ライフサイエンスコーパス: outer sphere

1 ositive charges of the magnesium ion and its outer sphere.

2 nificantly greater than those calculated for outer sphere activation barriers, with deviations betwee

3 cetate 1h corroborate C-N bond formation via outer-sphere addition.

4 lyst, Rh(L)H(3) (3), forms, which sits as an outer-sphere adduct 3.H(3)BNMeH(2) as the resting state.

5 o the free energy, yielding a preference for outer-sphere adsorption at the gold surface for ideal hy

6 Outer-sphere adsorption is found to dominate over inner-

7 hematite surfaces and additionally revealed outer-sphere adsorption modes not seen in the EXAFS.

8 species is shown to display both inner- and outer-sphere adsorption to the flat {1014} and the stepp

9 mary amine catalyst with a methyl-terminated outer-sphere also produces alcohol, albeit at a rate tha

10 The outer-sphere analysis indicates an Fe-Zn separation of a

11 evealing a synergistic interaction involving outer-sphere and inner-sphere complexation between disso

12 Both outer-sphere and inner-sphere pathways for the reduction

13 acterizing the pretreatment parameters using outer-sphere and inner-sphere redox couples, we measured

14 ow comparable electrochemical activities for outer-sphere and inner-sphere redox reactions.

15 ing results, which demonstrate that NO(3)(-) outer-sphere and PO(4)(3-) inner-sphere complexes promot

16 Electron transfer is outer-sphere and uncoupled from proton transfer.

17 i-acidity of the ligand central ring and the outer-sphere anion.

18 -bond networks, neutral organic ligands, and outer-sphere anions on their phase-change thermodynamics

19 tic reactions: inner-sphere syn-addition and outer-sphere anti-addition (Friedel-Crafts-type mechanis

20 rature at which water binds in the inner and outer spheres arise primarily from entropic effects.

21 3.28 A in clay while in CWF As was either an outer-sphere As(V) phase or a discrete arsenate phase wi

22 s involved in the formation of the precursor outer-sphere associate appear to be important overall ra

23 O(2) activation and assess the influence of outer sphere atoms, in two Rubisco forms of contrasted O

24 exation-assisted deprotonation and undergoes outer-sphere attack by the electrophilic silylating reag

25 Ring-opening then occurs via outer-sphere beta-O elimination assisted by coordination

26 in which the stereodetermining step involves outer-sphere bromine abstraction from a [(bisphosphine)R

27 radical carbometallation pathway followed by outer-sphere C-C bond formation, which potentially opens

28 Rather, the lipid phosphate groups provided outer-sphere calcium coordination through intervening wa

29 yer; we propose counterions to be inner- and outer-sphere calcium ions, with a population of inner-sp

30 luminate general principles of non-selective outer-sphere cation binding in RNA structure and functio

31 Probe molecules were used to assess outer-sphere charge transfer (Fe(CN)6(4-)) and organic c

32 1-methylpyridinium iodide, provides an early outer-sphere charge-transfer excited state that reports

33 Outer-sphere chemical reduction gives the Lewis acid sta

34 An outer-sphere complex and a monodentate inner-sphere comp

35 ed through transition-state stabilization by outer-sphere complex formation with substrate.

36 At both I = 0.02 and 0.1 M, the outer-sphere complex loading reaches maximum at pH appro

37 dicated that Cr(VI) was loosely sorbed as an outer-sphere complex on Mn(IV)O(2), while Cr(III) was ti

38 t-energy structure calculated to be an As-up outer-sphere complex.

39 s in the first coordination shell similar to outer-sphere complexation and a second coordination with

40 r high pH can occur through either inner- or outer-sphere complexation mechanisms depending on adsorp

41 Outer-sphere complexation occurs at equilibrium together

42 tion, and the competition between inner- and outer-sphere complexation.

43 (SCM), we have shown that sulfate forms both outer-sphere complexes and bidentate-binuclear inner-sph

44 xes, whereas Cr(VI) likely adsorbs mainly as outer-sphere complexes and Cd(II) as a mixture of inner-

45 In contrast, the formation of outer-sphere complexes and subsequent conformation chang

46 exes formed via the sluggish conversion from outer-sphere complexes during interrupted flow.

47 significant increase in relative fraction of outer-sphere complexes for all three oxyanions with incr

48 te on schwertmannite, whereas selenate forms outer-sphere complexes in the aluminum octahedral interl

49 Pb(II) forms inner- and outer-sphere complexes on mineral surfaces, and this ads

50 n behavior of anions forming both inner- and outer-sphere complexes on mineral surfaces.

51 e(II) was associated with more weakly bound, outer-sphere complexes on silica-ferrihydrite compared t

52 ial utilization of monomeric MAOM, bound via outer-sphere complexes to common iron and aluminum (hydr

53 Air-drying drastically converts the outer-sphere complexes to the inner-sphere complexes.

54 (RH) on the concentrations of Li+ inner- and outer-sphere complexes was then explored, the concentrat

55 Results suggest also that metal involved in outer-sphere complexes would display isotopic exchange b

56 to alumina (001) as a mixture of inner- and outer-sphere complexes, but Nd displayed a greater propo

57 showed that REE can exist as both inner- and outer-sphere complexes.

58 plexes and Cd(II) as a mixture of inner- and outer-sphere complexes.

59 An outer-sphere concerted hydrogen transfer was found to be

60 Mechanistic studies reveal a surprising outer-sphere concerted metalation/deprotonation pathway

61 In contrast, in outer sphere contact ion-pairs 7, 8, 9, and 10, the anio

62 ns, consistent with its ability to make only outer sphere contacts.

63 ozyme is a unique model to study the role of outer-sphere coordinated cations in folding of a catalyt

64 Simulations reveal that outer-sphere coordinated Mg(2+) ions fluctuate on the sa

65 inuum of diffuse ions, we observe a layer of outer-sphere coordinated Mg(2+) that is transiently boun

66 of 41 types of inner-sphere and 95 types of outer-sphere coordinating patterns.

67 ore important to consider the possibility of outer-sphere coordination of catalytic metal ions in rib

68 the cleavage activity of RNase P, suggesting outer-sphere coordination of O6 on G379 to a metal ion.

69 lity of [CoCl(4)](2-), which facilitates its outer-sphere coordination to cationic resin-bound cobalt

70 ermic changes, consistent with predominantly outer-sphere coordination.

71 in an acyl-transferase ribozyme acts through outer-sphere coordination.

72 mode, type of ancillary ligand, solvent, and outer-sphere counteranions.

73 e ACET step is intrinsically slower than its outer-sphere counterpart by at least four orders of magn

74 dies, a mechanism is proposed which involves outer-sphere dehydrogenations promoted by a unique ruthe

75 t effects have been collected in favor of an outer-sphere deprotonation process after the formation o

76 yano-terminated catalyst, demonstrating that outer-sphere dielectric constant affects catalyst activi

77 ongly supporting a pathway that proceeds via outer-sphere dissociative electron transfer.

78 ive theoretical treatment of the kinetics of outer sphere electrochemical reactions.

79 faradaic current for either inner-sphere or outer-sphere electrochemical reactions.

80 kinetic analysis of field-effect-controlled outer-sphere electrochemistry on ultrathin back-gated Zn

81 cing agents for Br-Cu(II)/L complexes via an outer sphere electron transfer (OSET) mechanism, enablin

82 ster to the SAM, which otherwise has a large outer sphere electron transfer barrier.

83 ld facilitate O O bond cleavage of H2O2, but outer sphere electron transfer from a second H2O2 in ano

84 de to Cu(II) in one portion of the cycle and outer sphere electron transfer from Cu(I) to superoxide

85 and quantum-chemical calculations suggest an outer sphere electron transfer from the COF to the co-ca

86 n 4-fluoroiodobenzene and benzene through an outer sphere electron transfer pathway, which expands th

87 As a radical clock experiment ruled out outer sphere electron transfer, an inner sphere electron

88 are consistent with the previously proposed outer sphere electron-transfer mechanism for N-methylqui

89 ystematically tuned by exposure to dissolved outer-sphere electron acceptors.

90 agents do not facilitate defect formation by outer-sphere electron and/or proton transfers, and thus

91 suggest a difference in mechanism, likely an outer-sphere electron transfer (ET) mechanism at the SiO

92 o resolve the key electronic interactions in outer-sphere electron transfer (OS-ET), a cornerstone el

93 Data rule out outer-sphere electron transfer and two-electron oxidativ

94 The self-exchange rate constant for outer-sphere electron transfer between [Co(H(2)bim)(3)](

95 issolved CO(2) do not impede the kinetics of outer-sphere electron transfer but decrease the solution

96 pends on pH; (3) a significant inhibition to outer-sphere electron transfer for the Ru(IV)=O2+/Ru(III

97 t a selective adsorption mechanism involving outer-sphere electron transfer from the framework to for

98 ascorbate monoanion, which does not react by outer-sphere electron transfer in solution, and complex

99 Our results implicate an outer-sphere electron transfer mechanism for decarboxyla

100 r it capable of binding O(2) through such an outer-sphere electron transfer mechanism represents a pr

101 none mechanism operates, then an alternative outer-sphere electron transfer must also exist to accoun

102 ow Mg2+ concentrations that is attributed to outer-sphere electron transfer on the basis of the known

103 yl radical formation, and contrasts with the outer-sphere electron transfer pathway observed for (PPh

104 rations argue against oxidative addition and outer-sphere electron transfer pathways for perfluoroare

105 The second electron transfer, also an outer-sphere electron transfer process, occurs along a t

106 thermodynamic properties, consistent with an outer-sphere electron transfer process, the set of ligat

107 particles do not become deactivated for the outer-sphere electron transfer reaction after attachment

108 The one-electron pathway occurs by outer-sphere electron transfer to form an aryl radical r

109 ffusional encounter of O(2) with protein, an outer-sphere electron transfer to O(2), and proton trans

110 transfer (PCET) reactions can proceed via an outer-sphere electron transfer to solution (OS-PCET) or

111 ypyridyl ligand, activates alkyl iodides via outer-sphere electron transfer, allowing for the selecti

112 For strong reducing agents the initial outer-sphere electron transfer, alone or possibly couple

113 s step could take place: oxidative addition, outer-sphere electron transfer, inner-sphere electron tr

114 Even though this aspect influences the outer-sphere electron transfer, it was not recognized th

115 n various pieces of evidence against initial outer-sphere electron transfer, proton transfer, or subs

116 t with simple rate limitation by an initial, outer-sphere electron transfer, suggesting that the line

117 In terms of the Marcus theory of outer-sphere electron transfer, we show here that D283,

118 te, making the red site unfavorable for fast outer-sphere electron transfer, while providing an excha

119 tionship (FER) based on the Marcus theory of outer-sphere electron transfer.

120 ctron oxidant capable of effectively driving outer-sphere electron-transfer reactions with reagents h

121 librium acid association to 1 is followed by outer-sphere electron-transfer reduction of 2 by decamet

122 ion sphere of ruthenium via an unprecedented outer-sphere electrophilic fluorination mechanism.

123 Precise control of the outer-sphere environment around the active sites of hete

124 imary amine catalysts, consisting of a polar outer-sphere environment derived from cyano-terminated c

125 sign demonstrates promise in controlling the outer-sphere environment of synthetic molecular catalyst

126 inocatalysis are critically dependent on the outer-sphere environment.

127 xed mechanism based on simultaneous ACET and outer-sphere ET steps.

128 ized state pK of Mn(3+)SOD corresponds to an outer-sphere event whereas that of Fe(3+)SOD corresponds

129 Outer-sphere EXAFS analysis indicates an Fe-Zn separatio

130 Using the simple outer-sphere Fc(0/+) process (Fc = ferrocene) as a model

131 l kinetic barrier, entropic contributions to outer sphere H(2) splitting lead to a unique temperature

132 l kinetic barrier, entropic contributions to outer sphere H(2) splitting lead to a unique temperature

133 experimental evidence for the importance of outer-sphere H-bonding interactions for the exceptional

134 These include reactions initiated through outer-sphere, halide-to-metal, and metal-to-ligand charg

135 We studied extremely fast kinetics of an outer-sphere heterogeneous electron transfer (ET) reacti

136 For an outer-sphere heterogeneous electron transfer, Ox + e = R

137 rbed as easily leachable 8- to 9-coordinated outer-sphere hydrated complexes, dominantly onto kaolini

138 ylate ligand, which in turn is influenced by outer-sphere hydrogen bonding.

139 cause the catalyst follows the prototypical "outer sphere" hydrogenation mechanism, comprehensive stu

140 egy is reported for efficiently manipulating outer-sphere influence on catalyst reactivity by modulat

141 echanistic criterion is proposed for various outer-sphere/inner-sphere ET processes based on the rela

142 roposed to be first activated by CuO through outer-sphere interaction, the rate-limiting step, follow

143 By pairing ion-specific outer-sphere interactions between the target ions and ap

144 However, unraveling how outer-sphere interactions can be predictably controlled

145 erize ligation to nucleotide base nitrogens, outer-sphere interactions with phosphate groups, distanc

146 These results highlight the role played by outer-sphere interactions, and the structural constraint

147 n pathway via phosphate-specific, reversible outer-sphere interactions.

148 lely by the appended chiral scaffold through outer-sphere interactions.

149 These outer sphere ion-pairs begin to exhibit significant evid

150 Outer-sphere ion clusters are inferred in many important

151 ectrostatic interactions may assemble stable outer-sphere ion clusters in organic solutions, elucidat

152 At higher temperatures, no outer-sphere ion pairs are formed, and the larger cluste

153 tructural inner-sphere ion and one catalytic outer-sphere ion.

154 to change such that the remaining aging PCM outer sphere is mechanically ruptured by cortical pullin

155 occurred, but less CA was retained than via outer-sphere kaolinite-CA complexation.

156 Here, we characterize trefoil-shaped outer-sphere lanthanide chloride and nitrate ion cluster

157 carboxylate abandons the role it plays as an outer sphere ligand in wild-type rat beta, rotating away

158 net that Co(NH(3))(6)(3+) ions displace only outer sphere magnesium ions.

159 stead, a hydride moiety is transferred in an outer-sphere manner to afford an ion-pair, and the corre

160 tic activity of naked In(I)(+) ions, with an outer sphere mechanism for the C-N bond formation and a

161 r is retained, consistent with the canonical outer sphere mechanism invoked for palladium-catalyzed a

162 imental and computational studies support an outer sphere mechanism where the N-H proton hydrogen bon

163 ttacks the pai-allylpalladium complex via an outer sphere mechanism.

164 diate with O(2) and are inconsistent with an outer-sphere mechanism for the reaction of the reduced e

165 We propose an outer-sphere mechanism in which protons do not seem to b

166 s disfavored relative to an unusual stepwise outer-sphere mechanism involving sequential proton and h

167 ness of the iridium complexes argued for the outer-sphere mechanism of the homogeneous oxidation reac

168 cals and proceeds by an unexpected binuclear outer-sphere mechanism to cleanly form trans-insertion p

169 Most of the reactions proceed through an outer-sphere mechanism, affording linear products when m

170 uld proceed via either an inner-sphere or an outer-sphere mechanism, remained unclear.

171 ecarboxylation and the reaction occurs in an outer-sphere mechanism.

172 and attacks the protonated substrate via an outer-sphere mechanism.

173 and reductive dechlorination proceeding via outer sphere mechanisms), in studies of in situ attenuat

174 died to distinguish between inner sphere and outer sphere mechanisms.

175 ncer ligands, of noninnocent ligands, and of outer sphere mechanisms.

176 without metal-ligand cooperation, inner- and outer-sphere mechanisms) leads us to conclude that the m

177 , and the effects of solvation on inner- and outer-sphere mechanisms.

178 re discussed, including comparisons between "outer sphere" mechanisms and "metal-ligand cooperation"

179 vent (aqueous ionic solution) is the primary outer-sphere medium for oxidation, contributing 0.60 eV

180 Distribution functions reveal that outer-sphere Mg(2+) are positioned by electronegative at

181 Outer-sphere Mg(2+) are separated from the RNA by a sing

182 Diffusion analysis suggests transient outer-sphere Mg(2+) dynamics are glassy.

183 Since outer-sphere Mg(2+) ions account for most of the Mg(2+)

184 Outer-sphere Mg(2+) ions responsible for these effects a

185 evealed the requirement of a fully hydrated (outer-sphere) Mg2+ ion for catalytic activity.

186 1 have been analyzed quantitatively using an outer-sphere model for bimolecular spin relaxation to ex

187 phere (SO(4)(2-) and AsO(4)(3-)) versus weak outer-sphere (NO(3)(-)) bonding and the control.

188 n state for syn-addition and a base-assisted outer-sphere nucleocupration mechanism for anti-addition

189 ively charged and strongly electron-donating outer sphere nucleophile, result in the lowest reaction

190 h inversion of configuration, followed by an outer sphere nucleophilic attack that leads to a second

191 catalyst is a Ni-pai-allyl complex, and the outer-sphere nucleophilic attack of H-bonded amine aggre

192 e first, the ionic interaction occurs in the outer sphere of the metal complex, using a ligand which

193 ns of the NISE model whereby Na adsorbed via outer-sphere on zeolite Y, inner-sphere on ZSM-5, and a

194 The nominally fast outer-sphere one-electron oxidation of 1,1'-ferrocenedim

195 The rate-limiting step is the outer-sphere one-electron oxidation of Li(2)O(2) to LiO(

196 trodes show fast charge transfer kinetics to outer-sphere one-electron redox couples such as ferro-/f

197 ith molecular descriptors associated with an outer-sphere one-electron transfer calculated using dens

198 electrode reactions have been investigated: outer-sphere (one-electron oxidation of ferrocenylmethyl

199 CN)6] as well as in contact with a series of outer-sphere, one-electron redox couples in nonaqueous e

200 interaction with the phosphate 5' to A7 but outer-sphere or structural effects that cause perturbati

201 lving intermolecular electron transfer to an outer-sphere oxidant coupled to intramolecular proton tr

202 With the outer-sphere oxidant ferrocenium, the data are consisten

203 e, but depend much less on the nature of the outer-sphere oxidant.

204 oxidation and generally considered to be an outer-sphere oxidant.

205 Oxidations of these phenols by outer-sphere oxidants yield distonic radical cations (*)

206 substituted fluorenyl-benzoates and varying outer-sphere oxidants.

207 field and are accessible to both inner- and outer-sphere oxidants: Cr(2+)- converts into Cr(3+)-subs

208 odium sequestering reagent, (5) inner versus outer sphere oxidation and (6) stability with respect to

209 Outer-sphere oxidation of this intermediate by 2 equiv o

210 Complex 2 is distinct from the outer-sphere oxidation product 1(ox) (UV-vis (lambda(max

211 bonds is energetically favored, followed by outer-sphere oxidation to intermediate [1A(OH)2](0).

212 perimental data are in support of an unusual outer-sphere oxidative addition mechanism where the cate

213 ble electrophilic activators to engage in an outer-sphere oxidative addition reaction and points towa

214 promote the reaction involving the emerging outer-sphere oxidative reaction step.

215 ecular homolytic substitution (S(H)2), as an outer sphere pathway to overcome these limitations.

216 on the HOPG surface ensures that the simple outer-sphere pathway mediates ultrafast electron transfe

217 ation barrier is significantly lower for the outer-sphere pathway than for the alternative inner-sphe

218 C-H activation and C-H functionalization via outer-sphere pathway, cross-dehydrogenative couplings, i

219 ack at the 1-position is able to utilize the outer-sphere pathway, while attacks on all other positio

220 ner-sphere pathways are lower in energy than outer-sphere pathways.

221 uction of Ru(NH3)6(3+), a model one electron outer sphere process, and applied to the derivation of t

222 In an alternative outer-sphere process, nucleophilic attack of a metal-pho

223 a catalytic cycle gives rise to interesting outer-sphere processes.

224 Our work suggests that outer-sphere protein reorganization is the dominant acti

225 First, the energetics of outer-sphere proton and electron transfer as well as cou

226 c investigations revealed a rate-determining outer-sphere proton transfer mechanism, which was corrob

227 Therefore, outer sphere protons have no influence on the reaction a

228 ng a ligand-centered semiquinone radical and outer-sphere pyrene trimethylammonium cations ([Pyr](2)[

229 classical Solomon-Bloembergen-Morgan and the outer-sphere quantum mechanical theories established on

230 ere Rb(+) slowly transforms to a less stable outer-sphere Rb(+).

231 en shown through intensive research to be an outer-sphere reaction.

232 alkenes do not ligate the metal in so-called outer-sphere reactions and instead react with a metal li

233 tionalizations that likely involve iterative outer-sphere reactions in which the substrate reacts dir

234 analysis of the voltammetric response of an outer sphere redox couple can be used to track changes i

235 icarbollide) is used as a fast, one-electron outer sphere redox couple in dye-sensitized solar cells.

236 of demonstrating fast electron transfer) for outer sphere redox couples, the following factors must b

237 otentials that absorb into the near-IR where outer sphere redox shuttles have failed to produce effic

238 o Au disk electrodes for the oxidation of an outer-sphere redox couple (ferrocene methanol) and two i

239 A series of nonadsorbing, one-electron, outer-sphere redox couples with formal reduction potenti

240 te constants for this series of one-electron outer-sphere redox couples.

241 pecifically, electrochemical oxidation of an outer-sphere redox mediator, 1,1-dimethylferrocene, in d

242 selectivity that does not exist in classical outer-sphere redox mediators.

243 perometry and cyclic voltammetry of an ideal outer-sphere redox probe, reversible ferrocene methanol

244 Although results show that outer-sphere redox probes are unproductive for particle

245 The electrochemical response of several outer-sphere redox probes on such BTB/CD electrodes is c

246 reactions from nanoparticle TiO(2) films to outer-sphere redox shuttles were investigated.

247 ON, it supports rapid electron exchange with outer-sphere redox systems, but not with dopamine, which

248 ved from 14% to 80% simply by addition of an outer-sphere reductant.

249 ery strong hydrogen atom donor as well as an outer-sphere reductant.

250 e of both hydrogen peroxide and one-electron outer-sphere reductants increases by 3 orders of magnitu

251 are very strong nucleophiles, they are mild outer-sphere reductants.

252 d adducts were bracketed through addition of outer-sphere reductants.

253 tively, the non-concerted mechanism mediates outer-sphere reduction and adsorption separately when th

254 onal theory and the examination of inner and outer-sphere reduction mechanisms.

255 tiary radical cross-coupling products via an outer-sphere reductive elimination step via triplet spin

256 est that the C-F bond formation proceeds via outer-sphere reductive elimination with direct incorpora

257 Outer-sphere reductive single electron transfer (OS-SET)

258 Adsorption of ordered inner- and outer-sphere REE species was substantially lower on alum

259 rates of desorption by coexisting inner- and outer-sphere REE surface complexes.

260 endent molecular dynamics simulations and an outer-sphere relaxation model, to quantitatively charact

261 tion is advanced that is based on changes in outer-sphere reorganization as a function of pH.

262 on energies, allows for an estimation of the outer-sphere reorganization energies with values as low

263 ese differences are attributed to the large, outer-sphere reorganization energy for charge transfer a

264 It is found that the outer-sphere reorganization energy is extremely small.

265 ggested to be due to small reductions in the outer-sphere reorganization energy of both component pro

266 d reactions and estimation of the inner- and outer-sphere reorganization energy of small molecules an

267 ated with density functional theory, and the outer-sphere reorganization energy of the protein is cal

268 P and TPA(+/0) make them excellent probes of outer-sphere reorganization energy, lambda(o), as lambda

269 Decomposing the outer-sphere reorganization free energy, we find that th

270 ntly because of the dominant contribution of outer-sphere reorganization to the activation barrier; w

271 ling combined with a strong increase of the (outer-sphere) reorganization energy with increasing dist

272 nchored with catalytic species, analogous to outer-sphere residue cooperativity within the active sit

273 -guided mutagenesis of a metal-ligand and an outer-sphere residue weakens metal binding to the LanD m

274 res methyl radical and engages in concurrent outer-sphere S(H)2 coupling.

275 , and thus their relative reactivity towards outer-sphere S(N) 2-type bond-forming reactions.

276 ates, the DAAA reaction proceeds through an "outer sphere" S(N)2 type of attack on the pi-allylpallad

277 e tautomer in primary amine catalysts having outer-sphere silanols partially replaced by aprotic func

278 Model reactants for outer-sphere single electron transfer generated large in

279 Ferrocenes, which are typically air-stable outer-sphere single-electron transfer reagents, were fou

280 oth steps proceed by a low activation energy outer-sphere single-electron-transfer (SET) mechanism.

281 previously reported isotope effects suggests outer-sphere-single-electron transfer or S(N)2 as possib

282 molecules facilitate the PCET necessary for outer-sphere SOD activity.

283 expansion of the Na-clay by participating in outer-sphere solvation of Na(+) and by disrupting the H-

284 be ascribed to putative translocation of an outer-sphere solvent molecule, which could destabilize t

285 ue mainly to the compensation of the smaller outer-sphere solvent reorganization energy for PCET by t

286 PCET depend on the inner-sphere (solute) and outer-sphere (solvent) reorganization energies and on th

287 s styrenes and benzyl bromides via iterative outer-sphere steps: metal-ligand-carbon interactions.

288 suggest the operation of a pathway involving outer-sphere stereoinvertive transmetalation.

289 ping territories organized into an inner and outer sphere that are removed from the centrosome at dif

290 These results provide support for an outer sphere transfer of hydrogen to the imine to genera

291 This step is accompanied by a proton-coupled outer-sphere transfer of the first electron from a C-H s

292 nd formation proceeds through a highly polar outer-sphere transition state (TS) stabilized by the THF

293 In addition to a floppy outer-sphere transition state which leads directly to ET

294 I(2) (and SmI(2)[bond]HMPA complexes) and an outer-sphere-type ET for the reduction of alkyl iodides

295 dded in a web of hydrogen bonds involving an outer sphere tyrosine residue (Tyr42).

296 ide new insight into the contribution of the outer sphere tyrosine to the stability of the dimanganes

297 The formation of secondary bonds in the outer sphere using, for example, electrostatic or H-bond

298 mate the contribution to relaxivity from the outer-sphere water molecules surrounding MS-325.

299 for Mg2+, and a weak catalytic site that is outer sphere with little preference for a particular div

300 crucial process is the transformation of an outer-sphere Zn/S complex to an inner-sphere ion pair.