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1 than its isostere 9-(2-methylnaphthalen-1-yl)phenanthrene.
2 droponic systems with high concentrations of phenanthrene.
3 the plants against the phytotoxic effects of phenanthrene.
4 and a pi-bonding pattern similar to that in phenanthrene.
5 ght to arise from epoxidation of some of the phenanthrene.
6 y protected isoindolin-1-one to the required phenanthrene.
7 nged the region of oxidation of biphenyl and phenanthrene.
8 ignificant effects on product formation from phenanthrene.
9 hanged the site of oxidation of biphenyl and phenanthrene.
10 d altered regioselectivity with biphenyl and phenanthrene.
11 er of 19.7 kcal/mol, and then reoxidation to phenanthrene.
12 ed and naturally occurring 4,5-disubstituted phenanthrenes.
13 by naphthalene, phenanthrene, and alkylated phenanthrenes.
14 s access to a wide variety of functionalized phenanthrenes.
16 Systems studied were 1-methylcyclopenta[def]phenanthrene 2, 11H-benz[bc]aceanthrylene 8, 5H-benzo[b]
17 ydroxy-1,2-dihydro-6-methylchrysene, benzo[c]phenanthrene, 2-amino-6-methyldipyridol[1,2-a:3',2'-d]im
18 that UBP791 ((2S*,3R*)-1-(7-(2-carboxyethyl)phenanthrene-2-carbonyl)piperazine-2,3-dicarboxylic acid
19 ino-5-phosphonopentanoic acid (D-AP5) and 1-(phenanthrene-2-carbonyl)piperazine-2,3-dicarboxylic acid
20 t of UBP1700 ((2S*,3R*)-1-(7-(2-carboxyvinyl)phenanthrene-2-carbonyl)piperazine-2,3-dicarboxylic acid
21 result from trans opening at C-1 of benzo[c]phenanthrene 3,4-diol 1,2-epoxide (B[c]PhDE) isomers (i.
22 epoxide (BaP DE) and dA adducts from benzo[c]phenanthrene 3,4-diol 1,2-epoxide (BcPh DE) on DNA repli
23 s-opening at C-1 of the enantiomeric benzo[c]phenanthrene 3,4-diol 1,2-epoxides in which the epoxide
24 g]chrysene, 3,4-dihydroxy-3,4-dihydrobenzo[c]phenanthrene, 3-amino-1,4-dimethyl-5H-pyrido[4,3-b]indol
25 ysis (FS-FVP) method afforded cyclopenta[def]phenanthrene 31 and cyclopenta[jk]fluorene 52 as the pri
26 yclotris[(2,9-bis[trans-Pt(PEt(3))(2)(PF(6))]phenanthrene)(4,4'-dipyridyl)], and cyclotris[bis[cis-Pt
29 converted to isomeric 5- and 6-fluorobenzo[c]phenanthrene, 5-and 6-fluorochrysene, and 9- and 10-benz
30 hapes, X-ray data for 5- and 6-fluorobenzo[c]phenanthrene, 6-fluorochrysene, 9- and 10-fluorobenzo[g]
31 e final products being phenanthrene (P1) and phenanthrene 9,10-oxide (P3), the latter being thought t
32 11b-hexahydro-3-thia-5-azacyclopent-1-ena[c]phenanthrene-9,10-diol (5) emerged as the compound with
33 dro-2-propyl-3-thia-5-azacyclopent-1-ena[c ]-phenanthrene-9,10-diol (A86929)]; isochromans [(1R,3S)-3
34 gested by the presence of the dione product, phenanthrene-9,10-dione (P2), thought to arise from furt
35 stereoselectivity toward (2R)-1, (2S)-1, and phenanthrene-9,10-oxide, suggesting that modifications a
37 for automerization of outer ring carbons in phenanthrene, a reaction demonstrated previously by Bala
39 tion was also responsible for the changes of phenanthrene adsorption on FA in the presence of HA.
40 he presence of NaC (both 100 and 8000 mg/L), phenanthrene adsorption on graphene was decreased due to
41 on of multilayer graphene and its effects on phenanthrene adsorption were investigated using a passiv
42 inity and blocking capacity, naphthalene and phenanthrene aldehydes were the most potent effectors.
43 within the anthracene nucleus of azonafide; phenanthrene analogues, in which the linear anthracene n
45 clopentylidene-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene and 1-cyclobutylidene-1a,9b-dihydro-1H-cycl
46 etection were determined to be 0.14 fmol for phenanthrene and 4 amol for caffeine and to a printed ca
47 PAHs leading to more complex structures like phenanthrene and anthracene at temperatures down to 10 K
48 five-ring PAHs as well as alkylated forms of phenanthrene and anthracene in grass and wood chars prod
49 al mutant in native form and in complex with phenanthrene and anthracene, along with those of wild-ty
51 ontents of three-ring PAHs, namely fluorene, phenanthrene and anthracene, in dark-roasted beans were
55 ept, the NAIMS technique has been applied to phenanthrene and caffeine samples for which the limits o
58 , to give derivatives of tricyclic fluorene, phenanthrene and dibenzo[7]annulene, respectively, with
60 aimed at determining the combined effects of phenanthrene and drought on the survival of the terrestr
61 f magnitude, from 0.017 to 658 mug L(-1) for phenanthrene and from 0.006 to 90.0 mug L(-1) for fluora
62 rillonite samples were loaded with pyrene or phenanthrene and ground manually or in a ball mill for s
63 hree distinct antibody clones that recognize phenanthrene and methylphenanthrenes were selected, and
65 exfoliation weakened the competition between phenanthrene and NaC and enhanced the adsorption capacit
67 tals with polyaromatic hydrocarbons, such as phenanthrene and picene, but the composition and structu
69 most abundant chemicals found in films were phenanthrene and pyrene (22%), followed by perylene (21%
70 urfactant on biodegradation of (14)C-labeled phenanthrene and pyrene under desorption-limiting condit
71 iori parameter uncertainty distributions for phenanthrene and pyrene, and leads to higher values for
73 en-1-yl)propan-2-ol in benzene-d(6) afforded phenanthrene and the beta-hydroxycarbene intermediate 2-
74 ihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene and the corresponding (-)-(1R,2S,3S,4R) iso
75 sis of polycyclic aromatic hydrocarbons like phenanthrenes and chrysenes (and tetraphene) from beta-b
78 became a classical tool for the synthesis of phenanthrenes and their heterocyclic analogues (Mallory
79 s presorbed with pollutants (nonylphenol and phenanthrene) and additive chemicals (Triclosan and PBDE
80 thesized such that an energy transfer donor (phenanthrene) and an energy transfer acceptor (anthracen
81 aphthalene, 3.84 +/- 1.47 mg m(-2) d(-1) for phenanthrene, and 2.46 +/- 0.86 mg m(-2) d(-1) for pyren
82 ed percent of the naphthalene, fluorene, and phenanthrene, and 46% of the chrysene in the oil were bi
87 ne, dibenzothiophene, fluorene, naphthalene, phenanthrene, and pyrene were used to prepare a PAH mixt
91 and mixed brominated/chlorinated anthracenes/phenanthrenes, and pyrenes/fluoranthenes (Cl-PAHs and X-
92 e of wild-type NDO-O(9816-4) in complex with phenanthrene, anthracene, and 3-nitrotoluene, are presen
93 oxidize biphenyl, the LMW PAHs naphthalene, phenanthrene, anthracene, and fluorene, and the HMW PAHs
94 Relative standard deviations were <30% for phenanthrene, anthracene, fluoranthene, and pyrene imply
95 Hs) (acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, and pyrene) from
97 d the presence of seven compounds: fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)
98 d the presence of seven compounds: fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)
99 th macrophages and fibroblasts, DEP extract, phenanthrene, anthracene, phenanthrenequinone, and beta-
100 of methoxy/hydroxy-substituted naphthalenes, phenanthrenes, anthracenes, etc. with Oxone in an aceton
102 iol epoxides of benzo[g]chrysene and benzo[c]phenanthrene (anti-BGCDE and anti-BCPDE, respectively).
103 hydroxy-1,2-epoxy-1,2,3,4-tetrahydro-benzo[c]phenanthrene (anti-BPhDE) isomers are diol epoxide metab
105 bstituted naphthalene amino esters including phenanthrene aromatic structural units is described.
106 ures were obtained with either hexadecane or phenanthrene as sole carbon source and sulfate as a term
109 repeated using 2-(2,6-dichlorophenyl)benzo[c]phenanthrene as the starting material, benzo[a]corannule
112 ibenz[a,h]anthracene (DB[a,h]A), and benzo[c]phenanthrene (B[c]Ph) by direct chiral stationary-phase
113 bons like benzo[a]pyrene (B[a]P) and benzo[c]phenanthrene (B[c]Ph) impede replication and transcripti
115 hydroxy-1, 2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene [(-)-B[c]PhDE; fjord-region diol epoxide] o
116 mperature protonation of substituted benzo[c]phenanthrenes, B[c]Phs, and their charge delocalization
124 ta[def]chrysene 22), monosubstituted benzo[c]phenanthrenes BcPh (3-methoxy- 23, 3-hydroxy- 24), and m
125 thynylphenyl)naphthalenes to various benzo[c]phenanthrene (BcPh) analogues was accomplished smoothly
126 diol 1,2-epoxide (DE) DNA adducts of benzo[c]phenanthrene (BcPh) at N6 of adenine on helicase activit
127 a]pyrene (BaP) diol epoxide (DE) and benzo[c]phenanthrene (BcPh) DE adducts at deoxyadenosine (dA) or
128 In contrast to BaP, the pair of benzo[c] phenanthrene (BcPh) DE adducts at G(+2), which intercala
129 ntercalating dA adducts derived from benzo[c]phenanthrene (BcPh) DEs inhibit WRN activity in a strand
131 ened 3,4-diol 1,2-epoxide adducts of benzo[c]phenanthrene (BcPh) were introduced at single N2-deoxygu
132 lpha,2alpha-epoxy-1,2,3,4-tetrahydrobenzo[c ]phenanthrene [BcPh DE-2 (2)] by hexafluoropropan-2-ol (H
133 ng degrees by benzo[a]pyrene (BP) or benzo[c]phenanthrene (BPh) adducts at purine bases within the 3'
136 250 min-1 for the R47L/Y51F/F87A mutant with phenanthrene) but the coupling efficiencies were relativ
140 silicone controlled the chemical activity of phenanthrene (chemical stress), while saline solutions c
141 up of aporphinoids, which all share a common phenanthrene chromophore motif that is thought to be res
142 or polycyclic aromatic hydrocarbons (pyrene, phenanthrene, chrysene, benzo[a]pyrene, anthracene, naph
143 (-)-biphenyl cis-(3S,4R)-dihydrodiol and (-)-phenanthrene cis-(1S,2R)-dihydrodiol from biphenyl and p
144 nzyme also formed the opposite enantiomer of phenanthrene cis-1,2-dihydrodiol from phenanthrene to th
145 Both molecules contain an alternate aromatic phenanthrene- co-quinoidal pyrene structure to satisfy C
146 f macrocycles consisting of 9,10-substituted phenanthrenes connected by butadiynylene linkers in posi
147 relatively weak, whereas for the triangular phenanthrene-containing structures, there was a clear in
148 Here we isolate the binary caesium salts of phenanthrene, Cs(C14H10) and Cs2(C14H10), to show that t
150 ably, adsorbed phosphate increased anaerobic phenanthrene degradation and bzdN catabolic gene prevale
151 ios of 12.25:1 for hexadecane and 8.25:1 for phenanthrene degradation coupled to sulfate reduction.
152 sis showed a remarkably higher expression of phenanthrene degradation genes 4 h after inoculation, co
153 enome-assembled genomes (MAGs) revealed that phenanthrene degradation is likely mediated by novel gen
154 This indicates that the cells were active in phenanthrene degradation while experiencing stress.
156 anthrene carboxylic acid was detected in the phenanthrene-degrading enrichment cultures, providing ev
157 ween %F(rap) and the fractions degraded by a phenanthrene-degrading inoculum (%F(min)) indicated that
159 (13)C) compound-specific isotope analysis on phenanthrene deposited in a lake from the Athabasca sect
160 ndicates that the radical ion stabilities in phenanthrene derivatives are drastically improved by inc
165 rogenerated chemiluminescence (ECL) of three phenanthrene derivatives, 3,6-diphenyl-9,10-bis-(4-tert-
166 es and decreased nonplanarity in the benzo[c]phenanthrene derivatives, but its influence was most pro
169 ically activated to the enantiomeric benzo[c]phenanthrene diol epoxides (B[c]PhDEs), (+)-(1S,2R,3R,4S
170 Across the entire tropical Atlantic Ocean, phenanthrene displayed on average highest dissolved conc
172 enivorans (family Desulfobacteraceae), while phenanthrene-enriched populations were most closely rela
173 ded %F(rap), indicating a fraction of sorbed phenanthrene (%F(slow)) remained microbially accessible.
175 humans and the environment in Africa toward phenanthrene, fluoranthene, pyrene, benzo(a)pyrene, 2,3,
176 M-Green to oxidize the three-ring compounds, phenanthrene, fluorene, and anthracene faster than the w
178 and C(4)G3 dendrimers afforded considerable phenanthrene formation, in addition to cis-stilbene, whe
179 Cyclohexanol, phenol, benzoic acid, and phenanthrene fractional removal (italicized words are de
180 ly (%F(rap)) and slowly (%F(slow)) desorbing phenanthrene fractions and their rate constants were det
181 ollowing: conversion of 2-ethynylbiphenyl to phenanthrene, fragmentation of phthalic anhydride to ben
182 There was an additional 25-40% removal of phenanthrene from soil by the willow and grasses, respec
183 method for the synthesis of substituted 9,10-phenanthrenes from 2-biaryl triflates with alkynes has b
184 avelength absorptions than the corresponding phenanthrene fused structure, although the differences w
186 hese results suggest the potential use of [a]phenanthrene-fused BODIPYs as NIR bioimaging probes.
188 systems such as naphthalene, anthracene, or phenanthrene generally only produces minor bathochromic
189 or example, FVP of 2-(o-chlorophenyl)benzo[c]phenanthrene gives 1-phenylbenzo[ghi]fluoranthene as the
191 An efficient synthesis of functionalized phenanthrenes has been developed for the first time invo
192 nally substituted 9-fluorenylidenes and 9,10-phenanthrenes have been synthesized from substituted o-h
194 lling evidence on the efficient synthesis of phenanthrene in carbon-rich circumstellar environments.
195 he desorption kinetics and mineralization of phenanthrene in four soils was investigated after 1, 25,
196 ation of the polycyclic aromatic hydrocarbon phenanthrene in the absence and presence of bacterial fo
200 ous 1,2-diarylethylenes for the synthesis of phenanthrenes in excellent yield has been described.
201 nylethylidene)-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene, in C6H6 (or C6D6), at ambient temperature,
202 1-benzylidene-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene, in deuterated benzene at ambient temperatu
206 cyclization to form an unstable 8a,9-dihydro-phenanthrene intermediate, followed by exothermic unimol
210 edient synthesis of 13-aryl-13H-indeno[1,2-l]phenanthrene is described by a double annulations of 2-a
212 n oxidative photocyclization of stilbenes to phenanthrenes is a well-known and synthetically valuable
213 ased ligands; A = 2,9-bis[trans-Pt(PEt3)2NO3]phenanthrene) is described with emission wavelengths spa
214 cenaphthene C12H10 (L2); anthracene (L3) and phenanthrene (L4), C14H10; pyrene (L5) and fluoranthene
217 It differed from the (-)-trans-anti-benzo[c]phenanthrene-N(2)-dG adduct having S stereochemistry at
218 eoisomeric "fjord" region trans-anti-benzo[c]phenanthrene-N2-guanine (designated (BPh)G) adducts posi
222 The efficient preparation of Sn-substituted phenanthrenes opens access to convenient building blocks
224 been observed for their fjord-region benzo[c]phenanthrene or bay-region benzo[a]pyrene analogues.
226 oximately 1.5 per thousand) in delta(13)C of phenanthrene over the last three decades pointed to an i
227 aturation activity, the final products being phenanthrene (P1) and phenanthrene 9,10-oxide (P3), the
229 .e., alpha- and gamma-hexachlorocyclohexane, phenanthrene, PCB-18 and PCB-52) in samples collected at
230 veloped and applied for the determination of phenanthrene (PHE) and pyrene (PYR) in chrysanthemum tea
231 s fluoranthene (FLA), naphthalene (NAP), and phenanthrene (PHE) as sole carbon sources for energy and
232 with decay) and tested it with three aerobic phenanthrene (PHE) degraders: Novosphingobium pentaromat
233 co-metabolically degraded up to 1.8 mumol of phenanthrene (PHE) in approximately 48 h, and hydroxyphe
234 demonstrated the uptake and accumulation of phenanthrene (PHE) in lipid vesicles and its active tran
235 nature of mixtures of Cu, Cd, V, or Ni with phenanthrene (PHE) or phenanthrenequinone (PHQ) using th
237 laboratory microcosm with passive dosing of phenanthrene (PHE) to a model soil-atmosphere interface
238 heir sorption of dibutyl phthalate (DBP) and phenanthrene (PHE) were investigated in this study.
239 Ss) were exposed to atmospheric pollution by phenanthrene (PHE), a gaseous PAH, for 2 weeks in exampl
241 ree polycyclic aromatic hydrocarbons (PAHs): phenanthrene (PHE), pyrene (PYR), and benzo[a]pyrene (Ba
242 ferent volatilities, we conduct analyses for phenanthrene (PHE), pyrene (PYR), and benzo[a]pyrene (Ba
243 n the (1)H NMR spectrum, suggesting that the phenanthrenes pi-stack on coordination of silver(I).
246 below the minimum measured concentrations of phenanthrene, pyrene, and benzo(a)pyrene in the environm
247 purine adducts of PAHs, such as naphthalene, phenanthrene, pyrene, and chrysene, could be prepared by
248 Symmetric meso-tetraarylporphyrins bearing phenanthrene, pyrene, and corannulene moieties in meta p
249 tions of PAHs across the entire cruise, with phenanthrene, pyrene, and fluoranthrene all >1 ng L(-1).
250 tions of fire-derived PAH compounds, namely, phenanthrene, pyrene, benzo( e)pyrene, and indeno(123- c
251 ived from naphthalene, fluorene, anthracene, phenanthrene, pyrene, fluoranthene, chrysene, and benzo[
252 plexation, which were measured in DMF-d7 for phenanthrene, pyrene, triphenylene, and coronene by dyna
253 s that affords multifunctional naphthalenes, phenanthrenes, quinolines, and benzo[b]carbazoles via Kn
254 tures (e.g., total monomethylphenanthrene to phenanthrene ratios, MP/P ~2-3) at intermediate temperat
255 olite of the environmental pollutant benzo[c]phenanthrene, reacts with DNA primarily at the exocyclic
256 cence quantum yield of all nonsubstituted BN-phenanthrenes reported to date ( (F) = 0.61), has been s
261 arbaporphyrins with fused acenaphthylene and phenanthrene rings have been prepared, and the former de
265 ihydroxy-1,2-epoxy-1,2,3,4-tetrahydrobenzo[c]phenanthrene stereoisomer, in which intercalation is als
266 )(), providing the first example of an alpha-phenanthrene-substituted carbocation from phenanthrene C
267 (petrogenic) versus unmethylated (pyrogenic) phenanthrenes; such antibodies will be useful in detecti
269 omerism, and they were converted to a single phenanthrene target by way of ring-closing metathesis.
271 graphene had higher adsorption capacity for phenanthrene than carbon nanotube and graphite due to th
272 ining a heavy fuel spiked with (14)C-labeled phenanthrene that were incubated in the presence or abse
273 naphthalen-2-yl)-9,10-bis(4-tert-butylphenyl)phenanthrene (TnaP, T2), and 3,6-di(pyrene-1-yl)-9,10-bi
275 ions for the PAHs benzo[a]pyrene, pyrene and phenanthrene to simulated spatially resolved concentrati
276 lied that diffusive exchange was a source of phenanthrene to surface waters, while acenaphthylene vol
277 mer of phenanthrene cis-1,2-dihydrodiol from phenanthrene to that formed by biphenyl dioxygenase from
278 n kinetics of typical wastewater pollutants (phenanthrene, tonalide, and benzophenone) at different d
280 s, 3,6-diphenyl-9,10-bis-(4-tert-butylphenyl)phenanthrene (TphP, T1), 3,6-di(naphthalen-2-yl)-9,10-bi
281 -di(pyrene-1-yl)-9,10-bis(4-tert-butylphenyl)phenanthrene (TpyP, T3), are investigated in an acetonit
282 ketone rearrangement and the benzopinacol to phenanthrene transformation suggest that the complex has
283 yclobutylidene-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene undergo photolysis in solution at ambient t
284 dramatically enhanced the mineralization of phenanthrene, up to 30 times greater than the rate witho
285 drocarbons (PAHs), exemplified by pyrene and phenanthrene, using mild grinding in the presence of com
286 however, biofilm formation was incipient and phenanthrene was mineralized following zero-order kineti
294 nd 0.78 mug kg(-1)) and both naphthalene and phenanthrene were found in two commercial guarana powder
296 ates, one based on biphenyl and the other on phenanthrene, which have different degrees of planarity
297 the same conditions, FVP of 2-phenylbenzo[c]phenanthrene, which lacks a radical precursor, gave prim
298 emperature thermal rearrangement can lead to phenanthrene, which was the major product observed by Br
299 increasing trend in the adsorbed amounts of phenanthrene, while a stepwise pattern was apparent.
300 because the bacterial strain alone degraded phenanthrene with sigmoidal kinetics but could not degra