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1 so far unprecedented reaction is proposed to proceed via 1,2-dioxane derivatives, which decompose und
4 nt, the PMe(2)Ar(Dipp)(2) system is shown to proceed via 4(Dipp)(+) as an intermediate en route to th
5 T calculations revealed that these reactions proceed via a bimolecular mechanism in which either the
6 Conversion between DHP and CPD is thought to proceed via a biradical intermediate; bimolecular events
8 intermediates, this transformation does not proceed via a carbene intermediate, nor does it require
10 C-C cleavage and C-H hydroxylation pathways proceed via a common key intermediate, i.e., an alpha-pe
11 types of reactions shows that all reactions proceed via a common rate-determining step, the nucleoph
12 dots, and we establish that these reactions proceed via a dark surface prereduction step prior to ph
16 culations show that the nitrofuran reactions proceed via a highly asynchronous transition state allow
17 volving remote participation are believed to proceed via a key ionic intermediate, the glycosyl catio
21 Mechanistic studies suggest the reaction to proceed via a nonstabilized, aliphatic, cyclic oxocarben
22 number of human diseases, and is thought to proceed via a nucleation-dependent polymerization mechan
23 idue, such that the translocase reaction can proceed via a nucleophilic attack of the phosphate moiet
25 w that, for the wide range of catalysts that proceed via a radical intermediate, a unifying framework
26 studies suggest that this reaction does not proceed via a radical mechanism, which is in contrast to
30 ways and nonclassical two-step pathways that proceed via a solid-solid transformation of a crystal in
31 , we find that R-loop formation and collapse proceed via a transient discrete intermediate, consisten
32 and were especially unstable, the reactions proceeded via a "dead-end" polymerization mechanism, and
33 ashi catalyst, copper iodide, and Hunig base proceeded via a multicascade route, affording the title
34 VO2(+), HxV4O12+x((4+x)-) (V4), and HVO4(2-) proceeded via a one-electron transfer, while that of Nax
35 d the involvement of aryl radical anions and proceeded via a single-electron-transfer (SET) mechanism
37 reversible deaggregation, with the reaction proceeding via a disolvated-monomer-based transition str
38 ort a conceptually novel borylation reaction proceeding via a mild photoinduced decarboxylation of re
40 ar 1,2-carboamination of unactivated alkenes proceeding via a Pd(II)/Pd(IV) catalytic cycle has been
41 ntal studies are consistent with methylation proceeding via a S(N)2 mechanism, with a strength compar
43 of sulfinyl nitrenes, with nitrene formation proceeding via a transient triplet intermediate before r
44 arbonate was used, the reaction with phenols proceeds via a bicyclic aziridinium intermediate leading
48 tphos)Ni(I)-mediated alkyl halide activation proceeds via a concerted halogen-atom abstraction mechan
49 suggest that carbon-fluorine bond formation proceeds via a concerted transition state rather than a
51 carried out indicating that the cyclization proceeds via a cooperative action of diorganyl diselenid
52 xperimental data suggested that the reaction proceeds via a covalent intermediate using a ping-pong m
56 on affirms that FePc demetalation during ORR proceeds via a direct loss of Fe(2+) and that carbon cor
58 anine ligase by the antibiotic D-cycloserine proceeds via a distinct phosphorylated form of the drug.
60 ies reveal that the metal-free C-H insertion proceeds via a frustrated Lewis pair mechanism involving
62 ial matrix via the proton inlet half channel proceeds via a Grotthus mechanism, and a similar mechani
65 he enzyme system's strand-exchange mechanism proceeds via a Holliday-junction (HJ) intermediate; howe
68 ur experiments reveal that the pore assembly proceeds via a membrane-bound prepore intermediate state
69 -N bond-forming reductive elimination, which proceeds via a mixed-valent Ni(II) -Ni(III) intermediate
70 utational studies indicate that the reaction proceeds via a nonclassical carbocation followed by anti
71 and that the synthesis of stealthin C likely proceeds via a nonenzymatic S-N-type Smiles rearrangemen
72 d rearrangements of thioesters, the reaction proceeds via a novel Dieckmann-like cyclization pathway.
73 studies show that this diamination reaction proceeds via a nucleophilic amino cyclization followed b
74 nvolving N-tosylhydrazones and bromophenols, proceeds via a palladium-catalyzed Barluenga-Valdes cros
75 lves formation of overall four C-C bonds and proceeds via a palladium-catalyzed oxidative transformat
76 ur at FRAXA following folate deprivation but proceeds via a pathway that shows some mechanistic diffe
78 Experimental evidence suggests the reaction proceeds via a radical mechanism where the vinyl pyridin
80 athway in which carbon-carbon bond formation proceeds via a radical-chain process wherein a nickel(I)
84 The formation of diketopiperazinoindolines proceeds via a regio- and diastereoselective Conia-ene r
86 Mechanistic studies reveal that the reaction proceeds via a Ru-catalyzed asymmetric hydrogen autotran
87 at the transformation of the precursor anion proceeds via a series of intermediate structures charact
89 ducing bacterium, Shewanella oneidensis MR1, proceeds via a single electron transfer to form a pentav
91 a coherent picture of when a S(N)Ar reaction proceeds via a stepwise and when via a concerted mechani
95 ic studies revealed that the reaction likely proceeds via a tandem hydroamination/Hofmann-Martius rea
101 Mechanistic study revealed that the reaction proceeds via alcohol activation by metal-ligand cooperat
102 inated oxaphosphetane (OPA) intermediate can proceed via alkaline hydrolysis in the presence of D(2)
103 vated amide C-N bond to a Ni(0) catalyst and proceeds via alkene insertion into a Ni(II)-acyl bond.
109 oup stereoelectronics direct the reaction to proceed via an asynchronous one-step mechanism through a
111 valent twist is required for the reaction to proceed via an energetically more accessible route.
112 udies reveal that initiation and propagation proceed via an external alkoxide attack on the coordinat
114 catalyzed methodologies that are believed to proceed via an inner-sphere-type mechanism, with an emph
117 nal to the concentration of H(2) O(2) and to proceed via an unprecedented pathway that avoids the pro
122 hosphino)pyrrole as the ligand, the reaction proceeds via an alkoxy palladium intermediate that incre
123 that the diastereoselective alkylation step proceeds via an alpha-substituted malonate-imidazolidino
124 w demonstrate that the initial cycloaddition proceeds via an ambimodal transition state that can lead
125 atalyzed methylenecyclopropane rearrangement proceeds via an argento-stabilized biradical or whether
126 nce of the hydroxyl group the O(2) reduction proceeds via an electron transfer followed by proton tra
130 y of the cyclotriphosphate opening reactions proceeds via an in-line substitution mechanism that disp
133 tmosphere, on the other hand, H(2) evolution proceeds via an intermediate that positions a hydride li
134 tingly, we found that the adsorption of PhOH proceeds via an intermediate, weakly bound state in whic
135 t the aggregation of mutant huntingtin exon1 proceeds via an intramolecular collapse of the expanded
136 tationally, which revealed that the reaction proceeds via an N-heterocyclic carbene (NHC) siloxygermy
137 ytic phase, like those of all herpesviruses, proceeds via an orderly cascade that integrates DNA repl
139 g that the benzoate release from Ar(2)CH-OBz proceeds via an unassisted S(N)1-type mechanism followed
140 Mtb and an l-leucine catabolic pathway that proceeds via an unprecedented (R)-3-hydroxy-3-methylglut
142 hols catalyzed by supported Au nanoparticles proceeds via an unsymmetrical concerted transition state
143 oarsenates at pH 7.0 suggest mobilization to proceed via arsenite desorption, reaction with dissolved
144 tic investigations suggest that the reaction proceeds via Au(I)-catalyzed hydrofunctionalization of t
146 rent flow, charge transfer in living systems proceeds via biomolecules that are nominally insulating.
149 The proposed mechanism for this reaction proceeds via C-N reductive elimination from a Cp*Ir(V) n
150 known, but signal transduction is thought to proceed via canonical, G protein-coupled receptor-depend
151 witnessed an increase in fragment couplings proceeding via carbanionic and open shell (free radical)
152 witnessed an increase in fragment couplings proceeding via carbanionic and open-shell (free radical)
154 tic experiments, the reaction is proposed to proceed via catalytic P(III)/P(V) horizontal lineO cycli
155 employ diphosphate-activated donors and each proceed via cationic species: allylic cations and oxocar
157 r intermediates) revealed that this reaction proceeds via chairlike transition state and is exothermi
158 erol and caveolin-1 and that internalization proceeds via clathrin-independent, lipid raft-mediated e
159 ciphering if biodegradation will most likely proceed via cometabolism (ROI < 1) or direct metabolism
160 radiation damage in crystalline solids often proceeds via complex dynamic annealing processes, involv
162 m calculation demonstrates that the reaction proceeds via conrotatory ring closure in the triplet exc
163 cently been used in catalytic C-H activation proceeding via coordination of an internal sulfoxide to
164 zed methylcubane oxidations which notionally proceed via cubylmethyl radical intermediates yet are re
165 Quantum calculations show that the reaction proceeds via cyclization in the triplet excited state to
167 This base-promoted formal [4+2] annulation proceeds via cyclohexanone formation and involves the ca
168 the catalytic mechanism is monometallic and proceeds via dearomative rearrangement of the phenethylc
169 de genetic evidence that the omega-7 pathway proceeds via Delta(9) desaturation of palmitoyl-ACP foll
171 that the mechanism of S-oxygenation does not proceed via direct attack at the thiolate sulfurs; the a
173 d DFT calculations suggest that the reaction proceeds via direct C2-allylation, rather than C3-allyla
174 pending on GB character, the SCM is found to proceed via dislocation slipping in the <100> or <110> m
176 We conclude that the methanation reaction proceeds via dissociation of CO2, followed by reduction
177 cording to the DFT calculations the reaction proceeds via dissociation of the metal-bound complex of
179 stituted styrenes indicate that the coupling proceeds via double C-H addition of a styrene molecule,
180 r findings suggest that mycobacterial HR can proceed via DSB unwinding and protein capture of the dis
181 d biological nitrogen fixation is thought to proceed via either a sequence of proton and electron tra
182 hanistic details of the reaction, that could proceed via either an inner-sphere or an outer-sphere me
185 H2Ph)](py) (7) which Fukui analysis shows to proceed via electrophilic insertion of the nitride into
186 undergo second Matsuda-Heck coupling, which proceeds via endo-selective beta-H-elimination to give d
187 ntal observations suggests that the reaction proceeds via exchange of the NR and O substituents throu
189 sses these compounds by a distinct mechanism proceeding via fluoride abstraction, migratory insertion
190 Topoisomerase 2 (TOP2) DNA transactions proceed via formation of the TOP2 cleavage complex (TOP2
195 se, 5-hydroxymethylfurfural formation mainly proceeded via fructofuranosyl cation dehydration rather
196 t characteristics: The swaps of beta-strands proceed via global unfolding, whereas the alpha-helices
198 lysis, we found that silencing establishment proceeded via gradual repression of transcription in ind
199 The established mechanism of autoxidation proceeds via H-atom abstraction through a cyclic network
200 This suggests more generally that evolution proceeds via hard sweeps if resistance is unlikely and v
201 ion of prFMN is light-dependent and probably proceeds via high-energy intermediates but is independen
202 culations showed that the formation of NO(x) proceeds via homolytic cleavage of the RN-NO(2) bond in
205 ative and covalent) formation, with examples proceeding via initial C-B and N-B bond formation domina
206 mputational study suggests that the reaction proceeds via initial addition of the alkoxide to the sul
208 onal and organoleptic attributes of oils can proceed via interesterification of oils blends catalyzed
209 tions (B3LYP/6-311+G(d,p)) the rearrangement proceeds via intermediate formation of a diazo compound,
210 sed wherein the alternating copolymerization proceeds via intermediates that have carboxylate ligatio
211 ion (MATPASS) NMR, we show that the reaction proceeds via internal electron transfer from V(4+) to [S
213 CF), i.e., a mechanism of ice formation that proceeds via liquid water condensation in pores, is a do
214 ase, atherosclerosis, and even cancer, which proceed via mechanisms involving enzymatic and free radi
217 d than this simple picture and, instead, can proceed via multiple transformations of metastable struc
221 the chloroindium(III) chelate; the reaction proceeds via Nazarov cyclization (to form the isocyclic
222 d shows the transition from AF to FM regions proceeds via nucleation of small vortex structures, whic
225 have highlighted that these reactions could proceed via numerous different species and steps and, mo
226 nce, shows that the (CF3)2CFCN + OH reaction proceeds via OH addition to -C( identical withN), follow
227 vast majority of community detection methods proceed via optimization of a quality function, which is
228 d oxygen-dependent JmjC KDMs, respectively), proceeds via oxidation of the N-methyl group, resulting
229 alculations indicate that H2 activation at 2 proceeds via oxidative cleavage at Ru with concomitant h
230 f the Fe(III)-O(2)(-) species to Fe(III)-OOH proceeds via PCET when a pendant phenol is present, it f
233 imers stabilized by disulfide bonds and then proceeds via primary nucleation and fibril elongation pr
236 f magnetization in Tb(2) @C(79) N below 15 K proceeds via quantum tunneling of magnetization with the
237 strate scope of this indicates that it might proceed via quinomethoxy methide as a key intermediate l
238 tic investigations suggest that the reaction proceeds via radical-radical coupling, consistent with t
239 gether, these data suggest that the reaction proceeds via rapid formation of the dioxonium cation 9,
244 m-catalyzed C-H amination is hypothesized to proceed via Rh2-nitrene intermediates in either the Rh2(
245 TFAM cross-links) revealed that the reaction proceeds via Schiff base chemistry facilitated by lysine
247 l-catalyzed activation of amide N-C(O) bonds proceeds via selective metal insertion into the carbon-n
248 double functionalization of diazo compounds proceeds via selective S-alkylation followed by intramol
250 le different cell fusion processes appear to proceed via similar membrane rearrangements, proteins th
251 duct nanoparticles, including CsOH and CsCl, proceeded via SiO2 condensation over aggregates of Zn-Fe
252 at both the mono- and co-catalytic processes proceed via stepwise [4 + 2] cycloaddition reactions inv
255 isional dynamics reveal that O(2) production proceeds via strongly-bent CO(2) configurations, without
256 ecedented synthesis of 1-methyl naphthalenes proceeds via tandem methenylation/double dehydrogenation
258 n of the spirocyclic framework is thought to proceed via the formation of Rh(II) carbene species foll
259 y, it is proposed that the decomposition may proceed via the interaction of a ketene intermediate res
260 electron transfer across a hydrogen bond may proceed via the known proton-coupled pathway, as well as
264 nsition-metal-catalyzed [3 + 2] processes in proceeding via the condensation of aldehydes and ketones
265 C)-catalyzed intramolecular Stetter reaction proceeding via the endo-fashion was the key step for the
266 cohols followed by NHC-catalyzed cyclization proceeding via the imidoyl azoliums under oxidative cond
269 e case of 3-methylphenyl azide, the reaction proceeds via the cis/syn form of nitroso oxide with a re
271 Mechanistic studies indicate the reaction proceeds via the flavin semiquinone/quinone redox couple
274 t a model in which polymerization activation proceeds via the induction of a conformational change in
275 esults, indicates that the detection pathway proceeds via the initial step of a five-membered ring fo
278 st-translationally modified peptides (RiPPs) proceeds via the multistep maturation of genetically enc
280 trol experiments establish that the reaction proceeds via the oxidation of alcohol to ketone, alpha-t
281 evidence shows this transformation initially proceeds via the oxidative addition of a C(sp(3) )-H bon
283 propose that C-C bond coupling in Y-DeAlBEA proceeds via the reaction of coadsorbed acetaldehyde and
287 ong competing pathways, the probabilities of proceeding via these pathways are shown to be invariant
289 magnetite resembles an intercalation process-proceeding via topotactic reaction with the cubic close
290 l three-state folding mechanism, which might proceed via transient structural changes rather than req
292 ed thioesters proceeding are reported, which proceed via two distinct mechanistic pathways: enantiose
299 table two-dimensional (2D) in-membrane state proceeds via well-defined sequence of intermediates, inc