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1 substituent, respectively, impacts the PCET rate constant.
2 ionships between the aggregation and binding rate constants.
3 ome of the charge-transfer and corresponding rate constants.
4 s BCFs are slightly more accessible than the rate constants.
5 distribution of association and dissociation rate constants.
6 breastmilk-to-infant and infant elimination rate constants.
7 se without the need to introduce fluctuating rate constants.
8 primarily due to differences in dissociation rate constants.
9 tively) due mainly to decreases in radiative rate constants.
10 y of HAT energy for predicting NAC reduction rate constants.
11 dithiolanes were then predicted by using the rate constants.
12 association rate constants and dissociation rate constants.
13 of starvation and to determine translocation rate constants.
14 ies of directly measuring (3)CDOM* quenching rate constants.
15 determine photoreduction and photobleaching rate constants.
16 y and ratio of the dissolution and diffusion rate-constants.
17 n-rate constant 1.61-fold greater and an off-rate constant 0.563-fold smaller than that of albumin.
18 cm(-2)) and heterogeneous electron transfer rate constant (0.0032 s(-1)) which indicate enhanced sur
19 y), standard heterogeneous electron transfer rate constant (0.336 s(-1) and 0.590 s(-1) for AT and VC
23 or SWCNTs than albumin, with a fibrinogen on-rate constant 1.61-fold greater and an off-rate constant
24 ter cleaning and then decreased with removal rate constants 1.2-7.2 times larger than ACR, indicating
26 between the heterogeneous electron-transfer rate constant (10(-3) cm s(-1)) and the diffusion coeffi
27 C(P)SOH to C(P)SO(2) (-) with a second-order rate constant 2 orders of magnitude higher than that of
28 process was run and the kinetic parameters (rate constant, activation energy, and temperature quotie
29 ications dramatically change binding kinetic rate constants, affording compounds with a clozapine-lik
30 e of an emissive transition with a radiative rate constant an order of magnitude higher than that of
35 portional relationships between the measured rate constants and associated gene transcripts for nitri
38 chloride were used to extrapolate unfolding rate constants and half-lives of the crystallins in the
39 tic modeling yielded invariable second-order rate constants and increasing concentrations of reactive
40 the initial guess of model parameters (i.e., rate constants and initial counts of molecules in a cell
43 sp(3) C-H bonds up to 87 kcal/mol to afford rate constants and kinetic isotope effects (KIEs) of 2-6
45 The linear free energy relationships between rate constants and pK(a) of the leaving group are curved
46 tamol clearance, determined from elimination rate constants and reported total larval volumes of 253,
48 ing a Lewis base X, affording faster kinetic rate constants and the ability to cleave stronger C-H bo
49 QCM setup, the association and dissociation rate constants and the associated equilibrium constants
51 a and the TK parameters (sorption and uptake rate constants and the resulting BCF) were found, but no
52 a protein and a small molecule with defined rate constants and, thus, K(d) of their interaction-allo
53 hydrolysis of a model organophosphate, with rate constants approximately 10(5)-fold higher than the
54 cond molecular dynamics, and the ET and PCET rate constants are calculated with the corresponding non
57 the intermolecular binding and dissociation rate constants are quantitatively and independently dete
58 ic tetrazines that react with isonitriles at rate constants as high as 57 L mol(-1) s(-1) were access
59 charged side chains bracket the experimental rate constants, as expected for the acidic bath used in
60 f the thiazoline product, and determined the rate constants associated with the stepwise condensation
62 a(2) can be calculated, one can compare the rate constants at different times with statistical rigor
63 dots") show similar singlet oxygen quenching rate constants, based on the molar concentration of the
64 )) and the influx (K (1)) and efflux (k (2)) rate constants between plasma and selected brain regions
66 ceable differences in the (3)CDOM* quenching rate constants by HDA and unquenchable triplet fractions
67 ues, we developed a simple algorithm for the rate constant calculation based on a single labeled samp
68 The improved 2 time-point method enables the rate constant calculation with less than 10% relative er
69 t concentrations; (ii) different gill uptake rate constant calculations (k(1)); (iii) protein binding
71 ameters such as the receptor desensitization rate constant can be estimated if the mechanism is known
72 ole, the DOM concentration dependence of the rate constant consisted of a sharp decrease up to ~1.0 m
73 ary displacements or slow the working stroke rate constant, consistent with the mutation disrupting a
79 ndicate that this variant has a dissociation rate constant essentially equivalent to the wild type, i
80 ti-compartmental pharmacokinetic model (with rate constants estimated from in vitro experiments) pred
81 h of the spacer and correlated well with the rate constants estimated from the BP triplet lifetimes.
85 our analysis suggests that the few-parameter rate constant expression of Marcus theory explains both
87 For the major isomer 5a, the computed SCT rate constant for bond shifting at 80 K is 0.16 s(-1), c
88 ever, even at the optimal driving force, the rate constant for charge transfer from the triplet state
89 esults show that m(6)A minimally impacts the rate constant for duplex dissociation, changing k(off) b
90 ard TC dissociation rather than by a smaller rate constant for GTP hydrolysis for near- and non-cogna
91 sterol depletion did not affect the observed rate constant for K(+) occlusion by phosphorylated Na(+)
92 and have uncovered a mechanism in which the rate constant for pyrophosphate release is slowed for ce
97 and led to an increased enzymatic hydrolysis rate constant for the first stage of hydrolysis and fina
98 tronic absorption spectrum and calculate the rate constant for the photolytic process HNO(3) + hnu ->
100 ignal in the hypoperfused myocardium, K (1) (rate constant for transfer from arterial plasma to tissu
101 the proton-coupled electron transfer (PCET) rate constants for a series of biomimetic oligoproline p
102 We experimentally parameterized conditional rate constants for aqueous U uptake, dietary U uptake, a
106 rmodynamic equilibrium constants and kinetic rate constants for complex, multiple-step biological int
107 ted at unconfined type-(i) environments, the rate constants for cyclohexene epoxidation (323 K, 0.05
108 ping peptides that cover the whole sequence, rate constants for each amide hydrogen exchange (or equi
111 e more than 100 ab initio computed (MP2:DFT) rate constants for H-SSZ-13 are used in a batch reactor
112 ted a three-step model and provided apparent rate constants for intermediate formation (i.e. a k'(2)
114 o examine whether the experimentally derived rate constants for N. triangulifer could be generalized
116 es of anthracene-phenol-pyridine triads give rate constants for PCET charge recombination that are sl
117 ed with gamma-terpinene concentration, while rate constants for radical-trapping were unchanged by ga
118 generate statistically unbiased estimates of rate constants for rare events such as folding; no biasi
119 ion, with observed decreases consistent with rate constants for reactions of the compounds with hydro
121 vibronically nonadiabatic PCET theory yield rate constants for simultaneous tunneling of the electro
124 drogen-bonding equilibrium constants and the rate constants for the PCET event from deconvolution of
131 ficient [Formula: see text] and with the ORR rate constant [Formula: see text] in nonaqueous Li-, Na-
132 8 in LUFA 2.2 soil decreased the dissolution rate constant from 0.56 mol(1/3).kg(1/3).s(-1) to 0.17 m
133 dictions and experimentally measured removal rate constants from the water column were strongly corre
135 d in good agreement with the model peptide's rate constant, highlighting the potential of using model
136 omparison with the experimentally determined rate constant in aqueous solution yields a k(calculated)
137 scaffold, were noted, with the second-order rate constant in cycloadditions with diazoacetamides exc
138 By comparison, related intramolecular ET rate constants in very similar constructs were reported
142 e air-water interface, a lower limit for the rate constant is k = 1.2 x 10(-9) cm(3).molecule(-1).s(-
143 inetic histogram "number of cells versus the rate constant" is used to determine quantitative paramet
144 can be explained by a wide variation of the rate constant k Additionally, by developing a mathematic
145 ism, the new 3-step mechanism being: A -> B (rate constant k(1)), A + B -> C (rate constant k(2)), an
146 ng: A -> B (rate constant k(1)), A + B -> C (rate constant k(2)), and A + C -> 1.5C (rate constant k(
147 > C (rate constant k(2)), and A + C -> 1.5C (rate constant k(3)), where A represents the monomeric na
148 ), propagation oxidizability R(n), composite rate constant k(c), and LOOH decomposition rate constant
151 d by induction period IP, overall initiation rate constant k(IP), initiation oxidizability O(i), and
153 fluorescence (TADF) emitter with a radiative rate constant k(r) of ca. 9 x 10(5) s(-1), exceeding tho
154 facial enhancement in the observed catalytic rate constant k(s) (~5 orders of magnitude) over the mon
155 odels was performed to calculate the kinetic rate constants K (1), k (2), k (3), and k (4) The analys
157 mpd-II(LutH(+)) reacts with the second order rate constants k(2)(9,10-dihydroanthracene; DHA) = 0.485
158 -1.17), the apparent second-order hydroxide rate constant (k(1)('), rho = 0.87), the hydroxide-indep
159 wash-in and wash-out traces, the association rate constant (k(1)) is somewhat decreased for both AMT
160 MT and RMT in the S31N, but the dissociation rate constant (k(2)) is dramatically increased compared
161 veloped to quantify the SO(4)(*-) scavenging rate constant (k(=S)) for alumina, a naturally occurring
164 sfer NMR experiments to measure the exchange rate constant (k(ex)) of the imino protons in the unboun
165 ingle cardiomyocyte in terms of the apparent rate constant (k(f)) of the regeneration rate of ferroce
166 ar acids, which causes the oxidation by HOCl rate constant (k(HOCl)) to nearly double and oxidation b
172 molecule experiments, but motor reattachment rate constants (k (on)) are generally unknown, as they i
174 eased rapidly and irreversibly, with removal rate constants (k(H(2)O(2))) 17-73 times larger than air
176 ate law for both Mg anode materials, and the rate constants (k) depended upon the struvite layer morp
178 by IR spectroscopy, temperature-independent rate constants (k~1.4x10(-3) s(-1) ; half-life of ~8 min
179 ward volume transfer constant [K(trans)] and rate constant [K(ep)]) and apparent diffusion coefficien
181 PFA, with determined ICT-based inactivation rate constants, k(d), of 1.024 +/- 0.038 L/(mg.min) and
182 K(eq), that span ~6 orders and dissociation rate constants, k(diss), that span ~7 orders of magnitud
183 epsilon decreases with increasing reduction rate constants normalized by cell density and initial U(
184 f ligand binding in the MFED and the kinetic rate constants observed agree with independent measureme
185 )O, and HOCl were computed from experimental rate constants obtained at various pH values, [Cl(-)], a
186 y chain-carrying HO(2)(*) occurs with a high rate constant of >=6 x 10(8) M(-1) s(-1) (toluene).
187 ion of sulfinate is also significant, with a rate constant of (4.1 +/- 0.6) x 10(6) M(-1) s(-1) in me
188 emely fast redox kinetics (electron-transfer rate constant of 0.32 cm s(-1) ), excellent stability in
189 ) undergoes cyclopropane ring opening with a rate constant of 1.7 x 10(8) s(-1), demonstrating that l
190 acts with internalized NO with a bimolecular rate constant of 10(10) M(-1) s(-1) forming nitrate, whi
191 with the cysteine of GSH, with a calculated rate constant of 2 x 10(5) m(-1) s(-1) (pH 8.0, 23 degre
192 boxyl moieties of Finland trityl with a high rate constant of 3.53 x 10(8) M(-1) s(-1), leading to a
194 e-lapse fluorescence microscopy to measure a rate constant of a catalytic reaction in individual cell
195 nts is robust, with an intrinsic association rate constant of a magnitude similar to that mediating m
197 well-mixed ODE model is that the association rate constant of binding reactions is multiplied by a co
201 fficient (D), rate of nucleation (N(0)), and rate constant of electrolyte decomposition (k(SEI)), can
202 In apple and orange juices, the reaction rate constant of glucosone formation was found higher th
205 terms of initial hydrolysis rate, r(0), and rate constant of hydrolysis, k(h), and enzyme inactivati
206 ent removal kinetics with a maximum apparent rate constant of k ~1 x 10(4) M(-1) s(-1) at pH >= 9.
208 n undergoes cyclopropane ring opening with a rate constant of only 4.1 x 10(4) s(-1), too slow to com
210 the distal histidine (His211); (2) The decay rate constant of the ferryl intermediate is not strongly
212 nsitivity across all species was the killing rate constant of the GUTS-RED-SD model (the reduced gene
213 tions (k(H)) of 10(5) s(-1) and the reaction rate constant of the phenoxy radicals (k(R)) in the orde
215 the QDs with isonicotinic acid increases the rate constant of this reaction by a factor of 2.4 by col
217 l indicated a relatively low estimate of the rate constant of tracer trapping, suggesting that the 1-
220 in a sequence of second-order reactions with rate constants of 4.0 +/- 0.4, 2.7 +/- 0.3, and 0.28 +/-
221 erved for carbon-normalized photodegradation rate constants of atorvastatin, carbamazepine, and venla
222 tivariate models to predict the second order rate constants of bioorthogonal inverse-electron demand
224 f this work, including oxidation bimolecular rate constants of CPA and CPA analogs (~9 x 10(8) to 4 x
226 r the first time that the pseudo-first-order rate constants of fast bimolecular processes in solution
227 dical clocks have been used to determine the rate constants of HAT reactions (k(H)), but no radical c
228 ange of conditions allowed estimation of the rate constants of PAA with (*)OH (k((*)OH/PAA) = 1.3 +/-
230 constants between DNA and Ag(+), the kinetic rate constants of sequence-specific Ag(+) reduction path
239 s utilized to determine kinetic profiles and rate constants of the reaction uncovering o-quinone meth
241 egradation, and DNA damage repair) and using rate constants of these reactions to establish accurate
245 xponential voltage-dependent gating variable rate constants, parameterized to fit experimental iPSC-C
248 om 50 to 510 mg L(-1) d(-1), and first-order rate constants ranged from 60 to 400 d(-1), which agree
249 alues characterizing the extraction process (rate constants ranging from 0.21 to 0.01 min(-1) for the
250 y present in the catalyst resting state, the rate constants reflect confining environments exclusivel
251 erature effect on the kinetic parameters and rate constants representing lipid hydroperoxides (LOOH)
254 tion of the relevant equilibrium binding and rate constants requires the appropriate analysis of not
256 molecular dynamics simulations predict that rate constants should be exquisitely sensitive to the ch
257 measured their (1)O(2) bimolecular reaction rate constants, showing slow photooxidation under enviro
258 pon hydroxylation, oxidation occurred with a rate constant similar to the k (cat) The structure of As
259 We find that post-replication remethylation rate constants span approximately two orders of magnitud
261 encounter duration rather than a standard on-rate constant, suggesting that membrane fluidity and dyn
263 Gln intracellular transport, was the kinetic rate constant that was most correlated both with SUV at
265 , glutamate binding with a diffusion-limited rate constant to iGlu(h) and Fl-GluBP is detected for th
266 e parent ferrocene, leading the dissociation rate constant to increase by several orders of magnitude
267 planation for the greater sensitivity of the rate constant to the carboxylate basicity than to the re
269 is provided well-constrained values for nine rate constants to establish a complete free-energy profi
270 s, enabling the large range in deadenylation rate constants to impart a similarly large range in stab
271 ial selection is achieved by larger backward rate constants toward TC dissociation rather than by a s
272 ecies have an enhanced catalytic impact with rate constants up to 1000 times larger than would be est
273 s utilized to predict the ratio of quenching rate constants upon changing the PC, enabling selection
274 ree descriptors with experimental activation rate constants using multivariate linear regression.
276 arison with a water-benzene mixture, and the rate constant values depend on the type of surfactant us
278 r, the magnitude and accuracy of the binding rate constant-values was highly dependent on the used ra
279 critical for NO(2)(-) precursor ions, whose rate constant varied as a function of NO(2) concentratio
281 n of the fluorenyl-benzoate follows the same rate constant vs driving force trend determined for ther
284 d transducers - k(o) (standard heterogeneous rate constant) was 2.56 x 10(-3) cm(2)/s (nu = 100 mV/s
285 ddition to establishing a HuNoV inactivation rate constant, we developed an approach using a single q
288 and, binding (k'(on)) and unbinding (k(off)) rate constants were extracted from (1)H-(1)H exchange sp
290 as well as actin-activated phosphate release rate constants were not significantly different from WT.
293 less shallow distance dependence of the PCET rate constant when imidazole rather than hydrogen phosph
294 ration efficiency, there was a wide range of rate constants when incorporating a correct nucleotide o
295 e maximum ATP hydrolysis and recovery-stroke rate constants, whereas the F750L mutation enhanced thes
296 e a broad (1000-fold) range of deadenylation rate constants, which correspond to cytoplasmic lifetime
297 for this metal, (ii) the first-order in-line rate constant with respect to divalent cations is >200 t
298 nopeptidase showed second-order inactivation rate constants with (1)O(2) comparable to those of free
300 s useful to quantify the interaction kinetic rate constants without using the traditional single-mole