ライフサイエンスコーパス: radical cation

1 ing activities against DPPH radical and ABTS radical cation.

2 on of the electrogenerated radical anion and radical cation.

3 -electron acceptor to destabilize the aminyl radical cation.

4 xanthin and lutein and on the formation of a radical cation.

5 7(*+) and trapping of the resulting distonic radical cation.

6 o to improved stability of the corresponding radical cation.

7 e anodic pulse due to the instability of the radical cation.

8 oposed to be electrolyzed byproduct from the radical cation.

9 P-BIPY(2+) unit is reduced to its P-BIPY(*+) radical cation.

10 ell as by deprotonation of the corresponding radical cation.

11 hat are common in crystals of other viologen radical cations.

12 d on the design of nanoparticles with stable radical cations.

13 es via the mesolytic cleavage of alkoxyamine radical cations.

14 al-pairing interactions between the BIPY(.+) radical cations.

15 ocess occurring in aryl tert-butyl sulfoxide radical cations.

16 onably due to a deprotonation of the sulfide radical cations.

17 h the phenyl ring and the sulfur atom of the radical cations.

18 spin densities (polarons) on molecular wire radical cations.

19 CH(3)(*), or even C(7)H(7)(*) giving stable radical cations.

20 lectron oxidation, forming the corresponding radical cations.

21 that is, by increasing the stability of the radical cations.

22 aldehyde and 2'-arylacetophenone oxime ether radical cations.

23 chlorobenzene, shifted the ionization toward radical cations.

24 e recognition motif associated with viologen radical cations.

25 , all triradicals produce very abundant DMDS radical cations.

26 to stable diaminocyclopropenium oxyl (DACO) radical cations.

27 he resonance stabilization of the coreleased radical-cations.

28 In this investigation, radical cation 1 is independently generated via beta-het

29 in reaction, the oxidation of CPA 1 to amine radical cation 1(+*) by product radical cation 3(+*) (ge

30 In particular, the reactive CPA radical cation 1(+*), the reduced photocatalyst Ru(I)(bp

31 s deriving from the C-S bond cleavage in the radical cations 1(*+)-5(*+) have been observed in the st

32 s deriving from the C-S bond cleavage in the radical cations 1(+*)-4(+*) have been observed in the st

33 rom alpha-C-S and alpha-C-H fragmentation of radical cations 1(+*)-4(+*), formed besides the S-oxidat

34 Thymidine radical cation (1) is produced by ionizing radiation and

35 stent with the formation of diffusively free radical cations (1, NMe-1).

36 discovered an electronically stabilized pai-radical cation [10(OTf)] that shows multiple intermolecu

37 ve generated two persistent pyridyl-appended radical cations: 10-(pyrid-2-yl)-10H-phenothiazinium (PP

38 rived from Calpha-S fragmentation of sulfide radical cations (2-phenyl-2-propanol and diaryl disulfid

39 the dimer of the 1,2,4-trithia-3,5-diazolyl radical cation (26a(2+)), and its Selena congeners and d

40 A 1 to amine radical cation 1(+*) by product radical cation 3(+*) (generated using online electrochem

41 bpz)3(+), and the [3 + 2] annulation product radical cation 3(+*) are all successfully detected and c

42 zation of a N-substituted, bisphenalenyl pai-radical cation [3(OTf)] that shows antiambipolar charge

43 N,N,N-trimethylammonium)methyl phenylperoxyl radical cation (4-Me3N([+])CH2-C6H4OO(*)), using linear

44 ld be oxidized by AgOTf to the corresponding radical cation 6 and dication 7 in-situ.

45 bis(3-ethylbenzothiazoline-6-sulphonic acid) radical cation (ABTS(+)), and the TBARS system based on

46 obis(3-ethylbenzothiazoline-6-sulfonic acid) radical cation (ABTS(+)).

47 A, the amount of the blue-green-colored free-radical cation (ABTS+) was reduced.

48 resolved LFP showed first-order decay of the radical cations accompanied by formation of the tripheny

49 lectron-withdrawing substituents enhance the radical-cation acidity.

50 ddition of a catalytically generated enamine radical cation across a pendent olefin serves to establi

51 chanism: the transiently generated carbazole radical cation acts as an oxidant to return the photocat

52 at results in both cases (in the form of its radical cation after ionization) was characterized by it

53 The stability of the radical cations also increases with n.

54 The 2,4,6-tridehydropyridine radical cation, an analogue of the elusive 1,2,3,5-tetra

55 triradical to generate the conventional DMDS radical cation and a neutral biradical.

56 specific orientation of the sulfur-centered radical cation and a phenyl ring stabilized by the fibri

57 states by comparing them to marker bands of radical cation and anion spectra.

58 , showed the evolution of characteristic PTZ radical cation and ANQ radical anion features upon excit

59 easurements, revealing stepwise formation of radical cation and dication species in solution.

60 elicene, while the inversion barriers in its radical cation and diradical dication were predicted by

61 significantly increased the lifetime of the radical cation and had a substantial effect on the profi

62 ducts in 67-89% yields via the corresponding radical cation and iminium ion intermediates, the reacti

63 erein olefin addition to a transient enamine radical cation and oxidation of the resulting radical fu

64 rty of being able to recognize both BIPY(*+) radical cation and pi-electron-rich guests simultaneousl

65 ls when fixing the substrate to generate the radical cation and scanning the tip to generate the radi

66 ntermediates, reactive pathways of the amine radical cation and the influence of oxygen and the light

67 ctions, leading to unstable electrogenerated radical cations and anions.

68 way of producing highly stabilized BIPY(*+) radical cations and open up more opportunities to use st

69 e Ru-CO bands upon stepwise oxidation to the radical cations and the dications and was found to be re

70 Moreover, radical cations and trans-dihydride intermediates captur

71 the para-substituted phenol radical-cations and the corresponding phenoxy radicals.

72 probe the first two electronic states of the radical cation, and resolve the vibrational fine structu

73 ioxidant activities (AA) using ABTS and DPPH radicals cation, and ferric reducing/antioxidant power (

74 ding the first voltammetric evidence for the radical cation [Ar2S2](+).

75 These reactions proceed through aminium radical cation (ARC) intermediates and occur at room tem

76 neither one-photon ionization nor long-lived radical cations are detected for the telomere repeat TTA

77 the switched state, the interacting BIPY(*+) radical cations are in a fast exchange regime.

78 Moreover, the corresponding enol radical cations are ruled out as relevant intermediates.

79 tion reveals that once converted to the aryl radical cation, aryl triflate would be more favorable to

80 ts along with a 4,4'-bipyridinium (BIPY(*+)) radical cation as three very different potential recogni

81 sing the fragmentation rate constants of the radical cations as indicated by a laser flash photolysis

82 straction products and small amounts of DMDS radical cation, as expected.

83 s method should be compatible with producing radical cations at defined positions within DNA.

84 A first-order decay of the sulfoxide radical cations, attributable to C-S bond cleavage, was

85 1 leads to the disappearance of the polaron (radical cation) band at >900 nm and an increase in the b

86 y roles of oxygen in photoredox catalysis of radical cation based Diels-Alder cycloadditions mediated

87 d coronenes, HTCGemini easily forms a stable radical cation, both in solution and in the bulk, upon o

88 in DNA, is significantly shifted toward the radical cation by a flanking dA.

89 ting the GOx-catalyzed reduction of the ABTS radical cation by glucose in anaerobic conditions.

90 )Co(II) (ONNO.BF(3) ), and the porphyrin pai-radical cation by-product of this reaction, and that the

91 Herein we report a paramagnetic beryllium radical cation, [(CAAC)(2)Be](+*) (2) [CAAC = cyclic (al

92 To a first approximation, the glycerol dimer radical cation can be described as a monomeric glycerol

93 e recombination occurs in 60 ps before the O radical cation can lose a deuteron to water.

94 tions as to how the formation of oxime ether radical cations can be tuned by substituents.

95 ful triplet excited state oxidant and longer radical cation chain length.

96 ilylate directly from such states of radical/radical cation character and yield the corresponding DHT

97 s proposed that the G(-H)(*) radicals retain radical cation character by sharing the N1-proton with t

98 ation of a high-valent diiron phthalocyanine radical cation complex with fluoride axial ligands, [(Pc

99 ction reactions by a) an oxoferryl porphyrin radical-cation complex [Por(.+) Fe(IV) (O)L(ax) ] and b)

100 Such radical cation complexes between naphthalene (Naph) and

101 cal tetraalkyl tetrazetidinetetracarboxylate radical cation, containing the elusive cyclic N(4) ring

102 ow that the C-C sigma bonding orbital of the radical cation contains only a single electron, giving r

103 s well as the thermodynamics and kinetics of radical cation cyclization, we provide an explanation fo

104 of selected Cr(III) complexes for promoting radical cation cycloadditions are described.

105 L(4) capsule promotes a range of bulk-phase, radical-cation cycloadditions.

106 The radical cation DABCO(+*), prepared in situ by oxidation

107 mixture of a disubstituted 4,4'-bipyridinium radical cation (DB(*+)) and an asymmetric cyclophane bis

108 voltammetry (CV), antioxidant capacity (ABTS radical cation decolorization assay and FRAP as Ferric R

109 antioxidant activities were measured by ABTS radical cation decolorization assay, varying from 17.5 t

110 d-state anthracenes and ground state aminium radical cations, define a single Marcus parabola in each

111 slow to compete with other processes such as radical cation deprotonation.

112 These Mn(IV)(O)(pi-radical-cation) derivatives exhibit dramatically inhibit

113 In contrast, the radical cation derived from 4-chloro-N-methyl-N-(2-pheny

114 l that the rate constant for ring opening of radical cations derived from 1'-methyl-3',4'-dihydro-1'H

115 The redox properties and the stability of radical cations derived from the catalysts were evaluate

116 tabilized by interacting with a bipyridinium radical cation, despite the presence of Coulombic repuls

117 nts showed an efficient formation of sulfide radical cations, detected in their dimeric form [(4-X-C6

118 The decay rate constants of radical cations, determined by LFP experiments, decrease

119 e neutral state and in the oxidized species (radical cations, dications and radical trications) has b

120 F and J were obtained by the intermolecular radical cation Diels-Alder (RCDA) reaction.

121 polypyridyl complexes promote the efficient radical cation Diels-Alder cycloaddition of electron-ric

122 the rate of a representative photocatalytic radical cation Diels-Alder reaction.

123 undamental understanding of the mechanism of radical cation dimer formation between constitutionally

124 butadiyne group, the distribution of the TTF radical-cation dimer can be changed from 60% to 100%.

125 The N,N-dimethylaniline (DMA) radical cation DMA(.+) , a long-sought transient interme

126 The produced radical cation (DMABN(*+)) was observed to react with se

127 c content, antioxidant capacity towards ABTS radical cation, DPPH and hydroxyl radicals as well as re

128 the formation of a sulfur thereforepi-bonded radical cation due to the methionine-phenylalanine inter

129 A covalently linked viologen radical cation dyad acts as a reversible thermomagnetic

130 nciples quantum calculations reveal that the radical cation (electron hole) generated by DNA oxidatio

131 nvolves photoionization and deprotonation of radical cation, followed by homolytic cleavage of the al

132 By analyzing the DeltaG(PET) associated with radical cation formation as well as the thermodynamics a

133 y-product of this reaction, and that the pai-radical cation formation likely occurs at the hyponitrit

134 role of the fluoroalcohol is to stabilize a radical cation formed by single electron transfer.

135 We present the discovery of a novel radical cation formed through one-electron oxidation of

136 e charge transfer bands in the mixed valence radical cations formed by one-electron oxidation, indica

137 ive hydrated electrons by stabilizing indole radical cations formed upon photolysis, and prevents the

138 ds initially to the formation of the guanine radical cation G(*+), its deptotonation product G(-H)(*)

139 mechanistic aspects of hydration of guanine radical cations, G(*+) in double- and single-stranded ol

140 n of two radical species, namely, the phenol radical cation generated directly by the laccase and the

141 ane, cyclobis(paraquat-p-phenylene), and the radical cation generated on reduction of a viologen disu

142 Radical cations, generated via one-electron oxidation of

143 Subsequent activation of the cyclotide radical cation generates dehydroalanine at a single cyst

144 antiferromagnetically coupled Cu(II) corrole radical cation ground state.

145 The same radical cation has been prepared by the oxidation of [(P

146 imerization, and a mechanism involving amine radical cation has been proposed.

147 lly, a mechanism that involves the carbazole radical cation has been traced (evidenced) and proposed

148 Radical cations have been generated for 10 bis[4-(diaryl

149 The solution-phase EPR spectra of the radical cations have Gaussian lineshapes with linewidths

150 , wherein the electron travels to a proximal radical cation in concert with proton transfer to a weak

151 encher in trimers, formation of a zeaxanthin radical cation in monomers.

152 ion can be described as a monomeric glycerol radical cation in the presence of a spectator glycerol,

153 is attributed to partial desolvation of the radical cation in the product encounter pair (P(*)/D(*+)

154 e effect in which the spin and charge of the radical cation in the ring-closed form is delocalized in

155 thraquinone radical anion and a triarylamine radical cation in three homologous series of rigid-rod-l

156 aromatics (benzenes and biphenyls) and their radical cations in acetonitrile follows a Sandros-Boltzm

157 ation leads to the relatively high amount of radical cations in air plasma.

158 Oxidatively generated guanine radical cations in DNA can undergo various nucleophilic

159 d mass spectrometry reveal that the BIPY(*+) radical cations in this series of [2]rotaxanes are stabi

160 es more reversible, and the stability of the radical cations increases as the conjugation of the subs

161 the ionization, with the relative amount of radical cations increasing from CO(2), to N(2), to air.

162 njection of holes, i.e. formation of the TPP radical cation, inside the junction was monitored by in

163 ons provide a means for rapidly trapping the radical cation intermediate in a manner that avoids comp

164 and a butylated hydroxytoluene-trapped aryl radical cation intermediate in high-resolution mass spec

165 ond formation proceeds through a key aminium radical cation intermediate that is generated via electr

166 highly reactive AaeAPO oxoiron(IV) porphyrin radical cation intermediate that is the active oxygen sp

167 oth the cationic photoredox catalyst and the radical cation intermediate, respectively.

168 selectivity-determining deprotonation of the radical cation intermediate.

169 r nucleophiles to trap an enol ether-derived radical cation intermediate.

170 vealed the structures and stabilities of the radical cation intermediates as well as the reaction ene

171 cases, the spin density maps of the aromatic radical cation intermediates calculated at the DFT UB3LY

172 x heterocycles through oxime and oxime ether radical cation intermediates produced via PET.

173 er may result in the formation of N-centered radical cation intermediates, which could lead to the ob

174 propanes are readily converted into reactive radical cation intermediates, which in turn participate

175 arise from the oxidation of the indoles into radical cation intermediates.

176 examine how the properties of photogenerated radical cations, intrinsic to TPA macrocycles, are alter

177 we present the detection of transient amine radical cations involved in the intermolecular [3 + 2] a

178 This implies that the rubrene radical cation is not hydrophilic enough to transfer int

179 ieties are nearly perpendicular, whereas the radical cation is present in two stable planar conformat

180 is produced in as high as 70% yield when the radical cation is produced in the presence of excess thi

181 Alcohol-trapping of the radical cation is the kinetically favored pathway and is

182 While olefin amination with aminium radical cations is a classical method for C-N bond forma

183 rted charge distribution (T radical anion, A radical cation), is not able to repair the CPD lesion.

184 ing reaction, both in the neutral and in the radical cation, is discussed on the basis of calculation

185 The deprotonation rate constant of radical-cations (k(H)) of 10(5) s(-1) and the reaction r

186 from the fragmentation rate constants of the radical cations (kf) and the S oxidation/fragmentation p

187 3-CN-NMQ(*) (lambdamax = 390 nm) and of the radical cations (lambdamax = 500-620 nm).

188 sm suggests facile C-N bond formation in the radical cation leading to a 5-exo intermediate.

189 alogs (~9 x 10(8) to 4 x 10(9) M(-1) s(-1)), radical cation lifetimes of CPA and its analogs (140-580

190 at the primary fragmentation of the glycerol radical cation (m/z 92) occurs only via two routes.

191 indicate comparable detection limits for the radical cations [M(*+)] and negative pseudomolecular ion

192 The corrole radical cation manganese(IV) hydroxo complex has been fu

193 of 11-cis-retinol, supporting a carbocation/radical cation mechanism of retinol isomerization.

194 e cannot distinguish between arenium ion and radical cation mechanisms for the cyclization steps.

195 Two BIPY(*+) radical cations, methyl viologen (MV(*+)) and a dibutyny

196 ationic redox state with the methyl viologen radical cation (MV(*+)) to give a 1:1 inclusion complex.

197 energy levels of the corresponding phosphine radical cations obtained by density functional theory co

198 s transfer to an added chemical oxidant, the radical cation of 2,2'-azino-bis(3-ethylbenzothiazoline-

199 The mixed-valent radical cation of a styrylruthenium-modified meso-tetraa

200 tead, we attribute this effect to the stable radical cation of diamondoids.

201 formed between the CBPQT(2(*+)) ring and the radical cation of methyl-phenylene-viologen (MPV(*+)).

202 The radical cation of N,N,N',N'-tetramethyl-p-phenylenediami

203 ly developed approach based on observing the radical cation of N,N,N',N'-tetramethyl-p-phenylenediami

204 TMPyP(4+) which reduces the enzyme to form a radical cation of the porphyrin with a k(ET) approximate

205 ot found to prevent the reaction between the radical cation of the probe and the superoxide, but it s

206 This is in contrast to the very acidic radical cation of tyrosine (pK(a) approximately -2).

207 The radical cations of a family of pi-conjugated porphyrin a

208 The radical cations of a series of aryl benzyl sulfoxides (4

209 s through direct observation of (3)sens* and radical cations of CPA and CPA analogs.

210 nd the intrinsically localized nature of the radical cations of the dinuclear complexes.

211 The radical cations of the E and the configurationally stabl

212 The radical cations of the more sterically constrained ortho

213 At physiological pH, the radical cations of the probes react rapidly with [Formul

214 reaction between [Formula: see text] and the radical cations of the probes.

215 d are often converted to their corresponding radical cations or radical anions via electron abstracti

216 rays show evidence for delocalization of the radical cation over both porphyrins in the dimer.

217 2N as Rh2(II,II) with a coordinated nitrene radical cation, (pi*)(4)(delta*)(2)(pi(nitrene,1))(1)(pi

218 effect" was most likely caused by changes in radical cation (polaron) mobility in the film.

219 e approach reveals that an important part of radical cation population survives up to a few milliseco

220 n survives up to a few milliseconds, whereas radical cations produced by chemical oxidants in various

221 A new triarylaminium radical cation promoted coupling of catharanthine with v

222 The packing pattern of the radical cations provides a rare example of an organic ka

223 the 1,4-dimethoxyphenylene and bipyridinium radical cations, providing new opportunities for the man

224 e their rate of oxidation by (3)CDOM* due to radical cation quenching (i.e., aniline(*+) -> aniline)

225 er these conditions, transient phosphoniumyl radical cations (R3P(*+)) are formed, and computational

226 Opportunities to further accelerate the radical-cation reaction are revealed by computational as

227 In the case of R = Mes, the radical cation salt [Mes3P.][(mu-HO)(Al(C6F5)3)2] is iso

228 Crystalline radical cation salts formulated as [(S,S)-1]2PF6, [(R,R)

229 The einkorn malts had high DPPH and ABTS radical cation scavenging activities, but the phenolic c

230 elline A (6), from this plant, revealed ABTS radical cation scavenging activity and 5 displayed an in

231 re evaluated for their DPPH radical and ABTS radical cation scavenging activity, ferric reduction cap

232 Because radical cations, second-generation cations (ions formed

233 the ancillary dtb-bpy ligand, where the TEA radical cation serves as an effective hydrogen atom dono

234 Substituted triphenylamine (TPA) radical cations show great potential as oxidants and as

235 The radical-cations showed a broad absorption band located b

236 A carotenoid radical cation signal was detected in the wild type, alt

237 on 3(2+) has similar energy to two [PMe3](+) radical cations, so that it is the lattice enthalpy of 3

238 lt of a change in charge distribution in the radical cation species with strongly electron-donating s

239 tions and simulations were consistent with a radical cation species, but not a radical anion or radic

240 lowed by mesolytic cleavage of the resulting radical cation species, which leads to the generation of

241 zation and sensitized photooxidation to form radical cation species, which then likely deprotonate an

242 nced by C-S bond cleavage to form a distonic radical cation species.

243 ashion: the 1:1 complexes pack in continuous radical cation stacks.

244 ow cross-conjugation can be used to tune the radical cation state independent of the neutral state.

245 jugation the electronic energy levels of the radical cation state may be controllably tuned independe

246 tectons from their dicationic state to their radical cation state, the driving force of the disassemb

247 other isomers, the meta-cation has a radical/radical cation structure in both spin states and thus tw

248 es as well as the corresponding reactions of radical-cation substrates generated under photoredox con

249 DFT computations of the radical cation suggest that SOMO and HOMO energy levels

250 on of the alkene to the corresponding alkene radical cation that gets trapped by an N-nucleophile and

251 inic acid and ionization to diphenyl sulfide radical cation that in turn led to diphenyl sulfoxide.

252 O(2) to the superoxide ion and the TPrAH(*+) radical cation that oxidizes this species to singlet O(2

253 Waals complexes of the oligomers with their radical cations that are models for the self-assembly of

254 -electron oxidant capable of generating base radical cations that can migrate over long distances in

255 ctron transfer, these donors form persistent radical cations that trap substrate-derived radicals.

256 luxing toluene engenders a contact ion-pair (radical cation) that leads, in the first instance, to th

257 ediamine (DMPD) probe to the colored DMPD(+) radical cation, the optical absorbance of which was meas

258 l the BIPY(2+) units are reduced to BIPY(*+) radical cations, the resulting CBPQT(2(*+)) diradical di

259 s and the stability of the resulting nitroso radical cations, the structures of which are determined

260 ine the bond dissociation free energy in the radical cations, the transition state energies associate

261 atom transfer with the quinuclidine-derived radical cation through polarity-matching and/or ion-pair

262 s delocalized in the tert-butyl group of the radical cations, thus explaining the small substituent e

263 Transition-metal hydride radical cations (TMHRCs) are involved in a variety of ch

264 initiates the proton movement from the 1-OH radical cation to a solvent water molecule in ~890 fs, f

265 species reduces the Diels-Alder cycloadduct radical cation to the final product and reforms oxygen.

266 Addition of hindered phenols causes the radical cations to decay, and protonated products and th

267 s deriving from the C-S fragmentation in the radical cations, together with sulfur-containing product

268 he reactivity of electrochemically generated radical cations toward alcohol and p-toluene sulfonamide

269 Manipulating the oscillator strengths of radical cation transitions allows for tuning of the colo

270 photolysis and reaction with (3)DOM form Trp radical cation (Trp(*+)) via Trp photoionization and dir

271 teristic of the generation of a tryptophanyl radical-cation (Trp(233*+)).

272 first example of the use of the chemistry of radical cations under nonoxidative conditions in total s

273 ing interactions between V(*+) and BB(2(*+)) radical cations under reductive conditions.

274 ron transfer (SET) because the corresponding radical cation undergoes cyclopropane ring opening with

275 cyclization of 2'-alkynylacetophenone oxime radical cations using photoinduced electron transfer (PE

276 intervalence charge-transfer bands of these radical cations vary from weak broad Gaussians, indicati

277 nated cyclotide cations are transformed into radical cations via ion/ion reaction with the sulfate ra

278 uted enhancement due to a positively charged radical cation was in agreement with the measured work f

279 ger delay times, the absorption of the dimer radical cation was replaced by an absorption band assign

280 ssentially complete by eight hours, and this radical cation was stable for at least 6 days; at room t

281 is extremely fast, and the decay of dithiane radical cations was not affected by the presence of wate

282 osses, SNLs) from the charge reduced peptide radical cations was studied using ETD.

283 Ready generation of radical cations was supported by cyclic voltammetry meas

284 Formation of sulfoxide radical cations was unequivocally established by laser f

285 analyte ions were detected in ESI-only mode, radical cations were detected in APCI-only mode, and bot

286 The radical cations were generated in solution by chemical a

287 The neutral hydrocarbons and their radical cations were studied utilizing density functiona

288 um cations (distonic isomers of the pyridine radical cation) were generated by ultraviolet photolysis

289 rm an elusive bis(silylene)-stabilized Si(I) radical cation which undergoes homocoupling to the corre

290 r, neutral formaldehyde, and a vinyl alcohol radical cation, which exhibits a binding energy of appro

291 idizes the sulfide to form the corresponding radical cation, which is eventually oxidized by 2 to the

292 onitored by transient absorption of the wire radical cation, which is given by bands in the 500 to 60

293 n transfer from a neutral chain, to generate radical cations, which are stabilized by the pendant sul

294 are able to convert the neutral dimers into radical cations, which can be isolated.

295 neration, in the MIM-precursors, of BIPY(.+) radical cations, while the metal itself, which is oxidiz

296 erived alkoxyamine substrate gives rise to a radical cation with a remarkably weak C-O bond.

297 n of the rate of the reaction of the guanine radical cation with oxygen.

298 They are oxidized to vibrantly colored radical cations with absorptions that span the visible s

299 onding calculations indicate phenothiazinium radical cations with minimal spin on the pyridine nitrog

300 (2+) ions upon UV irradiation to form MV(+*) radical cations within the crystal structure with half-l