent with the formation of organo-mineral bonds(8) but inconsistent with selective

134 To test how microbial metabolism and organo-mineral complexation alter amino acid and organic

135 ides the thermodynamic driving force for the organo-mineral complexation.

136 ften associated with organic matter and form organo-mineral complexes (OMCs), exhibiting different re

137 d plant inputs could modify the formation of organo-mineral complexes in tropical soils.

138 rimentally and computationally the effect of organo-mineral complexes on the nucleation kinetics of C

139 ic matter being occluded in aggregates or in organo-mineral complexes, and that C persisted in the fO

140 duced polarization (IP), to the formation of organo-mineral complexes, focusing on ferrihydrite (a co

141 e generate a large exchangeable reservoir of organo-mineral Fe colloids at the sediment water interfa

142 Organo-mineral interactions are known to regulate the tr

143 physicochemistry, Fe-bearing mineralogy, and organo-mineral interactions in magnetite Fe ore tailings

144 rminations can help improve understanding of organo-mineral interactions in soils.

145 pools.Most molecular scale knowledge on soil organo-mineral interactions remains qualitative due to i

146 ar binding provide mechanistic insights into organo-mineral interactions, which could potentially inf

147 ich is governed by its unique provenance and organo-mineral interactions.

148 oil carbon stabilization is mainly driven by organo-mineral interactions.

149 At the organo-mineral interface, 88% (72-92%) and 33% (16-53%)

150 nding of glyphosate behavior at redox-active organo-mineral interfaces and inform sustainable soil ma

151 amental insights into reactions happening at organo-mineral interfaces in soils.

152 We aim to understand how mechanisms at the organo-mineral interfaces influence SOC persistence in t

153 rganic interfaces in contrast to exclusively organo-mineral interfaces.

154 umulation of organic matter within aggregate organo-mineral microstructures has not yet been confirme

155 the pH-dependent oxyanion competition of the organo-mineral oxide fraction can be described.

156 microbial processes mediate the formation of organo-mineral particles in streamwater, with potential

157 For instance, erosion of upper organic and organo-mineral soil horizons provides a higher amount of

158 itter and py-OM C and N into uncomplexed and organo-mineral SOM fractions and CO2 fluxes and determin

159 Modifications were composed of organo-modification with different amounts of surfactant

160 Release assessment of organo-modified montmorillonite (O-MMT) nanoclay and the

161 ied montmorillonite (O-MMT) nanoclay and the organo-modifiers (surfactants) was performed on two type

162 A library of functionalized organo mono- and bis-selenides, including a potent biolo

163 The conversion of inorganic NOx species to organo-N compounds is an important component of the glob

164 is process, we investigated the formation of organo-nitrogen and light absorbing materials in evapora

165 unds found in aerosols, such as amino acids, organo-nitrogen compounds, and phenolic compounds have s

166 ma-bonded trans-bent [RSbSbR](*-) (R = bulky organo- or Ga-groups) that formally contain the Sb(2)(*3

167 The merger of photocatalysis with organo- or metalla-photocatalysis has brought novelty an

168 e to previously reported reactions involving organo- or photocatalytic strategies.

169 -size layers of C forms were detected at the organo-organic interface, showing alkyl C and nitrogen (

170 ron energy loss spectroscopy (EELS), we show organo-organic interfaces in contrast to exclusively org

171 te different stabilization processes than at organo-organic interfaces.

172 nine sulfoximine increase the selectivity of organo-Os complex FY26 for human ovarian cancer cells ve

173 exposed to three other structurally related organo-Os(II) compounds correlated with their antiprolif

174 ew light on the mechanism of action of these organo-osmium complexes.

175 contrast to platinum drugs, exposure to this organo-osmium compound does not cause significant apopto

176 ues of meso-fused carbatriphyrins(2.1.1) and organo P(V) complex of one of the meso-fused carbatriphy

177 The organo P(V) complex of one of the meso-fused carbatriphy

178 Harnessing the organo-palladium intermediates generated from electrophi

179 We report an organo-paramagnetic switch consisting of a linked bis(vi

180 dentified for its property to be modified by organo-phosphates (OPs), which in humans cause neuropath

181 Poly(organo)phosphazenes are a family of inorganic molecular

182 Aggregates formed between organo-phosphoric acids and imine bases in aprotic solve

183 eneous hydrolysis and alcoholysis of various organo-phosphorus (OP) compounds on the surface of KF/Al

184 alization of P4 and its transformation into (organo-)phosphorus compounds and materials of added valu

185 r the construction of densely functionalized organo-phosphorylated chromenes in good yields.

186 n the use of photocaged bases/nucleophiles, (organo)-photo catalysts, or radical photoinitiators, our

187 rd mechanistic pathway for thiourea-mediated organo-photocatalysis.

188 s salient features are the utilization of an organo photocatalyst, mild reaction conditions, and broa

189 Of note, the C(1)-symmetric organo/photocatalyst has shown a better catalytic activi

190 To address this, organo-photocatalysts that are based on atropisomeric th

191 yl bromides employing visible-light-mediated organo-photocatalytic SET processes.

192 We report an organo-photocatalyzed carboacylation reaction that offer

193 lication in optoelectronic devices of hybrid organo-plumbate or stannate are a hot topic of academic

194 ws light on the new properties of the hybrid organo-plumbate or stannate compounds and provides a new

195 Specifically, we investigate the impact of organo-pnictide ligands with varying steric and electron

196 dative environments is competitive with many organo-polyelectrolytes.

197 olecular constructs encompasses two twisted [organo-Pt(II)<--pyridine] coordination based irregular h

198 unctional groups can be delivered at once to organo-rare earth complexes, (L)MR(2) and (L)(2)MR (M =

199 ation in pyrite while promoting formation of organo-Re adducts; the latter are too mobile and reactiv

200 majority of accumulated Se was converted to organo-Se.

201 ed Se similarly with speciation dominated by organo-selenide ( approximately 61%).

202 We recently showed that organo-selenium compounds covalently attached to differe

203 Organo-selenium compounds detected were dimethyl selenid

204 urrent study investigates the efficacy of an organo-selenium dental sealant (SeLECT-Defense(TM) seala

205 ese bacteria produced both organo-sulfur and organo-selenium in the headspace gases above the culture

206 To determine if organo-selenium inhibits bacterial growth under the seal

207 0% of total selenium was biotransformed into organo-selenium species in which MeSeCys and SeMet were

208 The organo-selenium was synthesized and covalently attached

209 tic removal of silica cluster templates from organo-silica hybrid patchy particles.

210 tors can be achieved by the hybridization of organo-silicon structures (silicones, siloxanes, silsesq

211 monolayer on the surface to facilitate their organo-solubility and compatibility in a liquid-crystal

212 Using either organo-soluble bases or the newly introduced solid-state

213 Body condition, organo-somatic indices, and immunity were not affected b

214 Enantioselective organo-SOMO catalysis has, in the last two years, been t

215 ramolecular alpha-arylation of aldehydes via organo-SOMO catalysis was investigated using density fun

216 plexes were selected by using suitably sized organo substituents.

217 this work, we investigated the stability of organo-sulfate assemblages under Martian-like UV irradia

218 ysis of sand extracts detected S(w)C(x)H(y) (organo-sulfides) and elemental sulfur; XPS also indicate

219 As a member of the organo sulfidoboron (RBS) family, the hitherto elusive e

220 th to access the previously obscure class of organo sulfidoboron molecules, which are difficult to ac

221 in of chemical reactions ultimately forming (organo) sulfur molecules-among them precursors to sulfur

222 te or selenite, these bacteria produced both organo-sulfur and organo-selenium in the headspace gases

223 Organo-sulfur compounds detected were methanethiol, dime

224 A detailed description of the reactivity of organo-sulfur compounds is reported here with the aim of

225 The availability of a wide range of organo-sulfur species provides the opportunity for devel

226 l-catalyzed C-C bond forming reactions using organo-sulfur species.

227 (x)H(y), C(x)H(y)O(z), and S(w)C(x)H(y)O(z) (organo-sulfur) compounds.

228 ubset of boundary conditions converges to an organo-sulfur-based proto-metabolic network fuelled by a

229 s and in the melt veins, reflecting specific organo-synsthesis processes in close interaction with th

230 ng a direct relationship between the massive organo-synthesis occurring in interstellar clouds and th

231 The novel electrophilic organo-tantalum catalyst AlS/TaNp(x) (1) (Np=neopentyl)

232 e how to define and correlate cone angles of organo-trifluoroborates (R-BF(3) (-)) to the affinities

233 sforming growth factor-alpha were assayed in organo-typic cultures of utricles from the mature, undam