ライフサイエンスコーパス: singlet

1 on from a Zhang-Rice triplet to a Zhang-Rice singlet.

2 epitopes than intact proviruses observed as singlets.

3 smaller in pregnant vs. non-pregnant women (singlets: -0.01 +/- 0.01 s vs. -0.04 +/- 0.04 s, P < 0.0

4 rchetypal many-body states of the Zhang-Rice singlet(10,11), and reaches a coherent state assisted by

5 ursor, was found to spontaneously cyclize to singlet 4-fluoro-2,1-benzisoxazole.

6 pectroscopic evidence for ylide formation by singlet alpha-carbonyl carbene capture in aprotic nucleo

7 ran) and report an enol-mediated pathway for singlet alpha-carbonyl carbene reaction with alcohols (e

8 ntial energy surface for the reaction of the singlet alpha-carbonyl carbene with methanol shows that

9 Herein we report that a stable singlet ambiphilic carbene activates CO and catalyticall

10 erature-dependent interplay between emissive singlet and triplet charge-transfer states and amide-loc

11 cause it targets a linear combination of the singlet and triplet configurations involving the HOMO an

12 This independent modulation of singlet and triplet decay rates is highly desirable for

13 nt spectroscopy and modelling to unravel the singlet and triplet dynamics.

14 temperature may consequently consist of both singlet and triplet emission.

15 pinpoints the importance of realizing donor singlet and triplet excited states that have opposite el

16 velengths as well as their small gap between singlet and triplet excited states to reduce energy loss

17 y tailor the relative energies of the lowest singlet and triplet excited states, enhancing the yield

18 nd sensitively on the energies of the lowest singlet and triplet excited states.

19 In the case of Sn(II) and Ge(II), both singlet and triplet excitonic emission bands have been o

20 rge yield as a function of driving force for singlet and triplet excitons, including inverted regimes

21 /- 0.01) mT (hole); the separation rates for singlet and triplet polaron pairs: k(S,s) = (44.59 +/- 0

22 a small energy separation between the lowest singlet and triplet states (Delta E(S(1)-T(1)) = 500 cm(

23 and whose excitons interconvert between the singlet and triplet states ~36 times during one lifetime

24 icient spin-orbit coupling (SOC) between the singlet and triplet wavefunctions.

25 ccounting for standard errors of the modeled singlets and combination viabilities.

26 te of conversion of a singlet exciton into a singlet biexciton (triplet pair), using a simplified ver

27 The reaction of the singlet biradical [P(mu-NHyp)](2) (Hyp = hypersilyl, (Me

28 opentanediyl isomer represents an open-shell singlet biradical with interesting photochemical propert

29 tween multiple triplet excitons and emissive singlets by monitoring time-dependent fluorescence quenc

30 py is used to show competitive production of singlet carbene and ketene intermediates from the photoe

31 The stepwise mechanism proceeds through singlet carbene intermediates which can also participate

32 The intensified nucleophilicity of the singlet carbene is manifested in quantifiable ways.

33 iaminal carbenoids leads to the formation of singlet carbenes followed by their trapping via an intra

34 ectrons and a vacant orbital, reminiscent of singlet carbenes.

35 fluorescence emanating from the higher-lying singlet configuration with significant LMCT contribution

36 inescence studies reveal that the triplet-to-singlet conversion in exciplexes involves an artificiall

37 ccur to cooperatively operate the triplet-to-singlet conversion.

38 an AA9 LPMO with H(2)O(2) at higher pHs is a singlet Cu(II)-tyrosyl radical species, which is inactiv

39 mputations give the total ring strain of the singlet cyclobutyne to be 101 kcal/mol, with an in-plane

40 The singlet cyclobutyne transition state ( C(2 v)) exhibits

41 In contrast with previous studies, singlet cyclopropylidenemethylene in C(2 v) symmetry was

42 potent oxidizers hydroxyl radicals (OH) and singlet delta oxygen (SDO).

43 intermediate hydrogen-bonded complex between singlet diphenylcarbene and a protic solvent molecule, t

44 featuring two antiferromagnetically coupled singlet diradical diamine type ligands are described.

45 proton transfer involves the formation of a singlet diradical ground state, which requires multirefe

46 well-defined inexpensive and easy to prepare singlet diradical Ni(II)-catalysts featuring two antifer

47 n ABA(2+) and dianion ABA(2-) are open-shell singlet diradicaloids, while the longer dication ANA-TFA

48 o singlet fission solar cells by suppressing singlet dissociation at optimal driving forces for tripl

49 lations, support assignment of an open-shell singlet electronic structure that maintains a formal Fe(

50 has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surro

51 In this work, we show that the singlet energy of diketopyrrolopyrroles (DPPs) can be al

52 riplet pair also allow dimers to form on the singlet energy surface, creating an unwanted energy rela

53 s of our work indicate successful triplet-to-singlet energy transfer and a sizable increase in the tr

54 ities-triplet pentadiynylidene (HCCCCCH) and singlet ethynylcyclopropenylidene (c-C(5)H(2)) carbene-v

55 intersystem crossing (RISC) from triplet to singlet exciplex diminishes, a pronounced isotope effect

56 tyl-tpPDI exhibits strong mixing between its singlet excited state and a charge transfer state, yield

57 mple anti-aufbau DFT approach for estimating singlet excited state aromaticity suggested in a recent

58 The singlet excited state of Znby had a short life-time, lim

59 90% yield of electron transfer (ET) from the singlet excited state P* of the primary electron-donor P

60 d that the photoreaction took place from the singlet excited state while the Norrish type I reaction

61 ving the HOMO and LUMO rather than the first singlet excited state.

62 -infrared photoluminescence (PL) from a spin-singlet excited state.

63 ponent is thermal dissipation of chlorophyll singlet excited states and is called nonphotochemical qu

64 hases, from upper (S(2) ) and lowest (S(1) ) singlet excited states, even at room temperature in air.

65 Large singlet exciton diffusion lengths are a hallmark of high

66 ion in facilitating efficient intramolecular singlet exciton fission (iSEF) in pai-bridged pentacene

67 incorporated materials, exemplified here by singlet exciton fission followed by separation into weak

68 iplet excitons at the cost of one photon via singlet exciton fission in organic semiconductors can po

69 Singlet exciton fission photovoltaic technology requires

70 133 per cent, establishing the potential of singlet exciton fission to increase the efficiencies of

71 by sensitizing the silicon solar cell using singlet exciton fission, in which two excited states wit

72 locally maximize the rate of conversion of a singlet exciton into a singlet biexciton (triplet pair),

73 Singlet fission, the process of splitting a singlet exciton into two triplet excitons, has been prop

74 nic molecules in which a photogenerated spin-singlet exciton is rapidly and efficiently converted to

75 In chromophores where the singlet exciton is roughly isoergic with two triplet exc

76 t fission in organic semiconductors causes a singlet exciton to decay into a pair of triplet excitons

77 higher energy with singlet spin character (a singlet exciton)(3-5).

78 ess of forming two triplet excitons from one singlet exciton, is a characteristic reserved for only a

79 ultimately fuse two triplet excitons into a singlet exciton.

80 d promoting radiative decay of the resulting singlet exciton.

81 Photogenerated singlet excitons can be converted to triplet excitons on

82 and holes) that can later recombine to form singlet excitons during the phosphorescence spectrum mea

83 les that undergo singlet fission, converting singlet excitons into pairs of triplet excitons, have po

84 ng-range incoherent transport of delocalized singlet excitons on pico- to nanosecond time scales in s

85 The possible advantages of endothermic singlet fission (enhanced use of photon energy and large

86 nal IC pathway, an unexpected intramolecular singlet fission (iSF) process is responsible for excited

87 Singlet fission (SF) holds the potential to boost the ma

88 spectroscopy are applied to rationalize how singlet fission (SF) is affected by systematic chemical

89 teractions and, in turn, on the key steps in singlet fission (SF), that is, the (1)(S(1)S(0))-to-(1)(

90 ore the effects of exciton delocalization on singlet fission (SF).

91 on of the diabatic frontier orbital model of singlet fission (SF).

92 perylene oligomers that undergo endothermic singlet fission and have endothermicities in the range 5

93 important for multiexcitonic processes like singlet fission and photon upconversion.

94 t-pair state acts as an intermediate in both singlet fission and triplet-triplet annihilation and tha

95 Singlet fission and triplet-triplet annihilation represe

96 e oriented and immobilized in an inert host, singlet fission can be strongly state-selective.

97 lls the criteria on the state ordering for a singlet fission chromophore.

98 a geometric model for the identification of singlet fission chromophores, and we explore what factor

99 e full 108-atom molecular movie of ultrafast singlet fission in a pentacene dimer, explicitly treatin

100 Singlet fission in organic semiconductors causes a singl

101 Both macrocycles undergo singlet fission in solution with rates that differ by an

102 Singlet fission is a photoconversion process that genera

103 Singlet fission is an exciton multiplication process in

104 d chromophores needed to undergo endothermic singlet fission is three, which provides sufficient stat

105 Not only do we access novel singlet fission materials, they also exhibit excellent a

106 highly desirable for the design of efficient singlet fission materials.

107 t this is true for both endo- and exothermic singlet fission materials.

108 acene triplets are efficiently generated via singlet fission on the nanocrystal surface.

109 lso realised in organic chromophores through singlet fission or via charge recombination.

110 Such a singlet fission photon multiplication (SF-PM) process co

111 r, there has been no demonstration of such a singlet fission photon multiplication (SF-PM) process in

112 ailor new chromophores with potential use in singlet fission photovoltaics.

113 of the most promising methods to harness the singlet fission process is via the efficient extraction

114 urable energetics can play outsized roles in singlet fission processes.

115 this promise has not been fulfilled because singlet fission produces two low-energy triplet excitons

116 Singlet fission promises to surpass the Shockley-Queisse

117 ing the excellent stability of this class of singlet fission scaffold.

118 rs can thus provide a strategic advantage to singlet fission solar cells by suppressing singlet disso

119 entified obstacle to the design of efficient singlet fission solar cells.

120 Molecules that undergo singlet fission, converting singlet excitons into pairs

121 In organic semiconductors exhibiting singlet fission, the geometric relationship between mole

122 Singlet fission, the process of forming two triplet exci

123 Singlet fission, the process of splitting a singlet exci

124 Singlet fission-that is, the generation of two triplets

125 for ensuring high-yield T(1) formation from singlet fission.

126 ty, to tailor new potential chromophores for singlet fission.

127 inear processes in organic materials such as singlet-fission and triplet-triplet annihilation could i

128 We analyze correlated-triplet-pair (TT) singlet-fission intermediates toward two-triplet separat

129 wo new insights: (a) the canonical tetracene singlet-fission unit cell supports precisely three low-l

130 d 3J separate a singlet from a triplet and a singlet from a quintet, respectively.

131 nge-split energy gaps of J and 3J separate a singlet from a triplet and a singlet from a quintet, res

132 ominated by a transition from a triplet to a singlet ground state at low temperatures.

133 -)-centered diradical is predicted to have a singlet ground state by theory and variable temperature

134 CASSCF calculations reveal a closed-shell singlet ground state for 4 with a considerable diradical

135 irst known high temperature realization of a singlet ground state magnet, in which magnetism occurs t

136 hat cyclobutyne is a transition state in its singlet ground state, based on new coupled cluster and m

137 ne dimers exhibit an antiferromagnetic (S=0) singlet ground state.

138 ormation is the fact that it proceeds on the singlet hypersurface and that no triplet intermediates a

139 vity is determined within a Lewis acid bound singlet intermediate via a conical intersection.

140 structures that block access to unproductive singlet internal conversion conical intersections, which

141 ir triplet excited state and then triplet-to-singlet intersystem crossing in the nascent geminate rad

142 multiband superconductors with dominant spin singlet, intraband pairing of spin-1/2 electrons can und

143 5-) cluster, leading to a rare trimeric spin singlet involving d(2) Mo(4+) ions.

144 The singlet lifetime of (1) H singlets is up to (9.2+/-1.8) min, thus exceeding (1) H

145 The singlet lifetime of (1) H singlets is up to (9.2+/-1.8)

146 several orders of magnitude shorter than the singlet lifetimes of known transition-metal photoredox c

147 5) N T(1) times of up to (4.6+/-0.4) min and singlet lifetimes T(s) of up to (17.5+/-3.8) min are obs

148 nt inter-system crossing between triplet and singlet manifolds, indicating that optically-addressable

149 tural differences between the C(s)-symmetric singlet (omega(flap) = +/-44 deg) and C(2v)-symmetric tr

150 ways to deprotonation, including whether the singlet or triplet carbene is formed, are probed.

151 de a (Ppa) could be controllably released by singlet oxygen ((1) O(2) ) generated by light irradiatio

152 ptides nanolayer converts the H(2) O(2) into singlet oxygen ((1) O(2) ) in a sustained manner for neu

153 (fc2) that conditionally accumulates the ROS singlet oxygen ((1) O(2) ) leading to chloroplast degrad

154 (SPNpd) that not only efficiently generates singlet oxygen ((1) O(2) ) under NIR photoirradiation bu

155 pro-nanoenzyme not only generates cytotoxic singlet oxygen ((1)O(2)) for photodynamic therapy (PDT),

156 Singlet oxygen ((1)O(2)) generation quantum yields from

157 The importance of singlet oxygen ((1)O(2)) in the environmental and biomed

158 mic substance isolates and whole waters with singlet oxygen ((1)O(2)) phosphorescence and determined

159 The singlet oxygen ((1)O(2)) photosensitizing propensity of

160 sulting in a significant alteration of their singlet oxygen ((1)O(2)) production.

161 tates of dissolved organic matter ((3)DOM*), singlet oxygen ((1)O(2)), and hydroxyl radicals ((*)OH),

162 Singlet oxygen ((1)O(2)), the major reactive oxygen spec

163 oxin, is readily oxidized upon reaction with singlet oxygen ((1)O(2)).

164 udies, they seem susceptible to oxidation by singlet oxygen ((1)O(2)); therefore, we designed and syn

165 (catalase), hydroxyl radicals (mannitol) and singlet oxygen (sodium azide) and carbon-centered radica

166 truction is mainly caused by highly reactive singlet oxygen (Type II reaction).

167 ctions between the photosensitizer-generated singlet oxygen and substrate molecules remain elusive at

168 eration of reactive oxygen species including singlet oxygen and superoxide ion through both type 1 an

169 peroxide (H(2)O(2)), hypochlorous acid, and singlet oxygen are generated.

170 phospho-(1'-rac-glycerol) (POPG) mediated by singlet oxygen at the air-water interface of levitated w

171 se reactions are likely hydroxyl radical and singlet oxygen based on the use of selective quenchers.

172 As sustained generation of secondary singlet oxygen by the tumor cells is activated at the si

173 Singlet oxygen can severely damage biological tissue, wh

174 Herein, we show that use of the singlet oxygen ene reaction, combined with [2 + 2] cyclo

175 several protobruceol natural products using singlet oxygen ene reactions.

176 ong triplet lifetime ensures high-efficiency singlet oxygen evolution according to homogeneous photo-

177 h were tested for their ability to sensitize singlet oxygen formation, were found to do so efficientl

178 In PDT-induced hypoxia, providing singlet oxygen from stored chemical energy may enhance t

179 bystander effect-like spreading of secondary singlet oxygen generation and catalase inactivation with

180 With PDT, Ce6-SCs demonstrate high singlet oxygen generation and produce a significant dela

181 hancement, as well as a 1.9-fold increase in singlet oxygen generation efficiency over free rose beng

182 restoration of the fluorescence emission and singlet oxygen generation upon removal of the DNBS group

183 avor triplet-state formation as required for singlet oxygen generation, iodine substituents were intr

184 s-A(2)B(2) porphyrins showed decent in vitro singlet oxygen generation, which was supported by the in

185 d with antibodies, and then reacted with the singlet oxygen in the presence of specific antigens and

186 Singlet oxygen is a versatile reagent for the selective

187 The singlet oxygen is produced through quenching of an optic

188 esponse of tumor cells to generate secondary singlet oxygen is the essential motor for their self-des

189 ism called singlet oxygen priming (SOP), the singlet oxygen leads to hydroperoxides then to peroxyl r

190 irectly created through energy transfer from singlet oxygen molecules ((1)O(2)).

191 photosensitizer that can generate cytotoxic singlet oxygen molecules upon activation by X-rays.

192 Airborne singlet oxygen obtained from photosensitization of tripl

193 The total quenching rate constant (k(T)) of singlet oxygen of the alkene surfactant was measured to

194 sensitized manner and then thermally release singlet oxygen on demand on the other hand.

195 e design of highly effective sensitizers for singlet oxygen on one hand and the realization of materi

196 andwich-format immunoassay, the PPs produced singlet oxygen once sensitized by 680 nm diode lasers, a

197 y photo-oxidize DNA without the mediation of singlet oxygen or other reactive oxygen species, phototo

198 Singlet oxygen precursors were efficiently isolated, whi

199 Through a new mechanism called singlet oxygen priming (SOP), the singlet oxygen leads t

200 Importantly, one round of singlet oxygen produced a persistent secondary wave of m

201 Singlet oxygen produced from triplet excited chlorophyll

202 The singlet oxygen produced not only induced a significant p

203 article size, morphology, surface charge and singlet oxygen production during ultrasound exposure.

204 ight irradiation, Ti-TBP not only sensitizes singlet oxygen production, but also transfers electrons

205 etween MS2 and DOM sites with locally higher singlet oxygen production.

206 (50)(dark)/IC(50)(light) ratio of ~368 and a singlet oxygen quantum yield of about 20%.

207 Mg(II) porphyrazines (MgPzs) having similar singlet oxygen quantum yields and side groups with diffe

208 ulfur quantum dots ("lumidots") show similar singlet oxygen quenching rate constants, based on the mo

209 However, the latter serves as an effective singlet oxygen sensitizer, as demonstrated in the prefer

210 s, upon the laser irradiation, the generated singlet oxygen species are consumed by WONPs, in turn le

211 ox mediators are predominantly decomposed by singlet oxygen that forms during cycling.

212 d then elevate the production of tumor-toxic singlet oxygen to significantly enhance PDT.

213 Singlet oxygen was involved in aBL inactivation of N. go

214 The ability of phenalenones to generate singlet oxygen was then harnessed in three photooxygenat

215 t illumination, the photosensitizer produces singlet oxygen which oxidizes phenolic compounds present

216 henalenone molecular structure in generating singlet oxygen with high yields.

217 Ph)(10)] is indeed a very strong quencher of singlet oxygen with total rate constants for (1)O(2) rem

218 elease via photodynamic (photooxygenation by singlet oxygen) and photothermal effects.

219 n kinetics and localized oxidation caused by singlet oxygen, (1)O(2), a major photochemically derived

220 for physical and chemical studies involving singlet oxygen, single-walled carbon nanotubes, and othe

221 s various reactive oxygen species, including singlet oxygen, superoxide anion, hydrogen peroxide, and

222 This imprint is mediated by primary singlet oxygen, which is mainly generated through the in

223 composition, and fluorescence or affinity to singlet oxygen, within 2-3 orders of magnitude.

224 rug based on combretastatin A-4 (CA4) with a singlet oxygen-cleavable aminoacrylate linker, and a bio

225 cancerous tissue and design pH-controllable singlet oxygen-generating boron-dipyrromethene (BODIPY)

226 The resulting pH-controlled singlet oxygen-generating dyes with pK(a) values in the

227 rs, the environmental half-life of DA due to singlet oxygen-induced transformations is between 5 and

228 Development of a visible light-induced and singlet oxygen-mediated green protocol has been accompli

229 al motor for their self-destruction, after a singlet oxygen-mediated triggering process by CAP or PAM

230 toxic after the bacteria are pretreated with singlet oxygen.

231 dark toxicity effects following exposure to singlet oxygen.

232 ions on the generation and reactivity toward singlet oxygen.

233 must thus be designed for stability against singlet oxygen.

234 ors, photouncaging, photodynamic therapy, or singlet-oxygen detection.

235 ysical properties, such as quantum yields of singlet-oxygen formation, decomposition, and fluorescenc

236 class of photoactive material for efficient singlet-oxygen generation with potential photodynamic th

237 idone-tetraphenylethylene (DPPTPE) with high singlet-oxygen-generation ability both in dichloromethan

238 vity based on ELISA studies, indicating that singlet oxygenation could be an important natural detoxi

239 diene systems, were not observed during the singlet oxygenation of DA.

240 iled product studies revealed that the major singlet oxygenation reaction pathways were the [2 + 2] c

241 ng is much less understood than that of spin-singlet pairing explained by the Bardeen-Cooper-Schrieff

242 resonating valence bonds to Kondo-entangled singlet pairs at the QCP, causes a jump in the Fermi sur

243 /- 0.01) MHz, and the recombination rate for singlet polaron pair k(S,r) = (88 +/- 6) MHz.

244 g heavy-atom QMT through crossing triplet to singlet potential energy surfaces.

245 n statistics, the injected charges form spin-singlet (S(1)) excitons and spin-triplet (T(1)) excitons

246 The singlet's bent :CH-group favors bicyclo[2.1.0]pentane an

247 Degenerate bridge-flapping of the singlet's main bridge, which comprises the reactive diva

248 tra of all untreated cheeses showed only one singlet signal with a g-factor of 2.0064 +/- 0.0005.

249 in which charges are generated through rapid singlet-singlet annihilation and show lifetimes of sever

250 int toward the importance of controlling the singlet-singlet annihilation step in order to increase t

251 1,3-cyclobutanediyls as stable closed-shell singlet species from the reversible reactions of cyclotr

252 regarded as a rather unreactive closed-shell singlet species with one localized N=P and one C=P doubl

253 riplet intermediate before reaching a planar singlet species.

254 m a photoexcited state of higher energy with singlet spin character (a singlet exciton)(3-5).

255 g-lived dipole-bound resonances built on the singlet state below the detachment threshold is discusse

256 A nuclear spin singlet state can now be populated.

257 vents, with a current maximum of the excited-singlet state energy of 3.6 eV.

258 spin qubit (radical) pair in a pure initial singlet state fulfilling this criterion.

259 The neutral oxyallyl singlet state has a barrier-free route to cyclopropanone

260 -(13) C]pyruvate in addition to a long-lived singlet state in the [1,2-(13) C(2) ] form are readily c

261 e-light microscopy and discover a low-energy singlet state sparsely distributed throughout the microc

262 bidden horizontal transition from an excited singlet state to a higher vibrational level of the isoen

263 rules that connect the doubly excited, spin-singlet state to the manifold of quintet states and comm

264 As compared to the singlet state, in the triplet state, the Gibbs barrier f

265 , the generation of two triplets from a lone singlet state-has recently resurfaced as a promising pro

266 hilation-and a subsequent fast return to the singlet state.

267 ven upconversion in water with unprecedented singlet-state energies approaching 4 eV.

268 On the contrary, excitation to higher-lying singlet states (S(n), n > 1) drives the reaction toward

269 The spectra of these singlet states are consistent with slip-stacked molecula

270 ndly, introduced is a bimolecular switch for singlet states based on 3-(2) H-coumarin containing an i

271 iazirines to support hyperpolarized (1) H(2) singlet states in CH(2) groups of chiral molecules.

272 emonstrate the involvement of higher excited singlet states in the photochemistry of diazoalkanes.

273 econd-timescale kinetics of these low-energy singlet states matches that of the correlated triplet-pa

274 at efficiently convert triplet excitons into singlets through reverse intersystem crossing (RISC) riv

275 forbidden transitions from the ground-state singlet to excited-state triplets to gain oscillator str

276 Direct singlet-to-triplet metal-to-ligand charge transfer (MLCT

277 The 3D maps of microtubule doublet-singlet transitions generally display longitudinal gaps

278 unction protein is a major player in doublet-singlet transitions.

279 recedented high-spin (triplet) ground state, singlet triplet energy gap, DeltaE(ST) = 0.3 kcal mol(-1

280 ging technologies, but typically exhibit low singlet triplet energy gaps and possess limited thermal

281 By having different singlet-triplet energy differences (DeltaE(ST) ) in 9,9'

282 311G(d) theoretical model, indicated a large singlet-triplet energy gap (DeltaE(S-T) = -45 kcal/mol),

283 relationship between triplet aromaticity and singlet-triplet energy gap, confirming this novel strate

284 riplet ground state diradical 2 with a large singlet-triplet energy gap, Delta E(ST) >= 1.7 kcal mol(

285 d spin-orbit coupling(9-11) or tuning of the singlet-triplet energy splitting(12,13) via molecular de

286 eir optical and electronic properties, small singlet-triplet energy splitting, narrow emission line w

287 Overall, strong correlation between singlet-triplet gaps and hydrogenation enthalpies was ob

288 esponses up to 1100 nm and almost degenerate singlet-triplet ground states with weak antiferromagneti

289 rmed that increase the chance of finding the singlet-triplet intersection seam.

290 Here we propose a module consisting of spin singlet-triplet qubits and single microwave photons.

291 Here, we explore an important resource for singlet-triplet qubits: a transverse sweet spot (TSS) th

292 Alternatively, singlet-triplet readout enables high-fidelity spin-state

293 They are characterized by singlet-triplet spin-flip inelastic excitations with an

294 ical product pair coupled with the vanishing singlet-triplet splitting at long range.

295 g in the proximal position with F shifts the singlet-triplet splitting by +4.5 +/- 0.4 kcal mol(-1) f

296 well as harmonic vibrational frequencies and singlet-triplet splittings are computed using the benchm

297 ed triplet-pair state, which we attribute to singlet/triplet-pair interconversion at these sites.

298 ns and that the nature of the excited state (singlet vs triplet) is dependent on aromatic substitutio

299 The electronic structure is a singlet, where the Fe(IV) and Cu(II) are antiferromagnet

300 ing leads preferentially to the closed shell singlet zwitterion.