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1 f the polymerization is a tris-polymethylene organoborane.
2 ng but promising method for the synthesis of organoboranes.
3 are obtainable from the intermediate chiral organoboranes.
4 and atom-economic tool for the synthesis of organoboranes.
5 d for a highly enantioselective synthesis of organoboranes.
6 catalyst provided access to 16 novel chiral organoboranes.
8 latoboryl nucleophile with the electrophilic organoboranes, 9-BBN and Ph3 B, provide facile B-B' sing
9 ifunctionalization of terminal alkynes using organoboranes and allylic carbonates as coupling partner
10 es or the transfer of special units from the organoboranes and represent a useful generalization of t
12 ttractive endeavor, given that the resulting organoboranes are privileged synthons of utmost relevanc
20 aring almost any alkyl group available using organoborane chemistry and incorporating all features of
21 or the cross-coupling of formate esters with organoboranes, forming aldehydes under mild, additive-fr
24 ctions of aryl-stabilized sulfur ylides with organoboranes has been studied under a variety of condit
27 tic potential of the expected functionalised organoboranes, however, many groups have recently focuse
31 98:<2 site selectivity and furnish secondary organoborane isomers that complement those obtained thro
32 simple and intuitive matching of weak/strong organoborane LA and amine LB pairs offers access to a la
33 e homologation of phosphorus carbenoids with organoboranes leads to alpha-boranophosphorus compounds,
34 etermination of the isomeric distribution in organoborane mixtures resulting from common organoborane
36 particular focus has been the generation of organoboranes, organosilanes and organostannanes from si
38 mologation reaction to cyclic and polycyclic organoboranes permits the construction of unique oligome
43 Through this simple KH treatment, complex organoborane reaction mixtures are converted to the corr
44 al and straightforward route to these chiral organoborane reagents in one-pot has been developed alon
45 yde and ketone substrates using these chiral organoborane reagents in subsequent coupling reactions.
47 typal Lewis acids such that common routes to organoboranes rely on the reactivity of boron as an elec
48 ompete or possibly outperform the ubiquitous organoboranes, several groups, including ours, have enga
49 with pre-generated organozinc, Grignard and organoborane species has been used to furnish diverse mo
50 ferent approach toward highly functionalized organoborane synthesis by using recoverable ultrathin ca
51 d homolytic substitution (S(H)2) mechanisms, organoboranes that bear groups that can stabilize tetrac
52 rtunity for the development of new routes to organoboranes, the synthesis of current candidates is ge
53 ickel-catalyzed reaction with organozincs or organoboranes to afford densely functionalized cyclohexe
55 type reaction of imines, acid chlorides, and organoboranes to form alpha-substituted amides is descri
57 ccessible phosphorescence of heavy atom-free organoboranes via photochemical switching of sterically
59 thetic target of this method, polymeric star organoboranes with molecular weights of 1.5 million have
61 involves initial formation of a zwitterionic organoborane.ylide complex which breaks down in a rate-l