ライフサイエンスコーパス: reaction kinetics

1 stals requires atomic-level understanding of reaction kinetics.

2 el up to 5 mM had a negligibly effect on the reaction kinetics.

3 iation with a mathematical model of chemical reaction kinetics.

4 articularly suited for in situ monitoring of reaction kinetics.

5 sis method was used to delineate the complex reaction kinetics.

6 unting for the gain-of-function and improved reaction kinetics.

7 diate products, time-dependent processes and reaction kinetics.

8 making it possible to estimate the observed reaction kinetics.

9 etect RNA reactivity could bias the observed reaction kinetics.

10 ntrol over heat and mass transfer to control reaction kinetics.

11 played an important role in the ring-opening reaction kinetics.

12 in-8, cannot be explained by simple chemical reaction kinetics.

13 similarity in reactivity is due to very fast reaction kinetics.

14 f ligands to the NC surface, and the surface reaction kinetics.

15 nfluencing the gluconeogenic and anaplerotic reaction kinetics.

16 n mechanism and accurately measure electrode reaction kinetics.

17 transfer (smFRET) study of the dimerization reaction kinetics.

18 t indoor temperatures and RHs did not affect reaction kinetics.

19 n be modelled using stress-assisted chemical reaction kinetics.

20 tamin A but with a lower affinity and slower reaction kinetics.

21 mediated strand displacement for controlling reaction kinetics.

22 en heat transfer, fluid dynamics and surface reaction kinetics.

23 e migration of Na ions and thus the alloying reaction kinetics.

24 classical mass-action principles in modeling reaction kinetics.

25 unclear exactly how microorganisms influence reaction kinetics.

26 foundational knowledge regarding its surface reaction kinetics.

27 into the holding coil to accelerate the slow reaction kinetics.

28 er a period of 12h both followed first order reaction kinetics.

29 mediate, consistent with the analysis of the reaction kinetics.

30 P), k(CT), k(-CT)) and used to model overall reaction kinetics.

31 ation, regulate barrier height, and modulate reaction kinetics.

32 Temperature changes affect reaction kinetics.

33 rates, and analysis of steady-state and half-reaction kinetics.

34 racentrifugation, and steady-state and rapid-reaction kinetics.

35 n interpreted in terms of simple bimolecular reaction kinetics.

36 we used this probe to monitor single Pb(2+) reaction kinetics.

37 to control, often resulting in inconsistent reaction kinetics.

38 ituent effects in molecular interactions and reaction kinetics.

39 ar dynamics to kinetics) for QM-ReaxFF-based reaction kinetics.

40 ile maintaining efficient mass transport and reaction kinetics.

41 catalysis, electro-catalysis, and transient reaction kinetics.

42 an input L/Pd ratio of <<1 with no impact on reaction kinetics.

43 es, but a significant limitation is its poor reaction kinetics.

44 ature of substrate can have large effects on reaction kinetics, all controlled by selective molecular

45 the diiron complex taken as an example, the reaction kinetics analysis, including the H/D isotope ef

46 Informed by reaction kinetics analysis, relevant dinuclear Pd(III) c

47 ependency significantly influences the gross reaction kinetics and accounts for the observed nanoconf

48 Study of the reaction kinetics and aggregation behaviour suggests a m

49 Moreover, we use the system to determine reaction kinetics and argue how the multipoint detection

50 greater resistance to pulverization, faster reaction kinetics and better trapping of soluble polysul

51 The reaction kinetics and catalyst composition were studied

52 py, we observed deuteroxyl radical (OD) + CO reaction kinetics and detected stabilized trans-DOCO, th

53 Reaction kinetics and DFT calculations shed light on the

54 Temperature influences the reaction kinetics and evolvability of all enzymes.

55 Transition state theory fails to capture the reaction kinetics and explain the observed stereochemica

56 E to yield a variant (TES148C) with improved reaction kinetics and gain-of-function processing of an

57 The reaction kinetics and half-life for beta-carotene, lutei

58 e interfacial reaction area, leading to fast reaction kinetics and high reaction reversibility.

59 es with 2-aminoimidazole results in superior reaction kinetics and improved yields of primer extensio

60 rate constant, k, measures intracellular CK reaction kinetics and is independent of myocyte number w

61 rmination of substrates with unknown surface reaction kinetics and large topographical features.

62 mum active region suggests that the surface reaction kinetics and lateral electron transport on the

63 strategies, including improved control over reaction kinetics and low synthesis temperatures, afford

64 r results provide a strong case of different reaction kinetics and mechanisms of reactions occurring

65 knowledge of reactive species generation and reaction kinetics and mechanisms under UV/PAA, and provi

66 Reaction kinetics and mechanistic studies for ethylene-i

67 that PhqK can react with various substrates, reaction kinetics and molecular dynamics simulations ind

68 Although the reaction kinetics and molecular recognition of a few ind

69 thesis, involving initiation, control of the reaction kinetics and molecular structures, functionaliz

70 acity of 1,327 mAh/(g of S), along with fast reaction kinetics and negligible polysulfide dissolution

71 coefficient measurements are needed, such as reaction kinetics and particle size determinations.

72 Understanding the potential reaction kinetics and pathways of Cr(VI) remediation pro

73 enabling the observation of single disulfide reaction kinetics and pathways on a plasmonic nanopartic

74 Analysis of reaction kinetics and product distribution in channel mu

75 Here, we explore the reaction kinetics and products of key radicals in benzen

76 insights into the mechanism of this process, reaction kinetics and products were determined employing

77 y a reduction method, extending the study of reaction kinetics and providing a new way to synthesize

78 This transformation exhibits bimolecular reaction kinetics and represents a key step in a propose

79 of DASAs in solution, uniquely controllable reaction kinetics and resulting spatially-confined photo

80 We have examined the rapid reaction kinetics and spectroscopic properties of the mo

81 ystem, both mechanisms operate; however, the reaction kinetics and the antioxidant efficacy depend on

82 heoretical support for the simplification of reaction kinetics and the approximation of reactive zone

83 antioxidant compounds followed a first-order reaction kinetics and the degradation rate constants (k)

84 der highly alkaline conditions afford faster reaction kinetics and the deployment of inexpensive elec

85 A method for monitoring photochemical reaction kinetics and the dynamics of molecular excitati

86 lation, we need to understand GTP hydrolysis reaction kinetics and the GTP cap size.

87 Changes in the reaction kinetics and the ionic/nonionic nature of the T

88 degree, on which the interaction between the reaction kinetics and the network structure organise the

89 Degradation followed first-order reaction kinetics and the temperature-dependence of the

90 is known about how these assemblies modulate reaction kinetics and the ultimate propagation of signal

91 ductance switching allows the study of redox reaction kinetics and thermodynamics at single molecular

92 is in a lifeless environment are dictated by reaction kinetics and thermodynamics, so concentrations

93 oparticle surface, both of which control the reaction kinetics and thus enable the selective synthesi

94 parameters to quantitatively manipulate the reaction kinetics and thus the lower and upper limits th

95 ically elucidating parameters that influence reaction kinetics and total conversion, and highlighting

96 Through the control of reaction kinetics and vascular delivery rate, we filled

97 zacyclooctynone (BARAC) that has exceptional reaction kinetics and whose synthesis is designed to be

98 through an isotherm study, a column study of reaction kinetics, and a microstructure examination unde

99 sarily limited by the size of the electrode, reaction kinetics, and duration of the rest period.

100 rt of O(2-) anions, drastically improves the reaction kinetics, and enables the electrolysis at low t

101 e reagent and sample consumption, accelerate reaction kinetics, and enhance the sensitivity and speci

102 ide improved reaction safety and accelerated reaction kinetics, and have synthesised several active p

103 by computational modeling and a study of the reaction kinetics, and is also consistent with observed

104 r also results in phenomenologically simpler reaction kinetics, and overall these features have facil

105 king into account volume variation, chemical reaction kinetics, and passive transport across the memb

106 s supported by the reaction products formed, reaction kinetics, and quantum mechanical calculations.

107 n of the electrolyte, enhances the electrode reaction kinetics, and reduces the interface resistance

108 ffusion, molecular transport and biochemical reaction kinetics, and regulation of biomolecular intera

109 enables a closed form solution for ITP-aided reaction kinetics, and reveals a new characteristic time

110 hodes in terms of liquid-species clustering, reaction kinetics, and solid deposition.

111 tudies of chemical and biological systems as reaction kinetics are almost universally sensitive to te

112 Reaction kinetics are described by a rapid, low-fraction

113 The experimentally obtained reaction kinetics are discussed in light of molecular mo

114 roducts is obfuscated by labels, however, as reaction kinetics are inevitably perturbed.

115 vacancies and the mechanism determining the reaction kinetics are still unknown.

116 These experiments measure reaction kinetics as a function of applied force.

117 By studying the reaction kinetics as a function of average coating thick

118 with BaOCH3(+) Further investigations of the reaction kinetics as a function of collision energy over

119 ITP accelerates the reaction kinetics as the ionic spacer concurrently separ

120 g their extent can provide more insight into reaction kinetics as well as instrument operation.

121 Multiphase reaction kinetics at gaseous ozone concentrations of 131

122 0.1), that greatly improved oxygen reduction reaction kinetics at intermediate to low temperatures.

123 We successfully applied a reaction kinetics based combined hydrolysis factor (CHFX

124 A reaction kinetics based modeling of the edge-oriented 3D

125 In this paper, we present a reaction kinetics-based technique that solves this probl

126 er density and accelerated surface oxidation reaction kinetics become the key points for improved pho

127 immunosensor was developed to elucidate the reaction kinetics between a protein of unknown function

128 However, the reaction kinetics between a solution-phase mediator and

129 Analysis of reaction kinetics between CCl(4) and AA revealed an over

130 y hydrogen and fluorine plasmas, much slower reaction kinetics between the chlorine plasma and graphe

131 Through the combination of reaction kinetics (both catalytic and stoichiometric) an

132 Through the combination of reaction kinetics (both stoichiometric and catalytic), s

133 Ni(Fe)OOH is found to exhibit the fastest reaction kinetics but accumulates fewer states, resultin

134 ornerstone to enhance intrinsically sluggish reaction kinetics but the true active phases are often c

135 Removal of nitrite does not alter reaction kinetics, but modulates reaction products, with

136 that an aprotic organic solvent affects the reaction kinetics by changing the stabilization of the a

137 ss has been made toward analyzing more rapid reaction kinetics by ITC, the capabilities and limitatio

138 rbon surface, which synergistically promotes reaction kinetics by providing more exposed active sites

139 ynergistically combine to accelerate surface reaction kinetics by several orders of magnitude.

140 echanism of an enzymatic catalytic cycle and reaction kinetics can be engineered by modification of p

141 whole statistical mechanical description of reaction kinetics can be re-formulated via a mechanical

142 ough TA-Fe(3+) coordination, where the rapid reaction kinetics can benefit from efficient mixing of a

143 The reaction kinetics consisted of a pre-steady-state burst

144 etic resolution, how chemical anisotropy and reaction kinetics coordinate to generate highly ordered

145 action, we demonstrated that its first-order reaction kinetics could be accurately determined from th

146 for OPFRs are explored by investigating the reaction kinetics, degradation chemical mechanisms, and

147 e, mutagenesis combined with single-turnover reaction kinetics demonstrate that point mutations in th

148 However, differences in the reaction kinetics demonstrate that the mechanism of Pu(V

149 -ligand pair is determined by monitoring the reaction kinetics, demonstrating that silicon nanowire f

150 Reaction kinetics depend heavily on template length and

151 the diaurated intermediates with the overall reaction kinetics determined by NMR spectroscopy.

152 Here, using partial reaction kinetics determined via stopped-flow experiment

153 A novel DFT-based Reaction Kinetics (DFT-RK) simulation approach, employed

154 Reaction kinetics differ significantly between the K- an

155 copy is frequently used in the monitoring of reaction kinetics, due to its nondestructive nature and

156 ty, the two parameters governing the surface-reaction kinetics during growth, govern the structural q

157 ese volatiles was performed to compare their reaction kinetics during storage in differently sterilis

158 itory effect of hydrogen was observed on the reaction kinetics, effectively raising the apparent acti

159 We investigated NO reaction kinetics, effects on arterial NO signaling, and

160 main numerical model to effectively describe reaction kinetics either with distinctive apparent rate

161 Appropriate control of reaction kinetics enables the 2D morphology of the NPLs

162 nderstanding the synthesis mechanism and the reaction kinetics enables the rational, template-free sy

163 odel based on protonation-dependent chemical reaction kinetics established previously.

164 nctional theory (DFT-GGA-PW91) calculations, reaction kinetics experiments on a SiO2-supported Pd cat

165 y of model parametrizations of heterogeneous reaction kinetics focus on the population average of aer

166 reducing energetic barriers and accelerating reaction kinetics for catalyzing the oxygen evolution.

167 The observed reaction kinetics for loss of THC on glass and cotton su

168 the freeze-concentration effect in altering reaction kinetics for processes occurring in environment

169 The mechanism involves first-order reaction kinetics for the conversion of either the (C7-R

170 Reaction kinetics for the formation of CO are strongly d

171 Reaction kinetics for the reactions between four polyphe

172 elaxation of the standard constraints on the reaction kinetics for the Turing instability, increasing

173 S setup, we describe how one can extract the reaction kinetics from diffusion-coupled correlation cur

174 haSyn aggregates but with markedly different reaction kinetics from MSA; aggregation occurred later,

175 served, and indirect determinations of their reaction kinetics gave derived rate coefficients spannin

176 Controlling the reaction kinetics gives rise to enhanced separation effi

177 hase solid-solution pathway with exceptional reaction kinetics has been predicted to increase with de

178 ycloheptene) have been investigated, and the reaction kinetics have been analyzed.

179 uct can be advantageous in terms of improved reaction kinetics, higher yields, and selectivity.

180 n CO concentration was observed in the rapid reaction kinetics, however, suggesting that CO initially

181 mental confirmation to the theory describing reaction kinetics in a segregated flow system.

182 nce of facet capping, surface diffusion, and reaction kinetics in controlling the morphologies of bim

183 kinetics are more robust against changes in reaction kinetics in HCT-116 and HeLa than in DLD-1 cell

184 dramatically change molecular transport and reaction kinetics in heterogeneous catalysis.

185 we monitored GOx-assisted and GOx-free ATRP reaction kinetics in real time using quartz crystal micr

186 te the intrinsic mechanism that permits fast reaction kinetics in smaller nanoparticles.

187 ons or molecular interpretation of localized reaction kinetics in stretched polymers may require expl

188 rgies to some key reaction intermediates and reaction kinetics in the HER process.

189 Cyclopropene exhibited fast reaction kinetics in the photoclick reaction and allowed

190 We propose the slowing of enzyme reaction kinetics in the smaller droplets was the result

191 was developed with real time measurement of reactions kinetics in bulk reactors in mind, and was che

192 orescence imaging permits the measurement of reaction kinetics inside living organisms with minimal p

193 story and current situation, and discuss the reaction kinetics involved in DIBs, including various an

194 However, reaction kinetics involved in the precipitation of carbo

195 necessary to couple the physical chemistry, reaction kinetics, ion flow, heat generation, et cetera,

196 Tuning of the reaction kinetics is accomplished by balancing inhibitor

197 control through the synthesis conditions and reaction kinetics is an effective route to manipulate NC

198 ically active phases, which is controlled by reaction kinetics, is different.

199 Evaluation of reaction kinetics, isotope effects, and commitment-to-ca

200 reduced steric hindrance, Sph exhibited fast reaction kinetics (k2 up to 34,000 M(-1) s(-1)) in the p

201 xchange or alkene insertion, as supported by reaction kinetics, kinetic isotope effects, and isotopic

202 Their sluggish reaction kinetics lead to inefficient energy conversion.

203 139.2 kJ/mol), these catalysts display rapid reaction kinetics, leading to relatively low polydispers

204 ermore, thermodynamic computations show that reaction kinetics likely played a significant role in ou

205 ne, respectively) were always transport- and reaction/kinetics-limited within floodplain surface wate

206 ting the behavior of breast cancer cells via reaction kinetics may help unravel the mechanisms that u

207 Gas-phase reaction kinetics measurements in conjunction with first

208 Reaction kinetics measurements under steady-state and tr

209 Along with numerical simulation of a reaction kinetics model, the assay permits quantitative

210 tions for microwave heating and the chemical reaction kinetics model.

211 transformation pathways in combination with reaction kinetics models.

212 The N=P formation reaction kinetics obey the conventional Staudinger react

213 y, but there remain open questions about the reaction kinetics of (3)CDOM* with HDA due to the diffic

214 Enzyme-substrate reaction kinetics of AAO were described using Michaelis-

215 We measured reaction kinetics of calf intestinal alkaline phosphatas

216 edict FC concentration based on modeling the reaction kinetics of chlorine and amino acids.

217 cal catalysts to improve the selectivity and reaction kinetics of CO(2) reduction.

218 The reaction kinetics of DPPH scavenging activity in each st

219 In this study, the reaction kinetics of Fe(3+)-saturated montmorillonite ca

220 hodology we use is measuring a change in the reaction kinetics of ferro-ferricyanide redox couple at

221 Singlet oxygen ((1)O2) reaction kinetics of individual photooxidizable residues

222 A new method to investigate the reaction kinetics of intermediates in solution by electr

223 der temperatures might result from different reaction kinetics of nitrifying taxa, or that other orga

224 III) bioreduction, we investigated the redox reaction kinetics of reduced flavin mononucleotide (i.e.

225 arget sequence specificity, selectivity, and reaction kinetics of Streptococcus pyogenes Cas9 activit

226 The transient decay reaction kinetics of the 1,1,2,2-(2)H(4)-aminoethanol ge

227 The reaction kinetics of the copolymerization of carbon diox

228 The reaction kinetics of the dimer dissociation in a Zeonex

229 Here, we report production and reaction kinetics of the next larger Criegee intermediat

230 The temperature dependence of the reaction kinetics of the Rubisco enzyme implies that, at

231 n reactions and can be used to determine the reaction kinetics of these reactions.

232 pression and pressure-induced polymerization reaction kinetics of two polycyclic 1:1 arene-perfluoroa

233 . coli RNase P, we compared the steady state reaction kinetics of two ptRNAs that differ at sequences

234 ucidate the reaction mechanisms and simulate reaction kinetics of UV/PAA process.

235 Solid-state reaction kinetics on atomic length scales have not been

236 Herein we report detailed reaction kinetics on low-temperature standard NH3-SCR, s

237 Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologie

238 R measurements suitable for determination of reaction kinetics on time scales of 100 ms or longer hav

239 drawbacks, like hydrolytic instability, slow reaction kinetics or not readily available labeling reag

240 Reaction kinetics parameters obtained experimentally wer

241 res for developing microkinetic models using reaction kinetics parameters obtained from experimental

242 mbustion reaction and verifies that chemical reaction kinetics play a major role in determining the g

243 tely assessed due to the lack of data on the reaction kinetics, products, and toxicity associated wit

244 On-protein reaction kinetics reveal a rapid reaction with rate cons

245 The reaction kinetics reveal that Msh2-Msh6 binds a variety

246 Hammett analysis of the reaction kinetics revealed positive charge accumulation

247 on the Keggin surfaces, its influence on the reaction kinetics seems minimal as the carbon content di

248 els-Alder reactions owing to their excellent reaction kinetics, selectivity, and biocompatibility.

249 Assessment of the reaction kinetics showed zero-order in both the aziridin

250 reactions, together with its practical side (reaction kinetics simulations of real experimental condi

251 Thus, the reaction kinetics slow by a factor of 25 when substituen

252 reveal that compressive stresses change the reaction kinetics so that preferential lithiation occurs

253 led level the observed chemistry in terms of reaction kinetics, structure, and reactivity, and thus f

254 Reaction kinetics studies of the Bronsted acid-catalyzed

255 y manipulating crystal shape and solid-state reaction kinetics suggests that photoreactive molecular

256 Analysis of the binding reaction kinetics suggests the involvement of cation-pai

257 n but also accelerated the surface oxidation reaction kinetics, synergistically contributing to the i

258 lvents were found to be better predictors of reaction kinetics than calculated electrostatic potentia

259 ly favorable reaction and potentially faster reaction kinetics than the parent BH(4) (-) centers.

260 ty with TcO4(-) and CrO4(2-) and much slower reaction kinetics than those measured in studies with bi

261 ly because of the difficulty in establishing reaction kinetics that favors dopant incorporation by us

262 rovide an additional channel to describe the reaction kinetics that lead to ECL; good agreement was f

263 s have finally allowed to implement in-vitro reaction kinetics (the so called enzyme based logic) whi

264 To further enhance reaction kinetics, the designed (N,PO(4) (3-) )-MoS(2) n

265 By carefully controlling the reaction kinetics, the newly formed Ag atoms could be di

266 bromination is well explained by first-order reaction kinetics, thermodynamics prevail on Au(111), un

267 Reaction kinetics, thermodynamics, electrochemistry, EPR

268 phosphine probe because, despite their slow reaction kinetics, they remain the best-performing reage

269 In contrast, label-free biosensors measure reaction kinetics through direct binding, and with highe

270 well-controlled conditions, thereby allowing reaction kinetics to be followed and Arrhenius activatio

271 t merging for applications ranging from fast reaction kinetics to microfluidic high throughput screen

272 es of preconcentration, mixing, and chemical reaction kinetics under ITP.

273 ature heater by modulating the lithium-water reaction kinetics using bubbles in a channel.

274 We report a method to control reaction kinetics using electrochemically responsive het

275 t absolute binding free energies and analyze reaction kinetics using Markov state models and Perron-c

276 es on a reduced scale, spanning the study of reaction kinetics using on-chip liquid-liquid extraction

277 ct of particle mixing state on heterogeneous reaction kinetics using the N2O5 reactive uptake coeffic

278 Real-time evaluation of the reaction kinetics was accomplished by monitoring change

279 flow microreactor a detailed analysis of the reaction kinetics was performed.

280 's chemical properties and solvent-dependent reaction kinetics, we demonstrate its use for photo-cont

281 Informed by studies of reaction kinetics, we show that divergent sequence selec

282 Biexponential reaction kinetics were observed for all pressures, consi

283 e-turnover kinetic measurements, multiphasic reaction kinetics were observed for several uracil sites

284 Reaction kinetics were studied to quantify the effects o

285 irborne merged microdroplets to, e.g., study reaction kinetics when reaction times are short relative

286 Our data enabled quantitative modeling of reaction kinetics, which revealed that dynamic competiti

287 of the metal oxide, follow Mars-van Krevelen reaction kinetics, which utilize lattice oxygen atoms to

288 ht mass spectrometer, which permits study of reaction kinetics with a time between reaction initiatio

289 cle simulation package combining off-lattice reaction kinetics with arbitrary particle interaction fo

290 al propagons by comparing the multiplication reaction kinetics with controlled seeding data.

291 and UV/H(2)O(2) exhibited pseudo-first-order reaction kinetics with half-lives ranging from 3.0 to 9.

292 le modeling scheme that integrates ab initio reaction kinetics with mass transport simulations, expli

293 The oxime ligation demonstrates tunable reaction kinetics with pH and buffer strength, which ind

294 let oxygen ((1)O2) and analyzed the oligomer reaction kinetics with reverse transcription quantitativ

295 ffusion and adsorption of the gas during its reaction kinetics with the sensitive film itself.

296 Hammett analysis of reaction kinetics with these substrates is consistent wi

297 en investigated using steady-state and rapid reaction kinetics, with pH, substrate and solvent deuter

298 tensive characterization of enzyme-inhibitor reaction kinetics within a single experiment by tracking

299 active transients and determine the chemical reaction kinetics without the need for extensive scatter

300 ysts was investigated using a combination of reaction kinetics, X-ray crystallography, NMR spectrosco