ライフサイエンスコーパス: solvent

1 ser coupling product ArC=C-C=CAr and [Cu(I)](solvent).

2 ns using mixed aqueous media as the reaction solvent.

3 with the use of n-octanol only as extractant solvent.

4 ielding the hydrophobic tip of PPE4(mt) from solvent.

5 id space within the MOF is accessible to the solvent.

6 droplet motility relative to the underlying solvent.

7 buffer between the donor and the surrounding solvent.

8 of SCFA were only detected using methanol as solvent.

9 en performed in hexafluoroisopropanol as the solvent.

10 tautomerized to an enol and then ionized by solvent.

11 eaction is carried out in ethyl acetate as a solvent.

12 r ambient-atmosphere conditions and with wet solvent.

13 the 1,1,1,3,3,3-hexafluoroisopropanol (HFIP) solvent.

14 h monomeric water that is codissolved in the solvent.

15 RBS and evolving slower, but also exposed to solvent.

16 proton loss from the oxidized complex to the solvent.

17 of the alcohol component as a solvent or co-solvent.

18 making the non-OR region more exposed to the solvent.

19 oxidants, acids and bases, as well as polar solvents.

20 solvents, which lack the isotropy of liquid solvents.

21 ous solution, without involvement of organic solvents.

22 but not in microdroplets composed of organic solvents.

23 t of this work has been conducted in organic solvents.

24 face ligands that enable their dispersion in solvents.

25 her regulated compounds, such as chlorinated solvents.

26 exhibited good solubility in common organic solvents.

27 s prove the ion pair association in nonpolar solvents.

28 through activation and reimmersion in polar solvents.

29 on oxidation of Ga metal with AgOTf in arene solvents.

30 ative to the parent cyanine, even in viscous solvents.

31 n agents, aerosol propellants, and precision solvents.

32 tures and thermophysical properties of these solvents.

33 amework and are soluble in a wide variety of solvents.

34 sis in the presence of a (polar or nonpolar) solvent?

35 ion reaction of cyclohexanone in a 2-butanol solvent 10x faster than their hydrophilic analogues.

36 the utilization of environmentally friendly solvent 2-MeTHF in all steps of the synthesis.

37 t results were found using tert-butanol as a solvent, 20 g/L of lipase B from Candida Antarctica, and

38 tion time (1.83-2.09 times) and less organic solvent (3.39-173.25 times) to operate at a lower extrac

39 secondary structure features and per-residue solvent accessibility features of PTM sites, domain cont

40 ied group pKas is computationally intensive, solvent accessibility of ionizable groups is displayed,

41 lly, in addition to providing information on solvent accessibility of lysine sites, dead end iqPIR cr

42 ass spectrometry, we measure the decrease in solvent accessibility of one of beta2m's Trp residues, w

43 n about protein structure, due to changes in solvent accessibility.

44 over coordination geometry, reactivity, and solvent accessibility.

45 iality, tissue specificity, localization and solvent accessibility.

46 hereby yielding diagnostic information about solvent accessibility.

47 s (especially, O-atom bearing molecules) are solvent accessible.

48 rendipitous effect of D(2) O as a beneficial solvent additive for enhancing the power conversion effi

49 Generally applied solvent additives favor the formation of protonated and

50 borate) system as a function of temperature, solvent, ancillary ligand, and arene substituent.

51 f great interest, as ethanol is eco-friendly solvent and potential applications of torularhodin range

52 present in high relative abundance in rancid-solvent and rancid-stale samples.

53 To elucidate their properties, solvent and substitution effects on their light absorpti

54 In a first experimental setup, solvent and temperature gradients were used simultaneous

55 the samples using acetonitrile as extracting solvent and the extracts were purified through primary s

56 exchanges between the macromolecules and the solvent and the number of water molecules involved in th

57 ws high solubility in various common organic solvents and achieves a high reversible capacity of ca.

58 of the century" because they can be used as solvents and active catalysts in chemical reactions.

59 rted in the literature take place in organic solvents and are driven by the reagents' interaction wit

60 PIMs are readily dissolved in solvents and can be cast into robust microporous coating

61 tes 10 protocols, using different extraction solvents and sample processing methods for measuring the

62 ly a limited number of transitions in select solvents and were measured using spontaneous Raman scatt

63 C=CAr with concomitant generation of [Cu(I)](solvent) and {[Cu(I)]-C=CAr}(-), respectively.

64 ion time, water as an environmentally benign solvent, and the synthesis of vitamin B(12) component on

65 drophilic beads upon the addition of organic solvent, and various solutions of volatile salts or acid

66 r the use of softer nucleophiles, less polar solvents, and larger halogens on the electrophile.

67 sing, e.g. via reactive gas plasmas, organic solvents, and photolithography.

68 oparticles, often acting as reducing agents, solvents, and stabilizers.

69 ueous (H(2)O) rather than deuterated (D(2)O) solvents, and we now report a method that uses the magni

70 Coordinating solvents are commonly employed as ancillary ligands to s

71 long as no ancillary ligands or coordinating solvents are present.

72 ane/water and sulfolane/DMSO-d(6) binary NMR solvents are reported for the individualization of mixtu

73 ds smoothly in a "weakly coordinating" arene solvent as long as no ancillary ligands or coordinating

74 r connection with other nanocrystals needs a solvent as medium.

75 he chemical synthesis of peptides in organic solvent as well as the enzymatic synthesis of glycan epi

76 actions between these macromolecules and the solvent, as well as the volume changes associated with t

77 e of large volumes of hazardous reagents and solvents, as well as energy-intensive processes in synth

78 n, led to a large improvement with the three solvents assayed (acetone, hexane, ethanol).

79 f feijoa (Acca sellowiana), were isolated by Solvent-Assisted Flavour Evaporation (SAFE).

80 The fast drying of solvent at liquid surface leaves 3D-like perovskites whi

81 es (1.0 equiv), using dichloromethane as the solvent, at room temperature, 4-methylene-3-(organoselan

82 ins, nucleic acids, water, ligands and other solvent atoms, using models fitted to or derived from cr

83 is 1-2 orders of magnitude greater than for solvent-based batch methods.

84 The electrochemical degradation of two solvent-based electrolytes for Mg-metal batteries is inv

85 or hues were produced by micronization using solvent-based emulsification (CIE-h degrees = 33-37 degr

86 /PDMS stretchable composites prepared via co-solvent blending with tetrahydrofuran (THF) to disperse

87 ple noncovalent interactions like H-bonding, solvent bonding, S-H...pai, C-H...pai, pai-pai stacking,

88 rmamide (DMF) is an extensively used organic solvent but is also a potent pollutant.

89 rpins much of their ability to act as useful solvents, but its description is complicated by the long

90 to a total of ~130 mg/mL curcuminoids in the solvent by repeatedly extracting fresh rhizomes in the s

91 ine pruning OH extracts obtained using green solvents by an eco-friendly procedure were revealed as a

92 reatment, TPC yields were enhanced with both solvents by approximately 3 times compared to the negati

93 irectly from acetonitrile, a cheap commodity solvent, by combining/telescoping two consecutive reacti

94 that immediately coordinates an amine in the solvent cage, leading to B-pyridinium or B-ammonium bora

95 Implicit solvent calculations with molecule-shaped cavities show

96 because the electrochemical properties of a solvent can be heavily influenced by its solvation statu

97 six different polar-aprotic and polar-protic solvent combinations to disrupt the H-bonds and hydropho

98 Transfer to organic solvents commonly used in polymer and peptide synthesis

99 eatment and provide a mechanism by which the solvent components drive efficient biomass breakdown.

100 Systematic variations in solvent composition and temperatures in ASE revealed qua

101 Yeast tolerates a low pH and high solvent concentrations.

102 Examined in good solvent conditions, kinetoplasts appear as a wrinkled he

103 efins on a multigram scale in the absence of solvent-conditions that are attractive as environmentall

104 To this end, we have applied explicit solvent constant pH molecular dynamics using the multisi

105 ions (measured average: 38 or 312 ng/L) or a solvent control for 15 months using a mesocosm system.

106 ion reactions include molecular oxygen under solvent control or using different dioxiranes, as well a

107 M06-2X/6-31+G(d,p) level of theory with SMD solvent corrections is used to show that these thermal a

108 Finally, our work shows that explicit solvent CpHMD(MSlambdaD) provides a realistic pH-depende

109 re compatible with applications sensitive to solvent damage.

110 The effect of the solvent (Deltadelta in CDCl(3) > CD(2)Cl(2)) is analyzed

111 cyanine((+)).Br((-)) salts show a remarkable solvent dependence in non/polar solvents, exhibiting nar

112 tuted model system to explain the pronounced solvent dependency of the carbenoid stability.

113 CD analysis showed a solvent-dependent degree of helical content in the struc

114 isochroman-1-one skeletons are afforded in a solvent-dependent manner whereas difluoromethylene-subst

115 c reaction, a carbocation rearrangement, and solvent-dependent Pummerer-like reactions, demonstrating

116 matrix and ionic liquids (ILs)/deep eutectic solvent (DES) as the transport facilitator.

117 Deep eutectic solvents (DESs) have been considered "the organic reacti

118 Solvent-driven localization breaks the symmetry and trap

119 is achieved by a rapid evaporation of mixed solvents during the electrode fabrication process.

120 nnected pores, conferring different gel (and solvent) dynamics.

121 000 mug/L) with co-occurrence of chlorinated solvents (e.g., 0.5 to 8 mg/L), underscoring the need of

122 ered as a benign oxidant and EtOH as a green solvent, ease of product separation, readily available a

123 rocesses, as predictive understanding of the solvent effect remains lacking.

124 Although solvent effects in supramolecular chemistry have been re

125 ence in surface-hopping methods, the role of solvent effects, trivial unavoided crossings, analysis o

126 ochemical cell microscopy (SECCM) in aprotic solvent electrolyte media to address contemporary struct

127 lting in a small increase in entropy, as the solvent entropy gain from the water release is nearly ca

128 and explicit solvation: the influence of the solvent environment on these EIEs is essentially capture

129 Betanin is the least stable dye in both solvent environments and Red 40 exhibits the greatest de

130 synthesized by the polyol method, where the solvent (ethylene glycol) is considered the reducing age

131 cies formed by clustering inside droplets as solvent evaporation occurs.

132 olid-state nanostructured colored films upon solvent evaporation, even in the presence of templating

133 b-PCC-g-DC) polymeric nanoparticles (NPs) by solvent evaporation, resulting in a mean particle size o

134 a remarkable solvent dependence in non/polar solvents, exhibiting narrow, sharp band shapes in dichlo

135 lation of cryptic cysteine residues that are solvent exposed only upon changes in protein conformatio

136 Helix 12 is displaced from the solvent-exposed active conformation and occupies the ort

137 In this solvent-exposed conformation, AdoCbl undergoes facile tr

138 ny open questions regarding the hydration of solvent-exposed non-polar tracts and pockets in proteins

139 The CDK-bound form of CR8 has a solvent-exposed pyridyl moiety that induces the formatio

140 pins, a protease cleaves a peptide bond in a solvent-exposed reactive center loop (RCL) of the serpin

141 xal-5'-phosphate (PLP), apparently without a solvent-exposed Schiff base.

142 These solvent-exposed sites featured an axial ZFS of 0.21 cm(-

143 Finally, a solvent-exposed vector was defined from the pyridazinone

144 ironment while the edges are hydrophilic and solvent-exposed.

145 f amino acid side chains as well as by local solvent exposure.

146 Accelerated solvent extraction (ASE) was utilized for the first time

147 and extracts were obtained with accelerated solvent extraction (ASE).

148 y, the scalability of the supported membrane solvent extraction (MSX) process for the recovery of rar

149 Ultrasound assisted solvent extraction followed by high performance liquid c

150 ecovery of essential oil (EO), while organic solvent extraction using Soxhlet apparatus, microwave-as

151 A green ASE (accelerated solvent extraction) with a shorter UHPLC (ultra-high per

152 lds in the extracts compared to conventional solvent extraction.

153 ss using supercritical CO(2) and traditional solvent extraction.

154 e technique combines steam distillation with solvent extraction.

155 op a novel and simple method without organic solvent extractions for the detection of bovine and non-

156 s, ancillary ligands, and bases in different solvents followed by two deconvolution procedures, which

157 developed based on hydrophobic deep eutectic solvent for extraction of folic acid from flour samples

158 er does not necessitate that water is a poor solvent for its unfolded state.

159 Water acts as the solvent for natural biotic and abiotic processes and in

160 pectroscopy experiments that rely on viscous solvents for mixture analysis.

161 he aim of this work was to compare different solvents for PP extraction and to evaluate the effect of

162 new possibilities through the use of aprotic solvents for rational analysis/design in electrosynthesi

163 rozen sperm in 1:2 (v/v) chloroform-methanol solvent, fractionated into neutral and polar fractions,

164 EO has ultra-high catalytic activity for the solvent-free aerobic oxidation of benzyl alcohol.

165 -oxohex-5-enoates and can be performed under solvent-free conditions in many instances.

166 eir structures are normally determined under solvent-free conditions, the structures of solvated 2D C

167 The catalyst can be used under solvent-free conditions.

168 A new metal-, oxidant-, and solvent-free ecofriendly domino method has been establis

169 A continuous, scalable, and solvent-free method for the synthesis of various naphtha

170 tration synthesis (SIS) of alumina, a simple solvent-free process, stabilizes polyethersulfone (PES)

171 velop a facile, general, and high throughput solvent-free self-assembly strategy to synthesize a seri

172 nite dilution in the solvent to a completely solvent-free state, even at ambient conditions.

173 s, which is further impacted by changing the solvent from toluene to tetrahydrofuran to acetonitrile.

174 xtensive literature on GO systems in organic solvents-furnish quantitative explanations for the empir

175 etic control in the presence of six aromatic solvents has been successfully applied in the synthesis

176 ndustrial implementation of new eco-friendly solvents has highlighted the need to analyse both the st

177 ns and efficiencies using a single acidified solvent have been assessed.

178 The use of organic solvents improves digestion, generating more peptides fr

179 A DBS is eluted with 500 muL of elution solvent in a sample vial, and the eluate is directly sub

180 teraction of the thiocarbonyl group with the solvent in the host cavity, respectively.

181 To implement these solvents in industrial processes, the knowledge of their

182 ssifying a short selection of these emerging solvents, in particular halogenated ones, but also at pr

183 mbles when adding different ratios of protic solvents including an aqueous buffer.

184 mechanistic understanding of how nonaqueous solvents influence catalysis in microporous voids remain

185 ed interest in fundamental aspects of solute-solvent interactions has been sparked in the field of su

186 r polymers offer to gain insight into solute-solvent interactions have become clear relatively recent

187 When mixed with solvents, ionic liquids provide the unique opportunity t

188 One of the limitations of deep eutectic solvents is their toxicity to the environment but they a

189 y between an alkali metal cation and a polar solvent leads to high-quality 2D perovskite films with s

190 bonyl)-1H-pyrroles for a short time in inert solvents leads to the high-yield formation of benzo- and

191 It is shown that the solvent level abruptly increases with the particle cover

192 r ratio within lower polarity water-miscible solvents like dimethylsulfoxide, controls the homopolyme

193 ne-bisdithiocarbamate) with a supramolecular solvent liquid phase microextraction method.

194 H) has N(2) O reductase activity in methanol solvent, mediating 2 H(+) /2 e(-) reduction of N(2) O to

195 ptor complex, increasing the polarity of the solvent medium facilitates rare, thermally allowed full

196 of naturally abundant, renewable feedstocks, solvents, metal catalysts, energy, and redox reagents.

197 ntage of the "differentiating effect" of the solvent methanol, deuterations of electron-rich aromatic

198 ed using a single emulsion and mixed organic solvent method.

199 esults indicated that unconventional diluted solvent mixes containing acetone, butanol, and ethanol w

200 However, the potential of solvent mixes that can be generated by fermentation of b

201 Using a solvent-mixing strategy, we kinetically organized a mole

202 r carboxylates, even in a highly competitive solvent mixture (DMSO-d(6) + H(2)O 95:5 v/v).

203 Moreover, solvent mixture studies indicate a significant influence

204 describe the ability of a binary thiol-amine solvent mixture to dissolve the bulk bournonite mineral

205 n pairs by the use of water-miscible organic solvent mixtures, and its application in the direct ultr

206 ing any available combination of DFT theory, solvent model, and NMR-active nuclei, using both user-se

207 While implicit solvent models were inadequate, QM/QM' trajectories in e

208 included using the PCM and/or SMD continuum solvent models.

209 ic kirromycin, we employed all-atom explicit-solvent molecular dynamics simulations of the full ribos

210 mall-molecule coordination, visualization of solvent molecules and alternative conformations for mult

211 m-metal anode, the solvation behavior of the solvent molecules must be understood because the electro

212 As a result, the solvent molecules reorganize around the protein's small

213 hifting to the interactions between COFs and solvent molecules, which may weaken the attraction stren

214 rolyte interface due to the self-assembly of solvent molecules.

215 In particular, depending on the solvent nature-aromatic or aliphatic-cone-shaped C(3)-sy

216 The ordered H-bonding solvent network present in hydrophobic Sn-Beta stabilize

217 and avoids the need for a pK(a) scale in the solvent of interest.

218 illaries that direct and aspirate extraction solvents onto a ~350 mum diameter sample spot was develo

219 equire the use of the alcohol component as a solvent or co-solvent.

220 al chemical stability in organic and aqueous solvents over a wide pH range (pH 1-14), including in th

221 Regardless of whether solvent overlay was used, most strains with bioderivatiz

222 5]-spiroketalization dramatically depends on solvents; p-toluenesulfonic acid (PTSA) in 1:1 methanol-

223 mation on protein-cosolute interactions from solvent paramagnetic relaxation enhancement (sPRE) measu

224 ive-like avidin tetramers with deeply buried solvent particles; (2) applying high activation voltages

225 of maneb was extracted in the supramolecular solvent phase as 1-(2-pyridylazo)-2-naphthol complex at

226 netic gadolinium(III) chelate in a non-polar solvent, placed between two like-poles-facing NdFeB magn

227 ogy can be tuned by external stimuli such as solvent polarity, concentration, and base treatment.

228 From target analysis, the effect of solvent polarity, number of linked CT entities, and exci

229 to the external nucleophile and to continuum solvent polarity.

230 are firstly summarized, including serving as solvents, porogens, functional monomers, organic surface

231 reater extent than the liquid-like 2-butanol solvent present in hydrophilic Sn-Beta, giving rise to h

232 rs a pathway for efficient H doping in green solvent-processed metal oxide films and the promise of h

233 The thermal degradation of the e-liquid solvents propylene glycol and glycerol often generates m

234 inadequate, QM/QM' trajectories in explicit solvent provide an accurate prediction of the experiment

235 polyelectrolyte backbone flexibility and the solvent quality.

236 mized - pH 4 and 12, respectively; and flour-solvent ratio of 1:20 w/v.

237 For the original Fmoc removal cocktail (solvents ratio of 1:1), we evaluated the impact of quali

238 The optimum extraction conditions were of solvent/raw material ratio of 11.4 mL/g, extraction time

239 enched because exposure of this interface to solvent reduces protein stability and causes aggregation

240 , we experimentally demonstrate simultaneous solvent regeneration and CO(2) desorption in a continuou

241 While solvent removal causes decomposition of the MOF, magneto

242 Subsequent solvent removal makes these extraction procedures very t

243 partially compensated by an increase in the solvent reorganization entropy.

244 The data indicate that the solvent reorganization is indeed near zero and increases

245 While relatively low polarity solvents result in partial charge transfer in the host d

246 Solvent scattering is a valuable internal reference for

247 Solvent selection is a pressing challenge in developing

248 zed by single-crystal X-ray diffraction as a solvent-separated ion triplet with two potassium counter

249 sed simulations, calibrated against explicit solvent simulations, were employed for sampling multiple

250 The gelling solvent situated in the "molecular pocket" stitches the

251 The "solvent slaving" model predicts that protein motion is s

252 In nonpolar solvents, slow and reversible isomerization correspondin

253 ding access to more functionalized and polar-solvent-soluble structures as well as increased control

254 tructure morphology can be tuned by means of solvent solution and by strand substitution with DNA and

255 Curcuma longa is commonly done with aqueous solvent solutions.

256 Beta is driven by the breakup of intraporous solvent-solvent interactions, resulting in positive enth

257 scussing the fundamental differences between solvent spiking, water-accommodated fractions, and passi

258 y when the incipient ion pair is neither too solvent-stabilized nor too little.

259 These different intraporous 2-butanol solvent structures manifest as differences in the activa

260 ated the effect of the reaction temperature, solvent, substituent, and type of reducing agent using a

261 assembly parameters including type of mixing solvent, substrate temperature, particle concentration,

262 n order to identify how strongly associating solvent-substrate interactions change DMABN's photoisome

263 ep is time consuming and often employs toxic solvents such as chloroform.

264 e reduced cobalt(0) precatalysts, and protic solvents such as methanol and isopropanol were identifie

265 The use of short columns and direct solvent switches allowed for fast screening (3 min per p

266 od rhodopsin upon light absorption to form a solvent-swollen active state.

267 Novozym 435 and a binary solvent system of toluene/chloroform 9:1 (v/v) were foun

268 organic) or biphasic (organic/aqueous) model solvent systems.

269 Numerous reaction parameters such as solvent, temperature, or protonating agent were examined

270 fetime of the S(1) state of zeta-carotene in solvent, the lifetime decreases ~250-fold when zeta-caro

271 n dissociation from infinite dilution in the solvent to a completely solvent-free state, even at ambi

272 -stabilizing ligand and a high boiling point solvent to yield MoC(1-x) NPs that are colloidally stabl

273 lin/O(2) reactions was discovered using neat solvents to model the amino acids of a cofactor-independ

274 membrane filtration processes and no organic solvents to yield on average 23 mL of 10(11) plaque-form

275 llerenes, facilitating novel intermolecular, solvent tunable ground state electronic communication wi

276 Some experimental variables such as pH, DES solvent type and volume, aprotic solvent type and volume

277 pH, extraction time, stirring rate, elution solvent type and volume, sample volume, desorption time,

278 as pH, DES solvent type and volume, aprotic solvent type and volume, vortex time, sample volume and

279 r solutions (type, viscosity, conductivity), solvent type, process parameters (applied voltage betwee

280 ensity/lifetime appear quite stable in polar solvents up to ten weeks.

281 We investigated the impact of solvents used and the extraction time on the extracted i

282 y when it is both compatible with nonaqueous solvents utilized in organic synthesis and capable of ge

283 By solvent vapor annealing, a recrystallization and reorien

284 led to various aspects of water such as bulk solvent viscosity and local hydration shell dynamics.

285 usion when molecular tumbling is slow due to solvent viscosity, thus strongly favoring magnetization

286 Extraction parameters (e.g. time, solvent volume) were optimized using response surface me

287 The behavior of imprinted polymers in fluid solvents was also investigated by employing the AFM for

288 by the interaction of protein molecules and solvent water under the range of conditions normally enc

289 study 39 different hydrophobic deep eutectic solvents were evaluated for green extraction of ergoster

290 equilibrium constants measured across eleven solvents were found to be better predictors of reaction

291 Chlorinated solvents were once, and in many places are still, ubiqui

292 synergistic effects between the salt and the solvent when they coexist on electrode surfaces.

293 carboranyl NHC complex 3 is unstable in most solvents when paired with CPh(3)(+), novel synthesis met

294 e co-permeate the membrane into the acceptor solvent, whereas particulates and charged matrix compone

295 ns (high N(2)O concentrations, and flammable solvents), which can lead to detonation and suffered fro

296 s a key feature of acid catalysis in zeolite solvents, which lack the isotropy of liquid solvents.

297 times at room temperature in a wide range of solvents while also showing high water tolerability.

298 s run by LC-MS in both liquid chromatography solvent with (14)NH(3)-acetate buffer and in solvent wit

299 solvent with (14)NH(3)-acetate buffer and in solvent with the buffer modified with (15)NH(3)-formate.

300 eous PEO is a semiflexible polymer in a good solvent, with the latter scaling linearly with molecular