ライフサイエンスコーパス: radical

1 alcohol product and regenerate the aroyloxy radical.

2 w-probability conversion to a stable protein radical.

3 for their reactivity with a tertiary carbon radical.

4 rming the hydroperoxide species HP and TEMPO radical.

5 ), leading to a trisulfonated Finland trityl radical.

6 e of the S-C5' bond to generate the 5'-dAdo. radical.

7 various monofunctionalized sulfonated trityl radicals.

8 eir inherent reactivity with tertiary carbon radicals.

9 tylhydroperoxide and scavenged DPPH and ABTS radicals.

10 ndicating the involvement of carbon-centered radicals.

11 This was especially true against DPPH radicals.

12 ndergoing decarboxylation to generate methyl radicals.

13 s as precursors to unstabilized nucleophilic radicals.

14 yl, alpha-acyl, trifluoromethyl and sulfonyl radicals.

15 that the reaction occurs through free alkyl radicals.

16 rted by monitoring hydrogen elimination from radical a-ions produced by UVPD at the N-terminus of ADH

17 t capacities according to hydrophilic-oxygen radical absorbance capacity (H-ORAC(FL)) and ferric redu

18 The inhibition of DPPH radicals accelerated with an increase in the power level

19 a donor to the peroxyl radical; (b) peroxyl radical addition (PRA) to a "C=C" double bond.

20 including CO(2) and aldehydes, whereas CF(3) radical addition furnishes a wide range of gem-difluoroa

21 H arylation and intermolecular atom-transfer radical addition through oxidative quenching.

22 Such cascades can proceed through N-radical addition to an alkene with subsequent C-C bond f

23 nstalled prior to the C-N bond via initial C-radical addition to the alkene with subsequent beta-amin

24 complex, initiated by regioselective oxygen radical addition to the carbon-carbon double bond.

25 esented, achieving rapid degradation through radical addition-fragmentation chain transfer (AFCT) rea

26 i(II)-Ni(I)-Ni(III) and of elementary steps: radical addition-SET-oxidative addition-reductive elimin

27 nd involves an unprecedented decarboxylative radical addition/cross-coupling cascade of vinyl boronic

28 The example of silyl radical additions to coordinated nitrogen to form silyla

29 ndonuclease CRISPR-Cas technology has led to radical advances in biology.

30 Radical alkene carboamination can be achieved via three

31 nteractions between the neutral sulfonamidyl radical and a chiral phosphoric acid generated in the PC

32 d radical scavenging activities against DPPH radical and ABTS radical cation.

33 fragment coupling between a tertiary carbon radical and an electrophilic butenolide resulting in the

34 nism through a four-center transition state, radical and polar anti-addition mechanisms are postulate

35 facilitates the reaction between the carbon radical and the activated heteroarene but also accelerat

36 rearrangement was used to trap the substrate radical and to estimate the rate of the radical substitu

37 e di-tert-butyl peroxide as a source of free radicals and a dehydrogenating agent.

38 ponents of mineral surfaces such as silicate radicals and ferrous iron.

39 rays during radiotherapy (RT), creating free radicals and local tumor damage, effectively boosting th

40 es can undergo Ni homolysis to generate aryl radicals and Ni(I), both of which are supported experime

41 he surrounding biological substrates to form radicals and radical ions (Type I reaction); whereas in

42 that mechanical stress on collagen produces radicals and subsequently reactive oxygen species, essen

43 Scavengers of superoxide radical anion (superoxide dismutase), hydrogen peroxide

44 Back-electron transfer from the DCA radical anion followed by barrierless intramolecular pro

45 Instead, carbonate radical anion is formed from the Fenton reaction under c

46 rane lipids against oxidation and superoxide radical anion scavenging activity.

47 We detect the formation of an intermediate radical anion upon reaction of photogenerated holes with

48 al reduction to the [RSNO-B(C(6) F(5) )(3) ] radical anion, which is susceptible to N-N coupling prio

49 ase of the BNB-phenalenyl 7 (BMes, NMe), the radical-anion salt K[7(*)] was generated through chemica

50 ic studies confirmed the involvement of aryl radical anions and proceeded via a single-electron-trans

51 These were for ET from radical anions of polydecylthiophene (P3DT) to a series

52 le the barriers for the formation of alkoxyl radicals are as low as 13 kcal mol(-1).

53 llylic functionalization reactions involving radicals are comparatively underexplored, but provide a

54 The radicals are divided into two groups of isomers, named o

55 The resulting aryl radicals are engaged in (hetero)biaryl cross-coupling, b

56 Guanine radicals are important reactive intermediates in DNA dam

57 chemical calculations of the PAs of the (bi)radicals are in reasonably good agreement with the exper

58 Reactive alkoxy radicals are proposed as key intermediates, generated by

59 s led to unambiguous assignment of adenosine radicals as N-7 hydrogen atom adducts.

60 Sensitivity of dsDNA structure towards OH radicals as the pro-oxidants has been utilized as the de

61 using 365 nm light-emitting diodes, affords radicals at room temperature as observed by electron par

62 on Spin Resonance (ESR) were attributed to L-radicals attached to 2-methyl-2-nitrosopropane (MNP), on

63 m transfer (HAT) from a donor to the peroxyl radical; (b) peroxyl radical addition (PRA) to a "C=C" d

64 SAM dual reactivity and preventing unwanted radical-based chemistry before the K2 [Fe(4)S(4)] cluste

65 Mechanistic studies support a radical-based mechanism involving the photoexcitation of

66 oduction rates of phenol and bicyclic peroxy radical (BCP-peroxy) are experimentally constrained at 2

67 The anomeric alkoxyl radical beta-fragmentation (ARF) of carbohydrates posses

68 suggest the process features an MHAT-induced radical bicyclization with late-stage oxidation to regen

69 , hydrogen atom transfer (HAT)-mediated free radical bond formations (C20-C2 and C20-OH, respectively

70 d magnetic characterization of the series of radical-bridged dilanthanide complex salts [(Cp*(2)Ln)(2

71 m has been replaced by a halogen abstraction-radical capture (HARC) sequence that allows the generati

72 Radical capture represents the key C(sp)-C(sp3) bond-for

73 o perform both hydrogen atom abstraction and radical capture was leveraged to enable fluorination of

74 quential hydrogen atom abstraction (HAA) and radical capture.

75 difunctionalization of carbonyl groups by a radical-carbanion relay sequence (photo-Wolff-Kishner re

76 hiophene-based benzylic gem-diboronates, via radical carbo-cyclization/gem-diborylation of alkynes wi

77 A metal- and photocatalyst-free photoinduced radical cascade hydroalkylation of 1,7-enynes has been d

78 ations, where annulations are coupled with a radical cascade that connects two preexisting aromatic c

79 ting the GOx-catalyzed reduction of the ABTS radical cation by glucose in anaerobic conditions.

80 slow to compete with other processes such as radical cation deprotonation.

81 We present the discovery of a novel radical cation formed through one-electron oxidation of

82 ron transfer (SET) because the corresponding radical cation undergoes cyclopropane ring opening with

83 Herein we report a paramagnetic beryllium radical cation, [(CAAC)(2)Be](+*) (2) [CAAC = cyclic (al

84 ing activities against DPPH radical and ABTS radical cation.

85 l that the rate constant for ring opening of radical cations derived from 1'-methyl-3',4'-dihydro-1'H

86 Substituted triphenylamine (TPA) radical cations show great potential as oxidants and as

87 ct experimental evidence of gas-phase methyl radicals (CH(3) (.) ) in the ODHP reaction over boron-ba

88 pe of human learning and development poses a radical challenge for cognitive science.

89 d with repeated OW applications, and (iv) no radical change in Zn speciation was observed at the end

90 hotogalvanic effect can be attributed to the radical change of the band velocities when the chiral We

91 mical calculations reveal significant halide radical character for all complexes, suggesting their ab

92 other group 9 bridging nitride complexes, no radical character is detected at the bridging N atom of

93 Radical chemistry has gained considerable momentum in th

94 he reaction mechanisms, especially regarding radical chemistry of this system, remain elusive.

95 Here we explore selective radical chemistry to target aromatic residues applying C

96 es, namely, homoenolate chemistry, beta-keto radical chemistry, and acid-catalyzed ring-opening, as w

97 lves molecular scaffolds, metallochaperones, radical chemistry, and novel and unique biosynthetic int

98 momentum thanks to the rapid development of radical chemistry.

99 A radical clock system was developed to investigate single

100 ical approach on the linoleate-based peroxyl radical clock to enable the simultaneous measurement of

101 The fluorenylcyclopropyl radical clock was selected because it is the fastest kno

102 was selected because it is the fastest known radical clock.

103 l enzyme (GRE) superfamily utilizes a glycyl radical cofactor to catalyze difficult chemical reaction

104 ctose oxidase (GAO) contains a Cu(II)-ligand radical cofactor.

105 e-irradiation of the samples can restore the radical concentration back to a similar maximum concentr

106 The radical concentration in e-cigarettes was much lower as

107 Chemical reactions usually proceed through a radical, concerted or ionic mechanism; transformations i

108 trifluoroacetate to generate trifluoromethyl radicals, confined only to the laser-irradiated region,

109 Herein we present a new viologen-based radical-containing metal-organic framework (RMOF) Gd-IHE

110 ria remain damaged and vicious cycle of free radicals continues to self-propagate.

111 Here we report a one-step three-component radical coupling of [1.1.1]propellane to afford diverse

112 Implications to related Ni-catalyzed radical cross-couplings and the design of new transforma

113 y populations in which a policy of universal radical cure, combining artemisinin-based combination th

114 uire widespread access to safe and effective radical cure.

115 d hydrogen-atom transfer and copper-promoted radical cyanation-to accomplish highly enantioselective

116 ected side product formed through 4-exo-trig radical cyclization could be recycled through an unprece

117 bonyl Ugi-4CR adducts, employing an aromatic radical cyclization process promoted by tetrabutylammoni

118 g, followed by an aerobic, copper-catalyzed, radical cyclization to form Csp(2)-Csp(2) and O-Csp(2) b

119 Here, we report an enantioselective radical cyclization using alkyl iodides as precursors to

120 ntenance Bacillus Calmette-Guerin (mBCG) and radical cystectomy (RC).

121 The solid-state properties of organic radicals depend on radical-radical interactions that are

122 xperiments imply that the m-chlorobenzoyloxy radical derived from mCPBA cleaves C-H bonds in the alka

123 ) from the substrate to the photoexcited TAC radical dication, thus demonstrating a new reactivity mo

124 et oxygen (sodium azide) and carbon-centered radicals (DMPO) were tested to determine if any of the r

125 nd 300 nm generated higher concentrations of radicals (e.g., HO(*), ClO(*), Cl(*), and Cl(2)(-*)) tha

126 adical species, we report that sulfite anion radical efficiently substitutes the three carboxyl moiet

127 carbon of a (13) C(1) -labeled triarylmethyl radical enables the measurement of the probe rotational

128 The glycyl radical enzyme (GRE) superfamily utilizes a glycyl radic

129 front-end glow discharge source to generate radical fluoranthene reagent cations.

130 bsequent beta-scission event liberates alkyl radicals for coupling with electron-deficient olefins fo

131 e Fenton-like chemistry and produce reactive radicals from hydrogen peroxide activation have been ext

132 Eosin Y for a reductive generation of alkyl radicals from N-(acyloxy)phthalimide esters.

133 yl radical via beta-scission from a tertiary radical generated upon chlorine-mediated hydrogen atom t

134 Unlike conventional chemicals, the excess radicals generated in the ELT process are converted back

135 We present a new strategy for silyl radical generation via electroreduction of readily avail

136 radical precursors for homolytic on-protein radical generation; to study enzyme function with natura

137 Although oxidation of aromatics by these radicals has been studied for decades, the commonly acce

138 amino)carbene (CAAC)-stabilized borafluorene radicals have been isolated and characterized by element

139 Alkoxy radicals have long been known to enable remote C-H funct

140 Stable tetrathiatriarylmethyl radicals have significantly contributed to the recent pr

141 Chemical oxidation with hydroxyl radical (HO(*)) and sulfate radical (SO(4)(*-)) is often

142 to 9.7 x 10(5) molec cm(-3) and hydroperoxy radical (HO(2)) concentrations by 50-70% to 2.3 x 10(7)

143 eport a visible-light-induced intermolecular radical hydroalkylation of terminal alkenes that does no

144 functionalization, but never considered for radical hydrosulfonylation of alkenes.

145 ecological oncologists should recommend open radical hysterectomy for patients with early stage cervi

146 ree survival is lower for minimally invasive radical hysterectomy than for open surgery, and postoper

147 ries, patients undergoing minimally invasive radical hysterectomy, including those with tumor size <=

148 (1:1) to receive open or minimally invasive radical hysterectomy.

149 1, who were scheduled to have a type 2 or 3 radical hysterectomy.

150 rged species, tetraiodo-p-benzoquinone anion radicals (I(4) Q(-.) ) and iodide anions, was observed a

151 r key aspects of utilitarianism, such as its radical impartiality.

152 for sterically unprotected axial bicarbazole radical in comparison with monocarbazole and helical bic

153 that of the unsubstituted phthalimide-N-oxyl radical in most cases.

154 217T in relation to the RotaTeq vaccine were radical in nature and resulted in a change in polarity f

155 amino acid differences at position D195G was radical in nature and resulted in a change in polarity f

156 The structures of the radical in WT, V172I, and V172C variants have been estab

157 stem with the most effective use of hydroxyl radicals in oxidation treatment scenarios.

158 dly produced heat, but increased the organic radicals in termite bodies indicating non-thermal effect

159 l-known anti-aging element to capture oxygen-radicals in the human body, showing an "anti-aging" effe

160 were performed to confirm the involvement of radicals in the mechanism.

161 ex antioxidant mechanism for scavenging free radicals in wolfberries oxidative stress response.

162 ding to benzo[b]fluorenone derivatives via a radical intermediate as supported by EPR studies.

163 ates the electron transfer from the nitrogen radical intermediate to the Ir(IV) species in the cataly

164 periments confirmed the involvement of a non-radical intermediate.

165 onation event, which generates a key imidoyl radical intermediate.

166 es by single electron transfer to form alkyl radical intermediates and that carbon-halogen bond cleav

167 These radical intermediates are formed by the direct oxidation

168 ntial evolution channels of isomeric peroxyl radical intermediates at the 2- versus 3-positions.

169 in situ mechanistic study and capture of key radical intermediates when coupled with mass spectrometr

170 ations is inhibited when the iodine monoxide radical (IO) is intercepted by NO(2) to form the iodine

171 The ensuing charge separated radical ion paired complex is spectroscopically characte

172 ecules with complementary reactivities under radical, ionic, and metal-catalyzed conditions.

173 g biological substrates to form radicals and radical ions (Type I reaction); whereas in photodynamic

174 frequent reports in the literature, hydroxyl radical is not a key species participating in endogenous

175 understand the emissive properties of D-A(*) radicals, it is required that the electronic hybridizati

176 The rate-determining step in free radical lipid peroxidation is the propagation of the per

177 ase), hydrogen peroxide (catalase), hydroxyl radicals (mannitol) and singlet oxygen (sodium azide) an

178 This rationalizes why a radical mechanism is detected only in the presence of su

179 at a radical SAM enzyme MoaA accelerates the radical-mediated C-C bond formation.

180 , photocatalytic ability in superoxide anion radical-mediated coupling of (arylmethyl)amines and phot

181 tionalize peptides and proteins through free-radical-mediated dechalcogenation.

182 A new radical-mediated hydrazine coupling reaction was also di

183 le can significantly enhance the kinetics of radical-mediated oxidation reactions-pollutant degradati

184 Here, we present a radical method for reversible, light-induced tuning of f

185 Although hydroxyl radical ((*)OH) and hydrogen peroxide (H(2)O(2)) are reg

186 The hydroxyl radical ((*)OH) scavenging capacity is a useful paramete

187 chemistry coupling isoprene and the hydroxyl radical, OH-its primary sink(10-13).

188 chemistries of hydroxyl (OH) and hydroperoxy radicals, oxidized nitrogen species and organic peroxy r

189 Despite the fact that the radical pair is identical in all of the triads, remarkab

190 of the BTMPA(*+)-Im->AlPorF(n)-Ph-C(60)(*-) radical pair was found to be very different in each of t

191 e working details of the underlying stepwise radical pathway for the Co(II)-based C-H amination.

192 ), which uncovers the existence of gas-phase radical pathways.

193 organic transformations via either S(N)2 or radical pathways.

194 [Cu(II)]-C=CAr also captures the trityl radical Ph(3)C. to give Ph(3)C-C=CAr.

195 ns of vinyl ureas by way of a photocatalytic radical-polar crossover mechanism.

196 sis using a fired brick to control oxidative radical polymerization and deposition of a nanofibrillar

197 complex combines coordination insertion and radical polymerization to form polyolefin-polar block co

198 ation techniques, of reversible deactivation radical polymerization, and provide a forward-looking vi

199 sts, review their studies as Quantum PIs for radical polymerization, from suspension polymerization t

200 The tip is fabricated using the free radical polymerization.

201 functionalized bicyclopentanes using various radical precursors and heteroatom nucleophiles via a met

202 function and reactivity are used to install radical precursors for homolytic on-protein radical gene

203 asses and can accommodate a diverse array of radical precursors, including those that generate alkyl,

204 latinum nanoparticles combined with hydroxyl radical probes produced at the particle surface to devel

205 echanistic investigation strongly supports a radical process for the cyclization step.

206 site-selective acylation proceeds through a radical process.

207 in the realization of the enantioconvergent radical process.

208 owever, the control of enantioselectivity in radical processes remains one of the longstanding challe

209 int that "flight from the tyranny of tin" in radical processes was considered for a long time an unav

210 vides evidence for the importance of phenoxy radicals produced by one-electron transfer reactions ini

211 We predict hydroxyl (OH) and chlorine (Cl) radical production during these periods (10(6) and 10(7)

212 total of 187 patients had undergone primary radical prostatectomy (RP) (79/187 had secondary radioth

213 urrence (BCR) of prostate cancer (PCa) after radical prostatectomy (RP) using composite validation.

214 a standardized institutional protocol before radical prostatectomy was performed by using the same 1.

215 secutive patients with noncastrate BCR after radical prostatectomy who underwent (18)F-rhPSMA-7 PET/C

216 Among the 404 men who underwent subsequent radical prostatectomy, combined biopsy was associated wi

217 fers high detection rates in early BCR after radical prostatectomy, especially among patients with lo

218 (combined biopsy), and 404 (19.2%) underwent radical prostatectomy.

219 -standard pathologic specimens obtained from radical prostatectomy.

220 nd grade reclassification between biopsy and radical prostatectomy.

221 in the trial, and compared resection rates, radical (R0) resection rates and overall survival (OS) b

222 ad applicability to SET chemistry, including radical-radical cross-coupling, Minisci-type reactions,

223 ate properties of organic radicals depend on radical-radical interactions that are influenced by the

224 and water stability as a result of favorable radical-radical interactions, and their long-lifetime ra

225 sed for use in AOPWIN, a common model for OH radical rate constant estimations.

226 nts demonstrate that the intermediate cation radicals react with nucleophiles, resulting in aryl-Ge o

227 hemistry to seamlessly combine two canonical radical reactions-cobalt-mediated hydrogen-atom transfer

228 ity and enantioselectivity in intermolecular radical reactions.

229 e use of iron or cobalt complexes to promote radical reactivity which have been devised over the last

230 hrough hydrogen atom abstraction followed by radical rebound, as observed in the native C-H hydroxyla

231 ide C(sp)-C(sp3) coupled products R-C=CR via radical relay with (t)BuOO(t)Bu as oxidant.

232 eoperative chemoradiotherapy may improve the radical resection rate for resectable or borderline rese

233 molecular orbital (SOMO) of this hydrocarbon radical resembles both SOMOs of triangulene, but the spi

234 arboxylic acids to generate methyl and alkyl radicals, respectively, without the need for stoichiomet

235 adical interactions, and their long-lifetime radicals result in wide spectral absorption in the range

236 higher levels of nitric oxide and superoxide radicals, resulting in increased local peroxynitrite for

237 oxidized nitrogen species and organic peroxy radicals (RO(2)) in OFR.

238 NifB is a radical S-adenosyl-L-methionine (SAM) enzyme that is ess

239 Catalysis by canonical radical S-adenosyl-l-methionine (SAM) enzymes involves e

240 ral model for a proposed intermediate in the radical S-adenosyl-L-methionine biogenesis of the M-clus

241 Here, we report the first evidence that a radical SAM enzyme MoaA accelerates the radical-mediated

242 human cytomegalovirus co-opts the antiviral radical SAM enzyme viperin (virus-inhibitory protein, en

243 he intermediacy of organometallic species in radical SAM enzymes.

244 Among them, the radical SAM protein NifB plays an essential role, concom

245 SAM triggers the radical SAM reaction to complete the oxygen-sulfur swapp

246 Viperin is also notable as one of very few radical SAM-dependent enzymes present in higher animals;

247 ve approaches-normobaric hyperoxia, the free radical scavenger alpha-phenyl-butyl-tert-nitrone (alpha

248 T), a cysteine rich protein is involved as a radical scavenger in several pathological conditions ass

249 Melatonin, an endogenous free radical scavenger synthesized by neuronal mitochondria,

250 The oxygen radical scavenger, N-acetylcysteine (NAC), attenuates th

251 Using hydroxyurea as a radical scavenger, the spin-coupled hidden Cu(II) was ob

252 o assays namely, DPPH(*), ABTS(*+), hydroxyl radical scavenging ability, reducing activity, superoxid

253 In addition, EGC and its esters showed radical scavenging activities against DPPH radical and A

254 a high 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging activity (54.21-81.41%).

255 hyll contents, total phenolic content (TPC), radical scavenging activity (RSA), oxidative stability i

256 Furthermore, total phenolic content and DPPH radical scavenging activity was measured.

257 The films showed no DPPH radical scavenging properties but high FRAP (6.6 mMol Tr

258 re enhanced by seed priming, total phenolics radical-scavenging activities, and macro- and microeleme

259 the rate constants of the phthalimide-N-oxyl radicals' self-decay with different electron-withdrawing

260 f-generated movements underlie adaptation to radical sensorimotor distortions.

261 anar bicyclic frame with a terminal Al-O(*-) radical site, accompanied by a change from the Fe(+III)/

262 on with hydroxyl radical (HO(*)) and sulfate radical (SO(4)(*-)) is often used to treat water contami

263 Long-standing radical species have raised noteworthy concerns in organ

264 ther hand, improved hydrogen transfer to the radical species in the solution.

265 ed system, production and stabilization of a radical species were simultaneously found accompanied by

266 is able to scavenge different types of free radical species, showing strong neuroprotection and redu

267 erally considered inert toward many reactive radical species, we report that sulfite anion radical ef

268 e, we have successfully harnessed this novel radical strain-release amination as part of a multicompo

269 Overall, this radical strategy enables the rapid construction of novel

270 stics in Categorizing Acute Lung Infections (RADICAL) study.

271 Radical substitution on tetrasulfides is demonstrated to

272 rate radical and to estimate the rate of the radical substitution reaction involved in the methyl tra

273 Adenosine radicals tagged with a fixed-charge group were generated

274 ester, which decomposes to afford a tertiary radical that is readily trapped by the enyne.

275 m [4Fe-4S](+) to SAM, generating an R(3)S(0) radical that undergoes regioselective homolytic reductiv

276 activation of N-chloroamines to give aminium radicals that enable efficient alkene aminochlorination.

277 With sulfur-centered radicals, the carbanions are further functionalized by r

278 als, electrochemistry grants access to silyl radicals through energetically uphill reductive cleavage

279 which enables the generation of nucleophilic radicals through strain release.

280 Modification of the aryloxy radical to 2,6-di-tert-butyl-4-tritylphenoxyl radical, w

281 ged structure has been synthesized by double radical trans-hydroboration of benzo[3,4]cycloundec-3-en

282 d water chains appear critical for effective radical translocation along the PCET pathway.

283 Radical trapping experiments confirmed the involvement o

284 CRC) exhibit various clinical outcomes after radical treatments.

285 In ferroptosis, iron-mediated free radicals trigger lipid peroxidation under conditions of

286 ng proceeds with the generation of an alkoxy radical utilizing bond-dissociation free energy (BDFE) a

287 yl orthoformate serves as a source of methyl radical via beta-scission from a tertiary radical genera

288 Their ability to trap hydroxymethyl radical was evaluated by electron paramagnetic resonance

289 A 139-pai-electron nanographenoid radical was obtained by expanding the periphery of a nap

290 he hydrogen atom abstraction by the adenosyl radical were used to investigate the kinetic significanc

291 Stable radicals were detected directly in ground samples.

292 The dimer is cleaved into its parent radicals when exposed to ultraviolet or visible radiatio

293 roxidation is the propagation of the peroxyl radical, where generally two types of reactions occur: (

294 adical to 2,6-di-tert-butyl-4-tritylphenoxyl radical, which contains a trityl group at the para posit

295 ves C-H bonds in the alkane to form an alkyl radical, which subsequently reacts with mCPBA to afford

296 droperoxide, trapping of the generated alkyl radical with 2,2,6,6-tetramethylpiperidin-1-yl (TEMPO),

297 and features a beta scission of a 14-alkoxy radical with concomitant generation of the C8-C13 bond.

298 of ligands, the formation of carbon-centered radicals with long lifetimes, and the decomposition of m

299 , in theory, generate aminyl and carboxylate radicals, with the latter undergoing decarboxylation to

300 photoreduction of viologens (XV(2+)) to the radical XV(*+) in a homogeneous mixture with carbon nano