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1 limonene, and sabinene, initiated by benzoyl peroxy radical.
2 + oxidizes a peroxide to yield an initiating peroxy radical.
3  (NOx) (NMOG:NOx), which affects the fate of peroxy radicals.
4 formed via decomposition of the beta hydroxy peroxy radicals.
5 l instrument for measurements of atmospheric peroxy radicals.
6 ng the formation of both carbon-centered and peroxy radicals.
7 er rates than O(2) addition to form bicyclic peroxy radicals.
8 ssignment of electronic transitions in alkyl peroxy radicals.
9 cal as well as other hydrocarbon substituted peroxy radicals.
10 ibiting the lateral propagation of the lipid peroxy radicals.
11 c compound (VOC) reactivity, and the fate of peroxy radicals.
12 w synthetic methodology for the synthesis of peroxy radical addition-induced hydroperoxide formation.
13 nal oxygenated compounds formed through acyl peroxy radical + alkene reactions are potentially import
14                         Hydroxy, alkoxy, and peroxy radicals all have the potential to react with DNA
15 by an increase in the level of intracellular peroxy radicals and lipid peroxidation products, two ind
16 ttachment/detachment density diagrams of the peroxy radicals and present a qualitative picture of the
17 between intramolecular hydrogen migration of peroxy radicals and their bimolecular termination reacti
18 ns are unaffected by formation of stabilized peroxy radicals and to estimate atmospheric pressure yie
19 ation and bimolecular reactions with organic peroxy radicals are also possible.
20 the case of reaction with oxygen, persistent peroxy radicals are formed in high yield.
21                                              Peroxy radicals are mixed with high concentrations of NO
22  calibration method: peroxyacetyl and methyl peroxy radicals are produced by the photolysis of aceton
23                                     Aromatic peroxy radicals arising from initial OH and subsequent O
24 ize the electronic excitations of the phenyl peroxy radical as well as other hydrocarbon substituted
25 tive production rates of phenol and bicyclic peroxy radical (BCP-peroxy) are experimentally constrain
26 ntermediates (CI) produced from beta-hydroxy peroxy radicals (beta-OH-RO(2)*).
27 ical calculations, we show that the bicyclic peroxy radicals (BPRs) formed in OH-initiated aromatic o
28                          Dimerization of the peroxy radicals by recombination and cross-combination r
29 venging of reactive oxygen species and lipid peroxy radicals by tocopherols can result in the formati
30  the second-generation dihydroxy hydroperoxy peroxy radical (C5H11O6.) must undergo an intramolecular
31                            In this work, the peroxy radical chemical amplification (PERCA) method was
32          Laboratory characterizations of the peroxy radical chemical ionization mass spectrometer (Pe
33   In this review, laboratory studies of this peroxy radical chemistry are detailed, as they pertain t
34                                          The peroxy radical concentration was obtained from the ampli
35 t of CAPS baseline offsets on the calculated peroxy radical concentrations.
36 arbons such as isoprene and monoterpenes and peroxy radicals containing various functional groups.
37 find that the ratio of delta to beta hydroxy peroxy radicals depends on their bimolecular lifetime (t
38                             The chemistry of peroxy radicals derived from limonene upon addition of o
39                  Without this rearrangement, peroxy radicals derived from MTbuK and DTbuK cannot unde
40  experimental work has shown that the phenyl peroxy radical exhibits a transition in the visible regi
41          Gas-phase autoxidation-regenerative peroxy radical formation following intramolecular hydrog
42 d kinetic model results suggest that organic peroxy radicals formed by alpha-pinene reacting with sec
43                                     Nitrooxy-peroxy radicals formed from NO(3) chemistry suppress the
44 f the atmospheric fate of the entire pool of peroxy radicals formed via addition of OH at C4 for typi
45 idation mechanism mediated by particle-phase peroxy radicals greatly accelerates OA oxidation, with e
46 find that reactions between alkenes and acyl peroxy radicals have reaction rates high enough to be fe
47 ts, such as ozone (O3) and hydroxyl (OH) and peroxy radicals (HO2 + RO2), determines the lifetimes of
48                                              Peroxy radicals (HO2 and RO2) within this air are detect
49 rument for the quantification of atmospheric peroxy radicals (HO2, CH3O2, C2H5O2, etc.) using the che
50  PerCIMS provides measurements of the sum of peroxy radicals, HO2 + RO2 (HOxROx mode), or the HO2 com
51 ief discussion of methods used to detect the peroxy radicals in the laboratory is presented.
52                                   Thus, acyl peroxy radical-initiated oxidation chemistry may need to
53 eover, saturation vapor pressures of benzoyl peroxy radical-initiated oxidation intermediates were es
54 , only one isomeric pathway via the bicyclic peroxy radical is accessible to lead to ring cleavage.
55                 In this regime, beta hydroxy peroxy radical isomers comprise approximately 95% of the
56 H-shift isomerization of the Z-delta hydroxy peroxy radical isomers produced from OH addition to C4 i
57             In addition, the Z-delta hydroxy peroxy radical isomers undergo unimolecular 1,6 H-shift
58  difference in the relative stability of the peroxy radical isomers.
59 or beta to the OH group forming six distinct peroxy radical isomers.
60 OH) and molecular oxygen to produce isoprene peroxy radicals (ISOPOO).
61 on between unsaturated hydrocarbons and acyl peroxy radicals leads to an alkyl radical, to which mole
62 ility of the allylic radical, however, these peroxy radicals lose O2 in competition with bimolecular
63                          The formed perester peroxy radical may either undergo further H-shift reacti
64                                          The peroxy radical mixing ratio is determined by the differe
65                                      Organic peroxy radicals (often abbreviated RO(2)) play a central
66 rce of reactive species such as hydroxyl and peroxy radicals (OH and HO2, "HOx") indoors.
67  accurate evaluation of the concentration of peroxy radicals over a variety of atmospheric conditions
68 8-oxo-dG by HPLC/electrochemical analysis of peroxy radical oxidation of dG, suggesting that the G --
69  ISOP(OOH)2(C5H12O6), a major product of the peroxy radical reacting with HO2.
70 tion of DNA exposed to micromolar amounts of peroxy radical resulted in a 30-fold increase in mutatio
71 oducts have been shown to form via gas-phase peroxy radical (RO(2)) cross reactions.
72 for biogenic NPF, which are covalently bound peroxy radical (RO(2)) dimer association products.
73 terminating hydroperoxide formation from the peroxy radical (RO(2)) reaction with HO(2) and organonit
74 H) formation from heterogeneous HO(2)(*) and peroxy radicals (RO(2)(*)) reactions for the first time.
75 , depending on numerous parameters affecting peroxy radicals (RO(2)) autoxidation.
76 onstrates that rapid autoxidation of organic peroxy radicals (RO(2)) formed during VOC oxidation resu
77             Direct gas-phase measurements of peroxy radicals (RO(2)) from flowtube ozonolysis experim
78 n between nitrogen monoxide (NO) and organic peroxy radicals (RO(2)) greatly impacts the formation of
79 icals, oxidized nitrogen species and organic peroxy radicals (RO(2)) in OFR.
80  an oxidation flow reactor, in which ~95% of peroxy radicals (RO(2)) react with NO.
81 re through the gas-phase reaction of organic peroxy radicals (RO(2)) with hydroxyl radicals (OH).
82                      The reaction of hydroxy peroxy radicals (RO(2)) with NO represents one of the mo
83 t mimic the atmospheric chemistry of organic peroxy radicals (RO(2)), a key intermediate in VOC oxida
84 addition of a VOC that photolyzes to produce peroxy radicals (RO(2)), similar to pyruvic acid, into t
85 icture of a formation mechanism advancing by peroxy radical (RO2) isomerization through intramolecula
86         In HO2-dominant experiments, organic peroxy radicals (RO2) primarily react with HO2.
87 stigate the rate of autoxidation for organic peroxy radicals (RO2) produced in the oxidation of a pro
88 cations and strand break densities caused by peroxy radical (ROO*) oxidation were measured by glyoxal
89 ith monoterpenes, and the resulting isoprene peroxy radicals scavenge highly oxygenated monoterpene p
90 of the carbenoid, with a rhodium peroxide or peroxy radical species generated upon the activation of
91                                          The peroxy radical substituent is also compared against isoe
92             TDDFT calculations of the phenyl peroxy radical support an excitation in the visible spec
93 measurements of the reaction products of the peroxy radicals to diagnose this complex chemistry.
94 thereby constraining first-generation RO(2) (peroxy radicals) to react nearly exclusively with NO.
95 d in Escherichia coli upon transfection with peroxy radical treated DNA carrying the lacZ alpha gene
96                  Electrophoretic analysis of peroxy radical treated DNA exposed to NaOH, Nth, and Fpg
97 ation, ring-breaking reactions, and alpha-OH-peroxy radical unimolecular reactions.
98            In the amplification channel, the peroxy radicals were converted in an excess amount of NO
99 ation of 1-alkenylperoxy radicals, which are peroxy radicals where the OO moiety is bonded to an sp2-
100 > 10 s, the distribution of isoprene hydroxy peroxy radicals will be controlled primarily by the diff
101 e sensitivities of the instrument to organic peroxy radicals with different hydrocarbon groups.
102 u, and sensitive measurements of atmospheric peroxy radicals with fast time response.
103 ently inside the particle by the reaction of peroxy radicals with SO2.
104       In particular, the reaction of organic peroxy radicals with the HO2 radical and the H2 OHO2 rad

 
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