ライフサイエンスコーパス: photoinduced

1 e different scaling of electroabsorption and photoinduced absorption signals in transient absorption

2 on alpha-Fe2O3 photoanodes are studied using photoinduced absorption spectroscopy and transient photo

3 Later stage MSCs exhibited narrow photoinduced absorptions at lower-energy region like QDs

4 iation, and that oxygen is essential for the photoinduced action.

5 Target-selective and photoinduced actions demonstrated by DSAzB may have broa

6 fer (AT), whereas, in the absence of ligand, photoinduced activation likely proceeds through a single

7 ward approach involves in situ formation and photoinduced activation of N-chloroamines to give aminiu

8 so highlights the catalytic activity and the photoinduced activation of ruthenium(ii) complexes, thei

9 tural characteristics, the modeling of their photoinduced activity is a real challenge.

10 ctional theory (DFT) can be used to quantify photoinduced adsorption processes on transition metal ox

11 onamides (3), followed by intramolecular C-C photoinduced arylation under soft conditions without the

12 owever, details of mechanisms that can use a photoinduced base-promoted homolytic aromatic substituti

13 hich commence from (R)-carvone, employ a key photoinduced benzannulation sequence to forge the carbaz

14 Photoinduced bimolecular charge transfer processes invol

15 ry and model chromophore experiments such as photoinduced bimolecular charge transfer.

16 nd integrals of the pump-probe spectra where photoinduced bleaching rises abruptly 20 fs after photoe

17 t herein a simple, metal- and additive-free, photoinduced borylation of haloarenes, including electro

18 This photoinduced borylation protocol does not require expens

19 ing to these three photoinduced effects, the photoinduced BP-PAO fiber shows a high uranium adsorptio

20 The mechanism involves a photoinduced buildup of tension in the polymer, with a n

21 A highly selective and general photoinduced C-Cl borylation protocol that employs [Ni(I

22 We report herein a photoinduced carboborative ring contraction of monounsat

23 albic acid has been enabled by a sequence of photoinduced carboborative ring contraction, Rauhut-Curr

24 shed light on the strong correlation between photoinduced carriers and electronic structure in anisot

25 A photoinduced cascade strategy leading to a variety of di

26 pheroids treated with 1(4+), acute and rapid photoinduced cell death was observed throughout their de

27 Overall, we conclude that photoinduced changes in aromaticity facilitate the elect

28 The study of photoinduced changes in nuclear architecture is a flouri

29 e cycle scheme for enhanced detectability of photoinduced changes in the spectrum.

30 We demonstrate that photoinduced charge carriers from the [Formula: see text

31 anostructure for the effective production of photoinduced charge carriers to enhance the photocatalyt

32 tubes facilitate separation and migration of photoinduced charge carriers, enhance the adsorption and

33 s, showing the occurrence, in both cases, of photoinduced charge separation and corroborating the for

34 ffer molecular-level insights into ultrafast photoinduced charge separation potentially triggered by

35 Following photoinduced charge separation to form a contact radical

36 demonstrates the sensitivity of the yield of photoinduced charge transfer between a QD and a molecula

37 their excited states reveals that efficient photoinduced charge transfer can be achieved in the comp

38 semblies on a colloidal template and studies photoinduced charge transfer in them.

39 emission mechanism with increasing bias, and photoinduced charge transfer occurs at femtosecond times

40 ncorporation of FC60 allows for an effective photoinduced charge transfer quenching of the encased SW

41 e high sensitivity of HOMO-LUMO energies and photoinduced charge transfer toward sequential functiona

42 The dynamics and efficiency of photoinduced charge transport has been investigated in D

43 ete account of the mechanism and dynamics of photoinduced charge transport in these DNA hairpins.

44 Photoinduced charge-transfer is an important process in

45 ments can be engineered to optically trigger photoinduced charge-transfer-dynamic modulations in the

46 on of the azobenzenes, the complexity of the photoinduced conformational transition of the pentameric

47 s provides a detailed understanding of their photoinduced conformational transitions, resembling simi

48 Here we describe a photoinduced copper-catalyzed method for coupling readil

49 We describe both a new thermal and photoinduced copper-mediated cross-coupling between pota

50 cal, and product studies) to investigate the photoinduced, copper-catalyzed coupling of carbazole wit

51 y functionalized cryogel monoliths through a photoinduced cross-linking reaction.

52 Here we report an oxygen tolerant, photoinduced CRP approach which readily affords quantita

53 The photoinduced curing of a light-sensitive varnish was fol

54 and temperature dependence of both dark and photoinduced currents in carbon-based molecular junction

55 on PS-induced harm to diseased tissues, the photoinduced cycle of singlet oxygen generation has alwa

56 w levels of dark cytotoxicity and pronounced photoinduced cytotoxicity at submicromolar concentration

57 A new method was developed for the photoinduced dearomatization of arenes through an intram

58 el borylation reaction proceeding via a mild photoinduced decarboxylation of redox-activated aromatic

59 1-3, with amino acids at their rim, undergo photoinduced decarboxylations to give baskets 4-6 formin

60 A metal-free and mild, photoinduced decarboxylative 4-position alkylation of co

61 into 2D black In(2) O(3-) (x) nanosheets via photoinduced defect engineering is proposed.

62 tructure can be adjusted efficiently through photoinduced defect engineering; it can be anticipated t

63 nti vs syn dimer) of the [pai(4s) + pai(4s)] photoinduced dimerization is investigated.

64 These intermediates were generated via a photoinduced double elimination process occurring in (ch

65 nd some other photoresponsive proteins where photoinduced double-bond isomerization occurs.

66 t herein a simple, additive- and metal-free, photoinduced, dual C-H/C-X borylation of chloro-, bromo-

67 ith femto- to attosecond durations) to study photoinduced dynamical processes in atoms, molecules, na

68 Understanding the photoinduced dynamics in such materials is vital to prov

69 Observed photoinduced dynamics is further analyzed in details usi

70 Here we investigate the photoinduced dynamics of the [Fe(bmip)(2)](2+) photosens

71 Owing to these three photoinduced effects, the photoinduced BP-PAO fiber show

72 strated that the C-N regiospecificity of the photoinduced electrocyclization is a general feature of

73 vestigate how a benzene motif influences the photoinduced electrocyclization of dithienylethenes, a m

74 dent of singlet oxygen, occurring mainly via photoinduced electron abstraction of surrounding electro

75 The photoinduced electron parametric resonance measurements

76 article, we highlight the alterations in the photoinduced electron transfer (ET) and hydrogen atom tr

77 Photoinduced electron transfer (ET) is a cornerstone of

78 (epsilon(S)) within a protein matrix after a photoinduced electron transfer (ET) reaction.

79 velengths through simple regulation of their photoinduced electron transfer (PET) and intramolecular

80 Rhodamine Voltage Reporters, or RhoVRs, use photoinduced electron transfer (PeT) as a trigger for vo

81 uence of the thermodynamic driving force for photoinduced electron transfer (PET) between single-wall

82 he photoconjugation process proceeds through photoinduced electron transfer (PET) between Trp and the

83 a range of cyanine dyes, herein we show that photoinduced electron transfer (PeT) from a thiolate to

84 Photoinduced electron transfer (PET) is a phenomenon whe

85 n the basis of the pyridazinone scaffold and photoinduced electron transfer (PET) mechanism, we desig

86 lacement of the internal charge transfer and photoinduced electron transfer (PET) modulators on the s

87 sensors has been attributed to some form of photoinduced electron transfer (PET) quenching, which is

88 crown ether receptor due to reduction of the photoinduced electron transfer (PET) quenching.

89 Fluorescent photoinduced electron transfer (PET) sensor molecules ta

90 e intermediates, which are generated through photoinduced electron transfer (PET) with a photosensiti

91 ynylacetophenone oxime radical cations using photoinduced electron transfer (PET) with DCA as the pho

92 is switched ON upon protonation, preventing photoinduced electron transfer (PET) within the dye moie

93 l reconfiguration dynamics of the chain, and photoinduced electron transfer (PET), a contact-based me

94 ate locally excited triplet states by way of photoinduced electron transfer (PeT), followed by recomb

95 electron affinity material (acceptor) [i.e., photoinduced electron transfer (PET), which we term Chan

96 The dye/enzyme hybrids are composed of a photoinduced electron transfer (PeT)-based fluorescent v

97 introduction of an electronically decoupled, photoinduced electron transfer (PET)-capable subunit in

98 are triplet-state quenchers that operate via photoinduced electron transfer (PeT).

99 Photoinduced electron transfer and final regeneration of

100 sized and investigated in order to elucidate photoinduced electron transfer and hole migration mechan

101 ta rule out substrate activation by means of photoinduced electron transfer and instead support a mec

102 synthesized voltage-sensitive dyes that use photoinduced electron transfer as a voltage-sensing trig

103 The reaction proceeds by violet-light photoinduced electron transfer between an N-alkoxyphthal

104 has been established that the first step of photoinduced electron transfer can be fast, of order 100

105 Photoinduced electron transfer can produce radical pairs

106 ities for using Earth-abundant materials for photoinduced electron transfer chemistries.

107 abundant first-row analogs fail to engage in photoinduced electron transfer chemistry despite having

108 uggest that the elimination or mitigation of photoinduced electron transfer could substantially impro

109 were studied under native conditions, using photoinduced electron transfer coupled to fluorescence c

110 We show that these sites can be revealed by photoinduced electron transfer dissociation, which produ

111 The reaction begins with the photoinduced electron transfer from CsPbX3 NCs to dihalo

112 ransfer mechanism from Hb/AuNCs to Cyt c and photoinduced electron transfer from DNA/AgNCs to the apt

113 within {Mo(132)PO(4)} and furthermore showed photoinduced electron transfer from M to Mo.

114 K using a novel approach involving cryogenic photoinduced electron transfer from the [4Fe-4S](+) clus

115 We report here that low-temperature photoinduced electron transfer from the [4Fe-4S](1+) clu

116 nching of sensitized Eu(III) luminescence by photoinduced electron transfer from the excited light-ha

117 form a charge-separated state via ultrafast photoinduced electron transfer from the PE(4) segment to

118 An efficient photoinduced electron transfer from the tetraphenylborat

119 ability to use optical wavelength to control photoinduced electron transfer in a fully pai-conjugated

120 Subnanosecond photoinduced electron transfer in a structurally well-de

121 s in 1,3,5,8-tetrabromopyrene (TBP), and the photoinduced electron transfer in a TBPCExBox(4+) supram

122 Photoinduced electron transfer in fluorescent proteins f

123 The mechanism of this photoinduced electron transfer in the solid state and th

124 ghly efficient energy transfer and ultrafast photoinduced electron transfer in well-defined multichro

125 Redox sensing is mediated by a photoinduced electron transfer intramolecular switch.

126 Density functional theory studies validate a photoinduced electron transfer intramolecular switching

127 Photoinduced electron transfer is central to many biolog

128 Intramolecular photoinduced electron transfer leading to charge-separat

129 o and/or pLDH) were further characterized by photoinduced electron transfer PCR (PET-PCR).

130 catalyst system is achieved by a consecutive photoinduced electron transfer process (conPET) and allo

131 ical reactions, particularly those involving photoinduced electron transfer processes, establish a su

132 gates, and sequence defined polymers through photoinduced electron transfer reactions are also invest

133 ount of the fundamentals and applications of photoinduced electron transfer reactions in polymer synt

134 cohol macrocycle is quenched via fluorescent photoinduced electron transfer switching, meaning that i

135 Control of photoinduced electron transfer through selective excitat

136 threne at 256 nm enables a diffusion-limited photoinduced electron transfer to 1,4-dicyanobenzene.

137 ion implicate a photoredox pathway involving photoinduced electron transfer to generate a key radical

138 The contribution of photoinduced electron transfer to the overall reduction

139 These chemical-genetic hybrids feature a photoinduced electron transfer triggered RhoVR voltage-s

140 Furthermore, wavelength-dependent photoinduced electron transfer was not observed in eithe

141 Cu(I) and PET (photoinduced electron transfer) catalysis are treated se

142 s of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer,

143 Photoinduced electron transfer, initiated using 365 nm l

144 ng more intimate electronic coupling, likely photoinduced electron transfer, is responsible for the q

145 Following photoinduced electron transfer, the rate of charge recom

146 ts in significant loss of fluorescence via a photoinduced electron transfer-quenching mechanism as su

147 By developing cytocompatible PET-RAFT (photoinduced electron transfer-reversible addition-fragm

148 mpounds with first-row elements to engage in photoinduced electron transfer.

149 h dielectric constants (DMF), most likely by photoinduced electron transfer.

150 a decrease in the efficiency of collisional photoinduced electron transfer.

151 PY-ATP) was quenched by Fe(III) ions through photoinduced electron transfer.

152 light absorption and the greatly accelerated photoinduced electron-hole separation and transfer, whic

153 s of organic photovoltaics, the mechanism of photoinduced electron-hole separation at organic donor-a

154 studies have revealed the possibility for a photoinduced electron-transfer (PET) pathway.

155 e reveal the existence of a new, low-energy, photoinduced electron-transfer mechanism in molecules he

156 using an oxygen tolerant porphyrin-catalyzed photoinduced electron/energy transfer-reversible additio

157 polymerization via a visible-light-mediated photoinduced electron/energy transfer-reversible additio

158 groups inducing fluorescence quenching via a photoinduced-electron-transfer mechanism.

159 of a few picoseconds, as well as associated photoinduced electronic transitions and charge transfer

160 Transferring photoinduced electrons and holes at the same time, leadi

161 is investigation complements earlier work on photoinduced enantioconvergent N-alkylation, supporting

162 osition-dependent exciton decay dynamics and photoinduced energy transfer of QDs is addressed.

163 ers for the generation of singlet oxygen via photoinduced energy transfer processes, but under light

164 However, so far photoinduced enzymatic catalysis(6) has not been used fo

165 Photoinduced ET in HydG generates a trapped (*)CH(3) rad

166 n stark contrast to a recent report in which photoinduced ET in the RS enzyme pyruvate formate-lyase

167 the effective dielectric constant following photoinduced ET, from epsilon(S) approximately 8 to epsi

168 ing of a low-frequency vibration points to a photoinduced ferroelectric phase transition, with a spat

169 ver mechanical resonant oscillations and the photoinduced force from the light-matter interaction.

170 Infrared photoinduced force microscopy (IR-PiFM) is a scanning pr

171 One increasingly popular technique is photoinduced force microscopy (PiFM), which utilizes the

172 tain, and cryo-EM and by atomic force and IR-photoinduced force microscopy established that Ico8 asse

173 Photoinduced force microscopy shows that doping level ca

174 infrared imaging with the TIR excitation for photoinduced force microscopy.

175 romic shift of the absorption maximum of the photoinduced form, whereas no difference was found for c

176 ocatalytic processes, invariably starts with photoinduced generation of energy-rich electrons.

177 modular supramolecular approach to relay the photoinduced geometry changes of a hemithioindigo based

178 esearch provides a clear physical picture of photoinduced H(2) dissociation on Au clusters, which has

179 this work, we investigate the mechanism for photoinduced H(2) dissociation using a simple H(2)@Au(6)

180 long-lived electrons are essential to drive photoinduced H(2) generation in many photocatalysts, exc

181 By using a photoinduced hydrogen atom transfer strategy, this metal

182 -A light centered at 350 nm does not lead to photoinduced hydrogen transfer whereas the addition of a

183 The process includes the photoinduced in situ formation of acylazirines combined

184 d electronic transport properties during the photoinduced insulator-metal transitions in vanadium dio

185 Photoinduced interfacial charge transfer is at the heart

186 ations, we have been able to estimate in the photoinduced isomer the distance between hydrogen atom a

187 and unique photophysical properties from the photoinduced isomerization of a linear tetrapyrrole chro

188 Photoinduced isomerization reactions lie at the heart of

189 Photoinduced isomerization transforms the linear trans C

190 All new azo-PBIs showed photoinduced isomerization, which caused disaggregation

191 control the mechanism and kinetics of their photoinduced isomerization.

192 periments that provide in situ insights into photoinduced isomerizations.

193 ciation, representing a new manner to effect photoinduced ligand exchange.

194 wavelength-dependent conversion of two rapid photoinduced ligation reactions, i.e., the light activat

195 donor-sensitizer-acceptor compound in which photoinduced long-range electron transfer is coupled to

196 n recombination is thus inextricably tied to photoinduced magnetism.

197 Photoinduced metal-free atom transfer radical polymeriza

198 ts, were used as valuable substrates for the photoinduced metal-free synthesis of (hetero)biaryls wit

199 Photoinduced metal-mediated radical polymerization is a

200 provide direct evidence for this controlled photoinduced molecular deformation and its ultrashort ti

201 The relative contribution of the photoinduced monoclinic and rutile metals to the time-de

202 Here we report photoinduced motion (photomotility) in monolithic polyme

203 Thus, photoinduced Ni-aryl homolysis offers a novel mechanism

204 These nanocrystals undergo a reversible, photoinduced orthorhombic-to-cubic phase transition whic

205 on of the photoproducts can be attributed to photoinduced oxidation of oil.

206 o explain the kinetics and thermodynamics of photoinduced oxidation reactions at aqueous interfaces a

207 have chosen a few representative examples of photoinduced oxidation reactions to focus on in this Per

208 In this Perspective, we focus on photoinduced oxidation reactions, which have attracted e

209 jugated molecules for numerous applications, photoinduced oxidation upon exposure of the acene to lig

210 racene-substituted derivatives resist direct photoinduced oxidation.

211 A photoinduced palladium-catalyzed 1,2-carbofunctionalizat

212 insights into the nonequilibrium dynamics of photoinduced PCET in the Slr1694 BLUF photocycle that ha

213 n for the experimental observation of faster photoinduced PCET in this state.

214 of iodide species provides insight into the photoinduced phase segregation and its implication in th

215 lar cells have been fundamentally limited by photoinduced phase segregation and low open-circuit volt

216 ty and the formation of metastable phases in photoinduced phase transition of VO2 are elucidated thro

217 The photoinduced phase transition, starting with a compact c

218 ermal pathway for the initial process of the photoinduced phase transition.

219 hesis of photochromic liquid crystals (LCs), photoinduced phase transitions in LC, and photoalignment

220 The applications of photoinduced phase transitions, photoalignment, photomod

221 ed nano-antennas have the ability to enhance photoinduced phenomena such as localized electric fields

222 Based on the photoinduced photothermal, photoelectric, and photocatal

223 desirable attributes including glassy state photoinduced plasticity, toughness improvement during la

224 trinsic optoelectronic properties, including photoinduced polarization, high drift mobilities, and ef

225 nvestigation demonstrates the possibility of photoinduced polynitro-CNT explosion and provides a deta

226 We adopted a photoinduced post-synthetic copolymerization strategy to

227 the atomic-scale description of the initial photoinduced process, which couples intermetallic charge

228 The focus of the review is on photoinduced processes and on electronic properties impo

229 the thermodynamic and kinetic parameters of photoinduced processes in artificial reaction centers.

230 able now regarding the modeling of ultrafast photoinduced processes in complex molecular architecture

231 Among the numerous photoinduced processes in organic chromophores, analysis

232 Many photoinduced processes including photosynthesis and huma

233 ked molecules) as an electronic relay in the photoinduced processes is also highlighted.

234 cases to study, at the molecular level, the photoinduced processes that govern their excited state d

235 ach a complete and accurate picture of their photoinduced properties and dynamics.

236 sition metal- and oxidant-free visible light-photoinduced protocol for direct functionalization of 2-

237 eaction centers, are capable of generating a photoinduced proton gradient across the membrane.

238 The results of photoinduced proton transfer and voltage-driven proton-c

239 luminophore results in a complex cascade of photoinduced proton transfer processes and can be interp

240 ting trajectories trace out the mechanism of photoinduced proton-coupled electron transfer (PCET) in

241 rtant processes and serve as a prototype for photoinduced proton-coupled electron transfer (PCET).

242 icals from N-hydroxyphthalimide (NHPI) via a photoinduced proton-coupled electron transfer process is

243 trobenzene to aniline through six sequential photoinduced, proton-coupled electron transfers.

244 A metal- and photocatalyst-free photoinduced radical cascade hydroalkylation of 1,7-enyn

245 ene' reductase triggers the enantioselective photoinduced radical reaction.

246 FeMo-co state, denoted E4(2H)*, through the photoinduced re of the two bridging hydrides of E4(4H) a

247 regime and have been employed in monitoring photoinduced reaction cascades, ligand binding and disso

248 stabilized azomethine ylide was developed by photoinduced reaction catalyzed with eosin Y under green

249 n scattering (SERS), we directly monitor the photoinduced reaction dynamics of 4,4'-bipyridine molecu

250 The complex dynamics of ultrafast photoinduced reactions are governed by their evolution a

251 Such ultrafast photoinduced reactions do no longer obey the Kasha-Vavil

252 sm and can be generalized to other ultrafast photoinduced reactions in complex systems.

253 tifying the structural rearrangements during photoinduced reactions is a fundamental challenge for un

254 Photoinduced reactions play an important role in the pho

255 sign molecules to maximise the efficiency of photoinduced reactions.

256 The photoinduced rearrangement pathways of simple 2,5-dienon

257 t Fe(II) polypyridyl complexes can engage in photoinduced redox reactions but by a mechanism that is

258 The achievement of long-lived photoinduced redox separation lifetimes has long been a

259 These observations imply that photoinduced release of H2 involves a barrier to the com

260 Under basic conditions (pH = 11), a photoinduced release of the chloride anion followed by t

261 provement during large deformation, and even photoinduced reversal of the effects of physical aging r

262 Harnessing metal-free photoinduced reversible-deactivation radical polymerizat

263 The ultrafast photoinduced ring-opening of 1,3-cyclohexadiene constitu

264 However, cryogenic photoinduced S-C bond cleavage has regioselectively yiel

265 cted answer, founded on our observation that photoinduced S-C bond cleavage in multiple canonical RS

266 of iodine provided further insight into the photoinduced segregation of halide ions in mixed halide

267 at the dynamic band structure is caused by a photoinduced shear strain in the Te film that breaks the

268 Photoinduced single electron transfer has been initiated

269 salts and either Hantzsch ester or Et(3) N, photoinduced single-electron transfer could be initiated

270 adducts of complex 1 and NADH, facilitating photoinduced single-electron transfer.

271 A metal- and oxidant-free photoinduced strategy for thioxo sulfur-selective triflu

272 Our results record the overall sequence of photoinduced structural changes in the foldamer, startin

273 igh color vision ability and acuity but also photoinduced structural reorganizations.

274 The photoinduced structural switching results in spatial sep

275 Moreover, photoinduced structural transformation from 1D to 0D was

276 amine the influence of surface stress on the photoinduced structural transformation.

277 le fluorescent probes or as a source for the photoinduced supply of acidity.

278 This paper describes the photoinduced switching of conductance in tunneling junct

279 However, the photoinduced syntheses of non-metallic nanocrystalline p

280 Photoinduced syntheses offer significant advantages over

281 Herein, we demonstrate the first photoinduced synthesis of ultrafine (sub-2 nm) Ag2 S qua

282 velop a more complete understanding of these photoinduced synthetic transformations.

283 This photoinduced system operates with visible light (400 nm)

284 vary depending on the antiaromaticity of the photoinduced tautomers.

285 Cy regeneration via photoinduced thiol elimination is favored by adduct abso

286 Photoinduced threshold switching processes that lead to

287 Photoinduced toxicity following coexposure to ultraviole

288 d here provide evidence for the potential of photoinduced toxicity to occur in benthic organisms with

289 PAH photoinduced toxicity, which has been documented in a wi

290 i-mahi embryos being at particular risk from photoinduced toxicity.

291 vae exposed to intense UV may be at risk for photoinduced toxicity.

292 of the ionic liquid can be readily tuned by photoinduced trans-cis isomerization of the azobenzene u

293 recent experimental and theoretical work on photoinduced transformations in fluorescent proteins.

294 ion of the degree of chemical and structural photoinduced transformations.

295 mployed to study the reaction pathway in the photoinduced transition of VO2, using bulk and strain-fr

296 he nature of and the impact of strain on the photoinduced transition of VO2.

297 rap-assisted recombination through increased photoinduced trap states, PffBT4T-2OD:EH-IDTBR solar cel

298 Photoinduced water oxidation at the O2-evolving complex

299 ricyclic core becomes electron-rich, and the photoinduced Wolff rearrangement produces a highly emiss

300 reported class of photoswitches, proceeds by photoinduced Z-E isomerization, followed by a thermal, c