ライフサイエンスコーパス: pai

1 A 139-pai-electron nanographenoid radical was obtained by expa

2 Here, a series of 16 pai-extended triptycenes with up to three different perm

3 to a resonance dipolar structure of the [18]pai-conjugated system as the reduced congener with conco

4 gs has been replaced by a different (4n + 2) pai-electron system have so far been associated only wit

5 pounds are low spin with a (2) [(d(xy) )(2) (pai*(MoO))(1) ] configuration.

6 , 0) and electron pockets centred at (pai/2, pai/2).

7 character arises from a shrinking TTFtt(2-) pai-manifold from the Fe(II)-centered spin-crossover.

8 njugated covalent organic frameworks) and 2D pai-conjugated metal-organic frameworks, which are chara

9 i-conjugated polymers (also classified as 2D pai-conjugated covalent organic frameworks) and 2D pai-c

10 Typical 2D CCFs include 2D pai-conjugated polymers (also classified as 2D pai-conju

11 ompetitive situation for the two unequal [4n]pai subunits.

12 1,3-dipolar reaction between an imine and a pai-deficient dipolarophile in THF solution to form unna

13 servation of dispersing Majorana states at a pai-phase shift DW in a proximitized topological materia

14 vity of the reaction is attributed to both a pai-pai stacking effect and the steric hindrance between

15 bene] as red crystalline solids containing a pai-donor N-heterocyclic vinyl (NHV) substituent at the

16 e of the pore-lining helix, which contains a pai-helical segment in the closed and open conformations

17 with the aromatic SubPz core, resulting in a pai-extended chromophore that preserves the unique elect

18 te Zn(II) ions via a CN and that maximizes a pai-pai interaction with Trp(227) On the basis of these

19 n transfer through selective excitation of a pai-conjugated diblock oligomeric system featuring tetra

20 nkage plays a key role in the formation of a pai-conjugated structure, which facilitates charge trans

21 The chemical reduction of a pai-expanded polycyclic framework comprising a cycloocta

22 t 10(3) -fold chiroptical amplification of a pai-extended superhelicene when embedded in an achiral c

23 from 3-hydroxy-2-phenyl-4H-chromen-4-one, a pai-extended 3-hydroxyflavone photoCORM, in methanol usi

24 s essential for ligand recognition through a pai-cation interaction with the quaternary ammonium grou

25 nstrating the pivotal role of Y203 through a pai-pai stacking interaction with the inhibitor.

26 cent donor-acceptor-donor-acceptor (D-A-D-A) pai-conjugated macrocycle comprised of two U-shaped elec

27 i-D)(2,3) molecules with photoisomerizable A-pai-D branches.

28 l reactivity of quadrupolar and octupolar A-(pai-D)(2,3) molecules with photoisomerizable A-pai-D bra

29 Both linear donor-pai-donor and acceptor-pai-acceptor structures are observed to facilitate deloc

30 i sites show not only preferential acetylene pai-adsorption, but also enhanced ethylene desorption.

31 d-valence interactions between redox-active, pai-conjugated scaffolds is of interest when developing

32 koxy group and the establishment of adequate pai-pai interactions between the biaryl and the phosphin

33 Catalyst recycling after pai-conjugated polymerization has previously been imposs

34 through intermolecular amide-pai and alkene-pai interactions, but little is known about the driving

35 oposed to occur through intermolecular amide-pai and alkene-pai interactions, but little is known abo

36 We found that amide-pai interactions between AF9 and acyllysines are electro

37 des AF750-6Ahx-Sta-BBN via hydrogen bond and pai-pai bonds (NGO-BBN-AF750), and investigated their re

38 Crick base pairing, Hoogsteen H-bonding, and pai-pai stacking, resulting in unusual supramolecular pa

39 ia a series of intersheet hydrogen bonds and pai-pai interactions.

40 is tightly bound by a network of H bonds and pai-stacking interactions involving arginine and aromati

41 Cs and CAArCs) are stronger sigma-donors and pai-acceptors than imidazol-2-ylidenes and imidazolidin-

42 P1 catalyst dyad and C-H...pai, C-H...F, and pai...pai in C2-P1) in stereocontrolling transition stat

43 nt bonding, sliding of MXene nanosheets, and pai-pai bridging.

44 Similarly, the C-H...pai and pai...pai NCIs between the chiral catalyst and alpha-met

45 e demonstrate that the direct L-An sigma and pai donations combined with the An-L delta or phi back-d

46 e opposing effect on metal-ligand sigma- and pai-bonding.

47 ne pairs leading to low lying (n, pai*) and (pai, pai*) excited states which accelerate k(isc) throug

48 rom the potassium atoms occupies antibonding pai orbitals of the SWCNTs, weakening their C-C bonds, a

49 carriers are transferred to the antibonding (pai*) orbitals of O(2) strongly hybridized with the meta

50 The cations may react with (hetero)aromatic pai-nucleophiles in various directions, depending on the

51 ntribution from the antinodal region around (pai, 0), which is shared by other competing excitations.

52 ty on the adjacent top ring reduces the aryl pai-OH sigma* energy gap with a concomitant enhancement

53 jugation along x and y directions as well as pai conduction along the z axis across the pai columns.

54 consisting of both hole pockets centred at (pai, 0) and electron pockets centred at (pai/2, pai/2).

55 at (pai, 0) and electron pockets centred at (pai/2, pai/2).

56 4 mainly resides throughout the borafluorene pai-system, with significantly less delocalization over

57 labeled GO quenches the truncated aptamer by pai-stacking interactions.

58 areas where the PDW spatial phase changes by pai, as predicted by the theory of half-vortices in a PD

59 on performance of this material is driven by pai-pai stacking and multiple intermolecular interaction

60 Its 3D structure is held together by pai-pai stacking interactions between the labile pyridin

61 versity with ease", by combining classic C-C pai-bond click chemistry with recent developments in con

62 pair-pai, presumably n-pai*), sp(2)C-sp(2)C (pai-pai and/or hydrophobic), sp(2)O-sp(2)N (hydrogen bon

63 However, specially activated carbon pai-systems also exhibit specific reactivities that cann

64 th all classes of specially activated carbon pai-systems by discussing their general and specific rea

65 The chemistry of specially activated carbon pai-systems under homogeneous gold catalysis is extremel

66 In this family of carbon pai-systems, ynamides and their analogs, along with alky

67 -phenoxyacetophenone, the polarized carbonyl pai system apparently binds directly with the electron r

68 R complex suggests that an additional cation-pai interaction of the aromatic triazole moiety with the

69 gmented with arginine/lysine-aromatic cation-pai interactions consistently accounted for available ex

70 protease, and (b) Arg(19) which forms cation-pai interactions with Trp(291) of the S1' subsite and el

71 guests, originating from favorable cation...pai and (+)NC-H...pai interactions.

72 nions that relies on a neighbouring cationic pai-allyl palladium complex.

73 bilized by noncanonical lone pair-pai and CH-pai interactions, as well as hydrogen bonds.

74 indicate an unusual carbohydrate-aromatic CH-pai bonding that promotes glycopeptide self-assembly.

75 ]-cycloaddition pathway and an attractive CH-pai interaction between the catalyst's tBu group and the

76 2)N (hydrogen bonding) and sp(3)C-sp(2)C (CH-pai and/or hydrophobic).

77 complex with starch through non-covalent CH-pai bonds along alpha-(1 -> 4) glycosidic chains.

78 termediate is favoured due to stabilizing CH-pai-stacking interactions.

79 onally, we report for the first time that CH-pai interactions at Phe28 directly contribute to AF9's r

80 Potential biomaterials exploiting the CH-pai bond-based stabilization, as exemplified by an enzym

81 f saccharide-fullerene was formed through CH-pai and/or OH-pai interactions, and that the interaction

82 interact strongly with saccharides due to CH-pai and/or OH-pai interactions.

83 Chiral pai-conjugated molecules provide new materials with outs

84 l overview the existing literature on chiral pai-conjugated systems whose thin films have been charac

85 ecules have assembled primarily via cofacial pai...pai stacking interactions displaying mixed D-A-D-A

86 along the longitudinal axis of the columnar pai-stacking architectures.

87 d injects a charge into a helical conjugated pai-system without injecting a spin.

88 e units to form a high density of conjugated pai-systems throughout MOF pores.

89 are constructed from an unusual 12-connected pai-stacked pyrene secondary building unit (SBU) and a t

90 By comparing a conventional pai-conjugated polymer as the active material to a perde

91 ction of a dilithio borole dianion, a cyclic pai-ligand isoelectronic to ubiquitous cyclopentadienyls

92 which arise from the combination of a cyclic pai-system, strong electronic communication between the

93 in many borylene (:BR) complexes via metal d(pai) ->BR back-donation, despite the electron deficiency

94 he prism[5]arene here described shows a deep pai-electron-rich aromatic cavity that exhibits a great

95 properties owing to their highly delocalized pai-systems, low-lying frontier orbitals that stabilize

96 e central SiC(2) ring having two delocalized pai electrons.

97 e solid state and exhibit topology-dependent pai transmission and exciton migration; these key fundam

98 nism construction indicate that the designed pai-system provides a superior spin-delocalization effec

99 )C kinetic isotope effects (KIEs) for the di-pai-methane rearrangement of benzobarrelene fit with sta

100 t cluster around the S6 gate and distinctive pai-bulges.

101 We find that the distinctive pai-pai molecular packing of Y6 not only exists in molec

102 Consequently, a dominant pai-sigma* interaction in the amino substituted analogue

103 Both linear donor-pai-donor and acceptor-pai-acceptor structures are obser

104 ng that, to a degree, important LLPS-driving pai-related interactions are embodied in classical stati

105 Dynamic pai-electron interactions in 2D carbon systems open new

106 lative accord with the field strength (i.e., pai-acidity) of the variable ligand, the magnitude of th

107 Each pai-conjugated oligomeric segment has its own discrete i

108 r resonance form (sp(3) -C) over the E=C ene pai-bonded form (sp(2) -C), as group 15 is descended.

109 t the Si=C bonds are involved in an expanded pai-conjugated system.

110 hromophore ligands reveals that the expanded pai-system of the CAArC leads to relatively low energy a

111 used to create families of not-yet-explored pai-conjugated vinylene polymers.

112 que class of materials that combine extended pai-conjugation with a permanently microporous skeleton.

113 s resolved by chemically installing extended pai-rich alternating carbon-carbon linkages between the

114 The combination of extended pai-conjugated backbone and interlayer noncovalent pai-p

115 opper complex (1(2-)) featuring an extended, pai-delocalized, tetra-amidate macrocyclic ligand (TAML)

116 nducted which revealed that the face-to-face pai-core interaction induced by benzo[2,1,3]thiadiazole

117 process due to the formation of a favorable pai-complex host-guest interaction.

118 d helicenes are large, structurally flexible pai-frameworks that can be viewed as building blocks for

119 The differential cross sections for pai(0) photoproduction at forward angles were measured o

120 r polymers and liquid crystals obtained from pai-conjugated cone-shaped molecules are receiving incre

121 The 2D lattice enables full pai conjugation along x and y directions as well as pai

122 d synthesis has been used to prepare a fully pai-conjugated cyclic porphyrin octamer, composed of bot

123 ol photoinduced electron transfer in a fully pai-conjugated oligomer.

124 n their design, fully cross-linked and fully pai-conjugated.

125 scale), which, in combination with the fully pai-conjugated framework, makes these materials unique a

126 and exciton migration; these key fundamental pai functions are unique to sp(2) carbon-conjugated fram

127 tion of multiple reactive functional groups (pai-bonds, leaving group, etc.) is required within the s

128 metries, which account for the extended n -> pai* band tails.

129 mers and an increased separation of the n -> pai* bands between the trans- and cis-conformations, whi

130 ide bond and highlight the utility of the n->pai* interaction in molecular design.

131 The n->pai* interactions in ETPs make disulfide reduction much

132 t the disulfide bond is stabilized by two n->pai* interactions, each with large energies (3-5 kcal/mo

133 static interactions and the occurrence of n->pai* orbital delocalisation in C=O...C=O interactions.

134 n of inductive polarisation manifested by n->pai* orbital delocalisation.

135 ctions, while others implicated lone pair n->pai* orbital delocalisation.

136 that lp...pai contacts do not result from n->pai* orbital overlaps but from weak dispersion and elect

137 /MRCI calculations, show that (sigma, B p)->(pai, B p) transitions accelerate the ISC process.

138 Similarly, the C-H...pai and pai...pai NCIs between the chiral catalyst and a

139 ar, NCIs between the chiral catalysts (C-H...pai in C1-P1 catalyst dyad and C-H...pai, C-H...F, and p

140 led from SD/Ag78a through intercluster C-H...pai interactions can be formed by a simple drop-casting

141 hydrogen bond formation along with the C-H...pai interactions seem to be the most important factors t

142 , and due to the cap-core interaction (C-H...pai), only two enantiomeric isomers are formed (secondar

143 (C-H...pai in C1-P1 catalyst dyad and C-H...pai, C-H...F, and pai...pai in C2-P1) in stereocontrolli

144 H-bonding, solvent bonding, S-H...pai, C-H...pai, pai-pai stacking, charge-transfer complexation, etc

145 The C-H...pai, pai...pai, and lone pair...pai noncovalent interact

146 ous solution is sustained by multiple [C-H...pai] and [C-H...anion] interactions in addition to hydro

147 ng from favorable cation...pai and (+)NC-H...pai interactions.

148 tions like H-bonding, solvent bonding, S-H...pai, C-H...pai, pai-pai stacking, charge-transfer comple

149 ince the PHB-Xa block copolymers have a high pai conjugate structure and hydrophobicity, the use of t

150 p with the aromatic system results in a high pai-density at the phosphorus atom.

151 evidence of a tunable system wherein a HO...pai interaction switches incrementally to a nonconventio

152 ges of "switch"-starting with exclusive HO...pai, to partitioned HO...pai/OH...pai, and finally to ac

153 with exclusive HO...pai, to partitioned HO...pai/OH...pai, and finally to achieving exclusive OH...pa

154 sidues in the fibrils, including hydrophobic pai-pai interactions with aromatic rings of side chains

155 g between the ferrocenyl units and the imine pai system since breaking of the orbital symmetry result

156 stion at the indole-C3 position and improved pai-pai stacking interactions have been identified as ma

157 ndicate possibly minor role of the change in pai-electron conjugation length (and therefore conjugate

158 he reversible redox activity of azo group in pai-conjugated structures, azobenzene-based molecules re

159 e interactions between auxochromic groups in pai-conjugated functional molecules dictate their electr

160 Accessing the triplet manifold in pai-conjugated systems would also include a possible evo

161 gation of intermolecular charge transport in pai-conjugated materials is challenging.

162 e to electronic and steric effect, including pai-conjugation and H-bonding.

163 conjugation and bending on the incorporated pai-systems.

164 through desymmetrization of an intermediate pai-allylnickel complex.

165 tiomers and desymmetrization of intermediate pai-allylnickel complexes.

166 cs exhibited a high degree of intermolecular pai-pai stacking.

167 ed organic SBUs on its strong intermolecular pai-pai interactions.

168 rystallography indicates that intermolecular pai-pai stacking is completely suppressed in the crystal

169 rangement and a reduction of the interplanar pai-stacking separations by ca. 19-22% before the critic

170 s wrapped with acrylic fibers are woven into pai-type thermoelectric modules.

171 , several research efforts have investigated pai-pai stacking, ionic interactions as well as formatio

172 increases with the increasing acidity of its pai system, which depends on the substituent in the 4,5-

173 tate of strontium-73 must differ from its J (pai) = 1/2(-) mirror bromine-73.

174 We find that a J( pai) = 5/2(-) spin assignment is needed to explain the p

175 Picenophanes with a large pai-system and semi-rigid structure exhibited anomalous

176 A series of largely pai-extended multichromophoric molecules including cross

177 etal-ligand covalency due to metal -> ligand pai-backdonation.

178 gligible contribution from interlayer ligand pai-pai stacking, as incorporation of Zn(2+) in Cu-THQ s

179 ular hydrogen bonds within pyrazine ligands, pai-interactions, coordination to metal ions, and few ha

180 Herein we report the isolation of living pai-conjugated polymer chains, synthesized by catalyst-t

181 its activity to analogous systems with lower pai-delocalization (2(2-) and 3(2-)).

182 tacts may be of either the lone pair-pai (lp-pai) or the OH-pai type, in nature.

183 is reached at a shorter distance for the lp-pai interaction as compared to the OH-pai one (3.0 versu

184 Current interest in lone-pair...pai (lp...pai) interactions is gaining momentum in biochemistry an

185 energy decompositions, demonstrate that lp...pai contacts do not result from n->pai* orbital overlaps

186 These findings challenge the whole lp...pai concept that refers to elusive orbital interactions

187 rger pyrazinium-based cations with low-lying pai* orbitals that form the conduction band, substantial

188 a (porphinato)zinc(II) moiety with low-lying pai*-energy levels, sufficiently destabilize MC states a

189 operties of the molecular components, mainly pai-conjugated donor-acceptor (D-A) chromophores, and th

190 nt with an edge-on orientation and molecular pai-pai stacking along the coating direction on the surf

191 O- or N-lone pairs leading to low lying (n, pai*) and (pai, pai*) excited states which accelerate k(

192 for the design of RTP materials without (n, pai*) transitions.

193 he system in the in-form while a favorable n-pai* interaction reverses the orientation of the oxygen-

194 p with a concomitant enhancement of the OH n-pai* energy gap.

195 e sp(2)O-sp(2)C (lone pair-pai, presumably n-pai*), sp(2)C-sp(2)C (pai-pai and/or hydrophobic), sp(2)

196 ve nucleophilicity scale, which compares n-, pai-, and sigma-nucleophiles.

197 ctronic population of the [Cu(2)(mu(2)-NAr)] pai* manifold, contrasting previous methods for engender

198 better understanding the properties of NH...pai interactions involved in the stabilization of the se

199 st appropriate model with the strongest NH...pai interaction ever described.

200 It was shown that the NH...pai binding is especially effective when the NH-donor is

201 able structural changes and weakens the NH...pai interactions from 12-15 kcal mol(-1) in "naked" cati

202 ty and shortness (2.07 angstrom) of the NH...pai-centroid bond, was recognized as the most appropriat

203 njugated backbone and interlayer noncovalent pai-pai interactions endows TPAPC-COF with excellent abs

204 dG(N1-H)(.) ) via addition to the nucleobase pai-system and subsequent dehydration.

205 indicates the pressure-induced breakdown of pai-stacking by formation of sigma-bonded polymers.

206 Although long acenes remain a key class of pai-conjugated molecules for numerous applications, phot

207 whenever the relative phase is a multiple of pai.

208 ere created by seeded growth of two types of pai-conjugated polymeric building blocks, the triblock c

209 The use of pai-conjugated polymers (CPs) in conductive hydrogels re

210 ullerene was formed through CH-pai and/or OH-pai interactions, and that the interactions between sacc

211 gly with saccharides due to CH-pai and/or OH-pai interactions.

212 the lp-pai interaction as compared to the OH-pai one (3.0 versus 3.5 angstrom).

213 either the lone pair-pai (lp-pai) or the OH-pai type, in nature.

214 pai, and finally to achieving exclusive OH...pai forms.

215 ches incrementally to a nonconventional OH...pai hydrogen bonding (HB) interaction.

216 ional (NH...O) and two nonconventional (OH...pai) HBs, dimerizes and anchors the molecule in the unit

217 y on the qualitative characteristics of OH...pai hydrogen bonds therein.

218 usive HO...pai, to partitioned HO...pai/OH...pai, and finally to achieving exclusive OH...pai forms.

219 various analogues reveal that stronger OH...pai interactions in systems with electron-rich aromatic

220 ermining the mode of dimerization (sigma- or pai-dimer) by UV-vis spectroscopy and X-ray crystallogra

221 y matching between the ferrocene and organic pai* orbitals upon coordination, allowing superexchange

222 with built-in cavities and radially oriented pai-systems-was selected as a conceptually simple class

223 spersive interaction between the overlapping pai surfaces.

224 the orbital interaction, whereas the Fe -> P pai-back-donation corresponds to ~15% of the orbital int

225 irs leading to low lying (n, pai*) and (pai, pai*) excited states which accelerate k(isc) through El-

226 ding, solvent bonding, S-H...pai, C-H...pai, pai-pai stacking, charge-transfer complexation, etc.

227 The C-H...pai, pai...pai, and lone pair...pai noncovalent interactions

228 alyst dyad and C-H...pai, C-H...F, and pai...pai in C2-P1) in stereocontrolling transition states are

229 Similarly, the C-H...pai and pai...pai NCIs between the chiral catalyst and alpha-methylsty

230 have assembled primarily via cofacial pai...pai stacking interactions displaying mixed D-A-D-A stack

231 The C-H...pai, pai...pai, and lone pair...pai noncovalent interactions (NCIs)

232 structure analysis of 1 shows a strong pai...pai stacking interaction between the electron-deficient

233 Such contacts may be of either the lone pair-pai (lp-pai) or the OH-pai type, in nature.

234 f Gh is stabilized by noncanonical lone pair-pai and CH-pai interactions, as well as hydrogen bonds.

235 le interactions are sp(2)O-sp(2)C (lone pair-pai, presumably n-pai*), sp(2)C-sp(2)C (pai-pai and/or h

236 The C-H...pai, pai...pai, and lone pair...pai noncovalent interactions (NCIs) between the N-benzyl

237 Current interest in lone-pair...pai (lp...pai) interactions is gaining momentum in bioch

238 by their total angular momentum J and parity pai.

239 ability of the parallel arene-perfluoroarene pai-stacking arrangement and a reduction of the interpla

240 larify the effect of different perpendicular pai-moieties on the optoelectronic properties.

241 esponsible for the decay of the neutral pion pai(0) into two photons (gammagamma), leading to its unu

242 ons ([Formula: see text]), negative pions (- pai), and helium (He) ion beams resulted in 10, 17 and 1

243 acked periodic frameworks with high in-plane pai-conjugation.

244 se as 3.34 angstrom, clarifying out-of-plane pai-face-on molecular orientation in the nanocrystalline

245 eral approach to exploit host-enhanced polar-pai interactions in the design of robust aqueous supramo

246 A facile synthetic procedure to prepare pai-extended seven-membered phosphorus heterocycles, bot

247 A putative pai-allyl palladium radical-polar crossover path is prop

248 nneling in the area of pericyclic reactions, pai-bond-shifting, and other processes.

249 al halide perovskites by incorporating rigid pai-conjugated organic ligands.

250 Si(II), cleanly gives a borole half-sandwich pai-complex of Si(II) and silicocene.

251 y functional theory indicates that secondary pai-type interactions between the [Au@Pb(11)](3-) ligand

252 =N) is associated with improved selectivity, pai-conjugation, and reactivity at multiple points in th

253 npaired spin in the ground state, open-shell pai-conjugated molecules can achieve optoelectronic prop

254 ia their end groups/cores, with the shortest pai-pai distance as close as 3.34 angstrom, clarifying o

255 I)=N=Co(III) canonical form with significant pai-bonding between the cobalt centers and the nitride a

256 In the solid state, pai-pai stacking suppresses their emission, limiting the

257 ystal structure analysis of 1 shows a strong pai...pai stacking interaction between the electron-defi

258 ngulene (TANG) building block enables strong pai-electron interactions manifested in broad absorption

259 similarity contrasts the multitude of strong pai-cation, dipole-cation, and ion-pair interactions bet

260 culation, the phenyl fragment reveals strong pai-pai interaction for steric hindrance around the meta

261 enhanced afterglow is attributed to stronger pai-pai stacking and intermolecular electronic coupling

262 tes and inhibitors and that this symmetrical pai-pai interaction "clamps" the ligand into the binding

263 Current approaches to synthesize pai-conjugated polymers (CPs) are dominated by thermally

264 a of this partially fused nanoring show that pai-conjugation extends around the whole macrocycle, and

265 While calculations suggest that pai to pai* transitions are dominant, intramolecular cha

266 The pai-chromophore is essentially that of trans-1-vinylprop

267 The pai-manifold of the central BC(5) ring coordinates to ch

268 s pai conduction along the z axis across the pai columns.

269 electrophile and migrating group across the pai system.

270 rged group, for example, Me(2)NH(+), and the pai-donor is an electron-rich aromatic substituent, in p

271 ecular orbital energy levels and enhance the pai-conjugation.

272 epare O-doped nanographenes derived from the pai-extension of pyrene.

273 The "through-space" approach harnesses the pai-pai stacking interactions between organic moieties.

274 e attractive London dispersion forces in the pai-dimers lead to improved forecasts of sigma- vs pai-d

275 ch is accompanied by a large increase in the pai-stabilization energy upon adduct formation.

276 tion pathway over a metal palladation of the pai system of the ynamide.

277 ions show that the strong interaction of the pai-donating NR(2) group with the aromatic system result

278 l [2 + 2] cycloaddition cross-linking of the pai-stacked layers in 3D COFs.

279 R has become a standard tool for scaling the pai-accepting character of carbenes.

280 Structural modeling implied that the pai-pai interactions from each F439 monomer mediated the

281 lization of the low-spin state is due to the pai-acceptor properties of the formazanate ligand, resul

282 nts revealed that nucleophilic attack to the pai-allylpalladium intermediate is the enantio-determini

283 features of diverse ABCG2 ligands using the pai-pai clamp along with structural studies created a ph

284 demonstrated by GQD nanosurfactants via the pai-pai stacking interaction, leading to the printing of

285 and shape of the catalytic pocket, while the pai-methyl-l-histidine (Pmh) moiety transfers the electr

286 2D polymer layers (0.28 eV) and along their pai-stacked direction (0.95 eV).

287 All of them enable their pai-pai stacking onto low-dimensional nanocarbons includ

288 the C-terminal moiety from methoxy (21a) to pai bond-containing (23a and 23b) or cycloalkane substit

289 ation of reduced graphene oxide (RGO) due to pai-pai stacking is a recurrent problem in graphene-base

290 While calculations suggest that pai to pai* transitions are dominant, intramolecular charge tra

291 hannel opening is accompanied by an alpha-to-pai helical transition in the pore-lining transmembrane

292 tonation evolving to a zwitterion that traps pai-electrophiles in a formal [3 + 2] process.

293 oping and detect a topologically non-trivial pai Berry phase in quantum Hall sequences.

294 cs, can be effectively blocked by the unique pai-conjugated structure of PANI.

295 Amide NH...O=C hydrogen bonding and various pai-system interactions have been better characterized s

296 d molecular parameters lead to sigma- versus pai-dimerization.

297 mers lead to improved forecasts of sigma- vs pai-dimerization mode, and suggest that a balance of spi

298 ata are consistent with a mechanism in which pai-participation by the nucleophilic olefin facilitates

299 ansfer can be achieved in the complexes with pai-extended analogue of tetrathiafulvalene (exTTF), zin

300 d strength of conflict scale positively with pai, suggesting that demographic or life history factors