ライフサイエンスコーパス: organometallic

1 not yet been introduced via the addition of organometallics.

2 ter linked by a cysteinyl bridge to a unique organometallic [2Fe](H)-subcluster assigned as the site

3 s solution, a critical feature for achieving organometallic ACS activity, and binds CO and -CH3 group

4 ergo different kinds of reactions, including organometallics addition, metal catalyzed vinylation and

5 s led to the development of a broad range of organometallic and coordination compounds featuring prop

6 ver, Ag(111) and Ag(110) on the formation of organometallic and covalent structures for Ullmann-type

7 The incorporation of CO(2) into organometallic and organic molecules represents a sustai

8 Examples from organic, inorganic, organometallic and surface chemistry as well as molecula

9 polymers offer an alternative to prevailing organometallics and nanomaterials, and they may benefit

10 ch as coordination complexes and frameworks, organometallics and organic molecules.

11 ilyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles.

12 pact on various aspects of the coordination, organometallic, and catalytic chemistry of the 3d metals

13 that the effect of bulky groups in organic, organometallic, and inorganic chemistry is not only repu

14 In principle, these organometallic APNCs should not require harsh pretreatme

15 However, 2-pyridine organometallics are capricious coupling partners and 2-p

16 SO4 thus gave methylated Fc, contrary to non-organometallic aromatics giving mixtures of HO and MeO d

17 Here we demonstrate that ordered organometallic arrays can be formed spontaneously by rea

18 hts obtained from the application of our new organometallic aryl-Co(III) compounds in alkyne annulati

19 , we provide crystallographic evidence of an organometallic aryl-Co(III) intermediate proposed in 8-a

20 dies indicates that a mechanism involving an organometallic aryl-Co(III)-alkynyl intermediate species

21 nyl N-heterocyclic carbenes (NHCs) to create organometallic -ate complexes of Au(I) that serve both a

22 arting with aromatic substrates in the 1980s organometallic backbones, e.g. ferrocenes, have also bee

23 Organic and organometallic-based electroactive materials are green a

24 metal catalysis or stoichiometric amounts of organometallic building blocks.

25 ber of synthetic steps and the production of organometallic byproducts.

26 ith other families of molecules that present organometallic C-Au bonds, we conclude that the conducta

27 chemo- and position selectivities within an organometallic C-C activation manifold.

28 chemistry (SOMC), and, by extension, surface organometallic catalysis (SOMCat), have demonstrated tha

29 aspects of single atom catalysis and surface organometallic catalysis by considering several specific

30 predisposing the incarcerated cobalt ion for organometallic catalysis has remained obscure.

31 The viability of excited-state organometallic catalysis via direct photoexcitation has

32 Here, we demonstrate excited-state organometallic catalysis via such an activation pathway:

33 tors, with a particular focus on homogeneous organometallic catalysis.

34 f second coordination sphere interactions in organometallic catalysis.

35 nyl groups were probed as substituents in an organometallic catalyst.

36 Single-site supported organometallic catalysts bring together the favorable as

37 rization of ubiquitous isopropyl moieties by organometallic catalysts has remained an unanswered chal

38 itization mechanisms to access excited-state organometallic catalysts have lagged far behind.

39 ocess that requires homogeneous liquid-phase organometallic catalysts with corrosive halide-based coc

40 tly transformed into novel single-site solid organometallic catalysts without homogeneous analogs for

41 ole in modifying and controlling homogeneous organometallic catalysts, and they often provide a conve

42 ortant in the design of electrocatalysts and organometallic catalysts.

43 there is an exchange of ligands between two organometallic catalysts?

44 e spectroscopies reveals that it contains an organometallic center in which the 5' carbon of a SAM-de

45 In sharp contrast, organometallic cerium(iv) compounds are still exceedingl

46 gen-bonded 2D networks, which transform into organometallic chains and rings after debromination.

47 culations reveal that the template effect of organometallic chains obtained under specific kinetic co

48 A bright future is ahead of the organometallic chemist, thanks to these novel technologi

49 kane binding, by using solid-state molecular organometallic chemistry (SMOM-chem), well-defined isobu

50 (2)(t)Bu)H{IrH(2)(Cp*)}], 6, using a surface organometallic chemistry (SOMC) approach.

51 t the molecular level using advanced surface organometallic chemistry (SOMC) characterization techniq

52 rous MOF, namely Zr-NU-1000, using a Surface Organometallic Chemistry (SOMC) concept and methodology.

53 In another extreme of the spectrum, surface organometallic chemistry (SOMC), and, by extension, surf

54 H(3))(CF(3))(2); py = pyridine), via surface organometallic chemistry (SOMC).

55 xylated silica (silica700) using the surface organometallic chemistry approach.

56 ve synthetic coordination and, increasingly, organometallic chemistry are at the heart of advances in

57 this analytical tool had been rarely used in organometallic chemistry before but turns out to be a se

58 basic principles in molecular catalysis and organometallic chemistry can be effectively used to desi

59 rved, which shows that fundamental neptunium organometallic chemistry can provide new insights into t

60 ligand design and exploration of fundamental organometallic chemistry coupled with mechanistic unders

61 A key organometallic chemistry feature of the NiFe active site

62 anoparticles (ca. 2 nm) prepared via surface organometallic chemistry from a mesityl complex [Cu5Mes5

63 e (NHC) compounds in organic, inorganic, and organometallic chemistry has been extended to another di

64 undamental bonding model in coordination and organometallic chemistry is the synergic, donor-acceptor

65 the historic and current development of the organometallic chemistry of cerium in its oxidation stat

66 Over the past decade the organometallic chemistry of gold(III) has seen remarkabl

67 cent progress in the preparative organic and organometallic chemistry of polypyridines has resulted i

68 These functions are connected by the organometallic chemistry of the MNR2BH3 group.

69 Unlike the organometallic chemistry of uranium, which has focused s

70 for adjustable platforms for coordination or organometallic chemistry, anion binding, or mechanistic

71 disciplines of inorganic chemistry including organometallic chemistry, bioinorganic chemistry, and cl

72 e or single atom), here prepared via surface organometallic chemistry, by grafting [(COD)Pt(OSi(OtBu)

73 hylated variants, are extremely important in organometallic chemistry.

74 ay constitute concepts of broad relevance to organometallic chemistry.

75 n are defining reactions of transition-metal organometallic chemistry.

76 mechanistically using the familiar tools of organometallic chemistry.

77 perhaps be employed in synthetic organic or organometallic chemistry.

78 They have also been prepared via surface organometallic chemistry.

79 rged as an important approach in organic and organometallic chemistry.

80 , agrochemistry, coordination chemistry, and organometallic chemistry.

81 ways been the most important alkali metal in organometallic chemistry.

82 a broad range of applications in organic and organometallic chemistry.

83 ry, medical research, radical reactions, and organometallic chemistry.

84 hemists but may be a little less familiar to organometallic chemists.

85 al addressability in a series of synthesized organometallic, chromium(IV) molecules.

86 ntal evidence for intermediates, although an organometallic Co(III) species is generally implicated.

87 Cobalamin is a complex organometallic cofactor that is processed and targeted v

88 lot and determined that the inclusion of the organometallic complex in the cavitand was endothermic a

89 ermine the three-dimensional structure of an organometallic complex on an amorphous silica surface us

90 COD was 5 kcal mol(-1) higher as an included organometallic complex than as free in solution.

91 ursues ligand-induced activation of a stable organometallic complex toward PCET reactivity.

92 ve function theory calculations on an Am(3+) organometallic complex, [Am(C(5) Me(4) H)(3) ] (1).

93 a rare cross-coupling reaction of a tertiary organometallic complex.

94 the first time by successively grafting two organometallic complexes [W(Me)6 (1) followed by ZrNp4 (

95 cesses involved in the disproportionation of organometallic complexes and have allowed the identifica

96 ules toward the formation of one-dimensional organometallic complexes and N-GNRs are gained by a comb

97 ign of many transition metal coordination or organometallic complexes and their assessment as antican

98 dox control or stabilization by formation of organometallic complexes following post-eruptive redistr

99 Studies of transuranic organometallic complexes provide a particularly valuable

100 rbenes (NHCs) have been known as ligands for organometallic complexes since the 1960s, these carbenes

101 rmational and configurational preferences of organometallic complexes stabilized by vicinal heteroato

102 s shown to enable the efficient synthesis of organometallic complexes that are difficult to generate

103 metal catalysis has traditionally relied on organometallic complexes that can cycle through a series

104 Organometallic complexes with metal-nitrogen/carbon (M-N

105 biomedical and bioanalytical applications of organometallic complexes, that is, metal compounds with

106 ication and characterization of the relevant organometallic complexes, uniquely exhibiting the trappi

107 Two compatible organometallic complexes, W(Me)6 (1) and TiNp4 (2), were

108 nt in many biologically active compounds and organometallic complexes.

109 that can be used for the isolation of chiral organometallic complexes.

110 ls, peptides, chiral catalysts, polymers and organometallic complexes.

111 ic and electronic structures of these Cu(II) organometallic complexes.

112 Organometallic complexes: these two words jump to the mi

113 dE, HydF, and HydG-synthesize and insert the organometallic component of the [FeFe]-hydrogenase activ

114 o date been limited to use of the BCP as the organometallic component, which restricts scope due to t

115 ylcaffein-8-ylidene)2 ]BF4 is an exceptional organometallic compound of profound interest as a prospe

116 Iron(0) pentacarbonyl is an organometallic compound with a long history.

117 including the radiochemical synthesis of one organometallic compound), and the available anhydrous st

118 tens of metal atoms, bridge the gap between organometallic compounds and crystalline metal nanoparti

119 This review describes organometallic compounds and materials that are capable

120 m platform includes voltammetric analysis of organometallic compounds and quantitative analysis of as

121 we report the synthesis of three new Np(III) organometallic compounds and the characterization of the

122 be used for the removal of toxic metals and organometallic compounds from aqueous systems.

123 main challenge is to transfer air-sensitive organometallic compounds from inert atmosphere to the io

124 Rational characterization of most organometallic compounds is hampered by their high react

125 s comprising singlet fluorophores or iridium organometallic compounds provided further improved detec

126 s, a deviation from traditional strong-field organometallic compounds that promote catalytic C-C bond

127 These results show that initial binding of organometallic compounds to MerB occurs at D99 followed,

128 d isolate a myriad of fleeting species (i.e. organometallic compounds, cationic species, radical init

129 that treatment of N-chlorodialkylamines with organometallic compounds, for example, Grignard reagents

130 While facilitating the synthesis of organometallic compounds, these enabling technologies al

131 nzosulfonamides as well as challenging alkyl organometallics containing beta-hydrogen afford alkylate

132 we report the synthesis of the mixed-valent organometallic copper APNC, [Cu20(CCPh)12(OAc)6)] (1), v

133 and benzhydryl bromides in competition with organometallic coupling (ipso) is shown.

134 ry alkylaluminum reagents can be utilized as organometallic coupling partners.

135 We have introduced a new class of stable organometallic Cr reagents (compounds 1-4) that are read

136 Despite advances in organometallic cross-coupling of alkyl electrophiles, th

137 rcumvents prefunctionalization, isolation of organometallic cross-coupling partners, and/or stoichiom

138 nthetic schemes designed around conventional organometallic cross-coupling.

139 The organometallic derivatives also retained strongly aromat

140 ds, thereby circumventing the preparation of organometallic derivatives and decreasing the overall pr

141 was converted into silver(III) and gold(III) organometallic derivatives.

142 This finding indicates that the new organometallics display different modes of action than t

143 Since then, these organometallic entities have proven to be uniquely effec

144 This arrangement includes the biomimetic and organometallic Fe-C sigma bond, which enables bidirectio

145 Cp2, of the {FeNO}(7) complex 1 leads to the organometallic {FeNO}(8) species 2.

146 classes of aqueous redox-active organics and organometallics for which cycling lifetime results have

147 lkanes bind in preference to the HFCs to the organometallic fragments employed in this study.

148 or Xe in a non-porous solid-state molecular organometallic framework of [Rh(Cy(2) PCH(2) PCy(2) )(NB

149 of unmodified CDs' inclusion complexes with organometallic guests and update the research in this fi

150 K, the axial spinning motion of the included organometallic guests was slow on the (1)H NMR time scal

151 Organometallic halide perovskite solar cells (PSCs) have

152 Highly reproducible organometallic-halide-perovskite-based devices are fabri

153 ollowed by reaction with both aryl and alkyl organometallics have been developed.

154 s are synthesized using a new, highly active organometallic heterodinuclear Zn(II)/Mg(II) catalyst ap

155 Anchoring organometallic homogeneous catalysts to surfaces creates

156 This provides a direct link with the organometallic homogeneous Rh(I) complexes capable of ca

157 Extended organometallic honeycomb alkynyl-silver networks have be

158 lar to that of protonation reactions to more organometallic-inspired reactivity, including insertions

159 s, we evaluate the circumstances in which an organometallic intermediate can direct the 5'-dAdo* towa

160 er reductively cleaves SAM to form the Omega organometallic intermediate in which the 5'-deoxyadenosy

161 nstrate that this unusual reaction forms the organometallic intermediate Omega in which the unique Fe

162 explain how 5'-dAdo. subsequently forms the organometallic intermediate Omega.

163 rnover of substrate tyrosine and forming the organometallic intermediate Omega.

164 Organometallic intermediate species were observed and ch

165 s used to follow the emergence of metastable organometallic intermediates and their conversion to the

166 HydG generates the first organometallic intermediates in this process, ultimately

167 revealed the mixed Li/Mn constitution of the organometallic intermediates involved in these reactions

168 nowledge of how oxygen reacts with important organometallic intermediates.

169 ethyl group through a series of nickel-based organometallic intermediates.

170 A low-coordinate, high spin (S = 3/2) organometallic iron(I) complex is a catalyst for the iso

171 de reduction, which includes metals, alloys, organometallics, layered materials and carbon nanostruct

172 their derivatives may provide a new type of organometallic ligand for high-performance single-molecu

173 Monocarbaporphyrinoids are superior organometallic ligands and form stable complexes with co

174 ng how covalently bonding, soft, carbocyclic organometallic ligands provide an excellent platform for

175 ly precise nanoclusters (APNCs) protected by organometallic ligands, such as acetylides and hydrides,

176 diversity and potential in e.g. coordination/organometallic main group and transition metal chemistry

177 c (Au(I)(-)/Ag(I)(+); Au(I)(-)/Ir(I)(+)) and organometallic/main group ion pairs (Au(I)(-)/(CPh(3)(+)

178 ared in fair to good yields by a Zn-mediated organometallic Mannich reaction, followed by an intramol

179 suggests that these are of heavy organic or organometallic material.

180 to further demonstrate the compatibility of organometallic mechanisms with the complex environment o

181 Organometallic medicinal chemistry is a relatively young

182 ted magnesium(I) adduct complexes as soluble organometallic models for the study of reductive C-C bon

183 ation of peptides to such medicinally active organometallic moieties started only about 20 years ago,

184 ne (either N- or C-terminally, or both) with organometallic moieties will be described, including the

185 meworks have been decorated with an array of organometallic moieties, the incorporation of metallocar

186 group transfer was specific not only for the organometallic moiety only, but for other acyl groups in

187 is challenge was addressed by introducing an organometallic molecular compound, ferrocene, as a new p

188 rface engineering of functional redox-active organometallic molecule can be efficient in the field of

189 ty years have passed since the foundation of organometallic neptunium chemistry, and yet only a handf

190 ytic systems proposed to involve high-valent organometallic Ni intermediates.

191 eophyl) allows for the synthesis of isolable organometallic Ni(II), Ni(III), and Ni(IV) complexes.

192 characterization, and reactivity studies of organometallic Ni(III) complexes of general structure Tp

193 For example, organometallic Ni(III) intermediates with aryl and/or al

194 thiophosphorus acids from H-phosphinates, an organometallic nucleophile, and quenching with elemental

195 view, we describe the use of enantioenriched organometallic nucleophiles in stereospecific, Pd-cataly

196 tionally stable, enantioenriched, main-group organometallic nucleophiles to form C(sp (3))-C(sp (2))

197 acceptor, undergo reactions with a range of organometallic nucleophiles to generate alpha-functional

198 titution reactions of alkyl electrophiles by organometallic nucleophiles, including enantioconvergent

199 essible and stable olefins as surrogates for organometallic nucleophiles.

200 regiospecific ring-opening at C6 position by organometallic nucleophiles.

201 es have been altered by their conjugation to organometallic (OM) moieties.

202 existing coupling protocols with tert-alkyl organometallic or -alkyl halide reagents, and it enables

203 Metal centers in X-ray structures of small organometallic or coordination complexes are often extre

204 er transition-metal catalysis, the generated organometallic or radical intermediate is primed for fur

205 The binding of organometallic osmium carbonyl clusters onto the surface

206 Solution-processed organometallic perovskite solar cells have emerged as on

207 Organometallic perovskites, solution-processable materia

208 operty relations of a novel, dual-responsive organometallic poly(ionic liquid) (PIL), consisting of a

209 as those inorganic polymers (more precisely organometallic polymers) appear to be hitherto the only

210 on, were successfully hydrogenated using the organometallic precatalysts, [(eta(5)-C(5)Me(5))Rh(N-C)H

211 An organometallic precursor featuring an Fe-C bond between

212 g stability with reactivity in generating an organometallic precursor that is useful in catalysis.

213 en shown to construct a [Fe(Cys)(CO)(2)(CN)] organometallic precursor to the binuclear cluster.

214 nce studies on electron-induced reactions of organometallic precursors, cis-Pt(CO)2Cl2 (1) was design

215 toward engineering biological catalysts for organometallic processes.

216 metal exchange because chelation anchors the organometallic proximal to the electrophilic, tetrasubst

217 anistic studies are consistent with a hybrid organometallic-radical process.

218 E is broadly applicable to study organic and organometallic reaction classes, including addition, sub

219 undamental mechanistic insights into complex organometallic reaction pathways.

220 Reductive elimination is an elementary organometallic reaction step involving a formal oxidatio

221 y redox-neutral elimination as an elementary organometallic reaction step, may constitute concepts of

222 te the ability of these complexes to undergo organometallic reactions that are relevant to C(sp(2) )-

223 eir rich and varied cycloaddition chemistry, organometallic reactions, and theoretical studies that s

224 ng of C-N, C-O and C-S bonds via fundamental organometallic reactions, i.e. oxidative addition, reduc

225 ations, cycloadditions, and several types of organometallic reactions.

226 potential applications for a broad range of organometallic reactions.

227 A deeper understanding of fundamental organometallic reactivity of gold(III) has revealed unex

228 al catalysis, bioinspired model systems, and organometallic reactivity.

229 The reaction negates any requirement of organometallic reagent and needs a shorter reaction time

230 The addition of an organometallic reagent to the commercially available sul

231 e alkylations, only one of which requires an organometallic reagent.

232 etal-trapping strategies with lower polarity organometallic reagents (Mg(CH2 SiMe3 )2 and Al(TMP)iBu2

233 is of sulfonimidamides from widely available organometallic reagents and amines.

234 classical carbonyl additions, stoichiometric organometallic reagents and discrete alcohol-to-carbonyl

235 ctional groups incompatible with many common organometallic reagents and provides access to a broad r

236 artners obviates the need for stoichiometric organometallic reagents and tolerates a broad range of f

237 pe and by the use of highly reactive premade organometallic reagents at cryogenic temperatures.

238 Alkyl, (hetero)aryl, and alkenyl organometallic reagents can all be used as the first or

239 ve to the longstanding use of stoichiometric organometallic reagents in carbonyl addition.

240 ompatibility, requiring the use of preformed organometallic reagents in conjunction with a stoichiome

241 The range of effective organometallic reagents includes alkyl, allyl, alkynyl,

242 lic acids) and one low-availability reagent (organometallic reagents or alkyl iodides).

243 s but traditionally relies on stoichiometric organometallic reagents that are difficult to prepare, s

244 Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpe

245 Addition of Grignard or other organometallic reagents to 2-halocyclohex-2-en-1-ones be

246 actions that traditionally require preformed organometallic reagents to be conducted catalytically in

247 ng agent, pyridine boronic esters react with organometallic reagents to form a dihydropyridine boroni

248 e report the synthesis of sulfinamides using organometallic reagents, a sulfur dioxide reagent, and n

249 amide bond N-C cross-coupling reactions with organometallic reagents, are intrinsically twisted aroun

250 functionalizations of [1.1.1]propellane with organometallic reagents, organoboronic esters, and a var

251 The reaction, devoid of sensitive organometallic reagents, takes advantage of an in situ g

252 ophiles, for instance, alcohols, amines, and organometallic reagents, to provide a broad range of N-f

253 the traditional use of highly reactive alkyl organometallic reagents.

254 molecules without the use of stoichiometric organometallic reagents.

255 s is difficult because of high reactivity of organometallic reagents.

256 typically predicated on the use of reactive organometallic reagents.

257 so circumvents the use of moisture-sensitive organometallic reagents.

258 al alternative to conventional "organic" or "organometallic" realms.

259 A ferraquinone-ferrahydroquinone organometallic redox couple was prepared and characteriz

260 The current organometallic regime is the most regular one.

261 ly relevant C-C scission, and a well-defined organometallic rhodium(III) complex was identified as a

262 far this is problematic because established organometallic Ru precursors contain large organic ligan

263 sumanene (C21 H12 ) affords a novel type of organometallic sandwich [Cs(C21 H11(-) )2 ](-) , which c

264 rate a new synthesis route for the growth of organometallic sandwich molecular nanowires, taking the

265 (V) was the major species where as in juices organometallic Sb species were also present.

266 The organometallics showed inhibitory activity in the nanomo

267 a a variety of chemical approaches including organometallic, solvothermal/hydrothermal, templating, m

268 opic, and computational studies identify key organometallic species and PCET steps that control selec

269 Cross-couplings of alkyl halides and organometallic species based on single electron transfer

270 utylammonium acetate was found to remove the organometallic species from the surface, enabling soluti

271 by providing support for the intermediacy of organometallic species in radical SAM enzymes.

272 +) cluster, generating an ethyl-[4Fe-4S](3+) organometallic species termed Omega(E).

273 l reactive intermediates within the "zoo" of organometallic species that form on catalytic surfaces d

274 Highly reactive organometallic species that mediate reductive proton-cou

275 radical, as well as a small population of an organometallic species with an Fe-CH(3) bond, denoted Om

276 ic radical intermediates can reversibly form organometallic species, which helps to protect the free

277 rboxylic acids with both aryl and heteroaryl organometallic species.

278 differences can be extended to more complex, organometallic species.

279 ransfer reagent and helps in the fundamental organometallic steps by modulating the oxidation state o

280 can determine the exact nature of elementary organometallic steps remain limited, especially for sing

281 w mechanophores over previous generations of organometallic stress sensors stems from their reliance

282 Stoichiometric organometallic studies along with a comprehensive kineti

283 , ultrafast spectroscopy, and stoichiometric organometallic studies has enabled the elucidation of th

284 A combination of kinetic, spectroscopic, and organometallic studies reveals that a Ni-catalyzed, redu

285 ntion is given to the seminal stoichiometric organometallic studies which led to the corresponding ca

286 These observations of an organometallic surface intermediate, its elementary-step

287 was limited by the tools available for both organometallic synthesis and protein engineering.

288 largely unexplored class of one-dimensional organometallic systems with potential for exciting elect

289 ted to oxidation conditions or exchange with organometallics that are prepared from aryl halides.

290 across the metal centers in Cu(I) and Pd(II) organometallics that is assisted by the presence of a su

291 We identify Stannin, a peptide involved in organometallic toxicity, as the Hemotin functional homol

292 e been isolated and evaluated in fundamental organometallic transformations relevant to aldehyde form

293 Because fundamental organometallic transformations, such as oxidative additi

294 Here, we describe an alternative to the organometallic transmetallation step that is common in m

295 TMT, LiTMP performs the metalation, while an organometallic trap intercepts the emergent carbanion.

296 re picture has been derived for these unique organometallic variants of the key bioinorganic {FeNO}(x

297 These organometallic WCAs can be utilized to form both heterob

298 ive C-4 functionalization of quinolines with organometallics with nearly absolute regio- and stereose

299 on of C-I bonds followed by the formation of organometallic zigzag structures, consisting of molecule

300 l12](6-) nodes in ZrCl2-BTC, and then to the organometallic [Zr6(mu3-O)4(mu3-OLi)4R12](6-) nodes in Z