ライフサイエンスコーパス: rotaxane

1 mes longer, reaching 60 degrees C in the C24 rotaxane.

2 synthesis of a chain-centered macromolecular rotaxane.

3 d allowed the quantitative deslipping of the rotaxane.

4 s drive the assembly and replication of a [2]rotaxane.

5 f the wheel on the axle of the metal-free [2]rotaxane.

6 he rhenium(I) chlorocarbonyl complex of this rotaxane.

7 ane, a [2]rotaxane, and a doubly threaded [3]rotaxane.

8 y indicated by fluorescent changes of the [3]rotaxane.

9 yl) ether to efficiently provide up to a [20]rotaxane.

10 scence quantum yield upon encapsulation as a rotaxane.

11 synthesis of a series of [2]-, [3]-, and [4]rotaxanes.

12 taxanes into still larger [4]-, [5]- and [7]-rotaxanes.

13 topper groups provide efficient access to [n]rotaxanes.

14 ties residing in the resulting catenanes and rotaxanes.

15 backward in a homologous series of bistable rotaxanes.

16 e interactions between the components of the rotaxanes.

17 ions of the fully oxidized forms of these [2]rotaxanes.

18 hylene chain lengths across the series of [2]rotaxanes.

19 trapped on the dumbbell components of the [4]rotaxanes.

20 gh nanotubes to the formation of chromogenic rotaxanes.

21 cycle provides access to a modular series of rotaxanes.

22 -triazole product to give instead acrylamide rotaxanes.

23 scale translational movement in two bistable rotaxanes.

24 The [4]-rotaxane 3 is an isosceles triangle of three [2]-rotaxan

25 bound to the central triangle while the [3]-rotaxane 4 contains only two [2]-rotaxanes bound to the

26 The chemical structure is based on a rotaxane, a molecular ring threaded onto a molecular axl

27 ivity as a catalyst (2-14 % ee), whereas the rotaxane affords selectivities of up to 40 % ee with swi

28 T) processes by fixing the fluorophores in a rotaxane and (iv) establishing the principle of supramol

29 etween the components of this supramolecular rotaxane and are important for the development of materi

30 thogonal recognition-mediated processes, the rotaxane and thread can act as auto-catalytic templates

31 s with a stoppering maleimide group, forming rotaxane and thread, respectively.

32 simulations of the tristable and bistable [2]rotaxanes and [2]catenane reveal a mechanism which invol

33 Rotaxanes and catenanes are the leading examples of inte

34 synthesis and photophysical investigation of rotaxanes and catenanes decorated with peripheral electr

35 distinct molecular conformations adopted by rotaxanes and catenanes in the electron transfer dynamic

36 The assembly of our rotaxanes and catenanes is based on the classic 1,10-phe

37 work has led from the reliable synthesis of rotaxanes and catenanes to molecular rotary motors, shut

38 that upon excitation, our multichromophoric rotaxanes and catenanes undergo a cascade of sequential

39 mechanically interlocked compounds, such as rotaxanes and catenanes, the molecules are held together

40 arger interlocked dsDNA nanostructures, like rotaxanes and catenanes, to achieve diverse mechanical o

41 ked molecules (MIMs)--specifically, bistable rotaxanes and catenanes--which exhibit reset lifetimes b

42 aromatic residues in contiguous rings in the rotaxanes and consequently, a discrete rigid and rod-lik

43 d incorporated into hybrid organic-inorganic rotaxanes and into molecules containing up to 200 metal

44 as a result of orthogonal templation, two [4]rotaxanes and one [5]rotaxane in >90% yields inside 2 h

45 ed mechanism of switching of two bistable [2]rotaxanes and one bistable [2]catenane composed of CBPQT

46 Hybrid [2]rotaxanes and pseudorotaxanes are reported where the mag

47 Interlocked DNA rotaxanes and their different synthetic approaches are p

48 X-ray crystallographic analysis on six [2]rotaxanes and two [3]rotaxanes provides insight into the

49 structures that include a [2]catenane, a [2]rotaxane, and a doubly threaded [3]rotaxane.

50 Examples include the catenane, rotaxane, and knot interlocked structures.

51 hreading process, the half-life times of the rotaxanes, and the influence of temperature and solvents

52 es exist naturally in a threaded state as [1]rotaxanes, and we reasoned that lasso peptides cleaved i

53 Overall, these results suggest that the rotaxane architecture acts as a lever that accelerates t

54 eversible switching of a double-stranded DNA rotaxane architecture from a stationary pseudorotaxane m

55 erically protected from reprotonation by the rotaxane architecture, which renders the Cu(I)-C bond st

56 her based wheel along the axis of a bistable rotaxane are triggered by the decarboxylation of 2-cyano

57 Rotaxanes are a previously unexplored ligand architectur

58 The rotaxanes are formed within a few minutes simply through

59 Squaraine rotaxanes are mechanically interlocked molecules compris

60 The corresponding [2]rotaxanes are obtained by introduction of bulky stopperi

61 IPY(*+) radical cations in this series of [2]rotaxanes are stabilized against oxidation, both electro

62 Specifically, the use of the rotaxane as a scaffold to organize Au NP assemblies, and

63 organic framework by using an amide-based [2]rotaxane as linker and copper(II) ions as metal nodes.

64 biomimetic state for the tetradentate Cu(II) rotaxane, as well as the formation of stable Ni(I) speci

65 cle can be elongated after completion of the rotaxane assembly, giving rise to a unique structure tha

66 efficient syntheses of two catenanes and one rotaxane, assisted by radical-pairing interactions betwe

67 the pH actuation of the mechanically active rotaxane at the nanoscale influences the physical reticu

68 lly located chiral (S)-BINOL motif of the [3]rotaxane axle component facilitates the complexed dicarb

69 anes in one step, up to 95% yield and >100:1 rotaxane:axle selectivity, from primary amines, crown et

70 Two types of liquid crystalline [2]rotaxanes based on a conventional tetracatenar motif (a

71 We report a family of hybrid [2]rotaxanes based on inorganic [Cr(7)NiF(8)(O(2)C(t)Bu)(16

72 he near-quantitative aqueous synthesis of [2]rotaxanes based on neutral and charged aqueous hosts-cuc

73 port the synthesis and characterization of a rotaxane-based (129) Xe hyperCEST NMR contrast agent tha

74 A rotaxane-based Au catalyst was developed and the effect

75 t a series of tri-, tetra-, and pentadentate rotaxane-based ligands and a detailed study of their met

76 Increasingly complex rotaxane-based molecular devices are interfaced with pol

77 In spite of widespread interest in rotaxane-based molecular machines and materials, rotaxan

78 A rotaxane-based molecular shuttle has been synthesized in

79 A rotaxane-based switchable asymmetric organocatalyst has

80 synthesis and operation of a three-barrier, rotaxane-based, artificial molecular machine capable of

81 hreading of a series of succinamide-based [2]rotaxanes bearing benzylic amide macrocycles is reported

82 process to switch an appropriately designed rotaxane between prochiral and mechanically planar chira

83 e chalcogen atoms in the mechanically bonded rotaxane binding sites in organic and aqueous solvent mi

84 produce the first well-characterized protein-rotaxane bioconjugates.

85 xane 3 is an isosceles triangle of three [2]-rotaxanes bound to the central triangle while the [3]-ro

86 ile the [3]-rotaxane 4 contains only two [2]-rotaxanes bound to the central triangle.

87 as been previously used for the synthesis of rotaxanes but has not been applied to the development of

88 es of Coulombically challenged catenanes and rotaxanes, but it also opens up the possibility of synth

89 e topology and structural integrity of these rotaxanes by analyzing the intermediate and final produc

90 on of pH-sensitive bistable [c2] daisy chain rotaxanes by using copper(I)-catalyzed Huisgen 1,3-dipol

91 imetry (DSC) reveals that the longer polyyne rotaxanes (C16, C18, and C24) decompose at higher temper

92 m site located on the axle component of a [2]rotaxane can be reversibly modulated by changing the aff

93 However, the E-rotaxane can be smoothly converted into the Z-rotaxane i

94 donor recognition units in the tristable [2]rotaxane can prolong the lifetime and stability of the M

95 n demetalation the axle of a singly threaded rotaxane can slip through a macrocycle that is sufficien

96 These rotaxanes can be coordinated to [Cu(hfac)(2)] (where Hhf

97 For example, [4]rotaxanes can be prepared nearly quantitatively within a

98 e differences in the (1)H NMR spectra of the rotaxanes can be related to the presence of conformers i

99 Dynamic achiral [2]rotaxanes can show high isoselectivity (P(i) =0.8, 298 K

100 This "rotaxane-capping" protocol is significantly more efficie

101 binding catalysis sites of the dual-function rotaxane catalyst can be sequentially concealed or revea

102 e macrocycle dictates the facial bias of the rotaxane-catalyzed conjugate addition of aldehydes to vi

103 The ON-state of the rotaxane catalyzes the reduction of a nitrostyrene by tr

104 mechanically-interlocked molecules, such as rotaxanes, catenanes, Borromean rings, and Solomon knots

105 ulation experiments revealed that the chiral rotaxane cavity significantly enhances enantiodiscrimina

106 , structures, and properties of [4]- and [3]-rotaxane complexes are reported where [2]-rotaxanes, for

107 the nitrate and chloride halogen bonding [3]rotaxane complexes corroborate the (1) H NMR anion bindi

108 edox-active viologen subunits located on the rotaxane components can be accessed electrochemically in

109 subjected to redox control in a bistable [2]rotaxane comprised of a dumbbell component containing an

110 new means to control tacticity by exploiting rotaxane conformational dynamism is described.

111 Both rotaxanes consist of a tetra-amide macrocycle interlocke

112 mulated switching behavior of a tristable [2]rotaxane consisting of a cyclobis(paraquat-p-phenylene)

113 e structures and excited-state dynamics of a rotaxane consisting of a hexayne chain threaded through

114 A new copper-complexed [3]rotaxane consisting of two coordinating 30-membered ring

115 ling has been used to synthesize a series of rotaxanes consisting of a polyyne, with up to 24 contigu

116 A two-station [2]rotaxane, consisting of a dibenzo-24-crown-8 macrocycle

117 e) and the alpha-cyclodextrin-based pseudo[3]rotaxane containing axially chiral 1,1'-binaphthyl and p

118 However, the synthesis of a metal-free [2]rotaxane containing triazole with other functionalities

119 the present work, a novel photoresponsive [3]rotaxane containing two cucurbit[7]uril (CB[7]) rings an

120 irst examples of mechanically interlocked [2]rotaxanes containing ChB-donor groups are prepared via a

121 es of a family of structurally similar XB [2]rotaxanes containing different combinations of chiral an

122 sis and structural characterization of a [13]rotaxane, containing 150 metal centres.

123 The hetero[4]rotaxane contains an interlocked species in which a dibe

124 oninterlocked equivalent of the pentadentate rotaxane Cu(II) complex could be formed selectively, and

125 The phenanthrene rotaxane decomposes during attempted photochemical unmas

126 nt influence of the chiral macrocycle in our rotaxane design for determining the effectiveness of chi

127 We report on the synthesis of [2]rotaxanes driven by stabilization of the axle-forming tr

128 One of the new rotaxanes emits an orange light (560-650 nm), and there

129 ocycles produces the corresponding squaraine rotaxane endoperoxides (SREPs) quantitatively.

130 The [2]rotaxane exists in the ground-state co-conformation (GSC

131 We report on rotaxanes featuring a pyridyl-acyl hydrazone moiety on t

132 [4]Rotaxanes featuring three axles threaded through a singl

133 driven fluid delivery system and a squaraine rotaxane fluorophore, SeTau-647, as the fluorescent labe

134 dye completes the palette of known squaraine rotaxane fluorophores whose emission profiles span the c

135 scaffold, we employed a double-stranded DNA rotaxane for its ability to undergo programmable and pre

136 tailed investigation of the use of chiral XB rotaxanes for this purpose, extensive (1)H NMR binding s

137 tion on the more rigid SAM template, whereas rotaxanes form oriented layers on both SAMs.

138 The overall process, including the rotaxane formation and its further dethreading, has been

139 omplexes, causing thread formation to exceed rotaxane formation in the current experimental system.

140 Rotaxane formation is governed by a central, hydrogen-bo

141 pre-organisation during efficient and quick rotaxane formation.

142 3]-rotaxane complexes are reported where [2]-rotaxanes, formed from heterometallic {Cr(7)Ni} rings, a

143 hat readily available mechanically chelating rotaxanes give rise to complexes the noninterlocked equi

144 We find that the rotaxane gives improved enantioselectivity compared to a

145 ll rearrangement to form the desired polyyne rotaxanes has not yet been achieved.

146 Several rotaxanes have been synthesized to explore gem-dibromoet

147 Previous squaraine rotaxanes have employed planar squaraine dyes with 4-ami

148 xane-based molecular machines and materials, rotaxanes have not been attached covalently to proteins.

149 greater in comparison to a hydrogen bonding rotaxane host analogue.

150 yridinium axle containing halogen bonding [2]rotaxane host exhibits exceptionally strong halide bindi

151 In 50% H2O/CH3CN solvent mixtures the rotaxane host exhibits strong binding affinity and selec

152 the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense flu

153 a chloride anion templation strategy, the [3]rotaxane host recognises dicarboxylates through the form

154 he synthesis of the first halogen bonding [3]rotaxane host system containing a bis-iodo triazolium-bi

155 d application of a chiral halogen-bonding [3]rotaxane host system for the discrimination of stereo- a

156 is and anion binding properties of the first rotaxane host system to bind and sense anions purely thr

157 Quantification of iodide binding by rotaxane hosts reveals the strong binding by the XB-rota

158 rticle we show that bistable [c2]daisy chain rotaxanes (i.e., molecular muscles) can be linked into m

159 ional isomers of polymacrocycles as rings in rotaxanes, (iii) demonstrating solid-state fluorescence

160 onal templation, two [4]rotaxanes and one [5]rotaxane in >90% yields inside 2 h at 55 degrees C in ac

161 otaxane can be smoothly converted into the Z-rotaxane in 98% yield under UV irradiation.

162 reparation of a lanthanide-functionalized [2]rotaxane in high yield.

163 arative solution-state NMR studies of the [2]rotaxane in its unprotonated and protonated states were

164 six components in one pot affords a hetero[4]rotaxane in one minute in quantitative yield.

165 for production of mechanically planar chiral rotaxanes in excellent enantiopurity without the use of

166 e metal-free active template synthesis of [2]rotaxanes in one step, up to 95% yield and >100:1 rotaxa

167 er networks, knots along polymer chains, and rotaxanes in sliding ring gels, have important consequen

168 he solid-state structures of the [3]- and [4]rotaxanes in the R series and also on the basis of molec

169 idyl macrocycles generate triply threaded [4]rotaxanes in up to 11% yield.

170 amide macrocycle around the axle to form [2]rotaxanes in up to 85% yield; the corresponding Z-hydraz

171 para-xylylene bridge (2 and 3) gave pseudo[2]rotaxanes in which one dialkylammonium axle (4a-4e(+)) w

172 A homologous series of [2]rotaxanes, in which cyclobis(paraquat-p-phenylene) (CBPQ

173 This rotaxane incorporates a luminescent rhenium(I) bipyridyl

174 The change from tetra- to dicationic [2]rotaxanes increased not only the fluidity of their smect

175 We describe a three-compartment rotaxane information ratchet in which the macrocycle can

176 o link hybrid organic-inorganic [2]- and [3]-rotaxanes into still larger [4]-, [5]- and [7]-rotaxanes

177 lar switching devices, such as catenanes and rotaxanes; ion-channels by ligand gating; gelators for s

178 e hosts reveals the strong binding by the XB-rotaxane is driven exclusively by favourable enthalpic c

179 up to five times more of the fully saturated rotaxane is formed than is predicted based on a purely s

180 synthesis of ammonium-based oriented calix[2]rotaxane is here described.

181 inocatalysis "on" state of the dual-function rotaxane is inactive in anion-binding catalysis.

182 An analogous [3]rotaxane is obtained in excellent yield by replacing the

183 a replicating network favoring formation of rotaxane is possible.

184 alogen-bonding and hydrogen-bonding bistable rotaxane is prepared and demonstrated to undergo shuttli

185 teraction between the hexayne chains, the [3]rotaxane is remarkably stable under ambient conditions,

186 ion experiments revealed the halogen bonding rotaxane is selective for nitrate over the more basic ac

187 The hexayne unit in the rhenium-rotaxane is severely nonlinear; it is bent into an arc w

188 state for aminocatalysis by a switchable [2]rotaxane is shown to correspond to an "on" state for ani

189 Mechanical point-chirality in a [2]rotaxane is utilized for asymmetric catalysis.

190 lecular cyclization of N-benzylfumaramide [2]rotaxanes is described.

191 ions, whereas weaker association with the HB-rotaxanes is entropically driven.

192 In the case of the [5]rotaxane, it is possible to isolate a compound containin

193 nterlocked molecules (MIMs) - in particular, rotaxanes - its slow reaction rate and narrow substrate

194 The rotaxane ligands form complexes with most of the metal i

195 The rotaxane linkers are linear and result in nbo-type MOFs

196 reover, the usefulness of these novel copper-rotaxane materials as molecular dosing containers has al

197 thus affords two different three-station [2]rotaxane molecular machines, in which some of co-conform

198 A [2]rotaxane molecular shuttle containing secondary ammonium

199 We report on a switchable rotaxane molecular shuttle that features a pseudo-meso 2

200 eparation and dynamic behavior of degenerate rotaxane molecular shuttles are described in which a ben

201 n between two inequivalent spins in a hybrid rotaxane molecule.

202 linking ligands are mechanically interlocked rotaxane molecules is reviewed.

203 Rotaxane mono- and multilayers are shown to reversibly s

204 he amount of fuel added, the lifetime of the rotaxane ON-state can be regulated and temporal control

205 crocycles and the corresponding benzyl ether rotaxanes on gold substrates is investigated for the fir

206 no- and multilayers of chemically switchable rotaxanes on gold surfaces.

207 al-mediated self-assembly of macrocylces and rotaxanes on solid supports.

208 ulate the reactivity of stoppering groups in rotaxanes over a distance of about 2 nm.

209 dibutylamino groups as stoppers yielded the rotaxane precursor in a reasonable yield and allowed the

210 ers of NU-1000 and carboxylic acid groups of rotaxane precursors (semirotaxanes) as part of this buil

211 ses the yield of the target heterocircuit [3]rotaxane product at the expense of other threaded specie

212 analogous 39-membered macrocycle produced no rotaxane products under similar conditions.

213 cular DNA nanostructures, e.g., catenanes or rotaxanes, provide functional materials within the area

214 phic analysis on six [2]rotaxanes and two [3]rotaxanes provides insight into the noncovalent interact

215 the macrocycle during the elongation of the rotaxane provokes the accumulation of tensile and torsio

216 Unlike the non-interlocked thread, the rotaxane requires a catalytically innocent cofactor, the

217 Stable enantiomers of the rotaxane result from a bulky group in the middle of the

218 unmasking, whereas photolysis of the indane rotaxane results in unmasking of the polyyne thread to f

219 rm a unique 1:1 stoichiometric nitrate anion-rotaxane sandwich complex.

220 with Au NP/fluorophore hybrids loaded on the rotaxane scaffold, are introduced.

221 The X-ray crystal structures of the E- and Z-rotaxanes show different intercomponent hydrogen bonding

222 The crystal structure of one of these [3]rotaxanes shows that there is extremely close contact be

223 steric speed bumps has been demonstrated in rotaxane shuttles and macrocycle threading systems, the

224 Also in the diphenylethyne, rotaxane shuttling is rapid on the NMR time scale, indic

225 vage of the peptide with trypsin led to a [2]rotaxane structure that self-assembled into a [3]catenan

226 natural products typified by their threaded rotaxane structure.

227 eversible reconfiguration of the catenane or rotaxane structures provides a means to yield new DNA sw

228 yclic components in interlocked catenane and rotaxane structures, for constructing assemblies based o

229 -temperature (1)H NMR study in DMSO-d6 of [2]rotaxane supported the kinetic inertness of the interloc

230 A nanoring-rotaxane supramolecular assembly with a Cy7 cyanine dye

231 of electrochemically bistable 'daisy chain' rotaxane switches based on a derivative of the so-called

232 ons, we converted CB6 click chemistry from a rotaxane synthesis tool into a useful bioconjugation tec

233 In the new approach a preformed rotaxane synthon is attached to the end of an otherwise

234 nce allowed formation of an unprecedented [3]rotaxane templated around a dialkylphosphate.

235 wicz cross-coupling affords higher yields of rotaxanes than homocoupling.

236 The reactivity of a rotaxane that acts as an aminocatalyst for the functiona

237 ble spin labeled alpha-cyclodextrin-based [2]rotaxane that is characterized by the presence of nitrox

238 the multistep assembly of large DNA origami rotaxanes that are capable of programmable structural sw

239 The result is stable [9]cumulene rotaxanes that enable the study of properties as a funct

240 Here we describe two rotaxanes that encapsulate a 3,3-dimethylindoline squara

241 wo sites do not communicate, and that in the rotaxane the transfer of information between them is mad

242 raversed from the [3]- to the [4]- to the [5]rotaxane, the cooperativity becomes increasingly positiv

243 ith more conventional bistable catenanes and rotaxanes, the mechanical movement of the ring between r

244 mple and effective route to a broad range of rotaxanes, the strategy enables 1:1 interactions of crow

245 xayne (tau = 3.0 ps), whereas in the rhenium-rotaxane there is triplet EET, from the macrocycle compl

246 In the metal-free rotaxane, there is rapid singlet excitation energy trans

247 e between two different binding sites on the rotaxane thread.

248 change of position of the macrocycle on the rotaxane thread.

249 ort on the active template synthesis of a [2]rotaxane through a Goldberg copper-catalyzed C-N bond fo

250 rmationally restricted chiral cavities of [2]rotaxanes to achieve enantioselective anion recognition.

251 The rotaxane topology was confirmed by single-crystal X-ray

252 A rotaxane-type structure was proposed for the FA/beta-CD

253 n nanocomposites embedding a self-assembling rotaxane-type system that is responsive to both optical

254 corresponding Z-hydrazone thread affords no rotaxane under similar conditions.

255 Ordered arrays of stimulus-responsive rotaxanes undergoing well-controlled axle shuttling are

256 ge enough to prevent macrocycle threading or rotaxane unthreading.

257 ical dissociation of an ammonium/crown ether rotaxane using experimental (sonication) and computation

258 Both MAEs have been incorporated into rotaxanes via copper-mediated active metal template Glas

259 The [2]rotaxane was characterized by mass spectrometry, 1D and

260 A more stable [2]rotaxane was formed on irradiating 1 subset2b, whose cap

261 adiation of 1 subset2a, a kinetically labile rotaxane was obtained on irradiating the complex 1 subse

262 In addition, a permanently interlocked rotaxane was prepared by capping the end of a noncovalen

263 The hetero[4]rotaxane was prepared through two different stepwise syn

264 A [2]rotaxane was produced through the assembly of a picolina

265 onium with different sizes, a novel hetero[4]rotaxane was successfully prepared by employing the comb

266 ired by these findings, a self-immolative [2]rotaxane was then designed that self-destructs in the pr

267 mplicated chemical structure of the hetero[4]rotaxane was well-characterized by (1)H NMR spectroscopy

268 The identity of the rotaxanes was confirmed by NMR spectroscopy and mass spe

269 data of the shuttling behavior in the C(26) rotaxane were obtained from dynamic NMR spectroscopy.

270 Doubly threaded [3]rotaxanes were also obtained from the reactions but no [

271 The novel DNA-based rotaxanes were analyzed to assess the effect of the mech

272 The constitutions of the [4]rotaxanes were determined by NMR spectroscopy and mass s

273 the R' series, the [3]-, [4]-, [8]-, and [12]rotaxanes were isolated after reaction times of <5-30 mi

274 3]-, [4]-, [5]-, [8]-, [12]-, [16]-, and [20]rotaxanes were isolated in <5 min to 14 h in 88-98% yiel

275 e also obtained from the reactions but no [2]rotaxanes were isolated, suggesting that upon demetalati

276 The rotaxanes were prepared by a templated clipping reaction

277 Daisy chains are a class of rotaxanes which have been targeted to serve as artificia

278 amine macrocycle directs the assembly of the rotaxane, which can subsequently serve as a ligand for e

279 zed two structure-switching behaviors of our rotaxanes, which are both mediated by DNA hybridization.

280 Four redox-active rotaxanes, which drove a cyclobis(paraquat-p-phenylene)

281 g strategies are used to prepare nanohoop [2]rotaxanes, which owing to the pai-rich macrocycle are hi

282 In addition to the topologically trivial rotaxanes, whose structures may be captured by a planar

283 The MIM linker is a [2]rotaxane with a [24]crown-6 (24C6) macrocycle and an ani

284 in unmasking of the polyyne thread to form a rotaxane with a chain of 16 sp-hybridized carbon atoms.

285 g by ~70% compared to a structurally similar rotaxane with an all-alkane thread of the same length.

286 ecular interaction of the positively charged rotaxane with optically active anions causes an imbalanc

287 enation of permanently interlocked squaraine rotaxanes with anthracene-containing macrocycles produce

288 i) on the synthesis of highly ordered poly[n]rotaxanes with high conversion efficiencies.

289 velopment of triptycene-containing squaraine rotaxanes with high fluorescence quantum yields and larg

290 t the assembly line-like emergence of poly[n]rotaxanes with increasingly higher energies by harnessin

291 [2]Rotaxanes with linear side chains and minimum ratios of

292 architecture should prove useful to connect rotaxanes with polymers and surfaces for applications in

293 e synthesis of oligomeric homo- and hetero[n]rotaxanes with precise control over the position of each

294 the synthesis of main chain oligonucleotide rotaxanes with precise control over the position of the

295 This methodology has been used to prepare [3]rotaxanes with two polyyne chains locked through the sam

296 The MIM linkers are [2]rotaxanes with varying sizes of crown ether macrocycles

297 The smallest [2]rotaxane, with only three methylene groups on each side

298 nterlocked photoproduct (Phi = 0.06) is a [2]rotaxane, with the dimerized anthracenes assuming a head

299 The organization of trisradical rotaxanes within the channels of a Zr6-based metal-organ

300 pies all confirm the capture of redox-active rotaxanes within the mesoscale hexagonal channels of NU-