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1 esis, the transamination of phenylalanine to phenylpyruvate.
2 ay from a precursor other than Phe, possibly phenylpyruvate.
3 ; no turnover is observed in the presence of phenylpyruvate.
4 his specificity is the alternative substrate phenylpyruvate.
5  is synthesized from the amino acid Phe, via phenylpyruvate.
6 nine and tyrosine are synthesized either via phenylpyruvate/4-hydroxyphenylpyruvate or via arogenate.
7 ndence of the kcat/Km for the enolization of phenylpyruvate (6.0 +/- 0.1) are comparable and in reaso
8 ng with shikimate also led to prephenate and phenylpyruvate accumulation and a partial recovery of th
9 transforming activity of Ser101Leu102 or the phenylpyruvate activity of Pro101Lys102.
10 outcome of the work is the confirmation that phenylpyruvate acts as the intermediate in the synthesis
11 ermediate step between chorismate mutase and phenylpyruvate aminotransferase.
12 hat interconverts the enol and keto forms of phenylpyruvate and (p-hydroxyphenyl)pyruvate and convert
13 ut kinetic studies using the enol isomers of phenylpyruvate and (p-hydroxyphenyl)pyruvate.
14 ne and tryptophan are first deaminated (to 3-phenylpyruvate and 3-indolepyruvate, respectively) and t
15 ral basis for the affinity of native MDH for phenylpyruvate and a rationale for the improved catalyti
16 ative deamination of L-phenylalanine to form phenylpyruvate and ammonia.
17  initial structural analyses of the E.NAD(+).phenylpyruvate and E.NAD(+).
18 ared role in the light-mediated synthesis of phenylpyruvate and Phe, because they are iteratively int
19 fic role in blue light-mediated synthesis of phenylpyruvate and subsequently of phenylalanine (Phe).
20 ase (CHMI), and catalyzes the enolization of phenylpyruvate and the ketonization of (p-hydroxyphenyl)
21 m sensing, AMP/GMP-activated protein kinase, phenylpyruvate, and beta-hydroxybutyrate production prev
22 -naturally occurring D-isomer of dopachrome, phenylpyruvate, and certain catecholamines, suggesting t
23 tures described here, namely the enzyme.NAD+.phenylpyruvate, and enzyme.
24 eraction with a carboxylate oxygen at C-1 of phenylpyruvate, and it may be partially responsible for
25 from phenylalanine via its transamination to phenylpyruvate, and mining of the transcriptome identifi
26 cts' being released in the order of ammonia, phenylpyruvate, and NADH.
27 riant with Asn101Va1102 is as efficient with phenylpyruvate as is the wild-type enzyme (Asn101Gln102)
28 e contribution of an alternative pathway via phenylpyruvate, as occurs in most microbes, has not been
29 ned by direct monitoring of the formation of phenylpyruvate at 280 nm.
30 hway that produces a family of hybrid pterin-phenylpyruvate conjugates, which we named the colipterin
31 oxin oxidoreductase (PPFOR) and the other by phenylpyruvate decarboxylase (PPDC).
32 n summer as a heat adaptation that uses rose phenylpyruvate decarboxylase (RyPPDC) as a novel enzyme.
33 otential aromatic acetaldehyde synthases and phenylpyruvate decarboxylases in reconstructed plant gen
34 A production via oxidative and non-oxidative phenylpyruvate decarboxylation, respectively.
35 the latter had about one-seventh of the best phenylpyruvate dehydrogenase activity.
36 hways for PAA formation; one is catalyzed by phenylpyruvate:ferredoxin oxidoreductase (PPFOR) and the
37                   The specificity of MDH for phenylpyruvate has now been enhanced, and that for the p
38 lucidation of phenylalanine biosynthesis via phenylpyruvate in plants, showing that this pathway spli
39 ynthesized from prephenate exclusively via a phenylpyruvate intermediate in model microbes, the alter
40 ertainty as to whether plants use arogenate, phenylpyruvate, or both as obligatory intermediates in P
41 contained 76, 74, and 42% lower activity for phenylpyruvate, p-hydoxyphenylpyruvate, and indolepyruva
42 subcellular localization of a microbial-like phenylpyruvate pathway for phenylalanine biosynthesis in
43 ow that plants also utilize a microbial-like phenylpyruvate pathway to produce phenylalanine, and flu
44              Unexpectedly, we find the plant phenylpyruvate pathway utilizes a cytosolic aminotransfe
45 s cytosolic phenylalanine production via the phenylpyruvate pathway.
46 potential alternative to the known cytosolic phenylpyruvate pathway.
47 ponsible for the light-mediated synthesis of phenylpyruvate, Phe, and those metabolites that derive f
48                          The binding of HPP, phenylpyruvate (PPA), and pyruvate to the holoenzyme pro
49 e enzyme with the analogue of the substrate, phenylpyruvate (PPA), is noncatalytic.
50 el in transgenic petals, suggesting that the phenylpyruvate route can also operate in planta.
51 ized from prephenate via an arogenate and/or phenylpyruvate route in which arogenate dehydratase (ADT
52 IF), an immunoregulatory protein, exhibits a phenylpyruvate tautomerase (PPT) activity.
53                                              Phenylpyruvate tautomerase (PPT) has been studied period
54 p-hydroxyphenylpyruvate, a substrate for the phenylpyruvate tautomerase activity of MIF.
55 igration despite significantly reduced or no phenylpyruvate tautomerase activity.
56  as an immunoregulatory protein as well as a phenylpyruvate tautomerase.
57 ory perception (olfactory receptors, OR) and phenylpyruvate tautomerase/dopachrome isomerase activity
58 at catalyzes the conversion of prephenate to phenylpyruvate, the intermediate step between chorismate
59 n pea (Pisum sativum), the reverse reaction, phenylpyruvate to Phe, is also demonstrated.
60 omers {2-keto-3-[2H]-4-pentenoate and 3-[2H]-phenylpyruvate}, where the (3R)-isomers predominate.