ライフサイエンスコーパス: photochemically

1 drive the formation of ammonia from nitrogen photochemically.

2 sing of the "gate" of the host is controlled photochemically.

3 rresponding carbodiimides both thermally and photochemically.

4 factor was reduced by NADPH or dithionite or photochemically.

5 eactive benzyne derivatives can be initiated photochemically.

6 l, reversible NTB-N transition may be driven photochemically.

7 ne protonated Schiff base both thermally and photochemically.

8 iastereomeric states can interconvert solely photochemically.

9 Dihydrogen complexes typically lose H2 photochemically.

10 he isomers in the crystal both thermally and photochemically.

11 aks in an oligodeoxynucleotide by way of two photochemically activated (caged) building blocks placed

12 The photochemically activated combustion sol-gel a-IGZO TFTs

13 mammalian cells and zebrafish embryos using photochemically activated, caged guide RNAs (gRNAs).

14 By imaging the spread of H(+) ions from a photochemically-activated source (6-nitroveratraldehyde)

15 The phyA-V631M mutant protein is photochemically active and accumulates to a level simila

16 an's atmosphere, indicating that pI could be photochemically active and drive chemistry on the surfac

17 Identifying photochemically active compounds and understanding photo

18 dings should be useful for the design of new photochemically active compounds supported by main-group

19 nine-5,5'-disulfonic acid for detection or a photochemically active dye (chlorin(e6)) for therapy of

20 mmercial titanium dioxide as a proxy for its photochemically active fraction; to date, however, the v

21 flavin mononucleotide noncovalently and are photochemically active in solution.

22 totropism in transgenic Arabidopsis, whereas photochemically active LOV1 alone is not.

23 Moreover, photochemically active LOV2 alone in full-length phot1 i

24 l TiO2 nanoparticles surface modified with a photochemically active mimic of the PSII chlorophyll-Tyr

25 d excited spin state trapping (LIESST) and a photochemically active octacyanometalate(IV) unit.

26 t question: Is the lower atmosphere of Titan photochemically active or inert?

27 izing the bilin chromophore used to assemble photochemically active phys.

28 consistent with a substantial deficiency in photochemically active phys.

29 ed by the CP43 subunit, becomes exposed in a photochemically active PSII complex lacking CP43, it is

30 d by (Ru-Diad)8MspA at the TiO2 electrode is photochemically active.

31 K requires that its N-terminal LOV domain be photochemically active.

32 olecular receptors 1a and 1b consisting of a photochemically addressable azobenzene tether functional

33 f combusted biogas is tested under fresh and photochemically aged conditions.

34 rome yellow degradation pathways by studying photochemically aged model samples covered with a dammar

35 me OP assays respond to organics, especially photochemically aged organics, from sources like biomass

36 of anthropogenic and biogenic SOA that were photochemically aged under varying nitrogen oxide (NOx)

37 A concerted, photochemically allowed [4pis + 2pia] cycloaddition was

38 d the cardiopulmonary effects of exposure to photochemically altered particle-free multipollutant mix

39 Exposure to photochemically altered urban air pollution appears to a

40 mechanism in a global aerosol model yields a photochemically and biologically driven seasonal cycle o

41 complexes involving CO and Xe can be cleaved photochemically and reformed by mildly annealing the mat

42 we highlight recent progress in the field of photochemically and thermally induced electron transport

43 osed of (Br)U and U, which undergoes further photochemically and thermally induced transformations to

44 e cyclopropanone underwent CO extrusion both photochemically and thermally to give the cycloheptadien

45 Such reactions will be readily accessible photochemically and thermally, e.g., under the condition

46 s were virtually identical to those obtained photochemically, and thus the doubly reduced photoproduc

47 s entering the environment are mechanically, photochemically, and/or biologically degraded to the ext

48 rgano-hydride systems in electrochemically-, photochemically- and chemically-driven reductions of uns

49 Because electrons added photochemically are easily titrated, photodoping also al

50 to sunlit environments where *OH is produced photochemically, but a recent laboratory study proposed

51 The equilibrium can be perturbed photochemically by either intermolecular proton or elect

52 ((i)Pr(3)P)(H)(2)OsSn(trip) (2) thermally or photochemically by what appears to be a radical process.

53 nt an orthogonal approach which proceeds via photochemically catalyzed isomerization of the thermodyn

54 isolated using solid-phase extraction (SPE), photochemically characterized, and compared to the origi

55 novel noble-metal free complexes that can be photochemically charged in the presence of sacrificial e

56 A universal, photochemically cleavable DNA base analogue would add de

57 le linkers, a thermally labile linker, and a photochemically cleavable linker- all of which are used

58 Beads displaying photochemically cleavable pepstatin A were distributed i

59 synthesized based on our previous work with photochemically cleavable terminators.

60 a photoactivatable unnatural amino acid and photochemically cleave the backbone of the alpha subunit

61 aromatic disulfide that can be chemically or photochemically cleaved.

62 ring opening to a cyclooctatriene (12) that photochemically closes to 6.

63 r cores assembled in the plasma membrane are photochemically competent and can catalyze single turnov

64 tural and spectroscopic comparisons with the photochemically compromised D207A mutant revealed that s

65 A photochemically controlled AND gate was developed throug

66 -catalyzed and pH-sensitive processes can be photochemically controlled by using this type of photoac

67 ker in a hemicarcerand creates a new type of photochemically controlled gated hemicarcerand.

68 Proteins can be photochemically controlled through the site-specific ins

69 wedge )N)(3) complexes can be thermally and photochemically converted to facial forms, indicating th

70 Photochemically coupled Belousov-Zhabotinsky micro-oscil

71 We photochemically cross-linked heads and tails and produce

72 Photochemically cross-linked iAbeta42 displayed an oligo

73 icult management challenge and chemically or photochemically cross-linking the cornea for therapy pre

74 oligonucleotide containing a single 6-TG is photochemically crosslinked to cysteine-containing oligo

75 r weight reactive liquid precursors that are photochemically cured into highly proton conductive soli

76 DNA molecules have the undesirable effect of photochemically damaging the DNA through radical interme

77 ower or prolonged illumination in air, which photochemically degrades the polyviologen and thereby re

78 en indicates that models may need additional photochemically dependent pathways to low-volatility SOA

79 In this study Co-based catalysts were photochemically deposited as 10-30 nm nanoparticles on t

80 and gold particles were electrochemically or photochemically deposited on these crystals with the pre

81 ated planetesimals inherited sulfur that was photochemically derived from gases in the early inner so

82 n caused by singlet oxygen, (1)O(2), a major photochemically derived oxidant toward amino acids.

83 using the photosensitizer Pc 4 and red light photochemically destroys the antiapoptotic protein Bcl-2

84 onment has been used for the conversion of a photochemically driven chemical cycle for group 6 metal-

85 Efficiency of this photochemically driven direct arylation has been demonst

86 aryl substituent at position 2 undergo swift photochemically driven direct arylation, leading to bare

87 absorption and Raman monitoring to detect a photochemically driven EPT process (photo-EPT).

88 The mechanism of this photochemically driven pathway most likely involves the

89 scribed that is thermodynamically capable of photochemically driving the energy-storing reverse water

90 itters are currently the most chemically and photochemically efficient probes for two-photon photolys

91 romophore has great promise as a generic and photochemically efficient protecting group for both one-

92 s revealed that compounds in this class are "photochemically enhanced" inhibitors, in that they bind

93 In this paper, we demonstrate how photochemically enhancing the permeability of metal-orga

94 hat H-abstraction processes are initiated by photochemically excited dissolved organic matter which w

95 into individual subsections according to the photochemically excited olefin.

96 They absorb light through a flavin cofactor, photochemically form a covalent bond between the chromop

97 system to demonstrate that the lifetime of a photochemically formed radical pair is changed by applic

98 inyl group is activated using UV light which photochemically forms new covalent bonds among PQWs.

99 arrangement of 2-ethoxyethylidene, generated photochemically from a nonnitrogenous precursor, leads t

100 Siloxy carbenes, formed thermally or photochemically from acyl silanes via a 1,2-Brook rearra

101 eterolysis of a pyrimidine radical generated photochemically from an aryl sulfide.

102 ne-electron reducing intermediates generated photochemically from both untreated and borohydride-redu

103 Next, transient HCO is made photochemically from formaldehyde.

104 This compound can also be prepared photochemically from its iron(II) precursor by irradiati

105 orbornyloxychlorocarbenes (7) were generated photochemically from the corresponding diazirines (6).

106 iynylidene (MeC(5)Me, 1b) have been produced photochemically from their corresponding diazo compound

107 nd acetaldehyde, which are formed in the air photochemically from volatile organic compounds (VOCs),

108 en Rose Bengal or methylene blue was used to photochemically generate (1)O2 in the presence of Lys, w

109 uted anthraquinone (AQ), previously shown to photochemically generate benzaldehyde in methanol soluti

110 he 5020 s(-1) rate constant for decay of the photochemically generated aci-nitro intermediate (pH 7.0

111 n reactions, suggesting the involvement of a photochemically generated acid.

112 or in the rate of dark-state cleavage of the photochemically generated adduct.

113 high valent Fe(V)(O) intermediate species is photochemically generated as the active intermediate for

114 Photochemically generated benzyl radicals react with Sc(

115 The photochemically generated blue-absorbing state is in equ

116 Capture of a photochemically generated carbene 21 by methanol is the

117 ted enantioselective iminium ion trapping of photochemically generated carbon-centered radicals.

118 Transfer kinetics of photochemically generated cholesterol hydroperoxide (ChO

119 idation of the 5'-d(CCTACGCTACC) sequence by photochemically generated CO3*- radicals in low steady-s

120 is key to understanding the contribution of photochemically generated dissolved organic matter from

121 excess free thiol ligands, they replaced the photochemically generated disulfides and maintained the

122 chanical switch, capable of utilizing such a photochemically generated driving force to bring about c

123 resence of reduced metal ions, chemically or photochemically generated during the first stage, onto o

124 pate in C-H bond cleavage reactions with the photochemically generated fragment [Tp'Rh(CNR)] (Tp' = h

125 e thought to be silver nanoclusters that are photochemically generated from the oxide.

126 e in photodegradation could be attributed to photochemically generated halogen radicals rather than o

127 nthetically useful Diels-Alder trapping of a photochemically generated hydroxy-o-quinodimethane speci

128 Photochemically generated hydroxyl radicals were used to

129 ation concentration c* < 100 mug m(-3)) were photochemically generated in rapid bursts in situ in an

130 A very facile reaction between photochemically generated o-naphthoquinone methides (oNQ

131 The click chemistry based on the addition of photochemically generated oNQM to vinyl ether works well

132 e summertime due to higher concentrations of photochemically generated oxidants such as hydroxyl radi

133 question, the recombination efficiencies of photochemically generated radical cage pairs (denoted as

134 mass on the cage recombination efficiency of photochemically generated radical cage pairs.

135 tions of dissolved organic matter (DOM) with photochemically generated reactive halogen species (RHS)

136 Similarly, oxidative challenge by H(2)O(2), photochemically generated reactive oxygen species, or UV

137 f PCs for the assessment of the formation of photochemically generated RIs.

138 A hole scavenging reaction between the photochemically generated Ru(bpy)3(3+) and 1 occurs with

139 hore-assisted light inactivation (CALI) uses photochemically generated, reactive oxygen species to in

140 ation product of PBDE 153 that is capable of photochemically generating 2,3,7,8-tetrabromodibenzo-p-d

141 hown that all three compounds are capable of photochemically generating other compounds of concern, i

142 t is activated by light irradiation, thereby photochemically generating reactive oxygen species (ROS)

143 A layer of MIP was photochemically grafted over the polyaniline, via N,N'-d

144 After CIEF, charge variants are photochemically immobilized to the wall of a short coate

145 rn colonies indicate an accumulation of more photochemically impacted MeHg, supporting shallow MeHg p

146 The 2(1)Ag state, which is dark but photochemically important, is a prime source of this dif

147 tes and mechanisms of decay of ASQ generated photochemically in bifurcating NADH-dependent ferredoxin

148 h is thought to involve radical pairs formed photochemically in cryptochrome proteins in the retina.

149 Phenoxyl radical (C(6)H(5)O) was prepared photochemically in low-temperature argon matrices.

150 When the carbene is generated photochemically in methanol, it reacts by a protonation

151 n phosphatidylcholine liposomes and produced photochemically in tap water.

152 immunologic potencies of live-attenuated and photochemically inactivated nucleotide excision repair m

153 Photochemically inactivated vaccine strains maintained a

154 by light in the wild type but was limited in photochemically inactive and null mutants, indicating th

155 ngle crystal X-ray diffraction analysis of a photochemically inactive dichloromethane solvate was use

156 14 new photoswitching CBCRs, one apparently photochemically inactive protein exhibiting intense red

157 shifted state (from 701 to 702 nm), which is photochemically inactive to red or white light.

158 amically stable chelate was also found to be photochemically inactive, and a unique mechanism was dis

159 nits is polymerized in a single crystal by a photochemically induced [4 + 4] cycloaddition reaction b

160 enabled us to perform the first examples of photochemically induced arene exchange/expansion reactio

161 Photochemically induced bound residue formation of polar

162 enerated in a layer-by-layer fashion through photochemically induced C,H insertion reactions and cons

163 The photochemically induced coupling of aromatic ketones wit

164 The observed products of this photochemically induced cycloaddition showed a stereosel

165 ve concentration, followed by shear force or photochemically induced division.

166 Photochemically induced DSBs, but not general oxidative

167 it the large enhancements arising from (13)C photochemically induced dynamic nuclear polarization ((1

168 bsorption spectroscopy and confirmed by (1)H photochemically induced dynamic nuclear polarization (ph

169 p-cage' miniprotein known as TC5b, we report photochemically induced dynamic nuclear polarization NMR

170 Photochemically induced dynamic nuclear polarization was

171 Photo-CIDNP (photochemically induced dynamic nuclear polarization) ca

172 Photo-CIDNP (photochemically induced dynamic nuclear polarization) MA

173 mbotic occlusion of the carotid artery after photochemically induced endothelial cell injury.

174 Measurements of photochemically induced ET and subsequent charge recombi

175 hosen neurons are revealed by diffusion of a photochemically induced fluorescent product from their s

176 For Plesne Lake, the photochemically induced formation of particulate REEs ex

177 The utility of photochemically induced hetero-Diels-Alder reaction for

178 terference contrast microscopies, we monitor photochemically induced microtubule breakdown on the sup

179 y) results in rapid (half-lives ~20-60 min), photochemically induced nucleophile incorporation across

180 vironment via a series of binding events and photochemically induced oxidation events, but the full m

181 We studied photochemically induced precipitation of rare-earth elem

182 fter the end of irradiation, suggesting that photochemically induced reactions and/or continuing prec

183 s, the yields of target bromosulfones in the photochemically induced reactions can be increased by re

184 lated to decomposition of organic matter and photochemically induced reactions.

185 ical reactivity and role as intermediates in photochemically induced reactions.

186 At pH 5.0, the photochemically induced sediment flux was 3509 nmol m(-2

187 Observed photochemically induced sequestration of REEs into sedim

188 the protective effect of this enzyme against photochemically induced stress and UVB irradiation in ce

189 The latter acetals are photochemically inert but can be converted into photolab

190 ups can be armed in situ by the reduction of photochemically inert p-quinone precursors.

191 he SOM, increasing its O/C by up to 55% over photochemically inert SiO(2) while having negligible eff

192 [Os(N^N)3 ](2+) complexes are supposed to be photochemically inert to ligand loss, the complex [Os(bt

193 nd Zn(bpod)(2)(CH(3)COO)(2) compound (4) are photochemically inert under the same conditions.

194 med to explain why [4]PF(6) and [5]PF(6) are photochemically inert while [1]PF(6)-[3]PF(6) perform se

195 tic hydrogens of tyrosine O-methyl ether are photochemically inert, but become labile in the presence

196 gm in photopatterning: the surface itself is photochemically inert, while photoreactive component is

197 ated using the light reflected from a DMD to photochemically initiate atom-transfer radical polymeriz

198 Evidence of a photochemically initiated diradical cyclization pathway

199 controlling the yield and efficiency of the photochemically initiated immobilization.

200 n the rich organic chemistry associated with photochemically initiated reactions in the upper atmosph

201 The reaction involves a photochemically initiated reduction of a quinone mediate

202 2a-c are themselves easily accessed through photochemically initiated topochemical polymerization of

203 hPF4 and KKO selectively bound to photochemically injured endothelium at sites where surfa

204 ity for acetate release, whereas NHQ-OAc was photochemically insensitive.

205 We report the syntheses of the photochemically labile 9-diazo-4,5-diazafluorene (1) fra

206 The aromatic hydrogen nuclei of tyrosine are photochemically labile and exchange with deuterons in ne

207 ed product were orthogonally protected using photochemically labile and hydrazine labile groups.

208 dG(N(1)-H)(*) was generated photochemically (lambda(max) = 350 nm) from an N-aryloxy

209 Therefore, the mechanism of photochemically mediated ATRP is consistent with a photo

210 The polymerization mechanism of photochemically mediated Cu-based atom-transfer radical

211 The initiation mechanism of photochemically mediated Cu-based reversible-deactivatio

212 Other novel thermally and photochemically mediated skeletal rearrangement reaction

213 the first time that aldehydes have been made photochemically on a solid-supported phase.

214 riginated from soil humics and appears to be photochemically or microbially modified.

215 Several nitrile imines were generated photochemically or thermally and investigated by IR spec

216 the peroxo O-O bond can be initiated either photochemically or thermally to produce a new species as

217 and metal oxide catalysts have been used to photochemically oxidize water.

218 ese mineral, rhodochrosite (MnCO(3)), can be photochemically oxidized by light under anoxic, abiotic

219 present "missing" sources of urban SOA, were photochemically oxidized in an outdoor smog chamber faci

220 ed the spreading of phospholipid vesicles on photochemically patterned n-octadecylsiloxane monolayers

221 racy and large-area lateral uniformity using photochemically patterned single 1,2-dimyristoyl-sn-glyc

222 ers and rarely working in conjunction with a photochemically powered system.

223 Remarkably, the rate of the reaction of the photochemically prepared compound 2 toward sulfides incr

224 We photochemically prepared the species with stoichiometry

225 sorption band in the near IR spectrum of the photochemically prepared, mixed valence form, [(bpy)2ClR

226 ristics, and optical properties of fresh and photochemically processed emissions from biomass combust

227 ice coatings on preexisting grains that were photochemically processed into refractory organic matter

228 oredox agent into the chalcogels is shown to photochemically produce hydrogen.

229 Photochemically produced aerosols are common among the a

230 Here we quantitatively examine 1O2 photochemically produced from DOM in frozen and liquid a

231 arious systems involving complex mixtures of photochemically produced oxidants of differing natures.

232 through altering the accessibility of His to photochemically produced oxidants or through shifting th

233 ects on the formation of covalent bonds from photochemically produced pairs of radicals.

234 Detection of photochemically produced peroxyl radicals is achieved by

235 ) composition influences its ability to form photochemically produced reactive intermediates (PPRI).

236 n surface waters results in the formation of photochemically produced reactive intermediates (PPRIs)

237 ce of indirect photolysis pathways involving photochemically produced reactive intermediates (PPRIs).

238 We studied the formation of photochemically produced reactive intermediates (RI) fro

239 The antioxidant capacity and formation of photochemically produced reactive intermediates (RI) was

240 the apparent quantum yields (Phi(app,RI)) of photochemically produced reactive intermediates (RIs), s

241 ) or sensitize photodegradation by producing photochemically produced reactive intermediates but can

242 oric dissolved organic matter ((3)CDOM*) are photochemically produced reactive intermediates responsi

243 icroenvironments with high concentrations of photochemically produced reactive intermediates, such as

244 oducing singlet oxygen (1O2) alongside other photochemically produced reactive intermediates.

245 ic hot-spot and caused extreme enrichment of photochemically produced trace gases.

246 x-active moieties can reduce the lifetime of photochemically produced Trp(*+) and thus quench Trp deg

247 The synthesis is accomplished by photochemically promoted allylic substitution reactions

248 al bisadduct 12 can only undergo syn or anti photochemically promoted intramolecular tandem [4 + 4] a

249 Systems such as 26 readily participate in photochemically promoted oxa-di-pi-methane rearrangement

250 ing adduct to the tricyclic ketone 12, and a photochemically promoted rearrangement of this last comp

251 y) light-harvesting antenna complexes into a photochemically quenched state.

252 verall, the ability of these chromophores to photochemically react under substrate control may make u

253 duced to the mobile chamber and subsequently photochemically reacted.

254 reactive under thermal conditions, they were photochemically reactive.

255 ical S-nitroso compounds is to chemically or photochemically reduce SNO functional groups to release

256 present nanohybrids were further utilized to photochemically reduce the hexyl viologen dication in th

257 with Cl(-) or Br(-) may be less likely to be photochemically reduced and re-emitted to the atmosphere

258 d CO2 by using an electron supplied from the photochemically reduced Ru photosensitizer unit.

259 If SNO-actin is photochemically reduced with UV light or if actin filame

260 The framework can be photochemically reduced, allowing the storage of multipl

261 ning FeMoS inorganic clusters are capable of photochemically reducing N2 to NH3 under white light irr

262 ising from the meta-II signaling state while photochemically regenerating a pigment with ground state

263 A design principle for a two-photon photochemically removable protecting group based on sequ

264 jor outcome of this work is a novel class of photochemically removable protecting groups.

265 nylcyclopropenylidene (6), a process that is photochemically reversible at lambda=232 nm.

266 Three new photochemically reversible but thermally stable dithieny

267 cal twisting powers were found to experience photochemically reversible isomerization with thermal st

268 All the compounds exhibited photochemically reversible isomerization with thermal st

269 , this method provides a one-step route to a photochemically reversible thiol-protecting group.

270 c azobenzenophanes with axial chirality show photochemically reversible trans to cis isomerization in

271 The interaction with N2 is photochemically reversible.

272 romote degradation of chlorine-resistant and photochemically stable chemicals accumulated in swimming

273 bilized vinyl ether molecules resulting in a photochemically stable covalent link between a substrate

274 nanospheres, this pH-sensitive (pKa = 7.3), photochemically stable dye fluoresces in the red part of

275 Photochemically stable fluorescent heteroditopic ligands

276 The BHC-nicotinamide proved to be photochemically stable, which is also interpreted in ter

277 this specific base pair arrangement uniquely photochemically stable.

278 (-1)), whereas acetaldehyde and glyoxal were photochemically stable.

279 Reynders et al. reported a novel technology, PHOtochemically TArgeting Chimeras (PHOTACs) or opto-PRO

280 it was found that such systems do rearrange photochemically to afford cyclopentenes.

281 starting Rh(2)(0,II) complex is regenerated photochemically to close an oxygen-to-water reduction ph

282 med during disinfection with chlorine) react photochemically to form polychlorinated dibenzo-p-dioxin

283 mine and dissolved in toluene can be charged photochemically to give stable solutions in which electr

284 Here we report superconductivity in a photochemically transformed carbonaceous sulfur hydride

285 nia were randomly assigned to receive either photochemically treated (PCT) or conventional (control)

286 We report a transfusion trial of platelets photochemically treated for pathogen inactivation using

287 al (scsc) synthesis of a 2D polymer based on photochemically triggered [2 + 2]-cycloaddition is repor

288 The photochemically triggered displacement of the carotenoid

289 To investigate further the use of photochemically triggered manipulation of such pathways,

290 the fast kinetic phases observed in previous photochemically triggered spectroscopic studies of dynam

291 kyl and aryl radicals generated thermally or photochemically underwent substitution on readily prepar

292 terized, and screened for their potential to photochemically unmask a reactive Ru-Ru horizontal lineO

293 The latter were photochemically unstable and decomposed to form triplet

294 The nitrate radical, NO(3), is photochemically unstable but is one of the most chemical

295 Substitution reactions of the chemically and photochemically unusually stable perylenetetracarboxylic

296 Typically, ZnO photodoping is achieved photochemically using ethanol (EtOH) as a sacrificial re

297 composition of the triazides was carried out photochemically, using the matrix isolation technique.

298 n electron donor, these complexes produce H2 photochemically with quantum yields of up to 20%.

299 The polyurethane is cured photochemically with the screws in place; on curing, it

300 As a method to initiate radical formation photochemically within beta2, a single surface-exposed c